金属纳米阵列材料的制备和苯甲酸衍生物的THz光谱研究
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摘要
近年来,纳米科学技术得到迅速发展,利用化学和物理方法制备各种高度有序的纳米材料已经成为学术界的研究热点之一。本文以二次阳极氧化法制备得到的多孔阳极氧化铝(AAO)膜为模板,采用磁控溅射的方法直接复形得到了非常规则的具有纳米孔洞阵列的金膜和银膜。SEM和AFM结果表明,得到的金属膜的纳米孔洞排列规则,分布均匀,与AAO模板的孔洞排列一致。金属膜的孔径和厚度可以通过选择不同孔径的AAO模板和调节溅射时间、溅射电流、溅射气压控制。用这种方法复制金属纳米孔洞阵列膜工艺简单、快速、可控性强,为金属纳米膜的复制提供了一种新的工艺。
采用真空蒸镀的方法,在AAO模板上成功的制备了银量子点,量子点的直径与AAO模板纳米孔的直径相当,约80nm,大小均匀,排列与模板上纳米孔的排列一致,高度有序。并以对硝基苯胺作为探针分子,研究了银量子点做为表面增强拉曼散射光谱基底的特点。
苯甲酸及其衍生物是重要的化工原料和产品,广泛应用于高分子有机合成、染料工业和医药行业中。近几十年来,石油、化工、制药和印染工业的迅猛发展使其大量被使用,同时也带来了严重的环境污染问题。本文采用THz时域光谱测试的方法,研究了在室温氮气条件下,对羟基苯甲酸、间羟基苯甲酸、对氨基苯甲酸、间氨基苯甲酸在0.2~2.5THz波段的吸收谱和折射率谱。结果表明这四种苯甲酸衍生物分子在THz波段具有明显不同的吸收特性,本文给出了四种分子的THz标识谱,为有效地鉴别检测这四种分子提供了科学依据,也为进一步研究分子构象及相关问题提供了数据。
另外,本文介绍了一种能够在THz时域光谱探测技术中替代聚乙烯的分子——苏丹红二号,用它替代聚乙烯粉末,和对羟基苯甲酸样品混合后压片,进行太赫兹时域光谱检测,得到了理想的太赫兹吸收谱图。实验证明苏丹红二号在THz波段没有吸收峰,能够起到稀释样品、支撑样品的作用,价格约是聚乙烯的一半,且在国内市场就很容易获得,在THz时域光谱检测技术中有实际应用的价值。
In recent years, nano-science and technology have developed rapidly. It has become the focus of academics research to prepare highly ordered nano-materials with chemical and physical methods. We prepared anodic aluminum oxide (AAO) template by twice anodic oxidation, and at the same time, the gold membrane and silver membrane with very regular rules of the nano-holes array were obtained using the magnetron sputtering. SEM and AFM results show that the metal films with inerratic nano-holes are distributed evenly, and the AAO template holes are the same. Metal membrane pore size and thickness can be controlled by different aperture of, the AAO template, sputtering time, sputtering current as well as sputtering pressure. This technology of copying metal nano-holes array membrane is simple, rapid, and easy to control. Furthermore, it provides a new technology for the replication of metal nano-film.
The silver quantum dots whose diameter is about 80nm were prepared successfully on the AAO template with the method of vacuum evaporation. Quantum dots whose diameter is the same as AAO template have uniform size, consistent and highly ordered nano-holes. The silver quantum dots as the substrate of surface-enhanced Raman scattering spectroscopy were studied using p-nitroaniline as a probe.
Benzoic acid and its derivatives are an important chemical raw materials and, and they are widely used in organic synthesis and dye industry and the pharmaceutical industry. In recent decades, to a large number of these products have been used as the rapid development of petroleum, chemicals, pharmaceuticals and dyeing industry ,however, it also brings serious problem of pollution. THz absorption spectra of the band and refractive index spectrum between 0.2 ~ 2.5 of p-hydroxybenzoic acid, p-hydroxybenzoic acid between, p-aminobenzoic acid were studied under the nitrogen condition at room temperature with the of method of THz time-domain spectroscopy testing. The results show that these four elements in the THz band have distinctly different absorption properties. We also give four elements THz logo spectrum, which provide a scientific basis for the effective detection and identification of these four elements and also provide data for further study and related molecular conformation.
In addition, we introduced Sudan 2 who can be mixed and planished with p-hydroxybenzoic acid and detect THz in the terahertz time-domain spectroscopy technology to take the place of polyethylene powder, and have also obtained, the ideal THz absorption spectra. in experiments It has been proved that Sudan 2 did not have THz-band absorption peak and can play a diluted and supporting role of the sample. What’s more, the price is about half of polyethylene, and they can be easily accessed in the domestic market. There is a practical application value in THz time- domain spectroscopy detection technology.
