甲苯催化氧化催化剂的研究进展
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摘要
从甲苯催化氧化催化剂种类、制备方法及性能等方面,总结概述了近年来对此类催化剂的研究,发现对贵金属催化剂的研究主要集中于载体选择及负载方式,对非贵金属氧化物催化剂的研究则集中于金属间复合、元素掺杂、制备方法等方面,均旨在提高催化活性和稳定性。未来研究需注重催化剂抗中毒性能的提高,并考虑混合气体的高效催化氧化。
We summarized and overviewed recent researches on the catalysts from the perspective of type, preparation method and performance. The majority of present studies focus on the carrier selection and loading mode of noble metal catalysts, while on intermetallic complexes, element doping, preparation methods and etc. for non-noble metal oxides. All of aforementioned studies aim at improving catalytic activity and stability, however, we suggest more attentions to be paid on the improvement of catalyst anti-poisoning performance, and the high-efficiency catalytic oxidation of mixed gas.
We summarized and overviewed recent researches on the catalysts from the perspective of type, preparation method and performance. The majority of present studies focus on the carrier selection and loading mode of noble metal catalysts, while on intermetallic complexes, element doping, preparation methods and etc. for non-noble metal oxides. All of aforementioned studies aim at improving catalytic activity and stability, however, we suggest more attentions to be paid on the improvement of catalyst anti-poisoning performance, and the high-efficiency catalytic oxidation of mixed gas.
引文
[1] SHAHZAD K M,RAZZAK S A,HOSSAIN M M.Catalytic oxidation of volatile organic compounds (VOCs):A review[J].Atmospheric Environment,2016,140:117-134.
[2] YE Z,GIRAUDON J M,NUNS N,et al.Influence of the preparation method on the activity of copper-manganese oxides for toluene total oxidation[J].Applied Catalysis B:Environmental,2018,223:154-166.
[3] 赵倩,葛云丽,纪娜,等.催化氧化技术在可挥发性有机物处理的研究[J].化学进展,2016,28(12):1847-1859.ZHAO Q,GE Y L,JI N,et al.Removal of volatile organic compounds by catalytic oxidation technology[J].Progress in Chemistry,2016,28(12):1847-1859.
[4] HU J,LI W B,LIU R F.Highly efficient copper-doped manganese oxide nanorod catalysts derived from CuMnO hierarchical nanowire for catalytic combustion of VOCs[J].Catalysis Today,2018,314:147-153.
[5] LI W,YE H Q,LIU G G,et al.The role of graphene coating on cordierite-supported Pd monolithic catalysts for low-temperature combustion of toluene[J].Chinese Journal of Catalysis,2018,39(5):946-954.
[6] 李奔,周贝,李思汉,等.自组装低负载量Pd/γ-Al2O3催化剂催化氧化甲苯[J].精细化工,2018,35(9):1555-1561.LI B,ZHOU B,LI S H,et al.A Self-assembled Pd/γ-Al2O3 catalyst with low loading for catalytic oxidation of toluene[J].Fine Chemicals,2018,35(9):1555-1561.
[7] WANG H,YANG W,TIAN P H,et al.A highly active and anti-coking Pd-Pt/SiO2 catalyst for catalytic combustion of toluene at low temperature[J].Applied Catalysis A:General,2017,529:60-67.
[8] CHEN C,WANG X,ZHANG J,et al.Superior performance in catalytic combustion of toluene over KZSM-5 zeolite supported platinum catalyst[J].Catalysis Letters,2014,144(11):1851-1859.
[9] FU X R,LIU Y,YAO W Y,et al.One-step synthesis of bimetallic Pt-Pd/MCM-41 mesoporous materials with superior catalytic performance for toluene oxidation[J].Catalysis Communications,2016,83:22-26.
[10] PENG R S,SUN X B,LI S J,et al.Shape effect of Pt/CeO2 catalysts on the catalytic oxidation of toluene[J].Chemical Engineering Journal,2016,306:1234-1246.
[11] CARABINEIRO S A C ,CHEN X,MARTYNYUK O,et al.Gold supported on metal oxides for volatile organic compounds total oxidation[J].Catalysis Today,2015,244:103-114.
