SO_4~(2-)/M_xO_y型固体超强酸在氧化应用方面的研究进展
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摘要
重点根据SO■/M_xO_y型固体超强酸的结构模型,分析了酸中心形成机理,介绍了光催化氧化处理污染物、石油烃类产品氧化脱硫等催化氧化方面的应用。SO■/M_xO_y型固体超强酸催化剂在氧化方面的使用寿命以及催化氧化机理的完善仍是今后研究重点。
According to the structural model of SO■/M_xO_y solid superacid,the formation mechanism of acid center was analyzed.The application of photocatalytic oxidation treatment of pollutants and catalytic oxidation of petroleum hydrocarbon products such as oxidative desulfurization were introduced.The service life of SO■/M_xO_y solid superacid catalyst in oxidation and the improvement of catalytic oxidation mechanism are still the focus of future research.
According to the structural model of SO■/M_xO_y solid superacid,the formation mechanism of acid center was analyzed.The application of photocatalytic oxidation treatment of pollutants and catalytic oxidation of petroleum hydrocarbon products such as oxidative desulfurization were introduced.The service life of SO■/M_xO_y solid superacid catalyst in oxidation and the improvement of catalytic oxidation mechanism are still the focus of future research.
引文
[1] 孙炜,杨开莲,欧阳贻德.型固体超强酸催化剂的制备和改性研究进展[J].精细石油化工进展,2003,4(6):20-24.
[2] 刘焘,李利军,黄文艺,等.固体超强酸催化剂-高岭土制备乙酰丙酸[J].化工进展,2013,32(6):1300-1306.
[3] Reddy B M,Sreekanth P M,Lakshmanan P.Sulfated zirconia as an efficient catalyst for organic synthesis and transformation reactions[J].Journal of Molecular Catalysis A Chemical,2005,237(1):93-100.
[4] Hino M,Kobayashi S,Arata K.Solid catalyst treated with anion reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion.Solid superacid catalyst[J].Cheminform,1980,11(4):1259-1260.
[5] 吴越.取代硫酸、氢氟酸等液体催化剂的途径[J].催化进展,1998,10(2):158-171.
[6] 毛东森,卢文奎,陈庆龄,等.固体酸代替液体酸催化剂的环境友好新工艺[J].石油化工,2001,30(2):152-156.
[7] 陈颖,孙雪,李金莲,等.固体超强酸催化制备生物柴油研究进展[J].化工进展,2009,28(3):383-389.
[8] Furuta Satoshi,Matsuhashi Hiromi,Arata Kazushi.Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure[J].Catalysis Communications,2004,5(12):721-723.
[9] Xu Leilei,Yang Xia,Yu Xiaodan,et al.Preparation of mesoporous polyoxometalate-tantalum pentoxide composite catalyst for efficient esterification of fatty acid[J].Catalysis Communications,2008,9(7):1607-1611.
[10] Yori J C,D Amato M A,Grau J M,et al.Depression of the cloud point of biodiesel by reaction over solid acids[J].Energy Fuels,2006,20(6):2721-2726.
[11] 陈淑芬,张春兰,王安琪,等.固体超强酸催化废弃油脂制备生物柴油[J].石油化工应用,2018,37(8):91-94.
[12] 闫鹏,王赵志,吴燕妮,等.固体超强酸催化合成葡萄酒香料己酸正丁酯[J].石油化工,2012,41(4):415-419.
[13] 晋春,郭永,薛万华,等.固体超强酸催化合成乙酸正丁酯[J].工业催化,2009,17(12):50-54.
[14] 杨克儿,邱鸿华,佟珊玲,等.SO/TiO2固体超强酸新制备方法及其对形成邻苯二甲酸二丁酯的催化活性[J].分子催化,2005,19(5):59-63.
[15] 董壮龙,郭俊胜.固体超强酸SO/Fe2O3-TiO2催化合成癸二酸二乙酯的研究[J].精细石油化工,2003,(1):23-25.
[16] Wang A,Wang J,Lu C,et al.Esterification for biofuel synthesis over an eco-friendly and efficient kaolinite-supported SO/ZnAl2O4 macroporous solid acid catalys[J].Fuel,2018(234):430-440.