采用真空蒸镀的方法,在AAO模板上成功的制备了银量子点,量子点的直径与AAO模板纳米孔的直径相当,约80nm,大小均匀,排列与模板上纳米孔的排列一致,高度有序。并以对硝基苯胺作为探针分子,研究了银量子点做为表面增强拉曼散射光谱基底的特点。
苯甲酸及其衍生物是重要的化工原料和产品,广泛应用于高分子有机合成、染料工业和医药行业中。近几十年来,石油、化工、制药和印染工业的迅猛发展使其大量被使用,同时也带来了严重的环境污染问题。本文采用THz时域光谱测试的方法,研究了在室温氮气条件下,对羟基苯甲酸、间羟基苯甲酸、对氨基苯甲酸、间氨基苯甲酸在0.2~2.5THz波段的吸收谱和折射率谱。结果表明这四种苯甲酸衍生物分子在THz波段具有明显不同的吸收特性,本文给出了四种分子的THz标识谱,为有效地鉴别检测这四种分子提供了科学依据,也为进一步研究分子构象及相关问题提供了数据。
另外,本文介绍了一种能够在THz时域光谱探测技术中替代聚乙烯的分子——苏丹红二号,用它替代聚乙烯粉末,和对羟基苯甲酸样品混合后压片,进行太赫兹时域光谱检测,得到了理想的太赫兹吸收谱图。实验证明苏丹红二号在THz波段没有吸收峰,能够起到稀释样品、支撑样品的作用,价格约是聚乙烯的一半,且在国内市场就很容易获得,在THz时域光谱检测技术中有实际应用的价值。
In recent years, nano-science and technology have developed rapidly. It has become the focus of academics research to prepare highly ordered nano-materials with chemical and physical methods. We prepared anodic aluminum oxide (AAO) template by twice anodic oxidation, and at the same time, the gold membrane and silver membrane with very regular rules of the nano-holes array were obtained using the magnetron sputtering. SEM and AFM results show that the metal films with inerratic nano-holes are distributed evenly, and the AAO template holes are the same. Metal membrane pore size and thickness can be controlled by different aperture of, the AAO template, sputtering time, sputtering current as well as sputtering pressure. This technology of copying metal nano-holes array membrane is simple, rapid, and easy to control. Furthermore, it provides a new technology for the replication of metal nano-film.
The silver quantum dots whose diameter is about 80nm were prepared successfully on the AAO template with the method of vacuum evaporation. Quantum dots whose diameter is the same as AAO template have uniform size, consistent and highly ordered nano-holes. The silver quantum dots as the substrate of surface-enhanced Raman scattering spectroscopy were studied using p-nitroaniline as a probe.
Benzoic acid and its derivatives are an important chemical raw materials and, and they are widely used in organic synthesis and dye industry and the pharmaceutical industry. In recent decades, to a large number of these products have been used as the rapid development of petroleum, chemicals, pharmaceuticals and dyeing industry ,however, it also brings serious problem of pollution. THz absorption spectra of the band and refractive index spectrum between 0.2 ~ 2.5 of p-hydroxybenzoic acid, p-hydroxybenzoic acid between, p-aminobenzoic acid were studied under the nitrogen condition at room temperature with the of method of THz time-domain spectroscopy testing. The results show that these four elements in the THz band have distinctly different absorption properties. We also give four elements THz logo spectrum, which provide a scientific basis for the effective detection and identification of these four elements and also provide data for further study and related molecular conformation.
In addition, we introduced Sudan 2 who can be mixed and planished with p-hydroxybenzoic acid and detect THz in the terahertz time-domain spectroscopy technology to take the place of polyethylene powder, and have also obtained, the ideal THz absorption spectra. in experiments It has been proved that Sudan 2 did not have THz-band absorption peak and can play a diluted and supporting role of the sample. What’s more, the price is about half of polyethylene, and they can be easily accessed in the domestic market. There is a practical application value in THz time- domain spectroscopy detection technology.