[12] JOUNG H J,KIM J H,OH J S,et al.Catalytic oxidation of VOCs over CNT-supported platinum nanoparticles[J].Applied Surface Science,2014,290:267- 273.
[13] MALDONADO-HóDAR F J.Removing aromatic and oxygenated VOCs from polluted air stream using Pt-carbon aerogels:Assessment of their performance as adsorbents and combustion catalysts[J].Hazard Mater,2011,194:216-222.
[14] CHEN X,ZHAO Z L,ZHOU Y,et al.A facile route for spraying preparation of Pt/TiO2 monolithic catalysts toward VOCs combustion[J].Applied Catalysis A:General,2018,566:190-199.
[15] LI H,WANG Y,CHEN X,et al.Preparation of metallic monolithic Pt/FeCrAl fiber catalyst by suspension spraying for VOCs combustion[J].RSC Advances,2018,8:14806-14811.
[16] GORTE R J.Ceria in catalysis:from automotive applications to the water-gas shift reaction[J].AIChE J,2010,56(5):1126-1135.
[17] LóPEZ J M,GILBANK A L,GARCíA T,et al.The prevalence of surface oxygen vacancies over the mobility of bulk oxygen in nanostructured ceria for the total toluene oxidation[J].Applied Catalysis B:Environmental,2015,174/175:403-412.
[18] HU F Y,CHEN J J,PENG Y,et al.Novel nanowire self-assembled hierarchical CeO2 microspheres for low temperature toluene catalytic combustion[J].Chemical Engineering Journal,2018,331:425-434.
[19] EINAGA H,YAMAMOTO S,MAEDA N,et al.Structural analysis of manganese oxides supported on SiO2 for benzene oxidation with ozone[J].Catalysis Today,2015,242:287-293.
[20] LIAO Y N,ZHANG X,PENG R S,et al.Catalytic properties of manganese oxide polyhedra with hollow and solid morphologies in toluene removal[J].Applied Surface Science,2017,405:20-28.
[21] KIM S C,PARK Y K,NAH J W.Property of a highly active bimetallic catalyst based on a supported manganese oxide for the complete oxidation of toluene[J].Powder Technol,2014,266:292-298.
[22] 廖银念,张璇,牛文浩,等.不同形貌氧化锰催化降解甲苯的性能研究[J].环境工程,2018,36(1):62-66.LIAO Y N,ZHANG X,NIU W H,et al.Catalytic decomposition of toluene by manganese oxides with different morphologies[J].Environmental Engineering,2018,36(1):62-66.
[23] BUSCA G,DATURI M,FINOCCHIO E,et al.Transition metal mixed oxides as combustion catalysts:preparation,characterization and activity mechanisms[J].Catalysis Today,1997,33(1/2/3):239-249.
[24] FENG X Y,GUO J X,WEN X R,et al.Enhancing performance of Co/CeO2 catalyst by Sr doping for catalytic combustion of toluene[J].Applied Surface Science,2018,445:145-153.
[25] ROKICINSKA′ A,DROZDEK M,DUDEK B,et al.Cobalt-containing BEA zeolite for catalytic combustion of toluene[J].Applied Catalysis B:Environmental,2017,212:59-67.
[26] HERACLEOUS E,LEE A,WILSON K,et al.Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene:structural characterization and reactivity studies[J].Journal of Catalysis,2005,231(1):159-171.
[27] JIANG S J,HANDBERGA E S,LIU F,et al.Effect of doping the nitrogen into carbon nanotubes on the activity of NiO catalysts for the oxidation removal of toluene[J].Applied Catalysis B:Environmental,2014,160/161:716-721.
[28] PARK E J,LEE J H,KIM K D,et al.Toluene oxidation catalyzed by NiO/SiO2 and NiO/TiO2/SiO2:Towards development of humidity-resistant catalysts[J].Catalysis Today,2016,260:100-106.
[29] 张璇,廖银念,罗云,等.花状氧化铜催化降解甲苯的性能研究[J].环境科学与技术,2017,40(8):30-35.ZHANG X,LIAO Y N,LUO Y,et al.Performance of flower-like CuO for catalytic degradation of toluene[J].Environmental Science & Technology,2017,40(8):30-35.
