聚硅氧烷嵌段共聚物的研究进展
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摘要
聚硅氧烷作为一种有机硅高聚物,可通过嵌段共聚进行相应的化学改性。由于其原料种类丰富,改性产物性能优异,因此被学者们广泛研究。综述了国内外聚硅氧烷嵌段共聚物的研究进展,主要介绍聚脲型、聚氨酯型、聚酯型、聚酰胺型、聚酰亚胺型聚硅氧烷嵌段共聚物的合成,对其性能、应用进行概述,并对其应用前景进行了展望。
Polysiloxane, as an organic silicon polymer,can be chemically modified by block copolymerization. Because of its abundant raw materials and excellent properties of modified products, it has been extensively studied by scholars. In this paper, the research progress of polysiloxane block copolymers at home and abroad was reviewed. Some kind of polysiloxane block copolymers modified by polyurea, polyurethane, polyether, polyamide and polyimide were mainly introduced. Also, its performance and application were summarized, and the prospect of its application was forecasted.
Polysiloxane, as an organic silicon polymer,can be chemically modified by block copolymerization. Because of its abundant raw materials and excellent properties of modified products, it has been extensively studied by scholars. In this paper, the research progress of polysiloxane block copolymers at home and abroad was reviewed. Some kind of polysiloxane block copolymers modified by polyurea, polyurethane, polyether, polyamide and polyimide were mainly introduced. Also, its performance and application were summarized, and the prospect of its application was forecasted.
引文
[1]李俊妮,新型聚硅氧烷嵌段共聚物的合成研究进展[J].精细与专用化学品,2012,20(10):42-45.Li J N.Reseach progress in synthesis of novel polysiloxane block copolymers[J].Fine and Specialty Chemicals,2012,20(10):42-45.
[2]Bostick E E,Fessler W A.Condensation method for making multiple sequence organopolysiloxane block polymers:US3578726[P].1971.
[3]黄渝鸿,范敬辉,付强,等.三元嵌段共聚硅橡胶的合成与表征[J].绝缘材料,2008,41(2):15-18.Huang Y H,Fan J H,Fu Q,et al.Synthesis and characterization of tri-block copolymer of dimethyl siloxane diphenyl siloxane and methylvinyl siloxane[J].Insulating Materials,2008,41(2):15-18.
[4]He Y,Xie D,Zhang X.The structure,microphase-separated morphology,and property of polyurethanes and polyureas[J].Journal of Materials Science,2014,49(21):7339-7352.
[5]Paul,Donald R,Mark,et al.Fillers for polysiloxane(“silicone”)elastomers[J].Progress in Polymer Science,2015,35(7):893-901.
[6]Xiang W,Chen Q,Wang Y,et al.Improved air stability of perovskite hybrid solar cells via blending poly(dimethylsiloxane)-urea copolymers[J].Journal of Materials Chemistry A,2017,5(11):3695-3723.
[7]Yilgor I,Eynur T,Yilgor E,et al.Contribution of soft segment entanglement on the tensile properties of silicone-urea copolymers with low hard segment contents[J].Polymer,2009,50(19):4432-4437.
[8]Sheth J P,Yilgor E,Erenturk B,et al.Structure-property behavior of poly(dimethylsiloxane)based segmented polyurea copolymers modified with poly(propylene oxide)[J].Polymer,2005,46(19):8185-8193.
[9]Kinning D J.Bulk,surface,and interfacial characterization of silicone-polyurea segmented copolymers[J].Journal of Adhesion,2001,75(1):1-26.
[10]Zhao H,Hao T H,Hu G H,et al.Preparation and characterization of polyurethanes with cross-linked siloxane in the side chain by sol-gel reactions[J].Materials,2017,10(3):247.
[11]Gunatillake P A,Martin D J,Meijs G F,et al.Designing biostable polyurethane elastomers for biomedical implants[J].Cheminform,2003,34(41):545-557.
[12]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Effect of chain extender structure on the properties and morphology of polyurethanes based on H12MDI and mixed macrodiols(PDMS-PHMO)[J].Journal of Applied Polymer Science,2015,74(12):2979-2989.