[17] Deng J,Zhu X,Zhao W,et al.Production of dibutyl maleate with SO/Fe2O3 solid acid catalyst[J].Engineering and Technology Conference,2017(apetc):2004-2009.
[18] Wang J,Wang A,Tian X,et al.Development of palygorskite-SO/ZnAl2O4,composites as a novel solid acid catalyst for the esterification of acetic acid with n-butanol[J].Applied Clay Science,2017(135):596-602.
[19] Li X,Huang W.Synthesis of biodiesel from rap oil over sulfated titania-based solid superacid catalysts[J].International Journal of the Economics of Business,2009,31(18):1666-1672.
[20] Mantilla A,Ferrat A G.Catalytic behavior of sulfated TiO2 in light olefins oligomerization[J].Journal of Molecular Catalysis A:Chemical,2005,228(12):333-338.
[21] Khder A S,El-Sharkawy E A.Surface characterization and catalytic activity of sulfated tin oxide catalyst[J].Catalysis Communications,2008,9(5):769-777.
[22] Gardy J,Hassanpour A,Lai X,et al.Synthesis of Ti(SO4)O solid acid nano-catalyst and its application for biodiesel production from used cooking oil[J].Applied Catalysis A General,2016(527):81-95.
[23] Fang Y,Yang L,Qian Z,et al.Selective conversion of cotton cellulose to glucose and 5-hydroxymethyl furfural with SO/MxOy solid superacid catalyst[J].Carbohydrate Polymers,2015(131):9-14.
[24] Yang H,Lu R,Zhao J,et al.Sulfated binary oxide solid superacids[J].Materials Chemistry & Physics,2003,80(1):68-72.
[25] 唐新硕,王新平,金松寿.SO/ZrO2型超强酸酸中心形成机理研究[J].中国科学辑化学生命科学地学,1994,24(6):584-595.
[26] 付贤智,丁正新,苏文悦,等.二氧化钛基固体超强酸的结构及其光催化氧化性能[J].催化学报,1999,20(3):321-324.
[27] 杜金菊,徐安武,祝静艳.固体超强酸SO/TiO2制备及其光催化氧化性能[J].中山大学学报:自然科学版,2001,40(3):48-51.
[28] 彭少洪,黄运凤.薄膜化固体超强酸-光催化降解甲基橙[J].化学与生物工程,2012,29(12):48-50.
[29] Qin L,Zhang G,Zheng F,et al.Templated fabrication of hierarchically porous Fe-Ti bimetallic solid superacid for efficient photochemical oxidation of azo dyes under visible light[J].Chemical Engineering Journal,2014,244(10):296-306.
[30] Wang B,Zhu J,Ma H.Desulfurization from thiophene by SO/ZrO2,catalytic oxidation at room temperature and atmospheric pressure[J].Journal of Hazardous Materials,2009,164(1):256-264.
[31] 张娇静,王国建,柳艳修,等.催化氧化油品脱硫研究[J].化学工程,2015,43(2):10-15.
[32] 姬乔娜,张伟,余谟鑫,等.型固体超强酸改性及其催化氧化脱除噻吩类硫化物[J].功能材料,2009,40(11):1933-1937.
[33] 马道洁,李春虎,王亮.固体酸催化柴油氧化脱硫[J].化工进展,2009,28(s1):121-123.
[34] 罗瑞生.固体超强酸用于FCC汽油催化氧化脱硫的研究[D].青岛:中国海洋大学,2009.
[35] 郭宁,侯影飞,吴明铂,等.多孔炭负载固体超强酸催化氧化脱硫工艺研究[J].长春工程学院学报:自然科学版,2013,14(2):112-114.
[36] 郭宁,杨冲,刘振学,等.活性炭负载-催化剂的制备及其催化氧化脱硫性能[J].石油学报:石油加工,2015,31(6):1416-1424.
[37] Zhang C,Zhang J,Zhao Y,et al.Study on the preparation and catalytic activities of SO,promoted metal oxide solid superacid catalysts for model oil desulfurization[J].Catalysis Letters,2016,146(7):1256-1263.
[38] 乔亏,赵树峰,菅盘铭.复合氧化物固体超强酸催化氧化正丁醇合成正丁酸[J].工业催化,2008,16(4):59-62.
