重金属污染土壤的强化电动修复技术研究进展
|
摘要
在土壤重金属污染日益严重的背景下,寻找一种简单高效的土壤修复技术刻不容缓。电动修复技术由于操作简单、处理污染物多样、修复快速、成本低廉等优点,成为重金属污染土壤修复领域的研究热点。简述了中国土壤重金属污染的现状,电动修复的原理及其影响因素,综述了近年来国内外有关强化电动修复重金属污染土壤的研究进展及国内外应用实例,分析了电动修复技术中存在的问题,最后指明了强化电动修复技术未来的研究方向。
In the context of soil heavy metal contamination became more serious,it is urgent to find a simple and efficient soil remediation technology.Electrokinetic remediation with easy operation,efficient to multiple pollutants,less time consumption and less cost has become a research hotspot in this field.This paper illustrated the status quo of heavy metal pollution in soil,the principle of electrokinetic remediation and its influencing factors.Also,it summarized the progress and application examples of domestic and foreign researches on the enhanced electrokinetic remediation of heavy metal-contaminated soil.Finally,this paper analyzed the problems in electrokinetic remediation technology,and further pointed out the future direction for the research of enhanced electrokinetic remediation technology.
In the context of soil heavy metal contamination became more serious,it is urgent to find a simple and efficient soil remediation technology.Electrokinetic remediation with easy operation,efficient to multiple pollutants,less time consumption and less cost has become a research hotspot in this field.This paper illustrated the status quo of heavy metal pollution in soil,the principle of electrokinetic remediation and its influencing factors.Also,it summarized the progress and application examples of domestic and foreign researches on the enhanced electrokinetic remediation of heavy metal-contaminated soil.Finally,this paper analyzed the problems in electrokinetic remediation technology,and further pointed out the future direction for the research of enhanced electrokinetic remediation technology.
引文
[1]ZHAI X,LI Z,HUANG B,et al.Remediation of multiple heavy metal-contaminated soil through the combination of soil washing and in situ immobilization[J].Science of the Total Environment,2018,635:92-99.
[2]ZHANG J,WANG L H,YANG J C,et al.Health risk to residents and stimulation to inherent bacteria of various heavy metals in soil[J].Science of the Total Environment,2015,508(1):29-36.
[3]张毅,孙洪坤.土壤重金属污染损害赔偿实现路径研究[J].环境污染与防治,2014,36(12):100-103.
[4]陈能场,郑煜基,何晓峰,等.《全国土壤污染状况调查公报》探析[J].中国环保产业,2014,36(5):10-11.
[5]WU G,KANG H,ZHANG X,et al.A critical review on the bio-removal of hazardous heavy metals from contaminated soils:issues,progress,eco-environmental concerns and opportunities[J].Journal of Hazardous Materials,2010,174(1/2/3):1-8.
[6]宋伟,陈百明,刘琳.中国耕地土壤重金属污染概况[J].水土保持研究,2013,20(2):293-298.
[7]李发生.土壤污染防治行动计划[J].农村实用技术,2016(10):12-13.
[8]BARBA S,VILLASENOR J,RODRIGO M A,et al.Effect of the polarity reversal frequency in the electrokinetic-biological remediation of oxyfluorfen polluted soil[J].Chemosphere,2017,177:120-127.
[9]LOPEZ V R,YUSTRES A,ASENISO L,et al.Enhanced electrokinetic remediation of polluted soils by anolyte pH conditioning[J].Chemosphere,2018,199:477-485.
[10]NG Y S,GUPTA B S,HASHIM M A.Remediation of Pb/Cr co-contaminated soil using electrokinetic process and approaching electrode technique[J].Environmental Science and Pollution Research,2015,23(1):546-555.
[11]PANZOS M,SANROMAN M A,CAMESELLE C.Improvement in electrokinetic remediation of heavy metal spiked kaolin with the polarity exchange technique[J].Chemosphere,2006,62(5):817-822.
