催化材料在环境保护中的应用进展
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摘要
当今环境问题制约各国经济发展,如何低成本高效益地治理环境污染成为共同关注问题。催化材料处理是高效率的污染处理技术,引起全球关注。综述光催化纳米材料、稀土催化材料和异质结光催化材料等在工业废水、废渣、含硫含氮废气、生活垃圾及自来水净化等方面的应用。
Nowadays,environmental problems have been becoming issues restricting economic development in all countries. How to treat environment pollution with lower cost and higher efficiency has been becoming a common concern problem. Catalytic materials processing,which is one of efficient pollution treatment technologies,raises lots of concerns. This paper discusses the roles of heterojunction photo catalytic nanomaterials,rare earth catalytic material and nano-photocatalytic materials in dealing with industrial waste water,waste residue,sulfur nitrogen containing waste gases,living garbage,and water purification.
Nowadays,environmental problems have been becoming issues restricting economic development in all countries. How to treat environment pollution with lower cost and higher efficiency has been becoming a common concern problem. Catalytic materials processing,which is one of efficient pollution treatment technologies,raises lots of concerns. This paper discusses the roles of heterojunction photo catalytic nanomaterials,rare earth catalytic material and nano-photocatalytic materials in dealing with industrial waste water,waste residue,sulfur nitrogen containing waste gases,living garbage,and water purification.
引文
[1]杨宽辉,王保伟,许根慧.介质阻挡放电等离子体特性及其在化工中的应用[J].化工学报,2007,58(7):1609-1618.Yang Kuanhui,Wang Baowei,Xu Genhu.Dielectric-barrier discharge plasma characteristics and its application in chemical engineering[J].Journal of Chemical Industry and Engineering(China),2007,58(7):1609-1618.
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[3]杜长海,徐平,贺岩峰.多孔铝阳极氧化膜在催化中的研究进展[J].现代化工,2006,26(S1):119-121.Du Changhai,Xu Ping,He Yanfeng.Research progress in porous aluminum anodic oxide film in catalysis[J].Modern Chemical Industry,2006,26(S1):119-121.
[4]温勇,徐玲玲,沈艳华.柱撑粘土在水污染治理中的应用[J].污染防治技术,2003,(S1):84-86.Wen Yong,Xu Lingling,Shen Yanhua.Appliciaton of pillaerd interlayer clay to wasetwater treatment[J].Pollution Control Technology,2003,(S1):84-86.
[5]李建芬.纳米Ti O2的特性及其在环保方面的应用[J].环境技术,2005,24(6):22-25.Li Jianfen.The properties and application of nanometer Ti O2particles in environmental protection[J].Environmental Technology,2005,24(6):22-25.
[6]张文通,陈勇,陈超,等.纳米Ti O2光催化材料在环境土壤修复中的应用研究进展[J].材料导报,2015,29(11):49-54.Zhang Wentong,Chen Yong,Chen Chao,et al.Utilizing nanoTi O2as photocatalytic materials for environmental soil remediation[J].Materials Review,2015,29(11):49-54.
[7]强璐,石艳玲,徐俊,等.纳米材料在水处理中的应用研究进展[J].环境科学与技术,2014,37(2):252-256.Qiang Lu,Shi Yanling,Xu Jun,et al.Research and application progress of nanomaterials in water treatment[J].Environmental Science&Technology,2014,37(2):252-256.
[8]梁敏.纳米材料的特性及其在水处理工业中的应用[J].化工时刊,2015,29(7):37-39.Liang Min.Properties and applications in water treatment industry of nanometer materials[J].Chemical Industry Times,2015,29(7):37-39.
[9]李俊妮.纳米Ti O2光催化在废水处理中的应用[J].化工中间体,2012,9(2):48-53.Li Junni.Applications of photocatalysis in wastewater treatment by using namometer Ti O2[J].Chemical Intermediate,2012,9(2):48-53.
[10]罗菊仙,赵中一.半导体多相光催化氧化技术在环境保护中的应用研究进展[J].地球科学-中国地质大学学报,2000,25(5):536-541.Luo Juxian,Zhao Zhongyi.Application of semiconductor heterogeneous photocatalysis oxidation technology to environmental protection[J].Earth Science-Journal of ChinaUniversity of Geosciences,2000,25(5):536-541.
[11]于兵川,吴洪特,张万忠.光催化纳米材料在环境保护中的应用[J].石油化工,2005,34(5):491-495.Yu Bingchuan,Wu Hongte,Zhang Wanzhong.Application of nano-photocatalysts in environmental protection[J].Petrochemical Technology,2005,34(5):491-495.
