金属有机骨架材料在放射性核素去除中的研究
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摘要
核能利用的过程中,从铀矿开采、核燃料加工、核能发电到乏燃料后处理,会产生大量放射性废物,部分放射性核素会不可避免的释放到环境中,对环境和人类健康造成重大危害。放射性核素的高效去除是核电健康发展的重要关键科学问题之一。近年来,高化学稳定性、具有大量功能基团而且结构可调的多孔金属有机骨架材料(MOFs)在放射性污染治理方面受到国内外同行的高度关注。本文系统地介绍了MOFs及MOFs复合材料在放射性核素吸附去除方面的研究进展,通过宏观吸附、模型分析、先进光谱表征和理论计算四个方面描述放射性核素与MOFs材料的界面作用机理,并对MOFs材料的吸附性能与其它材料进行对比,评价MOFs材料在放射性污染治理中的应用前景。
With the development of nuclear energy, the long-lived radionuclides are inevitably released into the natural environment during the mine process, fuel manufacture, nuclear power usable and spent fuel management, which are dangerous to human health and environmental pollution. Thereby the efficient elimination of radionuclides is an important parameter which affects the development of nuclear power. In recent years, the metal-organic frameworks(MOFs) have attracted worldwide attention in the adsorption of radionuclides from large volume of aqueous solutions, because of their high chemical stability, abundant functional groups and changeable porous structures. In this review, we mainly summarized the recent works of MOFs in the efficient removal of radionuclides, and to understand the interaction mechanism from batch adsorption experiments, model analysis, advanced spectroscopy analysis, and theoretical calculation. The adsorption capacities of MOFs with other materials were also summarized, and the future research opportunities and challenges are given in the perspective.
With the development of nuclear energy, the long-lived radionuclides are inevitably released into the natural environment during the mine process, fuel manufacture, nuclear power usable and spent fuel management, which are dangerous to human health and environmental pollution. Thereby the efficient elimination of radionuclides is an important parameter which affects the development of nuclear power. In recent years, the metal-organic frameworks(MOFs) have attracted worldwide attention in the adsorption of radionuclides from large volume of aqueous solutions, because of their high chemical stability, abundant functional groups and changeable porous structures. In this review, we mainly summarized the recent works of MOFs in the efficient removal of radionuclides, and to understand the interaction mechanism from batch adsorption experiments, model analysis, advanced spectroscopy analysis, and theoretical calculation. The adsorption capacities of MOFs with other materials were also summarized, and the future research opportunities and challenges are given in the perspective.
引文
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[37]WANG X X,LIU Y,PANG H W,et al.Effect of graphene oxide surface modification on the elimination of Co(II)from aqueous solutions.Chemical Engineering Journal,2018,344:380-390.
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[41]GU P C,ZHANG S,LI X,et al.Recent advances in layered double hydroxide-based nanomaterials for the removal of radionuclides from aqueous solution.Environmental Pollution,2018,240:493-505.
[42]SONG W C,WANG X X,CHEN Z S,et al.Enhanced immobilization of U(VI)on Mucor circinelloides in presence of As(V):batch and XAFS investigation.Environmental Pollution,2018,237:228-236.
[43]TAN X L,FANG M,TAN L Q,et al.Core-shell hierarchical C@Na2Ti3O7·9H2O nanostructures for the efficient removal of radionuclides.Environmental Science:Nano,2018,5(5):1140-1149.
[44]NAEIMI S,FAGHIHIAN H.Performance of novel adsorbent prepared by magnetic metal-organic framework MOF modified by potassium nickel hexacyanoferrate for removal of Cs+from aqueous solution.Separation and Purification Technology,2017,175:255-265.
[45]ZHANG C L,LIU Y,LI X,et al.Highly uranium elimination by crab shells-derived porous graphitic carbon nitride:batch,EXAFSand theoretical calculations.Chemical Engineering Journal,2018,346:406-415.