引文
[1] Masuda H,Fukuda K..Ordered Metal Nanohole Arrays Made by a Two-step Replication of Honeycomb Structures of Anodic Alumina[J],Science,1995,268:1466-1468
[2] Xu Yajie, Xu Dongsheng, Chen Dapeng, Guo Guolin, and Li Chongjia.Electrochemistry Preparation and Characterization of CdS Nanowire Arrays[J],Acta Phys.Chim,1999,15(7):577-580
[3] D.AlMawlawi, N.Coombs, and M.Moskovits.Magnetic Properties of Fe Deposited into Anodic Aluminum Oxide Pores as a Function of Particle Size[J],J.Appl.Phys.,1990,70(8):4421-4425
[4] Charles R. Martin.Nanomaterials: A membrane-Based Synthetic Approach[J], Science, 1994, 263(23):1961-1966
[5] A. Saedi and M. Ghorbani.Electrodeposition of Ni–Fe–Co alloy nanowire in modified AAO template[J],Materials Chemistry and Physics,2005,91(2)
[6] Dmitri Routkevitch, Terry Bigioni, Martin Moskovits, and Jing Ming Xu.Electrochemical Fabrication of CdS Nanowire Arrays in Porous Anodic Aluminum Oxide[J],J.Phys.Chem.,1996,100:14037-14047
[7] A.P.Li, F. Müller, A.Birner, K.Nielsch, and U.Gosele.Hexagonal Pore Arrays with a 50～420nm Interpore Distance Formed by Self-organization in Anodic Alumina[J],JOURNAL OF APPLIED PHYSICS,1998,84(11):6023-6026
[8]郜涛,孟国文,张立德.金属氧化物纳米点薄膜的模板法合成[J],中国科学院研究生院学报,2003,2(1):69-72
[9]孔令彬,陈淼,力虎林.用AFM研究阳极氧化铝的不稳定生长[J],化学学报,2004,62(7):680-685
[1] FM.Penning.US-PS 2.46,025
[2] J.S.Chapin.US-PS 4 ,166.0l8
[3] CaminoD, Jones A H S,Mercs D, et a.l High performance sputtered carbon coatings forwear resistant applications[J].Vacuum, 1999, 52: 125-131.
[4]刘兴举,王成彪,于翔.非平衡磁控溅射制备氮化铬膜及其摩擦学性能研究[J].金属热处理, 2005, 30(5): 1-4.
[5] Mattox DM.Handbook ofPhysicalVaporDeposition (PVD) Processing[M]. Noyes:W illiam Andrew Publishing, 1998:253-256.
[6]达道安编.真空设计手册.北京:国防工业出版社,1991.698～702.
[7] Kukla R,Bahr M,Beibwengers et al.Thin Solid Films,1993,228:51 28
[8] Bouchard F,Dittmar M B,Manring B.J Vac Sci Technol,1993,A11(5):2765
[9] Ohara Y,Akiba M,Horiike H et al.J Appl Phys,1987,61(4):1323
[10]Ivanov I,Kzansky P,Hultman L et al.J Vac Sci Technol,1994,A12(2):314
[11]薛增泉.纳米电子学[J].现代科学仪器,1998(1-2) :8-16.
[12]KUNDUY S,HAZRAY S,BANERJEEY S, et al.[J].J Phys D: Appl Phys,1998, 31(23):L73-L77.
[13]薛增泉,吴全德,李洁.薄膜物理[M].北京:电子工业出版社,1991, 116-117.
[14]孔令英.半导体技术,1997,22(5):21-23.
[15]严东生.无机材料学报,1995, 10(1) :1-6.
[16]Li-ping You ,C.L. Heng, S.Y. Ma et al. Journal of Crystal Growth. 2000,212;109-114
[17]H.G.Prengel, P.C.Jindal, K.H.Wendt et al.Surface and Coatings Technology. 2001,139;2-34
[18]J.Musil, J.Vlcek. Surface and Coatings Technology. 1999,112:162-169
[19]Sam Zhang, Deen Sun, Yongqing Fu et al. Surface and Coatings Technology. 2003,167:113-119
[1]郑伟涛等.薄膜材料与薄膜技术.北京:化学工业出版社,2004,47-49
[2]唐伟忠.薄膜材料制备原理、技术及应用.北京:冶金工业出版社,2003,39-44
[3]陈光华,邓金祥.纳米薄膜技术与应用.北京:化学工业出版社,2004,30-32
[1]贾刚,汪力,张希成,学科进展与展望, 4, 200, 2002
[2]刘盛纲,中国基础科学·科学前沿, 1, 7, 2006
[3]王少宏,许景周,汪力,张希成,物理, 30, 612, 2001
[4] Markelz A G, Roitberg A, Heilweil E J, Chem. Phys. Lett., 320, 42, 2000
[5] Nagel M, Bolivar P H, Brucherseifer M, et al., Appl. Phys. Lett., 80, 154, 2002
[6] Dekorsy T, Auer H, Waschke C, et al., Phys. Rev. Lett., 74, 738, 1995
[7] Nuss M C, IEEE Circuits and Devices, 12, 25, 1996
[8] Wan Exter M, Fattinger C and Grischkowsky D, Opt. Lett., 14, 1128, 1989
[9] Duvillaret L, Garet F andCoutaz J L, IEEE Journal of Selected Topics in Quantμm Electronics, 2, 739, 1996
[10] Li M, Cho G C, Lu T M, Zhang X C, Wang S Q and Kennedy J T, Appl. Phys. Lett., 74, 2113, 1999
