催化裂化废催化剂再利用的途径
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摘要
介绍了流化催化裂化(FCC)废催化剂用于回收金属、作为原料合成分子筛和水泥、吸附有害物质、降解废塑料等几种再利用的途径。将FCC废催化剂作为二次资源,加以回收利用,不仅可以减轻环境污染,还可以充分利用资源,生产高附加值产品,带来经济效益,从根本上解决FCC废催化剂的处置问题。
The ways of using fluidized catalytic cracking(FCC)waste catalyst to recycle metal,synthesize zeolite and cement,adsorb harmful substances,degrade waste plastics are introduced.Taking FCC waste catalyst as the recovery resource and recycling it can not only reduce environmental pollution,but also make full use of resources to produce high value-added products,bringing economic benefits,and fundamentally solve the disposal problem of FCC waste catalyst.
The ways of using fluidized catalytic cracking(FCC)waste catalyst to recycle metal,synthesize zeolite and cement,adsorb harmful substances,degrade waste plastics are introduced.Taking FCC waste catalyst as the recovery resource and recycling it can not only reduce environmental pollution,but also make full use of resources to produce high value-added products,bringing economic benefits,and fundamentally solve the disposal problem of FCC waste catalyst.
引文
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[14]ZHENG S,HE L,YAO H,et al.Synthesis and application of a zeolite-containing composite material made from spent FCC catalyst[J].China Petroleum Processing&Petrochemical Technology,2015,17(4):46-54.
[15]VELZQUEZ S,MONZJ,BORRACHERO M V,et al.Evaluation of the pozzolanic activity of spent FCC catalyst/fly ash mixtures in Portland cement pastes[J].Thermochimica Acta,2016,632:29-36.
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[19]PAY,BORRACHERO,M V,et al.Studies on the behaviour of different spent fluidized-bed catalytic cracking catalysts on Portland cement[J].Materiales De Construccion,2009,59(296):37-52.
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[21]陈芳艳,张洪林,唐玉斌,等.FCC废催化剂对水中铜(Ⅱ)的吸附[J].中国环境科学,1999(2):153-156.
[22]唐玉斌,陈芳艳.FCC废催化剂对水中镉(Ⅱ)的吸附热力学及动力学研究[J].环境保护与循环经济,1998(5):19-23.
[23]陈芳艳,何军,唐玉斌,等.废FCC催化剂对水中铅离子的吸附特性研究[J].石油化工高等学校学报,1999,12(2):11-14.
[24]郑淑琴,黄石,钱东,等.FCC废催化剂的改性及其对重金属离子的吸附性能[J].石油学报(石油加工),2010,26(4):612-616.
[25]刘公召,安源.FCC废催化剂吸附溶液中微量镍的研究[J].北京化工大学学报(自然科学版),2003,30(3):10-12.
[26]谢杰,王哲,吴德意,等.表面活性剂改性沸石对水中酚类化合物吸附性能研究[J].环境科学,2012,33(12):4361-4366.
[27]何捍卫,孟佳,解东梅,等.废FCC催化剂吸附苯酚废水[J].粉末冶金材料科学与工程,2012,17(1):69-75.
[28]戚霖,宫红,王锐,等.废FCC催化剂吸附双酚A水溶液的研究[J/OL].应用化工,2018,47(9):1892-1895,1999.
[29]LEE K H,SHIN D H.A comparative study of liquid product on non-catalytic and catalytic degradation of waste plastics using spent FCC catalyst[J].Korean Journal of Chemical Engineering,2006,23(2):209-215.
[30]TRIVEDI P A,PARMAR P R,PARIKH P A.Spent FCCcatalyst:Potential anti-corrosive and anti-biofouling material[J].Journal of Industrial&Engineering Chemistry,2014,20(4):1388-1396.
[31]LIANG Z,YAN G,ZHENG L,et al.Preparation of alumina abrasion-resistant ceramic grinding ball with spent FCC equilibrium catalyst[J].Journal of China Petroleum Processing&Petrochemical Technology,2010,12(4):23-29.
[32]PU X,LUAN J N,SHI L.Reuse of spent FCC catalyst for removing trace olefins from aromatics[J].Bulletin-Korean Chemical Society,2012,33(8):44-49.
[2]赵晓敏.FCC废催化剂的综合回收利用[J].炼油技术与工程,2017,47(4):51-55.
[3]孙书红,庞新梅,刘从华,等.稀土形态与FCC催化剂性能关系的研究[J].燃料化学学报,2001,29(S1):43-45.
[4]李晚霞.从废FCC催化剂中回收稀土镧和铈的研究[D].兰州:西北师范大学,2014.
[5]何捍卫,孟佳.采用P507(HEH/EHP)从废FCC催化剂中回收稀土[J].中南大学学报(自然科学版),2011,42(9):2651-2657.
[6]巫树锋,赵琦,荣树茂,等.废催化裂化催化剂中稀土和铝元素的综合利用研究[J].石化技术与应用,2015,33(4):296-300.
