多功能纳米分子材料的制备及其性能
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摘要
利用八环氧基笼型倍半硅氧烷(E-POSS)与不同种类的胺类化合物反应,控制反应温度和时间,以AlCl_3为催化剂一步法制备了分别含有不同数量羟基、环氧基系列多功能纳米固体材料。其结构和性能经过固体核磁、红外光谱、热重分析等表征。结果表明,其初始分解温度最高为271.4℃。
A series of multifunctional nano solid materials including hydroxyl and epoxy groups were prepared by one-step method using AlCl_3 as catalyst through the reaction of epoxide-based silsesquioxane(E-POSS) with different kinds of amines. Its structure and properties are characterized by solid nuclear magnetic, elemental analysis, infrared spectroscopy and thermogravimetric analysis. The results show that the initial decomposition temperature is 271.4 ℃
A series of multifunctional nano solid materials including hydroxyl and epoxy groups were prepared by one-step method using AlCl_3 as catalyst through the reaction of epoxide-based silsesquioxane(E-POSS) with different kinds of amines. Its structure and properties are characterized by solid nuclear magnetic, elemental analysis, infrared spectroscopy and thermogravimetric analysis. The results show that the initial decomposition temperature is 271.4 ℃
引文
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[6] Li Yujin, Wang Jiusi, Tian Ling. Nano-material’s fundamental specific property development and the general situation of its application [J].Journal of Gansu Education College (Natural Sciences),2003,17(3):54-56(in Chinese). 李玉金, 王九思,田玲.纳米材料的基本特性及发展和应用概况[J].兰州文理学院学报(自然科学版),2003,17(3):54-56.
[7] Toshiaki N, Natsuki J.Prediction ofmechanical properties forhexagonal boron nitridenanosheets using molecular mechanics model [J].Applied Physics A, Materials Science Processing,2017,123(3):283-288.
[8] Ivancic W, Christopher L W.Combined effect of oxidative treatment and residual alcohol on themechanics of a multiwalled carbon nanotube laden interface [J].Colloids and Surfaces A,2018,551(4):42-49.
[9] Xu C,Zhang Y X,Xu P,et al.Graphene oxide/MnWO4 nanocomposite for magnetic resonance/photoacoustic dual-modelimaging and tumor photothermo-chemotherapy [J].Carbon,2018,138(7):397-409.
[10] Wu J J, Li S,Wei H. Multifunctional nanozymes:enzyme-like catalyticactivity combined with magnetism and surfaceplasmon resonance [J]. Nanoscale Horizons.2018, 3(3):367-382.
[11] Guo S H, Li X H, Ren X G,et al.Optical and electrical enhancement of hydrogen evolution by MoS2@MoO3 core-shell nanowires with designed tunable plasmon resonance [J].Advanced Functional Materials,2018, 28(10): 1802567-1802580.
[12] Yoo D Y, You I, Youn H,et al.Electrical and piezoresistive propertiesof cement composites withcarbon nanomaterials [J].Journal of Composite Materials, 2018,52(24):3325-3340.
[13] Marcin R, Przemys?aw W V. Optical pressure nano-sensor based on lanthanide doped SrB2O4 Sm2+ iuminescence-novel high-pressure nanomanometer [J].Sensors & Actuators: B Chemical,2018,273(6):585-591.
[14] Micheál D S, Evgeny S T, Jane S, et al.Gold nanofilms at liquid-liquid interfaces: an emerging platformfor redox electrocatalysis, nanoplasmonic sensors, and electrovariable optics [J].Chemical Reviews,2018,118(9):3722-3751.
[15] Ba L, John L, John C, et al.Rh(CAAC)-catalyzed arene hydrogenation: evidence for nanocatalysis and sterically controlled site-selective hydrogenation [J].ACS Catalysis,2018,8(7):8441-8449.
[16] Li W, Allioux F M, Muthupandian A. Ultrasound-assisted fabrication of metal nano-porous shells across polymer beads and their catalytic activity for reduction of 4-nitrophenol [J].Ultrasonics-Sonochemistry,2018, 4(7):63-68.