[11] Mickan S, Abbott D, Munch J, et al., Microel- ectronics Journal, 31, 503, 2000
[12] Smye S W, Chanberlain J M, Filzgerald A J, et al., Physics in medicine and biology, 46, 101, 2001
[13] Auston D H and Smith P R, Appl. Phys. Lett., 43, 631, 1983
[14] Fattinger Ch and Grischkowsky D, Appl. Phys. Lett., 54, 490, 1989
[15] Wu L, Zhang X C and Auston D H, Appl. Phys. Lett., 61, 1784, 1992
[16] Hu B B, Zhang X C and Auston D H, et al., Appl. Phys. Lett. 56, 506, 1990
[17] Han P Y and Zhang X C, Measurement Science And Tech., 12, 1, 2001
[18] Huber R, Tauser F and Brodschelm A, et al., Nature, 414, 286, 2001
[19]赵尚弘,陈国夫,赵卫等,激光技术, 24, 351, 2000
[20] Grischkowsky D, Ketchen M B and Chi C C, et al., IEEE J.Quantμm Electronics, 24, 221, 1988
[21] Rudd J V, Johnson J and Mittleman D M, Opti. Lett. 25, 1556, 2000
[22] Wu Q and Zhang X C, Optics & Quantμm Electronics, 28, 945, 1996
[23] Nahata A, Auston D H and Heinz T F, et al., Appl. Phys. Lett., 68, 150, 1996
[24] Bonvalet A, Joffre M, Martin J L and Migus A, Appl. Phys. Lett., 67, 2907, 1995
[25] Walther M, Jevsky K, Keidig S R, Takahiro H and Ito H, Opt. Lett., 25, 11, 2000
[26] Zhiping Jiang and Zhang X C, Appl. Phys. Lett., 72, 1945, 1998
[27] Auston D H, Cheung K P , Valdmanis J A, et al., Phys. Rev. Lett ., 53, 1555, 1984
[28] Mittleman D M, Hunsche S, Boivin L, et al., Opt. Lett., 22, 904, 1997
[29] Li M, Cho G C, Lu T M, et al., Appl. Phys. Lett., ,74, 2113, 1999
[30] Li Ming, Jeffery Fortin, Jin Y. Kim, et al., IEEE. Journal on Selected Topics in Quantμm Electronics, 7, 624, 2001
[31] Beard M C, Turner G M, Schmuttenmaer C A, Phys. Rev. B, 62, 15764, 2000
[32] Averitt R D, Rodriguez G, Siders J L W, et al., J. Opt. Soc. Am. B, 17, 327, 2000
[33] Nagel M, Bolivar P H, Brucherseifer M, et al., Appl. Optics., 41, 2074, 2002 [34 Haran G, Sun W D, Wynne K, et al., Chem. Phys. Lett ., 274, 365, 1997
[35] Beard M C , Turner G M , Schmuttenmaer C A, J. Phys. Chem. B, 106, 7146, 2002
[36] Ferguson B, Zhang X C, Nature Mater., 1, 26, 2002
[37] Woodward R M, Cole B E, Wallace V P, et al., Phys. Med. Biol., 47, 3853, 2002
[38] Choi M K, Taylor K, Bettermann A, et al., Phys. Med. Biol., 47, 3777, 2002
[1] Wang Yin Hai, Mou Ji Mei, Cai Wei Li, etal. Mechanism of Metal Deposited in Porous Alumina by Alternating Current [J]. Acta Phys . Chim. Sin., 2001, 17(2):116-118.
[2] Xun He , David A. Recent advances in synthesis and applications of ransition metal containing mesoporous molecular sieves [J]. A ngew Chem Int Ed , 2001 , 41 : 214-229.
[3] van Danny D , Carl-Fredrik M. Porous gold surfaces for biosensor applications[J] . Biosens Bioelect ron , 2000 , 15 : 203-209.
[4] Rintoul M D , Torquato S , Yeong C , et al . Structure and transport properties of a porous magnetic gel via X-ray microtomography[J] . Phys Rev E , 1996 , 54 : 2663-2669.
[5] Mitsunori H , Rafael G, Matt D , et al . Ultrasensitive quartz crystal microbalance with porous gold electrodes [J] . A pplied Physics Letters , 2004 , 84 : 628-630.
[6] Gregory B S , Torsten R , Burkhard R. Energy storage by the electrochemical reduction of CO2 to CO at a porous Au film [J]. J Elect roanal Chem , 2002 , 526 :125-133.
[7] Ebbesen T W , Lezec HJ , Ghaemi H F , et al . Extraordinary optical transmission through sub-wavelength hole arrays [J]. Nature, 1998, 391: 667-669.
