草海湖沉积物中重金属污染现状及生态风险评价
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摘要
贵州草海湖是典型的高原天然淡水湖泊,属于长江上游金沙江支流的上源湖泊,研究其沉积物中重金属分布特征及生态风险评价对该区域及下游的水质监控与污染防治具有重要意义.2017年7月采集贵州草海湖柱状沉积物,采用电感耦合等离子发射光谱仪法和双道原子荧光光度计法分析沉积物中Zn、Cd、Ni、Fe、V、Cr、Pb、Cu、As等9种重金属元素的质量分数,并利用地累积指数法、富集系数法和潜在生态风险指数法进行重金属污染评价.结果表明:草海湖表层沉积物各重金属质量分数平均值表现为w(Fe)(31 400.00 mg/kg)>w(Zn)(219.18 mg/kg)>w(V)(59.76 mg/kg)>w(Cr)(56.16 mg/kg)>w(Pb)(54.01 mg/kg)>w(Ni)(33.58 mg/kg)>w(Cu)(20.35 mg/kg)>w(As)(15.41 mg/kg)>w(Cd)(0.84 mg/kg).表层(0～10 cm)沉积物中w(Fe)、w(Cr)、w(V)、w(As)、w(Cu)、w(Ni)分布较均匀,其元素主要来源于岩石风化、土壤侵蚀等自然源;w(Zn)、w(Cd)、w(Pb)分布相对离散,主要来源于农业、炼锌业和交通运输等人为源;在垂直(0～25 cm)方向上,w(Pb)、w(Cu)、w(V)、w(Ni)以波动型为主,w(Zn)、w(Cd)、w(As)主要为稳定型,w(Cr)和w(Fe)为富集型.重金属污染评价结果显示,草海湖沉积物中元素Zn、Pb均为偏中度污染、Cd为中度污染,其潜在生态风险高低表现为下游>上游>中游.研究显示,草海湖下游区域为中等潜在生态风险,Cd为主要的潜在生态风险因子,重金属的质量分数主要受土法炼锌和农业施肥等人为活动的影响.
The Caohai lake in Guizhou Province is a typical natural freshwater lake in the plateau,which belongs to the upper source lake of Jinsha River tributary in the upper reaches of the Yangtze River. Studying the heavy metals in the sediments is important for understanding the monitoring of water quality and its pollution in the region and downstream area. In July 2017,the columnar sediment samples were collected from the Caohai Lake,and the mass fraction of Zn,Cd,Ni,Fe,V,Cr,Pb,Cu and As were analyzed by using an inductively coupled plasma emission spectrometer with dual channel atomic fluorescence photometer. The pollution of the nine heavy metals was evaluated by the cumulative index method,the enrichment coefficient method and potential ecological risk index. The results showed that the average mass fraction of the heavy metals in Caohai Lake surface sediment was w( Fe)( 31,400. 00 mg/kg),w( Zn)( 219. 18 mg/kg),w( V)( 59. 76 mg/kg),w( Cr)( 56. 16 mg/kg),w( Pb)( 54. 01 mg/kg),w( Ni)( 33. 58 mg/kg),w( Cu)( 20. 35 mg/kg),w( As)( 15. 41 mg/kg),w( Cd)( 0. 84 mg/kg). The distribution of w( Fe),w( Cr),w( V),w( As),w( Cu) and w( Ni) in the surface sediments( 0-10 cm) was relatively uniform,and the elements mainly came from natural sources such as rock weathering and soil erosion. The distribution of w( Zn),w( Cd) and w( Pb) was relatively discrete,which mainly came from human sources such asagriculture,Zn smelting industry and transportation. As for the vertical( 0-25 cm) direction,w( Pb),w( Cu),w( V) and w( Ni) were mainly undulatory type,w( Zn),w( Cd) and w( As) were mainly stable type,while w( Cr) and w( Fe) were enrichment type. The heavy metal pollution evaluation results showed that the Zn,Pb and Cd in the sediments of Caohai Lake were moderate pollutants,and the potential ecological risk was downstream,upstream and midstream from high to low. The study indicated that the downstream area of the Caohai Lake was a moderate potential ecological risk,Cd was the main potential ecological risk factor. Meanwhile,the heavy metal quality score was mainly affected by human activities,such as Zn smelting and agricultural fertilization.