[12]LU P,FENG Q,MENG Q,et al.Electrokinetic remediation of chromium-and cadmium-contaminated soil from abandoned industrial site[J].Separation and Purification Technology,2012,98(4):216-220.
[13]ZHOU M,XU J,ZHU S,et al.Exchange electrode-electrokinetic remediation of Cr-contaminated soil using solar energy[J].Separation and Purification Technology,2018,190:297-306.
[14]CAI Z P,DOREN J V,FANG Z Q,et al.Improvement in electrokinetic remediation of Pb-contaminated soil near lead acid battery factory[J].Transactions of Nonferrous Metals Society of China,2015,25(9):3088-3095.
[15]AMMAMI M T,BENAMAR A,WANG H,et al.Simultaneous electrokinetic removal of polycyclic aromatic hydrocarbons and metals from a sediment using mixed enhancing agents[J].International Journal of Environmental Science and Technology,2014,11(7):1801-1816.
[16]LI G,GUO S H,LI S C,et al.Comparison of approaching and fixed anodes for avoiding the‘focusing’effect during electrokinetic remediation of chromium-contaminated soil[J].Chemical Engineering Journal,2012,203:231-238.
[17]RAJI'CL,DALMACIJA B,DALMACIJA M,et al.Enhancing electrokinetic lead removal from sediment:utilizing the moving anode technique and increasing the cathode compartment length[J].Electrochimica Acta,2012,86(1):36-40.
[18]方一丰,郑余阳,唐娜,等.EDTA强化电动修复土壤铅污染[J].农业环境科学学报,2008,27(2):612-616.
[19]张涛,邹华,王娅娜,等.铅污染土壤电动修复增强技术的研究[J].环境工程学报,2013,7(9):3619-3623.
[20]樊广萍,朱海燕,郝秀珍,等.不同的增强试剂对重金属污染场地土壤的电动修复影响[J].中国环境科学,2015,35(5):1458-1465.
[21]FU R,WEN D,XIA X,et al.Electrokinetic remediation of chromium(Cr)-contaminated soil with citric acid(CA)and polyaspartic acid(PASP)as electrolytes[J].Chemical Engineering Journal,2017,316:601-608.
[22]SONG Y,AMMAMI M T,BENAMAR A,et al.Effect of ED-TA,EDDS,NTA and citric acid on electrokinetic remediation of As,Cd,Cr,Cu,Ni,Pb and Zn contaminated dredged marine sediment[J].Environmental Science and Pollution Research,2016,23(11):10577-10586.
[23]DING L,LV W,YAO K,et al.Remediation of Cd(Ⅱ)-contaminated soil via humin-enhanced electrokinetic technology[J].Environmental Science and Pollution Research,2017,24(4):3430-3436.
[24]HAO A,ZHAN M,CHENG H,et al.Effect of electrokinetic remediation on heavy metal contaminated soil by adding acetic acid[J].Chinese Journal of Environmental Engineering,2017,11(9):5283-5290.
[25]ZHANG Y,CHU G,DONG P,et al.Enhanced electrokinetic remediation of lead-and cadmium-contaminated paddy soil by composite electrolyte of sodium chloride and citric acid[J].Journal of Soils and Sediments,2018,18(5):1915-1924.
[26]CHEN X J,SHEN Z M,LEI Y M,et al.Enhanced electrokinetic remediation of Cd and Pb spiked soil coupled with cation exchange membrane[J].Soil Research,2006,44(5):523-529.
[27]徐宏婷,仓龙,宋岳.电动-氧化修复条件对土壤中多环芳烃和重金属去除的影响探索[J].环境污染与防治,2019,41(1):10-15.
[28]PEIGHAMBARDOUST S J,ROWSHANZAMIR S,AMJA-DI M.Review of the proton exchange membranes for fuel cell applications[J].International Journal of Hydrogen Energy,2010,35(17):9349-9384.