[8] Ghaemi H F , Thio T , Grupp D E , et al . Surface plasmons enhance optical transmission through subwave-length holes [J]. Phys Rev B, 1998, 58: 6779-6782.
[9] Stefanou N , Modinos A , Yannopapas V. Optical transparency of mesoporous metals [J] . Solid State Commun , 2001, 118 : 69-73.
[10] Yi Ding , Jonah E. Nanoporous metals with controlled multimodal pore size distribution[J] . J.Am. Chem.Soc. , 2003, 125 : 7772-7773.
[11] Jurczakowski R , Hitz C , Lasia A. Impedance of porous Au based electrodes[J] . J Electroanal Chem , 2004 , 572 : 355-366.
[12] Zhou Hui, Jin Lan, Xu Wei, A New Method to Fabricate Nanoporous Gold Films [J]. Journal of Fudan University, 2006, 45(3):362-366(in chinese)
[13] Masuda H ,Fukuda K. Ordered Metal Nanohole Arrays Made by a Two-Step Replication of Honeycomb Structures of Anodic Alumina[J]. Science,1995, 268: 1466-1468.
[14] Xu Yan Qi, Cai Wei Li, Wang Yin Hai,etal. Fabrication and Characterization of Ordered Nanoporous Ni Membranes[J]. Acta. Phys . Chim. Sin. ,2001,17(11):991-994.
[15] Zhao Xin Feng, Fang Yan. Metal nano-hole array copied from AAO template [J]. Acta Physica Sinica,2006, 55(7):3785-3788.
[1]刘虹霞,郭海明.阳极氧化铝模板表面自组织条纹的形成[J ] .物理学报,2004 ,53 (2) :656 - 660.
[2]宋国利,杨幼桐等.量子点的电子结构及量子效应[J ] .黑龙江大学自然科学学报,2002 ,19 (1) :80 -83.
[3] Shi G, Mo C M,Cai W L et al. Photoluminescence of ZnO nanoparticles in alumina membrane with ordered pore arrays[J]. Solid State Communications,2000, 115:253-256.
[1] M. Walther, P. Plochocka, B. Fischer, H. Helm and P. Uhd Jepsen,“Collective vibrational modes in biological molecules investigated by terahertz time-domain spectroscopy”, 2002, Biopolymers, 67, 310-313.
[2] Yue Wei-Wei, Wang Wei-Ning, Zhao Guo-Zhong, Zhang Cun-lin, and Yan Hai-Tao,“THz spectrum of aromatic amino acid”, ACTA PHYSICA SINICA (in Chinese), 2005, 54 (07), 3094-3099
[3] Wang W. N., Yue W. W., Yan H. T.,“THz time-domain spectroscopy of amino acids”, Chinese Science Bulletin, 2005, 50 (15), 1561-1565
[4] W. N. Wang, H. T. Yan, W. W. Yue, G. Z. Zhao, C. L. Zhang, H. B. Liu and X. C. Zhang,“THz Spectrum of Reduced Glutathione”Science in China Ser.G Physics, Mechanics & Astronomy, 2005, 48(5), 585-592
[5] Yan Haitao,Wang Weining,“Experimental and theoretical study of Carnosine in THz range”, Chinese Physics Letters, 2005, 22(12), 3179-3181
[6] A.G. Markelz, A. Roitberg and E. J. Heilweil,“Pulsed terahertz spectroscopy of DNA, bovine serum albumin and collagen between 0.1 and 2.0 THz”, Chem. Phys. Lett., 2000, 320, 42-48
[7] Y.C. Shen, P.C. Upadhya, E.H. Linfield and A.G. Davies,“Vibrational spectra of nucleosides studied using terahertz time-domain spectroscopy”, Vibrational Spectroscopy, 2004, 35, 111-114