The Caohai lake in Guizhou Province is a typical natural freshwater lake in the plateau,which belongs to the upper source lake of Jinsha River tributary in the upper reaches of the Yangtze River. Studying the heavy metals in the sediments is important for understanding the monitoring of water quality and its pollution in the region and downstream area. In July 2017,the columnar sediment samples were collected from the Caohai Lake,and the mass fraction of Zn,Cd,Ni,Fe,V,Cr,Pb,Cu and As were analyzed by using an inductively coupled plasma emission spectrometer with dual channel atomic fluorescence photometer. The pollution of the nine heavy metals was evaluated by the cumulative index method,the enrichment coefficient method and potential ecological risk index. The results showed that the average mass fraction of the heavy metals in Caohai Lake surface sediment was w( Fe)( 31,400. 00 mg/kg),w( Zn)( 219. 18 mg/kg),w( V)( 59. 76 mg/kg),w( Cr)( 56. 16 mg/kg),w( Pb)( 54. 01 mg/kg),w( Ni)( 33. 58 mg/kg),w( Cu)( 20. 35 mg/kg),w( As)( 15. 41 mg/kg),w( Cd)( 0. 84 mg/kg). The distribution of w( Fe),w( Cr),w( V),w( As),w( Cu) and w( Ni) in the surface sediments( 0-10 cm) was relatively uniform,and the elements mainly came from natural sources such as rock weathering and soil erosion. The distribution of w( Zn),w( Cd) and w( Pb) was relatively discrete,which mainly came from human sources such asagriculture,Zn smelting industry and transportation. As for the vertical( 0-25 cm) direction,w( Pb),w( Cu),w( V) and w( Ni) were mainly undulatory type,w( Zn),w( Cd) and w( As) were mainly stable type,while w( Cr) and w( Fe) were enrichment type. The heavy metal pollution evaluation results showed that the Zn,Pb and Cd in the sediments of Caohai Lake were moderate pollutants,and the potential ecological risk was downstream,upstream and midstream from high to low. The study indicated that the downstream area of the Caohai Lake was a moderate potential ecological risk,Cd was the main potential ecological risk factor. Meanwhile,the heavy metal quality score was mainly affected by human activities,such as Zn smelting and agricultural fertilization.
引文
[1]郭晶,李利强,黄代中,等.洞庭湖表层水和底泥中重金属污染状况及其变化趋势[J].环境科学研究,2016,29(1):44-51.GUO Jing,LI Liqiang,HUANG Daizhong,et al.Assessment of heavy metal pollution in surface water and sediment of Dongting Lake[J].Research of Environmental Sciences,2016,29(1):44-51.
[2] MARTIN E,JARA M,SOTO J,et al. Bulk and bioavailable heavy metals(Cd,Cu,Pb,and Zn)in surface sediment from Mazatlán Harbor SE Gulf of California[J]. Bulletin of Environmental Contamination&Toxicology,2008,80:150-153.
[3]韩倩,张丽娟,胡国成,等.中山高平工业园区周边水体沉积物中重金属污染特征及生态风险评价[J].农业环境科学学报,2015,34(8):1563-1568.HAN Qian,ZHANG Lijuan,HU Guocheng,et al. Pollution and ecological risk assessment of heavy metals in surface sediments of water bodies surrounding Gaoping Industrial Park of Zhongshan City[J].Journal of Agro-Environment Science,2015,34(8):1563-1568.
[4] BRULAND K W,BERTINE K,KOIDE M,et al. History of metal pollution in southern California coastal zone[J]. Environmental Science&Technology,1974,8(5):425-432.
[5] LIU Minxia,YANG Yuyi,YUN Xiaoyan,et al. Distribution and ecological assessment of heavy metals in surface sediments of the East Lake,China[J].Ecotoxicology,2014,23(1):92-101.
[6]蒋豫,吴召仕,赵中华,等.阳澄湖表层沉积物中氮磷及重金属的空间分布特征及污染评价[J].环境科学研究,2016,29(11):1590-1599.JIANG Yu,WU Zhaoshi,ZHAO Zhonghua,et al.Spatial distribution and pollution assessment of nitrogen,phosphorus and heavy metals in surface sediments of Lake Yangcheng,Jiangsu Province,China[J].Research of Environmental Sciences,2016,29(11):1590-1599.
[7] HILLMAN A L,ABBOTT M B,YU J,et al.Environmental Legacy of copper metallurgy and mongol silver smelting recorded in Yunnan Lake sediments[J].Environmental Science&Technology,2015,49(6):3349-3357.