[29]MARCEAU P,BROQUET P,BATICEL P.Electrokinetic remediation of cadmium-spiked clayey medium.Pilot test[J].Earth and Planetary Science,1999,328(1):37-43.
[30]KIM B K,PARK G Y,JEON E K,et al.Field application of in situ electrokinetic remediation for As-,Cu-,and Pb-contaminated paddy soil[J].Water Air and Soil Pollution,2013,224:1-10.
[31]KIM W S,PARK G Y,KIM D H,et al.In situ field scale electrokinetic remediation of multi-metals contaminated paddy soil:influence of electrode configuration[J].Electrochimica Acta,2012,86:89-95.
[32]刘慧,仓龙,郝秀珍,等.铜污染场地土壤的原位电动强化修复[J].环境工程学报,2016,10(7):3877-3883.
[33]JEON E K,JUNG J M,KIM W S,et al.In situ electrokinetic remediation of As-,Cu-,and Pb-contaminated paddy soil using hexagonal electrode configuration:a full scale study[J].Environmental Science and Pollution Research International,2015,22(1):711-720.
[2]ZHANG J,WANG L H,YANG J C,et al.Health risk to residents and stimulation to inherent bacteria of various heavy metals in soil[J].Science of the Total Environment,2015,508(1):29-36.
[3]张毅,孙洪坤.土壤重金属污染损害赔偿实现路径研究[J].环境污染与防治,2014,36(12):100-103.
[4]陈能场,郑煜基,何晓峰,等.《全国土壤污染状况调查公报》探析[J].中国环保产业,2014,36(5):10-11.
[5]WU G,KANG H,ZHANG X,et al.A critical review on the bio-removal of hazardous heavy metals from contaminated soils:issues,progress,eco-environmental concerns and opportunities[J].Journal of Hazardous Materials,2010,174(1/2/3):1-8.
[6]宋伟,陈百明,刘琳.中国耕地土壤重金属污染概况[J].水土保持研究,2013,20(2):293-298.
[7]李发生.土壤污染防治行动计划[J].农村实用技术,2016(10):12-13.
[8]BARBA S,VILLASENOR J,RODRIGO M A,et al.Effect of the polarity reversal frequency in the electrokinetic-biological remediation of oxyfluorfen polluted soil[J].Chemosphere,2017,177:120-127.
[9]LOPEZ V R,YUSTRES A,ASENISO L,et al.Enhanced electrokinetic remediation of polluted soils by anolyte pH conditioning[J].Chemosphere,2018,199:477-485.
[10]NG Y S,GUPTA B S,HASHIM M A.Remediation of Pb/Cr co-contaminated soil using electrokinetic process and approaching electrode technique[J].Environmental Science and Pollution Research,2015,23(1):546-555.
[11]PANZOS M,SANROMAN M A,CAMESELLE C.Improvement in electrokinetic remediation of heavy metal spiked kaolin with the polarity exchange technique[J].Chemosphere,2006,62(5):817-822.
[12]LU P,FENG Q,MENG Q,et al.Electrokinetic remediation of chromium-and cadmium-contaminated soil from abandoned industrial site[J].Separation and Purification Technology,2012,98(4):216-220.
[13]ZHOU M,XU J,ZHU S,et al.Exchange electrode-electrokinetic remediation of Cr-contaminated soil using solar energy[J].Separation and Purification Technology,2018,190:297-306.
[14]CAI Z P,DOREN J V,FANG Z Q,et al.Improvement in electrokinetic remediation of Pb-contaminated soil near lead acid battery factory[J].Transactions of Nonferrous Metals Society of China,2015,25(9):3088-3095.
[15]AMMAMI M T,BENAMAR A,WANG H,et al.Simultaneous electrokinetic removal of polycyclic aromatic hydrocarbons and metals from a sediment using mixed enhancing agents[J].International Journal of Environmental Science and Technology,2014,11(7):1801-1816.