[13]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Mixed macrodiol-based siloxane polyurethanes:Effect of the comacrodiol structure on properties and morphology[J].Journal of Applied Polymer Science,2015,78(5):1071-1082.
[14]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Low-modulus siloxane-based polyurethanes.I.Effect of the chain extender1,3-bis(4-hydroxybutyl)1,1,3,3-tetramethyldisiloxane(BHTD)on properties and morphology[J].Journal of Applied Polymer Science,2002,83(4):736-746.
[15]Adhikari R,Gunatillake P A,Bown M.Effect of polydimethylsiloxane macrodiol molecular weight on properties and morphology of polyurethane and polyurethaneurea[J].Journal of Applied Polymer Science,2010,90(6):1565-1573.
[16]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Low-modulus siloxane-polyurethanes.Part II.Effect of chain extender structure on properties and morphology[J].Journal of Applied Polymer Science,2003,87(7):1092-1100.
[17]陆浩翔,江斌,蒋红梅,等.湿固化聚氨酯/有机硅嵌段共聚物的合成与性能[J].上海交通大学学报,2007,41(10):1679-1682.Lu H X,Jiang B,Jiang H M,et al.The synthesis and properties of moisture-cured polyurethane/polysiloxane copolymers[J].Journal of Shanghai Jiaotong University,2007,41(10):1679-1682.
[18]牛冰.聚酯型聚氨酯的合成与改性研究[D].秦皇岛:燕山大学,2016.
[19]Abduallah A B E,Mallon P E.Microscopic surface and bulk morphology of semicrystalline poly(dimethylsiloxane)-polyester copolymers[J].Journal of Applied Polymer Science,2010,115(3):1518-1533.
[20]Racles C,Cozan V,Cazacu M.New arylidene-siloxane polyesters[J].High Performance Polymers,2003,15(3):231-242.
[21]Carmen R,Airinei A,Cozan V,et al.New arylidene-siloxane polyethers:Liquid-crystalline and photosensitive properties[J].Journal of Applied Polymer Science,2003,90(11):3093-3099.
[22]Y?lg?r E,Y?lg?r?.Hydrogen bonding:A critical parameter in designing silicone copolymers[J].Polymer,2001,42(19):7953-7959.
[23]Lei Y,Li C,Fu X,et al.Synthesis and characterization of a high performance polyamide-6 elastomer based on poly(etherblock-amide)multiblock copolymer by reactive processing in torque rheometer[J].Advances in Polymer Technology,2017,37(6):1782-1789.
[24]Senshu K,Furuzono T,Koshizaki N,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.8.1 surface studies of aramid-silicone resin by means of XPS,Static SIMS,and TEM[J].Macromolecules,1997,30(30):4421-4428.
[25]Furuzono T,Yashima E,Kishida A,et al.A novel biomaterial:Poly(dimethylsiloxane)-polyamide multiblock copolymer I.Synthesis and evaluation of blood compatibility[J].Journal of Biomaterials Science Polymer Edition,1993,5(1-2):89.
[26]Kishida A,Furuzono T,Ohshige T A,et al.,Study of the surface properties of ultrathin films of poly(dimethylsiloxane)-polyamide multiblock copolymers[J].Macromolecular Materials&Engineering,1994.220(1):89-97.
[27]Furuzono T,Kishida A,Yanagi M,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.V.The interaction between biomolecules and the surface of aramid-silicone resins[J].Journal of Biomaterials Science Polymer Edition,1996,7(10):871.
[28]Kishida A,Kanda T,Furuzono T,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.IX.Surface properties of blend film of aramid-silicone resins with aramid[J].Journal of Applied Polymer Science,2015,78(12):2198-2205.
[29]Kazuhisa S,Tsutomu F,Naoto K,et al.Novel functional polymers-poly(dimethylsiloxane)polyamide multiblock copolymer.3.Synthesis and surface-properties of disiloxane-aromatic polyamide multiblock copolymer[J].Journal of Applied Polymer Science,1996,59(7):1059-1065.