[8] HU Bingqi,LI Guogang,LI Jun,et al. Spatial distribution and ecotoxicological risk assessment of heavy metals in surface sediments of the southern Bohai Bay,China[J]. Environmental Science and Pollution Research,2013,20(6):4099-4110.
[9] EFFENDI H,WARDIATNO Y,KAWAROE M,et al. Spatial distribution and ecological risk assessment of heavy metal on surface sediment in west part of Java Sea[J]. Earth and Environmental Science,2017,54(1):1-10.
[10] TRIFUOGGI M,DONADIO C,MANGONI O. Distribution and enrichment of trace metals in surface marine sediments in the Gulf of Pozzuoli and off the coast of the brownfield metallurgical site of Ilva of Bagnoli(Campania,Italy)[J]. Marine Pollution Bulletin,2017,124(1):502-511.
[11] BRIKI M,JI Hongbing,LI Cai,et al.Characterization,distribution,and risk assessment of heavy metals in agricultural soil and products around mining and smelting areas of Hezhang,China[J].Environmental Monitoring&Assessment,2015,187(12):1-21.
[12] IIBRAHIN S,AMANSOUR A,SHAMY M,et al. Risk assessment and implication of human exposure to road dust heavy metals in Jeddah,Saudi Arabia[J]. International Journal of Environmental Research and Public Health,2017,15(1):15-36.
[13] LIANG Jie,LIU Jiayu,YUAN Xingzhong,et al.Spatial and temporal variation of heavy metal risk and source in sediments of Dongting Lake wetland,mid-south China[J]. Journal of Environmental Science&Health Part A:Toxic/Hazardous Substances&Environmental Engineering,2015,50(1):100-108.
[14]易昊旻,周生路,吴绍华,等.基于正态模糊数的区域土壤重金属污染综合评价[J].环境科学学报,2013,33(4):1127-1134.YI Haomin,ZHOU Shenglu,WU Shaohua,et al. An integrated assessment for regional heavy metal contamination in soil based on normal fuzzy number[J]. Acta Scientiae Circumstantiae,2013,33(4):1127-1134.
[15]潘少兵,任晓东.草海国家级自然保护区水生植物群落的数量分类与排序分析[J].生物学杂志,2010,27(5):60-64.PAN Shaobing, REN Xiaodong. Ananalysis on quantitative classification and ordination of aquatic plant communities in Caohai Natural Reserve[J].Journal of Biology,2010,27(5):60-64.
[16]钱晓莉,冯新斌,闭向阳,等.贵州省草海表层水体和沉积物间隙水中汞的含量和形态分布初步研究[J].湖泊科学,2008,20(5):563-570.QIAN Xiaoli,FENG Xinbin,BI Xiangyang,et al. Concentrations and distributions of mercury species in surface water and porewater of lake Caohai,Guizhou Province[J]. Journal of Lake Sciences,2008,20(5):563-570.
[17]韩会庆,苏志华,罗绪强,等. 2000—2010年草海自然保护区生境质量变化[J].西南林业大学学报,2016,36(5):157-163.HANG Huiqin,SU Zhihua,LUO Xuqiang,et al. Habitat quality change in Caohai nature reserve from 2000 to 2010[J]. Journal of Southwest Forestry University,2016,36(5):157-163.
[18] PRESLEY B J,TAYLOR R J,BOOTHE P N. Trace metal concentrations in sediments of the eastern Mississippi Bight[J].Marine Environmental Research,1992,33(4):267-282.
[19]甘国娟,刘伟,邱亚群,等.湘中某冶炼区农田土壤重金属污染及生态风险评价[J].环境化学,2013,32(1):132-138.GAN Guojuan,LIU Wei,QIU Yaqun,et al. Heavy metal pollution and ecological risk assessment of the paddy soils in a smelting area in central Hunan[J].Environmental Chemistry,2013,32(1):132-138.
[20] MLLER G. Index of geoaccumulation in sediments of the Rhine River[J].Geojournal,1969,2(3):108-118.
[21]宁增平,蓝小龙,黄正玉,等.贺江水系沉积物重金属空间分布特征/来源及潜在生态风险[J].中国环境科学,2017,37(8):3036-3047.NING Zengping,LAN Xiaolong,HUANG Zhengyu,et al. Spatial distribution characteristics/sources and potential ecological risk of heavy metals in sediments of the Hejiang River[J]. China Environmental Science,2017,37(8):3036-3047.
