邻菲咯啉碱土金属配合物的合成与结构表征
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摘要
本论文中,我们选取1,10-邻菲咯啉及间苯二甲酸或对苯二甲酸作为配体与碱土金属反应,合成了以镁、钙、锶、钡为中心金属离子的共九种配合物,它们分别是[Mg(H_2O)_2(phen)(Hip)_2](phen)(1), [Mg(H_2O)_4phen](tp)(2), [Mg(dipic)(H_2O)_3]2H_2O (3), [Ca(NO_3)(phen)_2(H_2O)](NO_3)(5), [Sr_2(phen)_2(Hip)_4]n(6), [Sr_2(tp)_2(phen)_2H_2O]n (7), [Ba(phen)_2(H_2tp)_2(H_2O)_4]n(8), [Ba2(phen)_4(tp)_2]n(9) (配合物4为孪晶)(phen =邻菲咯啉, H_2ip =间苯二甲酸, H_2tp =对苯二甲酸, H_2dipic=2,6-吡啶二甲酸)。通过元素分析,红外光谱,热重和X-射线单晶衍射分析,确定了这些配合物的结构。这些配合物的构型不同,配合物1-5是零维结构,配合物6,7和9是二维层状结构,配合物8为三维结构。此外对配合物1,2和7-9的荧光性质也进行了测试,结果表明其在室温条件下能够发出强的蓝色荧光,说明这些配合物在光学材料方面有着一定的潜在应用价值。
值得一提的是,合成出的配合物1的晶型为C2,为手性空间群,可以推测其具有一定的非线性光学性质。经过非线性光学性质测试(SHG)发现,其强度为相同条件下KDP的1.5倍,表明该晶体在非线性光学材料方面有一定的应用。
In this paper, a series of alkaline earth metal’s compounds, by using magnesium(II), calcium(II), strontium(II) and barium(II) as the center ion, phen and isophthalic acid or terephthalic acid as the ligands, were synthesized. And they are [Mg(H_2O)_2(phen) (Hip)_2](phen)(1), [Mg(H_2O)_4phen](tp)(2), [Mg(dipic)(H_2O)_3]2H_2O (3), [Ca(NO_3)(phen)_2 (H_2O)](NO_3)(5), [Sr_2(phen)_2(Hip)_4]n(6), [Sr_2(Htp)_4(phen)_2H_2O]n (7), [Ba(phen)_2(H_2tp)_2 (H_2O)_4]n(8), [Ba2(phen)_4 (tp)_2]n(9) (The crystal of complex 4 is twinning.) (phen =1,10- phenanthroline, H_2ip =1,3- benzene dicarboxylic acid,H_2tp = 1,4-benzene dicarboxylic acid, H_2dipic=2,6- pyridine carboxylic acid)。They were characterized by elemental analysis, IR spectra, TG, and X-ray single crystal diffraction analysis. The molecular geometries of complexes are different, complexes 1-5 are the zero-dimensional structure, complexes 6,7 and 9 are two-dimensional layered structure and structure of complex 8 is three-dimensional. While their fluorescent properties were determined at room temperature, the results showed that the series of complexes could emit strong blue fluorescence
It is worth mentioning is that the synthesis of complex 1 of the crystal for C2, as chiral space group, it can be assumed it has a certain degree of non-linear optical property. After testing the nonlinear optical properties (SHG) found that its intensity under the same conditions as KDP 1.5 times that of the nonlinear optical crystal materials in certain applications.
值得一提的是,合成出的配合物1的晶型为C2,为手性空间群,可以推测其具有一定的非线性光学性质。经过非线性光学性质测试(SHG)发现,其强度为相同条件下KDP的1.5倍,表明该晶体在非线性光学材料方面有一定的应用。
In this paper, a series of alkaline earth metal’s compounds, by using magnesium(II), calcium(II), strontium(II) and barium(II) as the center ion, phen and isophthalic acid or terephthalic acid as the ligands, were synthesized. And they are [Mg(H_2O)_2(phen) (Hip)_2](phen)(1), [Mg(H_2O)_4phen](tp)(2), [Mg(dipic)(H_2O)_3]2H_2O (3), [Ca(NO_3)(phen)_2 (H_2O)](NO_3)(5), [Sr_2(phen)_2(Hip)_4]n(6), [Sr_2(Htp)_4(phen)_2H_2O]n (7), [Ba(phen)_2(H_2tp)_2 (H_2O)_4]n(8), [Ba2(phen)_4 (tp)_2]n(9) (The crystal of complex 4 is twinning.) (phen =1,10- phenanthroline, H_2ip =1,3- benzene dicarboxylic acid,H_2tp = 1,4-benzene dicarboxylic acid, H_2dipic=2,6- pyridine carboxylic acid)。They were characterized by elemental analysis, IR spectra, TG, and X-ray single crystal diffraction analysis. The molecular geometries of complexes are different, complexes 1-5 are the zero-dimensional structure, complexes 6,7 and 9 are two-dimensional layered structure and structure of complex 8 is three-dimensional. While their fluorescent properties were determined at room temperature, the results showed that the series of complexes could emit strong blue fluorescence
It is worth mentioning is that the synthesis of complex 1 of the crystal for C2, as chiral space group, it can be assumed it has a certain degree of non-linear optical property. After testing the nonlinear optical properties (SHG) found that its intensity under the same conditions as KDP 1.5 times that of the nonlinear optical crystal materials in certain applications.