[30] 彭若斯.二氧化铈负载铂催化剂催化氧化甲苯的性能与反应机理研究[D].广州:华南理工大学,2017.PENG R S.Catalytic oxidation of toluene over platinum supported on ceria catalysts:performance and reaction mechanism[D].Guangzhou:South China University of Technology,2017.
[31] CARABINEIRO S A C,CHEN X,KONSOLAKIS M,et al.Catalytic oxidation of toluene on Ce-Co and La-Co mixed oxides synthesized by exotemplating and evaporation methods[J].Catalysis Today,2015,244:161-171.
[32] 朱红娜,吕德义,郇昌永.Cu/Mn/Ce三元氧化物催化剂对甲苯催化燃烧性能的研究[J].浙江化工,2016,47(10):29-35.ZHU H N,LV D Y,HUAN C Y.Study of the Cu/Mn/Ce ternary catalysts on performance for catalytic oxidation of toluene[J].Zhejiang Chemical Industry,2016,47(10):29-35.
[33] 董翠,曲振平,杜金鹏,等.Mn-Co氧化物制备及其甲苯催化性能研究[C]//中国化学会第30届学术年会摘要集:环境化学,大连,2006.DONG C,QU Z P,DU J P,et al.Preparation of Mn-Co oxide and its catalytic properties of toluene[C]//The 30th Annual Academic Meeting of the Chinese Chemical Society:Environmental Chemistry,Da Lian,China,2006.
[34] 刘兆信,黎维彬.在类棒状铜锰复合氧化物上甲苯的催化燃烧活性及其失活[J].物理化学学报,2016,32(7):1795-1800.LIU Z X,LI W B.Catalytic activity and deactivation of toluene combustion on rod-like copper-manganese mixed oxides[J].Acta Physico-chimica Sinica,2016,32(7):1795-1800.
[35] AHN C W,YOU Y W,HEO I,et al.Catalytic combustion of volatile organic compound over spherical-shaped copper-manganese oxide[J].Journal of Industrial and Engineering Chemistry,2017,47:439-445.
[36] 吴波.铜锰铈氧化物VOCs催化燃烧催化剂的制备与性能研究[D].成都:西南交通大学,2017.WU B.Based on catalytic combustion properties of catalyst copper manganese cerium oxide[D].Chengdu:Southwest Jiaotong University,2017.
[37] TARJOMANNEJAD A,FARZI A,NIAEI A,et al.An experimental and kinetic study of toluene oxidation over LaMn1-xBxO3 and La0.8A0.2Mn0.3B0.7O3(A=Sr,Ce and B=Cu,Fe) nano-perovskite catalysts[J].Korean Journal of Chemical Engineering,2016,33(9):2628-2637.
[38] HOSSEINI S A,ALVAREZ-GALVAN M C.Study of physical-chemical properties and catalytic activities of ZnCr2O4 spinel nano oxides obtained from different methods-Modeling the synthesis process by response surface methodology and optimization by genetic algorithm[J].Journal of the Taiwan Institute of Chemical Engineers,2016,61:261-269.
[2] YE Z,GIRAUDON J M,NUNS N,et al.Influence of the preparation method on the activity of copper-manganese oxides for toluene total oxidation[J].Applied Catalysis B:Environmental,2018,223:154-166.
[3] 赵倩,葛云丽,纪娜,等.催化氧化技术在可挥发性有机物处理的研究[J].化学进展,2016,28(12):1847-1859.ZHAO Q,GE Y L,JI N,et al.Removal of volatile organic compounds by catalytic oxidation technology[J].Progress in Chemistry,2016,28(12):1847-1859.
[4] HU J,LI W B,LIU R F.Highly efficient copper-doped manganese oxide nanorod catalysts derived from CuMnO hierarchical nanowire for catalytic combustion of VOCs[J].Catalysis Today,2018,314:147-153.
[5] LI W,YE H Q,LIU G G,et al.The role of graphene coating on cordierite-supported Pd monolithic catalysts for low-temperature combustion of toluene[J].Chinese Journal of Catalysis,2018,39(5):946-954.
[6] 李奔,周贝,李思汉,等.自组装低负载量Pd/γ-Al2O3催化剂催化氧化甲苯[J].精细化工,2018,35(9):1555-1561.LI B,ZHOU B,LI S H,et al.A Self-assembled Pd/γ-Al2O3 catalyst with low loading for catalytic oxidation of toluene[J].Fine Chemicals,2018,35(9):1555-1561.