[22] CHABUKDHARA M,NEMA A K. Assessment of heavy metal contamination in Hindon River sediments:a chemometric and geochemical approach[J].Chemosphere,2012,87(8):945-953.
[23] ACEVEO-FIGUEROA D,JIMENEZ B D,RODRIGUEZ-SIERRA C J.Trace metals in sediments of two estuarine lagoons from Puerto Rico[J].Environmental Pollution,2006,141(2):336-342.
[24] HAKANSON L. An ecological risk index for aquatic pollution control,a sedimentological approach[J]. Water Research,1980,14:975-1001.
[25] LI Fei,HUANG Jinhui,ZENG Guangming,et al. Spatial risk assessment and sources identification of heavy metals in surface sediments from Dongting Lake,Middle China[J]. Journal of Geochemical Exploration,2013,132(3):75-83.
[26]中华人民共和国环境保护部.GB 15618—1995土壤环境质量标准[S].北京:中国环境科学出版社,2006.
[27]闭向阳.西南土法炼锌导致的环境重金属污染研究[D].贵阳:中国科学院地球化学研究所,2007.
[28]林文杰,肖唐付,周晚春,等.黔西土法炼锌区Pb/Zn/Cd地球化学迁移特征[J].环境科学,2009,30(7):2065-2070.LIN Wenjie,XIAO Tangfu,ZHOU Wanchun,et al. Environmental concerns on geochemical mobility of Pb/Zn/Cd smelting areas:western Guizhou,China[J],Environmental Science,2009,30(7):2065-2070.
[29]李仲根,冯新斌,闭向阳,等.贵州省某土法炼锌点土壤重金属污染现状[J].生态学杂志,2011,30(5):897-901.LI Zhonggen,FENG Xinbin,BI Xiangyang,et al. Present situation of soil heavy metals contamination in an artisanal zinc-smelting zone of Guizhou,China[J]. Chinese Journal of Ecology,2011,30(5):897-901.
[30] WILDING L P. Spatial variability:its documentation,accommodation and implication to soil survey[J]. Spatial Variations,1985:166-194.
[31]张莉,袁丽娟,张大文,等.鄱阳湖丰水期悬浮颗粒物重金属的空间分布格局[J].环境化学,2017,36(10):2219-2226.ZHANG Li,YUAN Lijuan,ZHANG Dawen,et al. Spatial variation of heavy metals in suspended particulate matters of Poyang Lake[J].Environmental Chemistry,2017,36(10):2219-2226.
[32]闫兴成,杨晓薇,黄烯茜,等.太湖主要入湖河口表层沉积物重金属分布特征及风险评价[J].生态环境学报,2016,25(9):1515-1521.YAN Xingcheng, YANG Xiaowei, HUANG Xiqian, et al.Distribution and risk assessment of heavy metals in the surface estuarine sediments of main inflow rivers in Taihu Lake[J].Ecology and Environmental Sciences,2016,25(9):1515-1521.
[33]刘成,邵世光,范成新,等.巢湖重污染汇流湾区沉积物重金属污染特征及风险评价[J].中国环境科学,2014,34(4):1031-1037.LIU Cheng,SHAO Shiguang,FAN Chengxin,et al. Pollution status and risk assessment of heavy metal in the sediment of the severe polluted confluence area of Lake Chaohu[J]. China Environmental Science,2014,34(4):1031-1037.
[34]谢意南,欧阳美凤,黄代中,等.洞庭湖及其入湖口沉积物中重金属的污染特征、来源与生态风险[J].环境化学,2017,36(10):2253-2264.XIE Yinan,OUYANG Meifeng,HUANG Daizhong,et al. Pollution characteristics,sources and ecological risk of heavy metals in sediments from Dongting Lake and its Lake inlets[J].Environmental Chemistry,2017,36(10):2253-2264.
[35]余辉,张文斌,余建平.洪泽湖表层沉积物重金属分布特征及其风险评价[J].环境科学,2011,32(2):437-444.YU Hui,ZHANG Wenbin,YU Jianping. Distribution and potential ecological risk assessment of heavy metals in surface sediments of Hongze Lake[J].Environmental Science,2011,32(2):437-444.
[36]刘勇,朱元荣,吴丰昌,等.滇池沉积物中重金属污染特征及其生态风险评估[J].生态环境学报,2014,23(7):1181-1186.LIU Yong,ZHU Yuanrong,WU Fengchang,et al. Pollution characteristics and ecological risk assessment of heavy metals in sediments of Dianchi Lake[J]. Ecology and Environmental Sciences,2014,23(7):1181-1186.