[30]Khan M S U,Akhter Z,Naz T,et al.Study on the preparation and properties of novel block copolymeric materials based on structurally modified organometallic as well as organic polyamides and polydimethylsiloxane[J].Polymer International,2013,62(2):319-334.
[31]Pei X,Chen G,Fang X.Preparation and characterization of poly(imide siloxane)block copolymers based on diphenylthioether dianhydride isomer mixtures[J].High Performance Polymers,2011,23(8):625-632.
[32]Pei X,Chen G,Fang X.Synthesis and properties of poly(imide siloxane)block copolymers with different block lengths[J].Journal of Applied Polymer Science,2013,129(6):3718-3727.
[33]Ghosh A,Banerjeea S,Schneider K,et al.Synthesis and characterization of fluorinated poly(imide siloxane)block copolymers[J].European Polymer Journal,2009,45(5):1561-1569.
[34]Ghosh A,Banerjee S,Liane H,et al.New fluorinated poly(imide siloxane)random and block copolymers with variation of siloxane loading[J].Journal of Macromolecular Science:Part A-Chemistry,2010,47(7):671-680.
[35]Ghosh A,Banerjee S,Voit B.Synthesis and characterization of fluorinated poly(imide siloxane)copolymers containing anthracene moieties in the main chain[J].High Performance Polymers,2010,22(1):28-41.
[36]Ghosh A,Banerjee S,Voit B.New silicone grafted copoly(ether imide)from 4,4-(hexafluoro-isopropylidene)diphthalic anhydride[J].Journal of Macromolecular Science:Part A-Chemistry,2010,47(11):1069-1074.
[37]Ghosh A,Sen S K,Dasgupta B,et al.Synthesis,characterization and gas transport properties of new poly(imide siloxane)copolymers from 4,4‘-(4,4’-isopropylidenediphenoxy)bis(phthalic anhydride)[J].Journal of Membrane Science,2010,364(1):211-218.
[38]Ghosh A,Banerjee S,Komber H,et al.New semifluorinated siloxane-grafted copolyimides:Synthesis and comparison with their linear analogs[J].Macromolecular Materials&Engineering,2011,296(5):391-400.
[39]Ghosh A,Banerjee S,Wang D Y,et al.Synthesis,characterization,and properties of new siloxane grafted copolyimides[J].Journal of Applied Polymer Science,2011,123(5):2959-2967.
[40]Ghosh A,Banerjee S.Structure-property co-relationship of fluorinated poly(imide-siloxane)s[J].Polymers for Advanced Technologies,2010,19(11):1486-1494.
[41]Ghosh A,Banerjee S.Thermal,mechanical,and dielectric properties of novel fluorinated copoly(imide siloxanes)[J].Journal of Applied Polymer Science,2010,109(4):2329-2340.
[42]Ghosh A,Banerjee S.Synthesis,characterization,and comparison of properties of novel fluorinated poly(imide siloxane)copolymers[J].Journal of Applied Polymer Science,2010,107(3):1831-1841.
[43]Ghosh A.Synthesis,characterization and properties of new fluorinated poly(imide siloxane)co-polymers from 4,4′-(hexafluoro-isopropylidene)diphthalic anhydride[J].Designed Monomers&Polymers,2010,13(3):221-236.
[44]Li L,Xu Y,Che J,et al.Transparent fluorinated poly(imide siloxane)copolymers with good adhesivity[J].Macromolecular Research,2017,25(11):1076-1084.
[45]Jiang X,Gu J,Shen Y,et al.New fluorinated siloxane-imide block copolymer membranes for application in organophilic pervaporation[J].Desalination,2011,265(1):74-80.
[46]Lamba N,Kimberly A,Cooper S,et al.Polyurethanes in biomedical applications[J].Advances in Experimental Medicine&Biology,1997,553:83.
[47]徐震宇.有机硅改性聚酯的合成及其粉末涂料性能[D].杭州:浙江大学,2003.