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[48]ZHANG C L,LI X,CHEN Z S,et al.Synthesis of ordered mesoporous carbonaceous materials and its highly efficient capture of uranium from solutions.Science China Chemistry,2018,61(3):281-293.
[49]SUN Y B,LU S H,WANG X X,et al.Plasma-facilitated synthesis of amidoxime/carbon nanofiber hybrids for effective enrichment of238U(VI)and 241Am(III).Environmental Science&Technology,2017,51(21):12274-12282.
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[2]PANG H W,WANG X X,YAO W,et al.Removal of radionuclides by metal oxide materials and mechanism research.Scientia Sinica Chimica,2018,48:58-73.
[3]YANG S Y,WANG X X,CHEN Z S,et al.Synthesis of Fe3O4-based nanomaterials and their application in the removal of radionuclides and heavy metal ions.Progress in Chemistry,2018,30(2/3):225-242.
[4]YU S J,WANG X X,PANG H W,et al.Boron nitride-based materials for the removal of pollutants from aqueous solutions:a review.Chemical Engineering Journal,2018,333:343-360.
[5]YU S J,WANG X X,YANG S T,et al.Interaction of radionuclides with natural and manmade materials using XAFS technique.Science China Chemistry,2016,60(2):170-187.
[6]LI X,LIU Y,ZHANG C L,et al.Porous Fe2O3 microcubes derived from metal organic frameworks for efficient elimination of organic pollutants and heavy metal ions.Chemical Engineering Journal,2018,336:241-252.
[7]LIANG Y,GU P C,YAO W,et al.Adsorption of radionuclide uranium onto carbon-based nanomaterials from aqueous systems.Process in Chemistry,2017,29(9):1062-1071.
[8]DU Y C,WANG X K,HOU R Q,et al.In-situ growth of Nb2O5nanorods on diatomite and highly effective removal of Cr(VI).Journal of Inorganic Materials,2018,33(5):557-564.
[9]CHEN H J,HUANG S Y,ZHANG Z B,et al.Synthesis of functional nanoscale zero-valent iron composites for the application of radioactive uranium enrichment from environment:a review.Acta Chimica Sinica,2017,75(6):560-574.
[10]DU Y,WANG J,WANG H Q,et al.Research on sorption mechanism of radionuclides by manufactured nanomaterials.Journal of Agro-Environment Science,2016,35:1837-1847.
[11]WANG X N,MENG H,MA F Y,et al.Influence of preparation method on oxidation degree of graphene oxide and adsorption for Th(IV)and U(VI).Journal of Inorganic Materials,2016,31(5):454-460.
[12]GU P C,XING J L,WEN T,et al.Experimental and theoretical calculation investigation on efficient Pb(II)adsorption on etched Ti3AlC2 nanofibers and nanosheets.Environmental Science:Nano,2018,5(4):946-955.
[13]YAO W,WU Y H,PANG H W,et al.In-situ reduction synthesis of manganese dioxide@polypyrrole core/shell nanomaterial for highly efficient enrichment of U(VI)and Eu(III).Science China Chemistry,2018(7):1-12.
[14]SONG S,YIN L,WANG X X,et al.Interaction of U(VI)with ternary layered double hydroxides by combined batch experiments and spectroscopy study.Chemical Engineering Journal,2018,338:579-590.
[15]WANG P Y,YIN L,WANG X X,et al.L-cysteine intercalated layered double hydroxide for highly efficient capture of U(VI)from aqueous solutions.Journal of Environmental Management,2018,217:468-477.
[16]LIU W,DAI X,BAI Z L,et al.Highly sensitive and selective uranium detection in natural water systems using a luminescent mesoporous metal-organic framework equipped with abundant lewis basic sites:a combined batch,X-ray absorption spectroscopy,and first principles simulation investigation.Environmental Science&Technology,2017,51(7):3911-3921.
[17]LI J,WANG X X,ZHAO G X,et al.Metal-organic frameworkbased materials:superior adsorbents for the capture of toxic and radioactive metal ions.Chemical Society Reviews,2018,47(7):2322-2356.