[8] Li N., Shen J.L., Sun J.H., Liang L.S., Xu X.Y., Lu M.H. and Jia Y.“Study on the THz spectrum of methamphetamine”, Optics Express, 2005, 13, 6750-6755
[9]徐慧,韩家广,余笑寒,吉特,张增燕,李晴暖,李文新,朱志远“固态多环芳烃化合物的THz时域光谱研究”,化学通报,2005,3,220-225
[10]葛敏,赵红卫,张增艳,王文锋,余笑寒,李文新“两种联苯酚类化合物的太赫兹时域光谱研究”,Acta Phys. Chim. Sin., 2005, 21(9),1063-1066
[1] D. H. Auston, K. P. Cheung, J. A. Valdmanis and D. A. Kleinman 1984 Phys. Rev.Lett. 53 1555
[2] C. Fattinger and D. Grischkowsky 1988 Appl. Phys. Lett. 53 1480
[3] D. D. Timothy, G. B. Richard, M. M. Daniel 2001 Journal of the Optical Society of America A 18(7) 1562
[4] L. Duvillaret, F. Garet, J. L. Coutaz 1999 Applied Optics 38(2) 409
[2] Xu Yajie, Xu Dongsheng, Chen Dapeng, Guo Guolin, and Li Chongjia.Electrochemistry Preparation and Characterization of CdS Nanowire Arrays[J],Acta Phys.Chim,1999,15(7):577-580
[3] D.AlMawlawi, N.Coombs, and M.Moskovits.Magnetic Properties of Fe Deposited into Anodic Aluminum Oxide Pores as a Function of Particle Size[J],J.Appl.Phys.,1990,70(8):4421-4425
[4] Charles R. Martin.Nanomaterials: A membrane-Based Synthetic Approach[J], Science, 1994, 263(23):1961-1966
[5] A. Saedi and M. Ghorbani.Electrodeposition of Ni–Fe–Co alloy nanowire in modified AAO template[J],Materials Chemistry and Physics,2005,91(2)
[6] Dmitri Routkevitch, Terry Bigioni, Martin Moskovits, and Jing Ming Xu.Electrochemical Fabrication of CdS Nanowire Arrays in Porous Anodic Aluminum Oxide[J],J.Phys.Chem.,1996,100:14037-14047
[7] A.P.Li, F. Müller, A.Birner, K.Nielsch, and U.Gosele.Hexagonal Pore Arrays with a 50～420nm Interpore Distance Formed by Self-organization in Anodic Alumina[J],JOURNAL OF APPLIED PHYSICS,1998,84(11):6023-6026
[8]郜涛,孟国文,张立德.金属氧化物纳米点薄膜的模板法合成[J],中国科学院研究生院学报,2003,2(1):69-72
[9]孔令彬,陈淼,力虎林.用AFM研究阳极氧化铝的不稳定生长[J],化学学报,2004,62(7):680-685
[1] FM.Penning.US-PS 2.46,025
[2] J.S.Chapin.US-PS 4 ,166.0l8
[3] CaminoD, Jones A H S,Mercs D, et a.l High performance sputtered carbon coatings forwear resistant applications[J].Vacuum, 1999, 52: 125-131.
[4]刘兴举,王成彪,于翔.非平衡磁控溅射制备氮化铬膜及其摩擦学性能研究[J].金属热处理, 2005, 30(5): 1-4.
[5] Mattox DM.Handbook ofPhysicalVaporDeposition (PVD) Processing[M]. Noyes:W illiam Andrew Publishing, 1998:253-256.
[6]达道安编.真空设计手册.北京:国防工业出版社,1991.698～702.
[7] Kukla R,Bahr M,Beibwengers et al.Thin Solid Films,1993,228:51 28
[8] Bouchard F,Dittmar M B,Manring B.J Vac Sci Technol,1993,A11(5):2765
[9] Ohara Y,Akiba M,Horiike H et al.J Appl Phys,1987,61(4):1323
[10]Ivanov I,Kzansky P,Hultman L et al.J Vac Sci Technol,1994,A12(2):314
[11]薛增泉.纳米电子学[J].现代科学仪器,1998(1-2) :8-16.
[12]KUNDUY S,HAZRAY S,BANERJEEY S, et al.[J].J Phys D: Appl Phys,1998, 31(23):L73-L77.
[13]薛增泉,吴全德,李洁.薄膜物理[M].北京:电子工业出版社,1991, 116-117.
[14]孔令英.半导体技术,1997,22(5):21-23.
[15]严东生.无机材料学报,1995, 10(1) :1-6.