[48]Yilgor E,Sinmazcelik T,Yilgor I.Modification of polyolefins with silicone copolymers.Ⅱ.Thermal,mechanical,and tribological behavior of PP and HDPE blended with silicone copolymers[J].Journal of Applied Polymer Science,2002,84(3):535-540.
[49]Yilg?r E,Yilg?r ?,Süzer S.Surface properties of polyamides modified with reactive polydimethylsiloxane oligomers and copolymers[J].Polymer,2003,44(24):7271-7279.
[50]Ghosh A,Sen S K,Dasgupta B,et al.Synthesis,characterization and gas transport properties of new poly(imide siloxane)copolymers from 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride)[J].Journal of Membrane Science,2010,364(1-2):211-218.
[51]Jiang X,Gu J,Shen Y,et al.New fluorinated siloxane-imide block copolymer membranes for application in organophilic pervaporation[J].Desalination,2011,265(1-3):74-80.
[2]Bostick E E,Fessler W A.Condensation method for making multiple sequence organopolysiloxane block polymers:US3578726[P].1971.
[3]黄渝鸿,范敬辉,付强,等.三元嵌段共聚硅橡胶的合成与表征[J].绝缘材料,2008,41(2):15-18.Huang Y H,Fan J H,Fu Q,et al.Synthesis and characterization of tri-block copolymer of dimethyl siloxane diphenyl siloxane and methylvinyl siloxane[J].Insulating Materials,2008,41(2):15-18.
[4]He Y,Xie D,Zhang X.The structure,microphase-separated morphology,and property of polyurethanes and polyureas[J].Journal of Materials Science,2014,49(21):7339-7352.
[5]Paul,Donald R,Mark,et al.Fillers for polysiloxane(“silicone”)elastomers[J].Progress in Polymer Science,2015,35(7):893-901.
[6]Xiang W,Chen Q,Wang Y,et al.Improved air stability of perovskite hybrid solar cells via blending poly(dimethylsiloxane)-urea copolymers[J].Journal of Materials Chemistry A,2017,5(11):3695-3723.
[7]Yilgor I,Eynur T,Yilgor E,et al.Contribution of soft segment entanglement on the tensile properties of silicone-urea copolymers with low hard segment contents[J].Polymer,2009,50(19):4432-4437.
[8]Sheth J P,Yilgor E,Erenturk B,et al.Structure-property behavior of poly(dimethylsiloxane)based segmented polyurea copolymers modified with poly(propylene oxide)[J].Polymer,2005,46(19):8185-8193.
[9]Kinning D J.Bulk,surface,and interfacial characterization of silicone-polyurea segmented copolymers[J].Journal of Adhesion,2001,75(1):1-26.
[10]Zhao H,Hao T H,Hu G H,et al.Preparation and characterization of polyurethanes with cross-linked siloxane in the side chain by sol-gel reactions[J].Materials,2017,10(3):247.
[11]Gunatillake P A,Martin D J,Meijs G F,et al.Designing biostable polyurethane elastomers for biomedical implants[J].Cheminform,2003,34(41):545-557.
[12]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Effect of chain extender structure on the properties and morphology of polyurethanes based on H12MDI and mixed macrodiols(PDMS-PHMO)[J].Journal of Applied Polymer Science,2015,74(12):2979-2989.
[13]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Mixed macrodiol-based siloxane polyurethanes:Effect of the comacrodiol structure on properties and morphology[J].Journal of Applied Polymer Science,2015,78(5):1071-1082.
[14]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Low-modulus siloxane-based polyurethanes.I.Effect of the chain extender1,3-bis(4-hydroxybutyl)1,1,3,3-tetramethyldisiloxane(BHTD)on properties and morphology[J].Journal of Applied Polymer Science,2002,83(4):736-746.
[15]Adhikari R,Gunatillake P A,Bown M.Effect of polydimethylsiloxane macrodiol molecular weight on properties and morphology of polyurethane and polyurethaneurea[J].Journal of Applied Polymer Science,2010,90(6):1565-1573.
[16]Adhikari R,Gunatillake P A,Mccarthy S J,et al.Low-modulus siloxane-polyurethanes.Part II.Effect of chain extender structure on properties and morphology[J].Journal of Applied Polymer Science,2003,87(7):1092-1100.