[18]WU Y H,PANG H W,YAO W,et al.Synthesis of rod-like metal-organic framework(MOF-5)nanomaterial for efficient removal of U(VI):batch experiments and spectroscopy study.Science Bulletin,2018,63(13):831-839.
[19]DROUT R J,OTAKE K,HOWARTH A J,et al.Efficient capture of perrhenate and pertechnetate by a mesoporous Zr metal-organic framework and examination of anion binding motifs.Chemistry of Materials,2018,30(4):1277-1284.
[20]WANG Y L,LIU Z Y,LI Y X,et al.Umbellate distortions of the uranyl coordination environment result in a stable and porous polycatenated framework that can effectively remove cesium from aqueous solutions.Journal of America Chemistry Society,2015,137(19):6144-6147.
[21]BANERJEE D,KIM D,SCHWEIGER M J,et al.Removal of Tc O4-ions from solution:materials and future outlook.Chemical Society Reviews,2016,45(10):2724-2739.
[22]PANG H W,HUANG S Y,WU Y H,et al.Efficient elimination of U(VI)by polyethyleneimine decorated fly ash.Inorganic Chemistry Frontiers,2018,5:2399-2407
[23]YU S J,WANG X X,TAN X L,et al.Sorption of radionuclides from aqueous systems onto graphene oxide-based materials:a review.Inorganic Chemistry Frontiers,2015,2(7):593-612.
[24]DUAN L F,ZHANG Y,WANG L M,et al.Synthesis and characterization of MnFe2O4 with different morphologies and their application in water treatment.Journal of Inorganic Materials,2014,29(7):763-768.
[25]CARBONI M,ABNEY C W,LIU S B,et al.Highly porous and stable metal-organic frameworks for uranium extraction.Chemical Science,2013,4(6):2396-2402.
[26]BAI Z Q,YUAN L Y,ZHU L,et al.Introduction of amino groups into acid-resistant MOFs for enhanced U(VI)sorption.Journal of Materials Chemistry A,2015,3(2):525-534.
[27]LI L N,MA W,SHEN S S,et al.A combined experimental and theoretical study on the extraction of uranium by amino-derived metal-organic frameworks through post-synthetic strategy.ACSApplied Materials&Interfaces,2016,8(45):31032-31041.
[28]ZHU L,SHENG D P,XU C,et al.Identifying the recognition site for selective trapping of 99Tc O4-in a hydrolytically stable and radiation resistant cationic metal-organic framework.Journal of America Chemistry Society,2017,139(42):14873-14876.
[29]SHENG D P,ZHU L,XU C,et al.Efficient and selective uptake of Tc O4-by a cationic metal-organic framework material with open Ag+sites.Environmental Science&Technology,2017,51(6):3471-3479.
[30]YANG P P,LIU Q,LIU J Y,et al.Interfacial growth of a metal-organic framework(UiO-66)on functionalized graphene oxide(GO)as a suitable seawater adsorbent for extraction of uranium(VI).Journal of Materials Chemistry A,2017,5(34):17933-17942.
[31]ZHANG N,YUAN L Y,GUO W L,et al.Extending the use of highly porous and functionalized MOFs to Th(IV)capture.ACSApplied Materials&Interfaces,2017,9(30):25216-25224.
[32]PENG Y G,HUANG H L,LIU D H,et al.Radioactive barium ion trap based on metal-organic framework for efficient and irreversible removal of barium from nuclear wastewater.ACS Applied Materials&Interfaces,2016,8(13):8527-8535.
[33]YUAN G Y,TIAN Y,LIU J,et al.Schiff base anchored on metal-organic framework for Co(II)removal from aqueous solution.Chemical Engineering Journal,2017,326:691-699.
[34]GAO Y J,FENG M L,ZHANG B,et al.An easily synthesized microporous framework material for the selective capture of radioactive Cs+and Sr2+ions.Journal of Materials Chemistry A,2018,6(9):3967-3976.