[12]李川,古国榜,柳松.Ti O2光催化处理废水中贵重金属的研究进展[J].环境污染治理技术与设备,2003,4(11):6-11.Li Chuan,Gu Guobang,Liu Song.Progress in treatment of heavy metals and precious metals in wastewater by Ti O2photocatalysis[J].Techniques and Equipment for Environmental Pollution Control,2003,4(11):6-11
[13]李田,陈正夫.城市自来水光催化氧化深度净化效果[J].环境科学学报,1998,18(2):167-171.Li Tian,Chen Zhengfu.Performance of the immobile membrane photocatalytic reactor for main water purification[J].Acta Scientiae Circumstantiae,1998,18(2):167-171.
[14]胡将军,李英柳,彭卫华.吸-附光催化氧化净化甲醛废气的试验研究[J].化学与生物工程,2004,21(1):39-41.Hu Jiangju,Li Yingliu,Peng Weihua.The experimental study of adsorption-photocatalytic oxidation of formaldehyde with ACF and Ti O2[J].Chemistry&Bioengineering,2004,21(1):39-41.
[15]洪伟,古国榜,吴志伟,等.光催化氧化法治理恶臭污染的工程应用[J].环境工程,2002,20(6):40-42.Hong Wei,Gu Guobang,Wu Zhiwei,et al.Engineering application of treating odor pollution by photocatalytic oxidation process[J].Environmental Engineering,2002,20(6):40-42.
[16]卓成林,伍明华.纳米材料在环境保护方面的最新应用进展[J].化工时刊,2004,18(3):5-7.Zuo Chenglin,Wu Minghua.The latest application of nanomaterial in environmental protection[J].Chemical Industry Times,2004,18(3):5-7.
[17]刘欣伟,陈勇,陈超,等.Ti O2光催化材料在饮用水深度处理中的应用研究进展[J].材料开发与应用,2015,30(3):101-109.Liu Xinwei,Chen Yong,Chen Chao,et al.Progress in applied research of Ti O2photocatalytic materials in advanced treatment of drinking water[J].Development and Application of Materials,2015,30(3):101-109.
[18]张雪黎,罗来涛.稀土催化材料在工业废气、人居环境净化中的研究与应用综述[J].气象与减灾研究,2006,29(4):47-52.Zhang Xueli,Luo Laitao.Research and application of the rare earths catalytic materials in purification of industrial exhaust gas and living surroundings[J].Meteorology and Disaster Reduction Research,2006,29(4):47-52.
[19]翁端,冉锐,吴晓东.稀土催化材料的应用进展[J].稀土信息,2004,2:6-8.
[20]赵岳,张晓玲,胡辉.稀土催化剂在环境保护中的应用进展[J].工业催化,2008,16(3):13-17.Zhao Yue,Zhang Xiaoling,Hu Hui.Application of rareearth catalysts in environmental protection[J].Industrial Catalysis,2008,16(3):13-17.
[21]胡辉,李劲,张顺喜,等.Ce O2-La2O3/C-Al2O3稀土氧化物混合物催化还原SO2的实验研究[J].环境科学,2004,25(2):17-21.Hu Hui,Li Jin,Zhang Shunxi,et al.Experimental study of catalytic reduction of SO2on Ce O2-La2O3/γ-Al2O3rare earth mixed compounds[J].Chinese Journal of Environmental Science,2004,25(2):17-21.
[22]胡辉,李胜利,张顺喜,等.Ce O2-La2O3/γ-Al2O3催化还原SO2反应机理的研究[J].催化学报,2004,25(2):115-119.Hu Hui,Li Shengli,Zhang Shunxi,et al.Studies on reaction mechanism of SO2reduction catalyzed by Ce O2-La2O3/γ-Al2O3[J].Chinese Journal of Catalysis,2004,25(2):115-119.
[23]杨利均,周丹,罗仙平.焦化废水及其处理技术现状研究[J].四川有色金属,2011,(4):55-58.Yang Lijun,Zhou Dan,Luo Xianping.Study on the current situation of coking wastewater and its treatment technology[J].Sichuan Nonferrous Metals,2011,(4):55-58.
[24]王莹,侯党社,蒋绪,等.改性高岭土催化材料的制备表征及应用[J].合成材料老化与应用,2017,46(4):64-67.Wang Ying,Hou Dangshe,Jiang Xu,et al.Preparation,characterization of modified catalyst and its application[J].Synthetic Materials Aging and Application,2017,46(4):64-67.
[25]邹东雷,杨忠平,宋宝华,等.非均相催化氧化处理焦化废水[J].化工环保,2005,25(5):372-375.Zou Donglei,Yang Zhongping,Song Baohua,et al.Treatment of coking wastewater by heterogeneous catalytic oxidation process[J].Environmental Protection of Chemical Industry,2005,25(5):372-375.