[17]陆浩翔,江斌,蒋红梅,等.湿固化聚氨酯/有机硅嵌段共聚物的合成与性能[J].上海交通大学学报,2007,41(10):1679-1682.Lu H X,Jiang B,Jiang H M,et al.The synthesis and properties of moisture-cured polyurethane/polysiloxane copolymers[J].Journal of Shanghai Jiaotong University,2007,41(10):1679-1682.
[18]牛冰.聚酯型聚氨酯的合成与改性研究[D].秦皇岛:燕山大学,2016.
[19]Abduallah A B E,Mallon P E.Microscopic surface and bulk morphology of semicrystalline poly(dimethylsiloxane)-polyester copolymers[J].Journal of Applied Polymer Science,2010,115(3):1518-1533.
[20]Racles C,Cozan V,Cazacu M.New arylidene-siloxane polyesters[J].High Performance Polymers,2003,15(3):231-242.
[21]Carmen R,Airinei A,Cozan V,et al.New arylidene-siloxane polyethers:Liquid-crystalline and photosensitive properties[J].Journal of Applied Polymer Science,2003,90(11):3093-3099.
[22]Y?lg?r E,Y?lg?r?.Hydrogen bonding:A critical parameter in designing silicone copolymers[J].Polymer,2001,42(19):7953-7959.
[23]Lei Y,Li C,Fu X,et al.Synthesis and characterization of a high performance polyamide-6 elastomer based on poly(etherblock-amide)multiblock copolymer by reactive processing in torque rheometer[J].Advances in Polymer Technology,2017,37(6):1782-1789.
[24]Senshu K,Furuzono T,Koshizaki N,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.8.1 surface studies of aramid-silicone resin by means of XPS,Static SIMS,and TEM[J].Macromolecules,1997,30(30):4421-4428.
[25]Furuzono T,Yashima E,Kishida A,et al.A novel biomaterial:Poly(dimethylsiloxane)-polyamide multiblock copolymer I.Synthesis and evaluation of blood compatibility[J].Journal of Biomaterials Science Polymer Edition,1993,5(1-2):89.
[26]Kishida A,Furuzono T,Ohshige T A,et al.,Study of the surface properties of ultrathin films of poly(dimethylsiloxane)-polyamide multiblock copolymers[J].Macromolecular Materials&Engineering,1994.220(1):89-97.
[27]Furuzono T,Kishida A,Yanagi M,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.V.The interaction between biomolecules and the surface of aramid-silicone resins[J].Journal of Biomaterials Science Polymer Edition,1996,7(10):871.
[28]Kishida A,Kanda T,Furuzono T,et al.Novel functional polymers:Poly(dimethylsiloxane)-polyamide multiblock copolymer.IX.Surface properties of blend film of aramid-silicone resins with aramid[J].Journal of Applied Polymer Science,2015,78(12):2198-2205.
[29]Kazuhisa S,Tsutomu F,Naoto K,et al.Novel functional polymers-poly(dimethylsiloxane)polyamide multiblock copolymer.3.Synthesis and surface-properties of disiloxane-aromatic polyamide multiblock copolymer[J].Journal of Applied Polymer Science,1996,59(7):1059-1065.
[30]Khan M S U,Akhter Z,Naz T,et al.Study on the preparation and properties of novel block copolymeric materials based on structurally modified organometallic as well as organic polyamides and polydimethylsiloxane[J].Polymer International,2013,62(2):319-334.
[31]Pei X,Chen G,Fang X.Preparation and characterization of poly(imide siloxane)block copolymers based on diphenylthioether dianhydride isomer mixtures[J].High Performance Polymers,2011,23(8):625-632.
[32]Pei X,Chen G,Fang X.Synthesis and properties of poly(imide siloxane)block copolymers with different block lengths[J].Journal of Applied Polymer Science,2013,129(6):3718-3727.
[33]Ghosh A,Banerjeea S,Schneider K,et al.Synthesis and characterization of fluorinated poly(imide siloxane)block copolymers[J].European Polymer Journal,2009,45(5):1561-1569.