[16]LI G,GUO S H,LI S C,et al.Comparison of approaching and fixed anodes for avoiding the‘focusing’effect during electrokinetic remediation of chromium-contaminated soil[J].Chemical Engineering Journal,2012,203:231-238.
[17]RAJI'CL,DALMACIJA B,DALMACIJA M,et al.Enhancing electrokinetic lead removal from sediment:utilizing the moving anode technique and increasing the cathode compartment length[J].Electrochimica Acta,2012,86(1):36-40.
[18]方一丰,郑余阳,唐娜,等.EDTA强化电动修复土壤铅污染[J].农业环境科学学报,2008,27(2):612-616.
[19]张涛,邹华,王娅娜,等.铅污染土壤电动修复增强技术的研究[J].环境工程学报,2013,7(9):3619-3623.
[20]樊广萍,朱海燕,郝秀珍,等.不同的增强试剂对重金属污染场地土壤的电动修复影响[J].中国环境科学,2015,35(5):1458-1465.
[21]FU R,WEN D,XIA X,et al.Electrokinetic remediation of chromium(Cr)-contaminated soil with citric acid(CA)and polyaspartic acid(PASP)as electrolytes[J].Chemical Engineering Journal,2017,316:601-608.
[22]SONG Y,AMMAMI M T,BENAMAR A,et al.Effect of ED-TA,EDDS,NTA and citric acid on electrokinetic remediation of As,Cd,Cr,Cu,Ni,Pb and Zn contaminated dredged marine sediment[J].Environmental Science and Pollution Research,2016,23(11):10577-10586.
[23]DING L,LV W,YAO K,et al.Remediation of Cd(Ⅱ)-contaminated soil via humin-enhanced electrokinetic technology[J].Environmental Science and Pollution Research,2017,24(4):3430-3436.
[24]HAO A,ZHAN M,CHENG H,et al.Effect of electrokinetic remediation on heavy metal contaminated soil by adding acetic acid[J].Chinese Journal of Environmental Engineering,2017,11(9):5283-5290.
[25]ZHANG Y,CHU G,DONG P,et al.Enhanced electrokinetic remediation of lead-and cadmium-contaminated paddy soil by composite electrolyte of sodium chloride and citric acid[J].Journal of Soils and Sediments,2018,18(5):1915-1924.
[26]CHEN X J,SHEN Z M,LEI Y M,et al.Enhanced electrokinetic remediation of Cd and Pb spiked soil coupled with cation exchange membrane[J].Soil Research,2006,44(5):523-529.
[27]徐宏婷,仓龙,宋岳.电动-氧化修复条件对土壤中多环芳烃和重金属去除的影响探索[J].环境污染与防治,2019,41(1):10-15.
[28]PEIGHAMBARDOUST S J,ROWSHANZAMIR S,AMJA-DI M.Review of the proton exchange membranes for fuel cell applications[J].International Journal of Hydrogen Energy,2010,35(17):9349-9384.
[29]MARCEAU P,BROQUET P,BATICEL P.Electrokinetic remediation of cadmium-spiked clayey medium.Pilot test[J].Earth and Planetary Science,1999,328(1):37-43.
[30]KIM B K,PARK G Y,JEON E K,et al.Field application of in situ electrokinetic remediation for As-,Cu-,and Pb-contaminated paddy soil[J].Water Air and Soil Pollution,2013,224:1-10.
[31]KIM W S,PARK G Y,KIM D H,et al.In situ field scale electrokinetic remediation of multi-metals contaminated paddy soil:influence of electrode configuration[J].Electrochimica Acta,2012,86:89-95.
[32]刘慧,仓龙,郝秀珍,等.铜污染场地土壤的原位电动强化修复[J].环境工程学报,2016,10(7):3877-3883.
[33]JEON E K,JUNG J M,KIM W S,et al.In situ electrokinetic remediation of As-,Cu-,and Pb-contaminated paddy soil using hexagonal electrode configuration:a full scale study[J].Environmental Science and Pollution Research International,2015,22(1):711-720.