[39] 顾颖颖,刘易成,杨海宏,等.固体超强酸的合成及其对葡萄糖电催化氧化的研究[J].理化检验化学分册,2015,51(5):586-590.
[40] 肖静.SO/MxOy型固体超强酸催化低碳烷氧化偶联反应的研究[D].西安:陕西师范大学,2009.
[41] 汪颖军,孙博,张海菊.SO/MxOy型固体超强酸研究进展[J].工业催化,2008,16(2):12-17.
[42] 陈焕章,张悦,冯雪,等.SO/MxOy型固体超强酸催化剂的研究进展[J].化工进展,2018,37(5):1795-1803.
[2] 刘焘,李利军,黄文艺,等.固体超强酸催化剂-高岭土制备乙酰丙酸[J].化工进展,2013,32(6):1300-1306.
[3] Reddy B M,Sreekanth P M,Lakshmanan P.Sulfated zirconia as an efficient catalyst for organic synthesis and transformation reactions[J].Journal of Molecular Catalysis A Chemical,2005,237(1):93-100.
[4] Hino M,Kobayashi S,Arata K.Solid catalyst treated with anion reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion.Solid superacid catalyst[J].Cheminform,1980,11(4):1259-1260.
[5] 吴越.取代硫酸、氢氟酸等液体催化剂的途径[J].催化进展,1998,10(2):158-171.
[6] 毛东森,卢文奎,陈庆龄,等.固体酸代替液体酸催化剂的环境友好新工艺[J].石油化工,2001,30(2):152-156.
[7] 陈颖,孙雪,李金莲,等.固体超强酸催化制备生物柴油研究进展[J].化工进展,2009,28(3):383-389.
[8] Furuta Satoshi,Matsuhashi Hiromi,Arata Kazushi.Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure[J].Catalysis Communications,2004,5(12):721-723.
[9] Xu Leilei,Yang Xia,Yu Xiaodan,et al.Preparation of mesoporous polyoxometalate-tantalum pentoxide composite catalyst for efficient esterification of fatty acid[J].Catalysis Communications,2008,9(7):1607-1611.
[10] Yori J C,D Amato M A,Grau J M,et al.Depression of the cloud point of biodiesel by reaction over solid acids[J].Energy Fuels,2006,20(6):2721-2726.
[11] 陈淑芬,张春兰,王安琪,等.固体超强酸催化废弃油脂制备生物柴油[J].石油化工应用,2018,37(8):91-94.
[12] 闫鹏,王赵志,吴燕妮,等.固体超强酸催化合成葡萄酒香料己酸正丁酯[J].石油化工,2012,41(4):415-419.
[13] 晋春,郭永,薛万华,等.固体超强酸催化合成乙酸正丁酯[J].工业催化,2009,17(12):50-54.
[14] 杨克儿,邱鸿华,佟珊玲,等.SO/TiO2固体超强酸新制备方法及其对形成邻苯二甲酸二丁酯的催化活性[J].分子催化,2005,19(5):59-63.
[15] 董壮龙,郭俊胜.固体超强酸SO/Fe2O3-TiO2催化合成癸二酸二乙酯的研究[J].精细石油化工,2003,(1):23-25.
[16] Wang A,Wang J,Lu C,et al.Esterification for biofuel synthesis over an eco-friendly and efficient kaolinite-supported SO/ZnAl2O4 macroporous solid acid catalys[J].Fuel,2018(234):430-440.
[17] Deng J,Zhu X,Zhao W,et al.Production of dibutyl maleate with SO/Fe2O3 solid acid catalyst[J].Engineering and Technology Conference,2017(apetc):2004-2009.
[18] Wang J,Wang A,Tian X,et al.Development of palygorskite-SO/ZnAl2O4,composites as a novel solid acid catalyst for the esterification of acetic acid with n-butanol[J].Applied Clay Science,2017(135):596-602.
[19] Li X,Huang W.Synthesis of biodiesel from rap oil over sulfated titania-based solid superacid catalysts[J].International Journal of the Economics of Business,2009,31(18):1666-1672.