[7] WANG H,YANG W,TIAN P H,et al.A highly active and anti-coking Pd-Pt/SiO2 catalyst for catalytic combustion of toluene at low temperature[J].Applied Catalysis A:General,2017,529:60-67.
[8] CHEN C,WANG X,ZHANG J,et al.Superior performance in catalytic combustion of toluene over KZSM-5 zeolite supported platinum catalyst[J].Catalysis Letters,2014,144(11):1851-1859.
[9] FU X R,LIU Y,YAO W Y,et al.One-step synthesis of bimetallic Pt-Pd/MCM-41 mesoporous materials with superior catalytic performance for toluene oxidation[J].Catalysis Communications,2016,83:22-26.
[10] PENG R S,SUN X B,LI S J,et al.Shape effect of Pt/CeO2 catalysts on the catalytic oxidation of toluene[J].Chemical Engineering Journal,2016,306:1234-1246.
[11] CARABINEIRO S A C ,CHEN X,MARTYNYUK O,et al.Gold supported on metal oxides for volatile organic compounds total oxidation[J].Catalysis Today,2015,244:103-114.
[12] JOUNG H J,KIM J H,OH J S,et al.Catalytic oxidation of VOCs over CNT-supported platinum nanoparticles[J].Applied Surface Science,2014,290:267- 273.
[13] MALDONADO-HóDAR F J.Removing aromatic and oxygenated VOCs from polluted air stream using Pt-carbon aerogels:Assessment of their performance as adsorbents and combustion catalysts[J].Hazard Mater,2011,194:216-222.
[14] CHEN X,ZHAO Z L,ZHOU Y,et al.A facile route for spraying preparation of Pt/TiO2 monolithic catalysts toward VOCs combustion[J].Applied Catalysis A:General,2018,566:190-199.
[15] LI H,WANG Y,CHEN X,et al.Preparation of metallic monolithic Pt/FeCrAl fiber catalyst by suspension spraying for VOCs combustion[J].RSC Advances,2018,8:14806-14811.
[16] GORTE R J.Ceria in catalysis:from automotive applications to the water-gas shift reaction[J].AIChE J,2010,56(5):1126-1135.
[17] LóPEZ J M,GILBANK A L,GARCíA T,et al.The prevalence of surface oxygen vacancies over the mobility of bulk oxygen in nanostructured ceria for the total toluene oxidation[J].Applied Catalysis B:Environmental,2015,174/175:403-412.
[18] HU F Y,CHEN J J,PENG Y,et al.Novel nanowire self-assembled hierarchical CeO2 microspheres for low temperature toluene catalytic combustion[J].Chemical Engineering Journal,2018,331:425-434.
[19] EINAGA H,YAMAMOTO S,MAEDA N,et al.Structural analysis of manganese oxides supported on SiO2 for benzene oxidation with ozone[J].Catalysis Today,2015,242:287-293.
[20] LIAO Y N,ZHANG X,PENG R S,et al.Catalytic properties of manganese oxide polyhedra with hollow and solid morphologies in toluene removal[J].Applied Surface Science,2017,405:20-28.
[21] KIM S C,PARK Y K,NAH J W.Property of a highly active bimetallic catalyst based on a supported manganese oxide for the complete oxidation of toluene[J].Powder Technol,2014,266:292-298.
[22] 廖银念,张璇,牛文浩,等.不同形貌氧化锰催化降解甲苯的性能研究[J].环境工程,2018,36(1):62-66.LIAO Y N,ZHANG X,NIU W H,et al.Catalytic decomposition of toluene by manganese oxides with different morphologies[J].Environmental Engineering,2018,36(1):62-66.
[23] BUSCA G,DATURI M,FINOCCHIO E,et al.Transition metal mixed oxides as combustion catalysts:preparation,characterization and activity mechanisms[J].Catalysis Today,1997,33(1/2/3):239-249.
[24] FENG X Y,GUO J X,WEN X R,et al.Enhancing performance of Co/CeO2 catalyst by Sr doping for catalytic combustion of toluene[J].Applied Surface Science,2018,445:145-153.