[35]YAO W,WANG X X,LIANG Y,et al.Synthesis of novel flower-like layered double oxides/carbon dots nanocomposites for U(VI)and 241Am(III)efficient removal:batch and EXAFS studies.Chemical Engineering Journal,2018,332:775-786.
[36]WANG X X,YU S J,WU Y H,et al.The synergistic elimination of uranium(VI)species from aqueous solution using bi-functional nanocomposite of carbon sphere and layered double hydroxide.Chemical Engineering Journal,2018,342:321-330.
[37]WANG X X,LIU Y,PANG H W,et al.Effect of graphene oxide surface modification on the elimination of Co(II)from aqueous solutions.Chemical Engineering Journal,2018,344:380-390.
[38]YU S J,WANG J,SONG S,et al.One-pot synthesis of graphene oxide and Ni-Al layered double hydroxides nanocomposites for the efficient removal of U(VI)from wastewater.Science China Chemistry,2017,60(3):415-422.
[39]YU S J,WANG X X,CHEN Z S,et al.Interaction mechanism of radionickel on Na-montmorillonite:influences of pH,electrolyte cations,humic acid and temperature.Chemical Engineering Journal,2016,302:77-85.
[40]YIN L,SONG S,WANG X X,et al.Rationally designed core-shell and yolk-shell magnetic titanate nanosheets for efficient U(VI)adsorption performance.Environmental Pollution,2018,238:725-738.
[41]GU P C,ZHANG S,LI X,et al.Recent advances in layered double hydroxide-based nanomaterials for the removal of radionuclides from aqueous solution.Environmental Pollution,2018,240:493-505.
[42]SONG W C,WANG X X,CHEN Z S,et al.Enhanced immobilization of U(VI)on Mucor circinelloides in presence of As(V):batch and XAFS investigation.Environmental Pollution,2018,237:228-236.
[43]TAN X L,FANG M,TAN L Q,et al.Core-shell hierarchical C@Na2Ti3O7·9H2O nanostructures for the efficient removal of radionuclides.Environmental Science:Nano,2018,5(5):1140-1149.
[44]NAEIMI S,FAGHIHIAN H.Performance of novel adsorbent prepared by magnetic metal-organic framework MOF modified by potassium nickel hexacyanoferrate for removal of Cs+from aqueous solution.Separation and Purification Technology,2017,175:255-265.
[45]ZHANG C L,LIU Y,LI X,et al.Highly uranium elimination by crab shells-derived porous graphitic carbon nitride:batch,EXAFSand theoretical calculations.Chemical Engineering Journal,2018,346:406-415.
[46]HU Y Z,WANG X X,ZOU Y D,et al.Superior sorption capacities of Ca-Ti and Ca-Al bimetallic oxides for U(VI)from aqueous solutions.Chemical Engineering Journal,2017,316:419-428.
[47]CHEN Z S,WANG J,PU Z X,et al.Synthesis of magnetic Fe3O4/CFA composites for the efficient removal of U(VI)from wastewater.Chemical Engineering Journal,2017,320:448-457.
[48]ZHANG C L,LI X,CHEN Z S,et al.Synthesis of ordered mesoporous carbonaceous materials and its highly efficient capture of uranium from solutions.Science China Chemistry,2018,61(3):281-293.
[49]SUN Y B,LU S H,WANG X X,et al.Plasma-facilitated synthesis of amidoxime/carbon nanofiber hybrids for effective enrichment of238U(VI)and 241Am(III).Environmental Science&Technology,2017,51(21):12274-12282.
[50]WANG J,WANG X X,ZHAO G X,et al.Polyvinylpyrrolidone and polyacrylamide intercalated molybdenum disulfide as adsorbents for enhanced removal of chromium(VI)from aqueous solutions.Chemical Engineering Journal,2018,334:569-578.
[51]YANG D X,WANG X X,SONG G,et al.One-pot synthesis of arginine modified hydroxyapatite carbon microsphere composites for efficient removal of U(VI)from aqueous solutions.Science Bulletin,2017,62(23):1609-1618.
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