[16]Li-ping You ,C.L. Heng, S.Y. Ma et al. Journal of Crystal Growth. 2000,212;109-114
[17]H.G.Prengel, P.C.Jindal, K.H.Wendt et al.Surface and Coatings Technology. 2001,139;2-34
[18]J.Musil, J.Vlcek. Surface and Coatings Technology. 1999,112:162-169
[19]Sam Zhang, Deen Sun, Yongqing Fu et al. Surface and Coatings Technology. 2003,167:113-119
[1]郑伟涛等.薄膜材料与薄膜技术.北京:化学工业出版社,2004,47-49
[2]唐伟忠.薄膜材料制备原理、技术及应用.北京:冶金工业出版社,2003,39-44
[3]陈光华,邓金祥.纳米薄膜技术与应用.北京:化学工业出版社,2004,30-32
[1]贾刚,汪力,张希成,学科进展与展望, 4, 200, 2002
[2]刘盛纲,中国基础科学·科学前沿, 1, 7, 2006
[3]王少宏,许景周,汪力,张希成,物理, 30, 612, 2001
[4] Markelz A G, Roitberg A, Heilweil E J, Chem. Phys. Lett., 320, 42, 2000
[5] Nagel M, Bolivar P H, Brucherseifer M, et al., Appl. Phys. Lett., 80, 154, 2002
[6] Dekorsy T, Auer H, Waschke C, et al., Phys. Rev. Lett., 74, 738, 1995
[7] Nuss M C, IEEE Circuits and Devices, 12, 25, 1996
[8] Wan Exter M, Fattinger C and Grischkowsky D, Opt. Lett., 14, 1128, 1989
[9] Duvillaret L, Garet F andCoutaz J L, IEEE Journal of Selected Topics in Quantμm Electronics, 2, 739, 1996
[10] Li M, Cho G C, Lu T M, Zhang X C, Wang S Q and Kennedy J T, Appl. Phys. Lett., 74, 2113, 1999
[11] Mickan S, Abbott D, Munch J, et al., Microel- ectronics Journal, 31, 503, 2000
[12] Smye S W, Chanberlain J M, Filzgerald A J, et al., Physics in medicine and biology, 46, 101, 2001
[13] Auston D H and Smith P R, Appl. Phys. Lett., 43, 631, 1983
[14] Fattinger Ch and Grischkowsky D, Appl. Phys. Lett., 54, 490, 1989
[15] Wu L, Zhang X C and Auston D H, Appl. Phys. Lett., 61, 1784, 1992
[16] Hu B B, Zhang X C and Auston D H, et al., Appl. Phys. Lett. 56, 506, 1990
[17] Han P Y and Zhang X C, Measurement Science And Tech., 12, 1, 2001
[18] Huber R, Tauser F and Brodschelm A, et al., Nature, 414, 286, 2001
[19]赵尚弘,陈国夫,赵卫等,激光技术, 24, 351, 2000
[20] Grischkowsky D, Ketchen M B and Chi C C, et al., IEEE J.Quantμm Electronics, 24, 221, 1988
[21] Rudd J V, Johnson J and Mittleman D M, Opti. Lett. 25, 1556, 2000
[22] Wu Q and Zhang X C, Optics & Quantμm Electronics, 28, 945, 1996
[23] Nahata A, Auston D H and Heinz T F, et al., Appl. Phys. Lett., 68, 150, 1996
[24] Bonvalet A, Joffre M, Martin J L and Migus A, Appl. Phys. Lett., 67, 2907, 1995
[25] Walther M, Jevsky K, Keidig S R, Takahiro H and Ito H, Opt. Lett., 25, 11, 2000
[26] Zhiping Jiang and Zhang X C, Appl. Phys. Lett., 72, 1945, 1998
[27] Auston D H, Cheung K P , Valdmanis J A, et al., Phys. Rev. Lett ., 53, 1555, 1984
[28] Mittleman D M, Hunsche S, Boivin L, et al., Opt. Lett., 22, 904, 1997
[29] Li M, Cho G C, Lu T M, et al., Appl. Phys. Lett., ,74, 2113, 1999
[30] Li Ming, Jeffery Fortin, Jin Y. Kim, et al., IEEE. Journal on Selected Topics in Quantμm Electronics, 7, 624, 2001
[31] Beard M C, Turner G M, Schmuttenmaer C A, Phys. Rev. B, 62, 15764, 2000
[32] Averitt R D, Rodriguez G, Siders J L W, et al., J. Opt. Soc. Am. B, 17, 327, 2000
[33] Nagel M, Bolivar P H, Brucherseifer M, et al., Appl. Optics., 41, 2074, 2002 [34 Haran G, Sun W D, Wynne K, et al., Chem. Phys. Lett ., 274, 365, 1997
[35] Beard M C , Turner G M , Schmuttenmaer C A, J. Phys. Chem. B, 106, 7146, 2002
[36] Ferguson B, Zhang X C, Nature Mater., 1, 26, 2002
[37] Woodward R M, Cole B E, Wallace V P, et al., Phys. Med. Biol., 47, 3853, 2002
[38] Choi M K, Taylor K, Bettermann A, et al., Phys. Med. Biol., 47, 3777, 2002
[1] Wang Yin Hai, Mou Ji Mei, Cai Wei Li, etal. Mechanism of Metal Deposited in Porous Alumina by Alternating Current [J]. Acta Phys . Chim. Sin., 2001, 17(2):116-118.
[2] Xun He , David A. Recent advances in synthesis and applications of ransition metal containing mesoporous molecular sieves [J]. A ngew Chem Int Ed , 2001 , 41 : 214-229.
[3] van Danny D , Carl-Fredrik M. Porous gold surfaces for biosensor applications[J] . Biosens Bioelect ron , 2000 , 15 : 203-209.
[4] Rintoul M D , Torquato S , Yeong C , et al . Structure and transport properties of a porous magnetic gel via X-ray microtomography[J] . Phys Rev E , 1996 , 54 : 2663-2669.