[26]白爱英,梁伟.叠层型Cu沉积Ti O2复合薄膜的制备及光学性能[J].稀有金属,2011,35(4):510-514.Bai Aiying,Liang Wei.Preparation and visible light photocatalytic activity of Cu-Doped Ti O2film with laminated type[J].Chinese Journal of Rare Metals,2011,35(4):510-514.
[27]于洪涛,全燮.纳米异质结光催化材料在环境污染控制领域的研究进展[J].化学进展,2009,21(23):406-414.Yu Hongtao,Quan Xie.Nano-heterojunction photocatalytic materials in environmental pollution controlling[J].Progress in Chemistry,2009,21(23):406-414.
[2]胡安正,唐超群.纳米Ti O2光催化材料及其应用于环境保护的研究进展[J].功能材料,2001,32(6):586-589.Hu Anzheng,Tang Chaoqun.Progress in research of the nanosized Ti O2photocatalyticmaterials and their application in environment protection[J].Journal of Functional Materials,2001,32(6):586-589.
[3]杜长海,徐平,贺岩峰.多孔铝阳极氧化膜在催化中的研究进展[J].现代化工,2006,26(S1):119-121.Du Changhai,Xu Ping,He Yanfeng.Research progress in porous aluminum anodic oxide film in catalysis[J].Modern Chemical Industry,2006,26(S1):119-121.
[4]温勇,徐玲玲,沈艳华.柱撑粘土在水污染治理中的应用[J].污染防治技术,2003,(S1):84-86.Wen Yong,Xu Lingling,Shen Yanhua.Appliciaton of pillaerd interlayer clay to wasetwater treatment[J].Pollution Control Technology,2003,(S1):84-86.
[5]李建芬.纳米Ti O2的特性及其在环保方面的应用[J].环境技术,2005,24(6):22-25.Li Jianfen.The properties and application of nanometer Ti O2particles in environmental protection[J].Environmental Technology,2005,24(6):22-25.
[6]张文通,陈勇,陈超,等.纳米Ti O2光催化材料在环境土壤修复中的应用研究进展[J].材料导报,2015,29(11):49-54.Zhang Wentong,Chen Yong,Chen Chao,et al.Utilizing nanoTi O2as photocatalytic materials for environmental soil remediation[J].Materials Review,2015,29(11):49-54.
[7]强璐,石艳玲,徐俊,等.纳米材料在水处理中的应用研究进展[J].环境科学与技术,2014,37(2):252-256.Qiang Lu,Shi Yanling,Xu Jun,et al.Research and application progress of nanomaterials in water treatment[J].Environmental Science&Technology,2014,37(2):252-256.
[8]梁敏.纳米材料的特性及其在水处理工业中的应用[J].化工时刊,2015,29(7):37-39.Liang Min.Properties and applications in water treatment industry of nanometer materials[J].Chemical Industry Times,2015,29(7):37-39.
[9]李俊妮.纳米Ti O2光催化在废水处理中的应用[J].化工中间体,2012,9(2):48-53.Li Junni.Applications of photocatalysis in wastewater treatment by using namometer Ti O2[J].Chemical Intermediate,2012,9(2):48-53.
[10]罗菊仙,赵中一.半导体多相光催化氧化技术在环境保护中的应用研究进展[J].地球科学-中国地质大学学报,2000,25(5):536-541.Luo Juxian,Zhao Zhongyi.Application of semiconductor heterogeneous photocatalysis oxidation technology to environmental protection[J].Earth Science-Journal of ChinaUniversity of Geosciences,2000,25(5):536-541.
[11]于兵川,吴洪特,张万忠.光催化纳米材料在环境保护中的应用[J].石油化工,2005,34(5):491-495.Yu Bingchuan,Wu Hongte,Zhang Wanzhong.Application of nano-photocatalysts in environmental protection[J].Petrochemical Technology,2005,34(5):491-495.
[12]李川,古国榜,柳松.Ti O2光催化处理废水中贵重金属的研究进展[J].环境污染治理技术与设备,2003,4(11):6-11.Li Chuan,Gu Guobang,Liu Song.Progress in treatment of heavy metals and precious metals in wastewater by Ti O2photocatalysis[J].Techniques and Equipment for Environmental Pollution Control,2003,4(11):6-11
[13]李田,陈正夫.城市自来水光催化氧化深度净化效果[J].环境科学学报,1998,18(2):167-171.Li Tian,Chen Zhengfu.Performance of the immobile membrane photocatalytic reactor for main water purification[J].Acta Scientiae Circumstantiae,1998,18(2):167-171.
