摘要
Irregular-shaped or tabular grains of native gold (<20 μm) mainly associated with anhydrite and sphalerite have been identified in sulfate ore samples and Fe-rich massive sulfides by SEM/EDS observation and XPS analysis. To a lesser extent, gold occurs as submicroscopic particles deposited on the surface of coarse-grained pyrite. EPMA results indicate that high gold contents (with an average of 6 700×10-6 Au) are associated with late-stage, low-temperature (Fe-poor) sphalerite, and silver is significantly enriched in sulfosalt minerals (5.0%~6.7% Ag) occurring at the margins of exsolved chalcopyrite grains within sphalerite. In conclusion, the mineralization of precious metals in polymetallic massive sulfides is closely related to late-stage, low to moderate temperature hydrothermal ore-forming processes at the seafloor.