[34]Ghosh A,Banerjee S,Liane H,et al.New fluorinated poly(imide siloxane)random and block copolymers with variation of siloxane loading[J].Journal of Macromolecular Science:Part A-Chemistry,2010,47(7):671-680.
[35]Ghosh A,Banerjee S,Voit B.Synthesis and characterization of fluorinated poly(imide siloxane)copolymers containing anthracene moieties in the main chain[J].High Performance Polymers,2010,22(1):28-41.
[36]Ghosh A,Banerjee S,Voit B.New silicone grafted copoly(ether imide)from 4,4-(hexafluoro-isopropylidene)diphthalic anhydride[J].Journal of Macromolecular Science:Part A-Chemistry,2010,47(11):1069-1074.
[37]Ghosh A,Sen S K,Dasgupta B,et al.Synthesis,characterization and gas transport properties of new poly(imide siloxane)copolymers from 4,4‘-(4,4’-isopropylidenediphenoxy)bis(phthalic anhydride)[J].Journal of Membrane Science,2010,364(1):211-218.
[38]Ghosh A,Banerjee S,Komber H,et al.New semifluorinated siloxane-grafted copolyimides:Synthesis and comparison with their linear analogs[J].Macromolecular Materials&Engineering,2011,296(5):391-400.
[39]Ghosh A,Banerjee S,Wang D Y,et al.Synthesis,characterization,and properties of new siloxane grafted copolyimides[J].Journal of Applied Polymer Science,2011,123(5):2959-2967.
[40]Ghosh A,Banerjee S.Structure-property co-relationship of fluorinated poly(imide-siloxane)s[J].Polymers for Advanced Technologies,2010,19(11):1486-1494.
[41]Ghosh A,Banerjee S.Thermal,mechanical,and dielectric properties of novel fluorinated copoly(imide siloxanes)[J].Journal of Applied Polymer Science,2010,109(4):2329-2340.
[42]Ghosh A,Banerjee S.Synthesis,characterization,and comparison of properties of novel fluorinated poly(imide siloxane)copolymers[J].Journal of Applied Polymer Science,2010,107(3):1831-1841.
[43]Ghosh A.Synthesis,characterization and properties of new fluorinated poly(imide siloxane)co-polymers from 4,4′-(hexafluoro-isopropylidene)diphthalic anhydride[J].Designed Monomers&Polymers,2010,13(3):221-236.
[44]Li L,Xu Y,Che J,et al.Transparent fluorinated poly(imide siloxane)copolymers with good adhesivity[J].Macromolecular Research,2017,25(11):1076-1084.
[45]Jiang X,Gu J,Shen Y,et al.New fluorinated siloxane-imide block copolymer membranes for application in organophilic pervaporation[J].Desalination,2011,265(1):74-80.
[46]Lamba N,Kimberly A,Cooper S,et al.Polyurethanes in biomedical applications[J].Advances in Experimental Medicine&Biology,1997,553:83.
[47]徐震宇.有机硅改性聚酯的合成及其粉末涂料性能[D].杭州:浙江大学,2003.
[48]Yilgor E,Sinmazcelik T,Yilgor I.Modification of polyolefins with silicone copolymers.Ⅱ.Thermal,mechanical,and tribological behavior of PP and HDPE blended with silicone copolymers[J].Journal of Applied Polymer Science,2002,84(3):535-540.
[49]Yilg?r E,Yilg?r ?,Süzer S.Surface properties of polyamides modified with reactive polydimethylsiloxane oligomers and copolymers[J].Polymer,2003,44(24):7271-7279.
[50]Ghosh A,Sen S K,Dasgupta B,et al.Synthesis,characterization and gas transport properties of new poly(imide siloxane)copolymers from 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride)[J].Journal of Membrane Science,2010,364(1-2):211-218.
[51]Jiang X,Gu J,Shen Y,et al.New fluorinated siloxane-imide block copolymer membranes for application in organophilic pervaporation[J].Desalination,2011,265(1-3):74-80.
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