[14]胡将军,李英柳,彭卫华.吸-附光催化氧化净化甲醛废气的试验研究[J].化学与生物工程,2004,21(1):39-41.Hu Jiangju,Li Yingliu,Peng Weihua.The experimental study of adsorption-photocatalytic oxidation of formaldehyde with ACF and Ti O2[J].Chemistry&Bioengineering,2004,21(1):39-41.
[15]洪伟,古国榜,吴志伟,等.光催化氧化法治理恶臭污染的工程应用[J].环境工程,2002,20(6):40-42.Hong Wei,Gu Guobang,Wu Zhiwei,et al.Engineering application of treating odor pollution by photocatalytic oxidation process[J].Environmental Engineering,2002,20(6):40-42.
[16]卓成林,伍明华.纳米材料在环境保护方面的最新应用进展[J].化工时刊,2004,18(3):5-7.Zuo Chenglin,Wu Minghua.The latest application of nanomaterial in environmental protection[J].Chemical Industry Times,2004,18(3):5-7.
[17]刘欣伟,陈勇,陈超,等.Ti O2光催化材料在饮用水深度处理中的应用研究进展[J].材料开发与应用,2015,30(3):101-109.Liu Xinwei,Chen Yong,Chen Chao,et al.Progress in applied research of Ti O2photocatalytic materials in advanced treatment of drinking water[J].Development and Application of Materials,2015,30(3):101-109.
[18]张雪黎,罗来涛.稀土催化材料在工业废气、人居环境净化中的研究与应用综述[J].气象与减灾研究,2006,29(4):47-52.Zhang Xueli,Luo Laitao.Research and application of the rare earths catalytic materials in purification of industrial exhaust gas and living surroundings[J].Meteorology and Disaster Reduction Research,2006,29(4):47-52.
[19]翁端,冉锐,吴晓东.稀土催化材料的应用进展[J].稀土信息,2004,2:6-8.
[20]赵岳,张晓玲,胡辉.稀土催化剂在环境保护中的应用进展[J].工业催化,2008,16(3):13-17.Zhao Yue,Zhang Xiaoling,Hu Hui.Application of rareearth catalysts in environmental protection[J].Industrial Catalysis,2008,16(3):13-17.
[21]胡辉,李劲,张顺喜,等.Ce O2-La2O3/C-Al2O3稀土氧化物混合物催化还原SO2的实验研究[J].环境科学,2004,25(2):17-21.Hu Hui,Li Jin,Zhang Shunxi,et al.Experimental study of catalytic reduction of SO2on Ce O2-La2O3/γ-Al2O3rare earth mixed compounds[J].Chinese Journal of Environmental Science,2004,25(2):17-21.
[22]胡辉,李胜利,张顺喜,等.Ce O2-La2O3/γ-Al2O3催化还原SO2反应机理的研究[J].催化学报,2004,25(2):115-119.Hu Hui,Li Shengli,Zhang Shunxi,et al.Studies on reaction mechanism of SO2reduction catalyzed by Ce O2-La2O3/γ-Al2O3[J].Chinese Journal of Catalysis,2004,25(2):115-119.
[23]杨利均,周丹,罗仙平.焦化废水及其处理技术现状研究[J].四川有色金属,2011,(4):55-58.Yang Lijun,Zhou Dan,Luo Xianping.Study on the current situation of coking wastewater and its treatment technology[J].Sichuan Nonferrous Metals,2011,(4):55-58.
[24]王莹,侯党社,蒋绪,等.改性高岭土催化材料的制备表征及应用[J].合成材料老化与应用,2017,46(4):64-67.Wang Ying,Hou Dangshe,Jiang Xu,et al.Preparation,characterization of modified catalyst and its application[J].Synthetic Materials Aging and Application,2017,46(4):64-67.
[25]邹东雷,杨忠平,宋宝华,等.非均相催化氧化处理焦化废水[J].化工环保,2005,25(5):372-375.Zou Donglei,Yang Zhongping,Song Baohua,et al.Treatment of coking wastewater by heterogeneous catalytic oxidation process[J].Environmental Protection of Chemical Industry,2005,25(5):372-375.
[26]白爱英,梁伟.叠层型Cu沉积Ti O2复合薄膜的制备及光学性能[J].稀有金属,2011,35(4):510-514.Bai Aiying,Liang Wei.Preparation and visible light photocatalytic activity of Cu-Doped Ti O2film with laminated type[J].Chinese Journal of Rare Metals,2011,35(4):510-514.
[27]于洪涛,全燮.纳米异质结光催化材料在环境污染控制领域的研究进展[J].化学进展,2009,21(23):406-414.Yu Hongtao,Quan Xie.Nano-heterojunction photocatalytic materials in environmental pollution controlling[J].Progress in Chemistry,2009,21(23):406-414.
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