[37]王丹,孟鑫,张洪,等.梁子湖沉积物重金属污染现状分析及风险评价[J].环境科学学报,2016,36(6):1901-1909.WANG Dan,MENG Xin,ZHANG Hong,et al. Pollution analysis and ecological risk assessment of heavy metals in sediments of Liangzi Lake[J]. Acta Scientiae Circumstantiae,2016,36(6):1901-1909.
[38] BASTAMI K D,NEYESTANI M R,SHEMIRANI F,et al. Heavy metal pollution assessment in relation to sediment properties in the coastal sediments of the southern Caspian Sea[J].Marine Pollution Bulletin,2015,92(12):237-243.
[39] YAN Changzhou,LI Qingzhao,ZHANG Xian,et al. Mobility and ecological risk assessment of heavy metals in surface sediments of Xiamen Bay and its adjacent areas,China[J].Environmental Earth Sciences,2010,60(7):1469-1479.
[40] ABATA E O,AIYEANMI A F,ADEBAYO A O,et al.Assessment of heavy metal contamination and sediment quality in the urban river:a case of Ala River in southwestern-Nigeria[J].IOSR Journal of Applied Chemistry,2013,4(3):56-63.
[41]朱先芳,唐磊,季宏兵,等.北京北部水系沉积物中重金属的研究[J].环境科学学报,2010,30(12):2553-2562.ZHU Xianfang,TANG Lei,JI Hongbing,et al. Analysis of heavy metals in sediments of the water system in the north of Beijing[J].Acta Scientiae Circumstantiae,2010,30(12):2553-2562.
[42]葛晓立,刘晓端,潘晓川,等.密云水库水体的地球化学特征[J].岩矿测试,2003,22(1):44-48.GE Xiaoli,LIU Xiaoduan,PAN Xiaochun,et al. The geochemical characteristics of water body in Miyun Reservoir[J]. Rock and mineral ananlysis,2003,22(1):44-48.
[43]袁旭,赵为武,王萍.贵州草海农业土壤重金属污染的生态危害评价[J].贵州农业科学,2013,41(11):190-193.YUAN Xu,ZHAO Weiwu,WANG Ping.Eclogical risk assessment of heavy metal in agricultural soil in Caohai Guizhou[J]. Guizhou Agricultural Science,2013,41(11):190-193.
[44] GRAY C W,MCLAREN R G,ROBERTS A H C,et al.The effect of long-term phosphatic fertilizer applications on the amounts and forms of cadmium in soils under pasture in New Zealand[J].Nutrient Cycling in Agroecosystems,1999,54(3):267-277.
[45] SINGH H,PANDEY R,SINGH S K,et al. Assessment of heavy metal contamination in the sediment of the River Ghaghara,a major tributary of the River Ganga in Northern India[J]. Applied Water Science,2017,7(7):4133-4149.
[46] ALEKANDER-KWATERCZAK U, HELIO-RYBICKA E,Contaminated sediments as a potential source of Zn,Pb,and Cd for a river system in the historical metalliferous ore mining and smelting industry area of South Poland[J]. Journal of Soils&Sediments,2009,9(1):13-22.
[47] LI Ping,ZHANG Junfeng,WANG Jianxu,et al.Heavy metal(loid)pollution in mine wastes of a Carlin-type gold mine in southwestern Guizhou,China and its environmental impacts[J]. Acta Geochimica,2015,34(3):311-319.
[2] MARTIN E,JARA M,SOTO J,et al. Bulk and bioavailable heavy metals(Cd,Cu,Pb,and Zn)in surface sediment from Mazatlán Harbor SE Gulf of California[J]. Bulletin of Environmental Contamination&Toxicology,2008,80:150-153.
[3]韩倩,张丽娟,胡国成,等.中山高平工业园区周边水体沉积物中重金属污染特征及生态风险评价[J].农业环境科学学报,2015,34(8):1563-1568.HAN Qian,ZHANG Lijuan,HU Guocheng,et al. Pollution and ecological risk assessment of heavy metals in surface sediments of water bodies surrounding Gaoping Industrial Park of Zhongshan City[J].Journal of Agro-Environment Science,2015,34(8):1563-1568.
[4] BRULAND K W,BERTINE K,KOIDE M,et al. History of metal pollution in southern California coastal zone[J]. Environmental Science&Technology,1974,8(5):425-432.