[5] Mitsunori H , Rafael G, Matt D , et al . Ultrasensitive quartz crystal microbalance with porous gold electrodes [J] . A pplied Physics Letters , 2004 , 84 : 628-630.
[6] Gregory B S , Torsten R , Burkhard R. Energy storage by the electrochemical reduction of CO2 to CO at a porous Au film [J]. J Elect roanal Chem , 2002 , 526 :125-133.
[7] Ebbesen T W , Lezec HJ , Ghaemi H F , et al . Extraordinary optical transmission through sub-wavelength hole arrays [J]. Nature, 1998, 391: 667-669.
[8] Ghaemi H F , Thio T , Grupp D E , et al . Surface plasmons enhance optical transmission through subwave-length holes [J]. Phys Rev B, 1998, 58: 6779-6782.
[9] Stefanou N , Modinos A , Yannopapas V. Optical transparency of mesoporous metals [J] . Solid State Commun , 2001, 118 : 69-73.
[10] Yi Ding , Jonah E. Nanoporous metals with controlled multimodal pore size distribution[J] . J.Am. Chem.Soc. , 2003, 125 : 7772-7773.
[11] Jurczakowski R , Hitz C , Lasia A. Impedance of porous Au based electrodes[J] . J Electroanal Chem , 2004 , 572 : 355-366.
[12] Zhou Hui, Jin Lan, Xu Wei, A New Method to Fabricate Nanoporous Gold Films [J]. Journal of Fudan University, 2006, 45(3):362-366(in chinese)
[13] Masuda H ,Fukuda K. Ordered Metal Nanohole Arrays Made by a Two-Step Replication of Honeycomb Structures of Anodic Alumina[J]. Science,1995, 268: 1466-1468.
[14] Xu Yan Qi, Cai Wei Li, Wang Yin Hai,etal. Fabrication and Characterization of Ordered Nanoporous Ni Membranes[J]. Acta. Phys . Chim. Sin. ,2001,17(11):991-994.
[15] Zhao Xin Feng, Fang Yan. Metal nano-hole array copied from AAO template [J]. Acta Physica Sinica,2006, 55(7):3785-3788.
[1]刘虹霞,郭海明.阳极氧化铝模板表面自组织条纹的形成[J ] .物理学报,2004 ,53 (2) :656 - 660.
[2]宋国利,杨幼桐等.量子点的电子结构及量子效应[J ] .黑龙江大学自然科学学报,2002 ,19 (1) :80 -83.
[3] Shi G, Mo C M,Cai W L et al. Photoluminescence of ZnO nanoparticles in alumina membrane with ordered pore arrays[J]. Solid State Communications,2000, 115:253-256.
[1] M. Walther, P. Plochocka, B. Fischer, H. Helm and P. Uhd Jepsen,“Collective vibrational modes in biological molecules investigated by terahertz time-domain spectroscopy”, 2002, Biopolymers, 67, 310-313.
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[3] Wang W. N., Yue W. W., Yan H. T.,“THz time-domain spectroscopy of amino acids”, Chinese Science Bulletin, 2005, 50 (15), 1561-1565
[4] W. N. Wang, H. T. Yan, W. W. Yue, G. Z. Zhao, C. L. Zhang, H. B. Liu and X. C. Zhang,“THz Spectrum of Reduced Glutathione”Science in China Ser.G Physics, Mechanics & Astronomy, 2005, 48(5), 585-592
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[6] A.G. Markelz, A. Roitberg and E. J. Heilweil,“Pulsed terahertz spectroscopy of DNA, bovine serum albumin and collagen between 0.1 and 2.0 THz”, Chem. Phys. Lett., 2000, 320, 42-48
[7] Y.C. Shen, P.C. Upadhya, E.H. Linfield and A.G. Davies,“Vibrational spectra of nucleosides studied using terahertz time-domain spectroscopy”, Vibrational Spectroscopy, 2004, 35, 111-114
[8] Li N., Shen J.L., Sun J.H., Liang L.S., Xu X.Y., Lu M.H. and Jia Y.“Study on the THz spectrum of methamphetamine”, Optics Express, 2005, 13, 6750-6755
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[1] D. H. Auston, K. P. Cheung, J. A. Valdmanis and D. A. Kleinman 1984 Phys. Rev.Lett. 53 1555
[2] C. Fattinger and D. Grischkowsky 1988 Appl. Phys. Lett. 53 1480
[3] D. D. Timothy, G. B. Richard, M. M. Daniel 2001 Journal of the Optical Society of America A 18(7) 1562
[4] L. Duvillaret, F. Garet, J. L. Coutaz 1999 Applied Optics 38(2) 409