[25] ROKICINSKA′ A,DROZDEK M,DUDEK B,et al.Cobalt-containing BEA zeolite for catalytic combustion of toluene[J].Applied Catalysis B:Environmental,2017,212:59-67.
[26] HERACLEOUS E,LEE A,WILSON K,et al.Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene:structural characterization and reactivity studies[J].Journal of Catalysis,2005,231(1):159-171.
[27] JIANG S J,HANDBERGA E S,LIU F,et al.Effect of doping the nitrogen into carbon nanotubes on the activity of NiO catalysts for the oxidation removal of toluene[J].Applied Catalysis B:Environmental,2014,160/161:716-721.
[28] PARK E J,LEE J H,KIM K D,et al.Toluene oxidation catalyzed by NiO/SiO2 and NiO/TiO2/SiO2:Towards development of humidity-resistant catalysts[J].Catalysis Today,2016,260:100-106.
[29] 张璇,廖银念,罗云,等.花状氧化铜催化降解甲苯的性能研究[J].环境科学与技术,2017,40(8):30-35.ZHANG X,LIAO Y N,LUO Y,et al.Performance of flower-like CuO for catalytic degradation of toluene[J].Environmental Science & Technology,2017,40(8):30-35.
[30] 彭若斯.二氧化铈负载铂催化剂催化氧化甲苯的性能与反应机理研究[D].广州:华南理工大学,2017.PENG R S.Catalytic oxidation of toluene over platinum supported on ceria catalysts:performance and reaction mechanism[D].Guangzhou:South China University of Technology,2017.
[31] CARABINEIRO S A C,CHEN X,KONSOLAKIS M,et al.Catalytic oxidation of toluene on Ce-Co and La-Co mixed oxides synthesized by exotemplating and evaporation methods[J].Catalysis Today,2015,244:161-171.
[32] 朱红娜,吕德义,郇昌永.Cu/Mn/Ce三元氧化物催化剂对甲苯催化燃烧性能的研究[J].浙江化工,2016,47(10):29-35.ZHU H N,LV D Y,HUAN C Y.Study of the Cu/Mn/Ce ternary catalysts on performance for catalytic oxidation of toluene[J].Zhejiang Chemical Industry,2016,47(10):29-35.
[33] 董翠,曲振平,杜金鹏,等.Mn-Co氧化物制备及其甲苯催化性能研究[C]//中国化学会第30届学术年会摘要集:环境化学,大连,2006.DONG C,QU Z P,DU J P,et al.Preparation of Mn-Co oxide and its catalytic properties of toluene[C]//The 30th Annual Academic Meeting of the Chinese Chemical Society:Environmental Chemistry,Da Lian,China,2006.
[34] 刘兆信,黎维彬.在类棒状铜锰复合氧化物上甲苯的催化燃烧活性及其失活[J].物理化学学报,2016,32(7):1795-1800.LIU Z X,LI W B.Catalytic activity and deactivation of toluene combustion on rod-like copper-manganese mixed oxides[J].Acta Physico-chimica Sinica,2016,32(7):1795-1800.
[35] AHN C W,YOU Y W,HEO I,et al.Catalytic combustion of volatile organic compound over spherical-shaped copper-manganese oxide[J].Journal of Industrial and Engineering Chemistry,2017,47:439-445.
[36] 吴波.铜锰铈氧化物VOCs催化燃烧催化剂的制备与性能研究[D].成都:西南交通大学,2017.WU B.Based on catalytic combustion properties of catalyst copper manganese cerium oxide[D].Chengdu:Southwest Jiaotong University,2017.
[37] TARJOMANNEJAD A,FARZI A,NIAEI A,et al.An experimental and kinetic study of toluene oxidation over LaMn1-xBxO3 and La0.8A0.2Mn0.3B0.7O3(A=Sr,Ce and B=Cu,Fe) nano-perovskite catalysts[J].Korean Journal of Chemical Engineering,2016,33(9):2628-2637.
[38] HOSSEINI S A,ALVAREZ-GALVAN M C.Study of physical-chemical properties and catalytic activities of ZnCr2O4 spinel nano oxides obtained from different methods-Modeling the synthesis process by response surface methodology and optimization by genetic algorithm[J].Journal of the Taiwan Institute of Chemical Engineers,2016,61:261-269.