[5] LIU Minxia,YANG Yuyi,YUN Xiaoyan,et al. Distribution and ecological assessment of heavy metals in surface sediments of the East Lake,China[J].Ecotoxicology,2014,23(1):92-101.
[6]蒋豫,吴召仕,赵中华,等.阳澄湖表层沉积物中氮磷及重金属的空间分布特征及污染评价[J].环境科学研究,2016,29(11):1590-1599.JIANG Yu,WU Zhaoshi,ZHAO Zhonghua,et al.Spatial distribution and pollution assessment of nitrogen,phosphorus and heavy metals in surface sediments of Lake Yangcheng,Jiangsu Province,China[J].Research of Environmental Sciences,2016,29(11):1590-1599.
[7] HILLMAN A L,ABBOTT M B,YU J,et al.Environmental Legacy of copper metallurgy and mongol silver smelting recorded in Yunnan Lake sediments[J].Environmental Science&Technology,2015,49(6):3349-3357.
[8] HU Bingqi,LI Guogang,LI Jun,et al. Spatial distribution and ecotoxicological risk assessment of heavy metals in surface sediments of the southern Bohai Bay,China[J]. Environmental Science and Pollution Research,2013,20(6):4099-4110.
[9] EFFENDI H,WARDIATNO Y,KAWAROE M,et al. Spatial distribution and ecological risk assessment of heavy metal on surface sediment in west part of Java Sea[J]. Earth and Environmental Science,2017,54(1):1-10.
[10] TRIFUOGGI M,DONADIO C,MANGONI O. Distribution and enrichment of trace metals in surface marine sediments in the Gulf of Pozzuoli and off the coast of the brownfield metallurgical site of Ilva of Bagnoli(Campania,Italy)[J]. Marine Pollution Bulletin,2017,124(1):502-511.
[11] BRIKI M,JI Hongbing,LI Cai,et al.Characterization,distribution,and risk assessment of heavy metals in agricultural soil and products around mining and smelting areas of Hezhang,China[J].Environmental Monitoring&Assessment,2015,187(12):1-21.
[12] IIBRAHIN S,AMANSOUR A,SHAMY M,et al. Risk assessment and implication of human exposure to road dust heavy metals in Jeddah,Saudi Arabia[J]. International Journal of Environmental Research and Public Health,2017,15(1):15-36.
[13] LIANG Jie,LIU Jiayu,YUAN Xingzhong,et al.Spatial and temporal variation of heavy metal risk and source in sediments of Dongting Lake wetland,mid-south China[J]. Journal of Environmental Science&Health Part A:Toxic/Hazardous Substances&Environmental Engineering,2015,50(1):100-108.
[14]易昊旻,周生路,吴绍华,等.基于正态模糊数的区域土壤重金属污染综合评价[J].环境科学学报,2013,33(4):1127-1134.YI Haomin,ZHOU Shenglu,WU Shaohua,et al. An integrated assessment for regional heavy metal contamination in soil based on normal fuzzy number[J]. Acta Scientiae Circumstantiae,2013,33(4):1127-1134.
[15]潘少兵,任晓东.草海国家级自然保护区水生植物群落的数量分类与排序分析[J].生物学杂志,2010,27(5):60-64.PAN Shaobing, REN Xiaodong. Ananalysis on quantitative classification and ordination of aquatic plant communities in Caohai Natural Reserve[J].Journal of Biology,2010,27(5):60-64.
[16]钱晓莉,冯新斌,闭向阳,等.贵州省草海表层水体和沉积物间隙水中汞的含量和形态分布初步研究[J].湖泊科学,2008,20(5):563-570.QIAN Xiaoli,FENG Xinbin,BI Xiangyang,et al. Concentrations and distributions of mercury species in surface water and porewater of lake Caohai,Guizhou Province[J]. Journal of Lake Sciences,2008,20(5):563-570.
[17]韩会庆,苏志华,罗绪强,等. 2000—2010年草海自然保护区生境质量变化[J].西南林业大学学报,2016,36(5):157-163.HANG Huiqin,SU Zhihua,LUO Xuqiang,et al. Habitat quality change in Caohai nature reserve from 2000 to 2010[J]. Journal of Southwest Forestry University,2016,36(5):157-163.
[18] PRESLEY B J,TAYLOR R J,BOOTHE P N. Trace metal concentrations in sediments of the eastern Mississippi Bight[J].Marine Environmental Research,1992,33(4):267-282.