[7]ZHAO Z,QIU Z,YANG J,et al.Recovery of rare earth elements from spent fluid catalytic cracking catalysts using leaching and solvent extraction techniques[J].Hydrometallurgy,2017,167:183-188.
[8]周宁波,肖华,陈韬,等.炼油废催化剂中分离有害重金属工艺条件研究[J].无机盐工业,2014,46(1):69-72.
[9]LAI Y D,LIU J C.Leaching behaviors of Ni and V from spent catalyst[J].Journal of Hazardous Materials,1997,53(53):213-224.
[10]朝阳,春晖.从废催化剂中提取钒、钼、镍的试验[J].铁合金,2001,32(2):29-31.
[11]ESCARDINO A,BARBA A,SNCHEZ E,et al.Using spent catalyst from refinery FCC units to produce 4A-zeolite:synthesis,procedure,and kinetics[J].Advances in Applied Ceramics,1999,98(4):172-177.
[12]刘欣梅,李亮,杨婷婷,等.FCC废催化剂细粉合成超细Y型分子筛[J].石油学报(石油加工),2012,28(4):555-560.
[13]LIU X,LI L,YANG T,et al.Zeolite Y synthesized with FCC spent catalyst fines:particle size effect on catalytic reactions[J].Journal of Porous Materials,2012,19(1):133-139.
[14]ZHENG S,HE L,YAO H,et al.Synthesis and application of a zeolite-containing composite material made from spent FCC catalyst[J].China Petroleum Processing&Petrochemical Technology,2015,17(4):46-54.
[15]VELZQUEZ S,MONZJ,BORRACHERO M V,et al.Evaluation of the pozzolanic activity of spent FCC catalyst/fly ash mixtures in Portland cement pastes[J].Thermochimica Acta,2016,632:29-36.
[16]SORIANO L,PAYJ,MONZJ,et al.High strength mortars using ordinary Portland cement-fly ash-fluid catalytic cracking catalyst residue ternary system(OPC/FA/FCC)[J].Construction&Building Materials,2016,106:228-235.
[17]PACEWSKA B,NOWACKA M,WILIN'SKAI,et al.Studies on the influence of spent FCC catalyst on hydration of calcium aluminate cements at ambient temperature[J].Journal of Thermal Analysis&Calorimetry,2011,105(1):129-140.
[18]VAICIUKYNIENE D,GRINYS A,VITOLDAS V,et al.Purified waste fcc catalyst as a cement replacement material[J].Ceramics-Silikáty,2015,59(2):103-108.
[19]PAY,BORRACHERO,M V,et al.Studies on the behaviour of different spent fluidized-bed catalytic cracking catalysts on Portland cement[J].Materiales De Construccion,2009,59(296):37-52.
[20]苑志伟,孟佳,何捍卫.废FCC催化剂再生利用的研究现状及进展[J].当代石油石化,2010,18(7):27-30.
[21]陈芳艳,张洪林,唐玉斌,等.FCC废催化剂对水中铜(Ⅱ)的吸附[J].中国环境科学,1999(2):153-156.
[22]唐玉斌,陈芳艳.FCC废催化剂对水中镉(Ⅱ)的吸附热力学及动力学研究[J].环境保护与循环经济,1998(5):19-23.
[23]陈芳艳,何军,唐玉斌,等.废FCC催化剂对水中铅离子的吸附特性研究[J].石油化工高等学校学报,1999,12(2):11-14.
[24]郑淑琴,黄石,钱东,等.FCC废催化剂的改性及其对重金属离子的吸附性能[J].石油学报(石油加工),2010,26(4):612-616.
[25]刘公召,安源.FCC废催化剂吸附溶液中微量镍的研究[J].北京化工大学学报(自然科学版),2003,30(3):10-12.
[26]谢杰,王哲,吴德意,等.表面活性剂改性沸石对水中酚类化合物吸附性能研究[J].环境科学,2012,33(12):4361-4366.
[27]何捍卫,孟佳,解东梅,等.废FCC催化剂吸附苯酚废水[J].粉末冶金材料科学与工程,2012,17(1):69-75.
[28]戚霖,宫红,王锐,等.废FCC催化剂吸附双酚A水溶液的研究[J/OL].应用化工,2018,47(9):1892-1895,1999.
[29]LEE K H,SHIN D H.A comparative study of liquid product on non-catalytic and catalytic degradation of waste plastics using spent FCC catalyst[J].Korean Journal of Chemical Engineering,2006,23(2):209-215.
[30]TRIVEDI P A,PARMAR P R,PARIKH P A.Spent FCCcatalyst:Potential anti-corrosive and anti-biofouling material[J].Journal of Industrial&Engineering Chemistry,2014,20(4):1388-1396.
[31]LIANG Z,YAN G,ZHENG L,et al.Preparation of alumina abrasion-resistant ceramic grinding ball with spent FCC equilibrium catalyst[J].Journal of China Petroleum Processing&Petrochemical Technology,2010,12(4):23-29.
[32]PU X,LUAN J N,SHI L.Reuse of spent FCC catalyst for removing trace olefins from aromatics[J].Bulletin-Korean Chemical Society,2012,33(8):44-49.
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