[20] Mantilla A,Ferrat A G.Catalytic behavior of sulfated TiO2 in light olefins oligomerization[J].Journal of Molecular Catalysis A:Chemical,2005,228(12):333-338.
[21] Khder A S,El-Sharkawy E A.Surface characterization and catalytic activity of sulfated tin oxide catalyst[J].Catalysis Communications,2008,9(5):769-777.
[22] Gardy J,Hassanpour A,Lai X,et al.Synthesis of Ti(SO4)O solid acid nano-catalyst and its application for biodiesel production from used cooking oil[J].Applied Catalysis A General,2016(527):81-95.
[23] Fang Y,Yang L,Qian Z,et al.Selective conversion of cotton cellulose to glucose and 5-hydroxymethyl furfural with SO/MxOy solid superacid catalyst[J].Carbohydrate Polymers,2015(131):9-14.
[24] Yang H,Lu R,Zhao J,et al.Sulfated binary oxide solid superacids[J].Materials Chemistry & Physics,2003,80(1):68-72.
[25] 唐新硕,王新平,金松寿.SO/ZrO2型超强酸酸中心形成机理研究[J].中国科学辑化学生命科学地学,1994,24(6):584-595.
[26] 付贤智,丁正新,苏文悦,等.二氧化钛基固体超强酸的结构及其光催化氧化性能[J].催化学报,1999,20(3):321-324.
[27] 杜金菊,徐安武,祝静艳.固体超强酸SO/TiO2制备及其光催化氧化性能[J].中山大学学报:自然科学版,2001,40(3):48-51.
[28] 彭少洪,黄运凤.薄膜化固体超强酸-光催化降解甲基橙[J].化学与生物工程,2012,29(12):48-50.
[29] Qin L,Zhang G,Zheng F,et al.Templated fabrication of hierarchically porous Fe-Ti bimetallic solid superacid for efficient photochemical oxidation of azo dyes under visible light[J].Chemical Engineering Journal,2014,244(10):296-306.
[30] Wang B,Zhu J,Ma H.Desulfurization from thiophene by SO/ZrO2,catalytic oxidation at room temperature and atmospheric pressure[J].Journal of Hazardous Materials,2009,164(1):256-264.
[31] 张娇静,王国建,柳艳修,等.催化氧化油品脱硫研究[J].化学工程,2015,43(2):10-15.
[32] 姬乔娜,张伟,余谟鑫,等.型固体超强酸改性及其催化氧化脱除噻吩类硫化物[J].功能材料,2009,40(11):1933-1937.
[33] 马道洁,李春虎,王亮.固体酸催化柴油氧化脱硫[J].化工进展,2009,28(s1):121-123.
[34] 罗瑞生.固体超强酸用于FCC汽油催化氧化脱硫的研究[D].青岛:中国海洋大学,2009.
[35] 郭宁,侯影飞,吴明铂,等.多孔炭负载固体超强酸催化氧化脱硫工艺研究[J].长春工程学院学报:自然科学版,2013,14(2):112-114.
[36] 郭宁,杨冲,刘振学,等.活性炭负载-催化剂的制备及其催化氧化脱硫性能[J].石油学报:石油加工,2015,31(6):1416-1424.
[37] Zhang C,Zhang J,Zhao Y,et al.Study on the preparation and catalytic activities of SO,promoted metal oxide solid superacid catalysts for model oil desulfurization[J].Catalysis Letters,2016,146(7):1256-1263.
[38] 乔亏,赵树峰,菅盘铭.复合氧化物固体超强酸催化氧化正丁醇合成正丁酸[J].工业催化,2008,16(4):59-62.
[39] 顾颖颖,刘易成,杨海宏,等.固体超强酸的合成及其对葡萄糖电催化氧化的研究[J].理化检验化学分册,2015,51(5):586-590.
[40] 肖静.SO/MxOy型固体超强酸催化低碳烷氧化偶联反应的研究[D].西安:陕西师范大学,2009.
[41] 汪颖军,孙博,张海菊.SO/MxOy型固体超强酸研究进展[J].工业催化,2008,16(2):12-17.
[42] 陈焕章,张悦,冯雪,等.SO/MxOy型固体超强酸催化剂的研究进展[J].化工进展,2018,37(5):1795-1803.