[19]甘国娟,刘伟,邱亚群,等.湘中某冶炼区农田土壤重金属污染及生态风险评价[J].环境化学,2013,32(1):132-138.GAN Guojuan,LIU Wei,QIU Yaqun,et al. Heavy metal pollution and ecological risk assessment of the paddy soils in a smelting area in central Hunan[J].Environmental Chemistry,2013,32(1):132-138.
[20] MLLER G. Index of geoaccumulation in sediments of the Rhine River[J].Geojournal,1969,2(3):108-118.
[21]宁增平,蓝小龙,黄正玉,等.贺江水系沉积物重金属空间分布特征/来源及潜在生态风险[J].中国环境科学,2017,37(8):3036-3047.NING Zengping,LAN Xiaolong,HUANG Zhengyu,et al. Spatial distribution characteristics/sources and potential ecological risk of heavy metals in sediments of the Hejiang River[J]. China Environmental Science,2017,37(8):3036-3047.
[22] CHABUKDHARA M,NEMA A K. Assessment of heavy metal contamination in Hindon River sediments:a chemometric and geochemical approach[J].Chemosphere,2012,87(8):945-953.
[23] ACEVEO-FIGUEROA D,JIMENEZ B D,RODRIGUEZ-SIERRA C J.Trace metals in sediments of two estuarine lagoons from Puerto Rico[J].Environmental Pollution,2006,141(2):336-342.
[24] HAKANSON L. An ecological risk index for aquatic pollution control,a sedimentological approach[J]. Water Research,1980,14:975-1001.
[25] LI Fei,HUANG Jinhui,ZENG Guangming,et al. Spatial risk assessment and sources identification of heavy metals in surface sediments from Dongting Lake,Middle China[J]. Journal of Geochemical Exploration,2013,132(3):75-83.
[26]中华人民共和国环境保护部.GB 15618—1995土壤环境质量标准[S].北京:中国环境科学出版社,2006.
[27]闭向阳.西南土法炼锌导致的环境重金属污染研究[D].贵阳:中国科学院地球化学研究所,2007.
[28]林文杰,肖唐付,周晚春,等.黔西土法炼锌区Pb/Zn/Cd地球化学迁移特征[J].环境科学,2009,30(7):2065-2070.LIN Wenjie,XIAO Tangfu,ZHOU Wanchun,et al. Environmental concerns on geochemical mobility of Pb/Zn/Cd smelting areas:western Guizhou,China[J],Environmental Science,2009,30(7):2065-2070.
[29]李仲根,冯新斌,闭向阳,等.贵州省某土法炼锌点土壤重金属污染现状[J].生态学杂志,2011,30(5):897-901.LI Zhonggen,FENG Xinbin,BI Xiangyang,et al. Present situation of soil heavy metals contamination in an artisanal zinc-smelting zone of Guizhou,China[J]. Chinese Journal of Ecology,2011,30(5):897-901.
[30] WILDING L P. Spatial variability:its documentation,accommodation and implication to soil survey[J]. Spatial Variations,1985:166-194.
[31]张莉,袁丽娟,张大文,等.鄱阳湖丰水期悬浮颗粒物重金属的空间分布格局[J].环境化学,2017,36(10):2219-2226.ZHANG Li,YUAN Lijuan,ZHANG Dawen,et al. Spatial variation of heavy metals in suspended particulate matters of Poyang Lake[J].Environmental Chemistry,2017,36(10):2219-2226.
[32]闫兴成,杨晓薇,黄烯茜,等.太湖主要入湖河口表层沉积物重金属分布特征及风险评价[J].生态环境学报,2016,25(9):1515-1521.YAN Xingcheng, YANG Xiaowei, HUANG Xiqian, et al.Distribution and risk assessment of heavy metals in the surface estuarine sediments of main inflow rivers in Taihu Lake[J].Ecology and Environmental Sciences,2016,25(9):1515-1521.
[33]刘成,邵世光,范成新,等.巢湖重污染汇流湾区沉积物重金属污染特征及风险评价[J].中国环境科学,2014,34(4):1031-1037.LIU Cheng,SHAO Shiguang,FAN Chengxin,et al. Pollution status and risk assessment of heavy metal in the sediment of the severe polluted confluence area of Lake Chaohu[J]. China Environmental Science,2014,34(4):1031-1037.
[34]谢意南,欧阳美凤,黄代中,等.洞庭湖及其入湖口沉积物中重金属的污染特征、来源与生态风险[J].环境化学,2017,36(10):2253-2264.XIE Yinan,OUYANG Meifeng,HUANG Daizhong,et al. Pollution characteristics,sources and ecological risk of heavy metals in sediments from Dongting Lake and its Lake inlets[J].Environmental Chemistry,2017,36(10):2253-2264.
[35]余辉,张文斌,余建平.洪泽湖表层沉积物重金属分布特征及其风险评价[J].环境科学,2011,32(2):437-444.YU Hui,ZHANG Wenbin,YU Jianping. Distribution and potential ecological risk assessment of heavy metals in surface sediments of Hongze Lake[J].Environmental Science,2011,32(2):437-444.
[36]刘勇,朱元荣,吴丰昌,等.滇池沉积物中重金属污染特征及其生态风险评估[J].生态环境学报,2014,23(7):1181-1186.LIU Yong,ZHU Yuanrong,WU Fengchang,et al. Pollution characteristics and ecological risk assessment of heavy metals in sediments of Dianchi Lake[J]. Ecology and Environmental Sciences,2014,23(7):1181-1186.
[37]王丹,孟鑫,张洪,等.梁子湖沉积物重金属污染现状分析及风险评价[J].环境科学学报,2016,36(6):1901-1909.WANG Dan,MENG Xin,ZHANG Hong,et al. Pollution analysis and ecological risk assessment of heavy metals in sediments of Liangzi Lake[J]. Acta Scientiae Circumstantiae,2016,36(6):1901-1909.
[38] BASTAMI K D,NEYESTANI M R,SHEMIRANI F,et al. Heavy metal pollution assessment in relation to sediment properties in the coastal sediments of the southern Caspian Sea[J].Marine Pollution Bulletin,2015,92(12):237-243.
[39] YAN Changzhou,LI Qingzhao,ZHANG Xian,et al. Mobility and ecological risk assessment of heavy metals in surface sediments of Xiamen Bay and its adjacent areas,China[J].Environmental Earth Sciences,2010,60(7):1469-1479.
[40] ABATA E O,AIYEANMI A F,ADEBAYO A O,et al.Assessment of heavy metal contamination and sediment quality in the urban river:a case of Ala River in southwestern-Nigeria[J].IOSR Journal of Applied Chemistry,2013,4(3):56-63.
[41]朱先芳,唐磊,季宏兵,等.北京北部水系沉积物中重金属的研究[J].环境科学学报,2010,30(12):2553-2562.ZHU Xianfang,TANG Lei,JI Hongbing,et al. Analysis of heavy metals in sediments of the water system in the north of Beijing[J].Acta Scientiae Circumstantiae,2010,30(12):2553-2562.
[42]葛晓立,刘晓端,潘晓川,等.密云水库水体的地球化学特征[J].岩矿测试,2003,22(1):44-48.GE Xiaoli,LIU Xiaoduan,PAN Xiaochun,et al. The geochemical characteristics of water body in Miyun Reservoir[J]. Rock and mineral ananlysis,2003,22(1):44-48.
[43]袁旭,赵为武,王萍.贵州草海农业土壤重金属污染的生态危害评价[J].贵州农业科学,2013,41(11):190-193.YUAN Xu,ZHAO Weiwu,WANG Ping.Eclogical risk assessment of heavy metal in agricultural soil in Caohai Guizhou[J]. Guizhou Agricultural Science,2013,41(11):190-193.
[44] GRAY C W,MCLAREN R G,ROBERTS A H C,et al.The effect of long-term phosphatic fertilizer applications on the amounts and forms of cadmium in soils under pasture in New Zealand[J].Nutrient Cycling in Agroecosystems,1999,54(3):267-277.
[45] SINGH H,PANDEY R,SINGH S K,et al. Assessment of heavy metal contamination in the sediment of the River Ghaghara,a major tributary of the River Ganga in Northern India[J]. Applied Water Science,2017,7(7):4133-4149.
[46] ALEKANDER-KWATERCZAK U, HELIO-RYBICKA E,Contaminated sediments as a potential source of Zn,Pb,and Cd for a river system in the historical metalliferous ore mining and smelting industry area of South Poland[J]. Journal of Soils&Sediments,2009,9(1):13-22.
[47] LI Ping,ZHANG Junfeng,WANG Jianxu,et al.Heavy metal(loid)pollution in mine wastes of a Carlin-type gold mine in southwestern Guizhou,China and its environmental impacts[J]. Acta Geochimica,2015,34(3):311-319.
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