引文
[1] Wells, A. F.Three-dimensional nets and polyhedra[M].Wiley:New York:1977.
[2] Ye, B.-H.; Tong, M.-L.; Chen, X.-M.Metal-organic molecular architectures with 2,2'-bipyridyl-like and carboxylate ligands.Coordination Chemistry Reviews[J]2005, 249:545-565.
[3] Hoskins, B. F.; Robson, R.Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments.J. Am. Chem. Soc.[J]1989, 111,(15):5962-5964.
[4] Batten, S. R.; Robson, R.Interpenetrating Nets: Ordered, Periodic Entanglement.Angew. Chem. Int. Ed.[J]1998, 37,(11):1460-1494.
[5] Leininger, S.; Olenyuk, B.; Stang, P. J.Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals.Chem. Rev.[J]2000, 100:853-908.
[6] Swiegers, G. F.; Malefetse, T. J.New Self-Assembled Structural Motifs in Coordination Chemistry.Chem. Rev.[J]2000, 100,(9):3488-3538.
[7] Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M.Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks.Acc. Chem. Res.[J]2001, 34,(4):319-330.
[8] Holliday, B. J.; Mirkin, C. A.Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry Angew. Chem. Int. Ed.[J]2001, 40:2022-2043.
[9] Moulton, B.; Zaworotko, M. J.From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids.Chem. Rev.[J]2001, 101:1629-1658.
[10] Chen, X.-M.; Tong, M.-L.Solvothermal in Situ Metal/Ligand Reactions: A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry.Acc. Chem. Res.[J]2007, 40,(2):162-170.
[11]徐筱杰;唐有祺.晶体工程及其在化学中的应用.无机化学学报[J]2000, 16:157-166.
[12]洪茂椿;陈荣;梁文平.21世纪的无机化学[M].Vol.281-312.科学出版社:北京:2006.
[13] Etter, M. C.Encoding and decoding hydrogen-bond patterns of organic compounds.Acc. Chem. Res.[J]1990, 23,(4):120-126.
[14] Zaworotko, M. J.Crystal engineering of diamondoid networks.Chem. Soc. Rev.[J]1994, 23:283-288.
[15] Copp, S. B.; Holman, K. T.; Sangster, J. O. S.; Subramanian, S.; Zaworotko, M. J.Supramolecular chemistry of [{M(CO)_3(μ3-OH)}4](M = Mn or Re): a modular approach to crystal engineering of superdiamondoid networks.J. Chem. Soc., Dalton Trans.[J]1995:2233-2244.
[16] Ruben, M.; Rojo, J.; Romero-Salguero, F. J.; Uppadine, L. H.; Lehn, J.-M.Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays Angew. Chem. Int. Ed.[J]2004, 43,(38):3644-3662.
[17] Blake, A. J.; Champness, N. R.; Hubberstey, P.; Li, W.-S.; Withersby, M. A.; Schroder, M.Inorganic crystal engineering using self-assembly of tailored building-blocks.Coordination Chemistry Reviews[J]1999, 183:117-138.
[18] Beatty, A. M.Open-framework coordination complexes from hydrogen-bonded networks: toward host/guest complexes.Coordination Chemistry Reviews[J]2003, 246:131-143.
[19] Robin, A. Y.; Fromm, K. M.Coordination polymer networks with O- and N-donors: What they are, why and how they are made.Coordination Chemistry Reviews[J]2006, 250:2127-2157.
[20] Zhao, Y.; Hong, M.; Liang, Y.; Cao, R.; Li, W.; Weng, J.; Lu, S.A paramagnetic lamellar polymer with a high semiconductivity.Chem. Commun.[J]2001:1020-1021.
[21] Xu, Z.A selective review on the making of coordination networks with potential semiconductive properties.Coordination Chemistry Reviews[J]2006, 250:2745-2757.
[22] Sun, D.; Cao, R.; Weng, J.; Hong, M.; Liang, Y.A novel luminescent 3D polymer containing silver chains formed by ligand unsupported Ag–Ag interactions and organic spacers.J. Chem. Soc., Dalton Trans.[J]2002:291-292.
[23] Batten, S. R.; Murray, K. S.Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide.Coordination Chemistry Reviews[J]2003, 246:103-130.
[24] Noro, S.-i.; Miyasaka, H.; Kitagawa, S.; Wada, T.; Okubo, T.; Yamashita, M.; Mitani, T.Framework Control by a Metalloligand Having Multicoordination Ability: New Synthetic Approach for Crystal Structures and Magnetic Properties.Inorg. Chem.[J]2005, 44,(1):133-146.
[25] Kumagai, H.; Kepert, C. J.; Kurmoo, M.Construction of Hydrogen-Bonded and Coordination-BondedNetworks of Cobalt(II) with Pyromellitate: Synthesis, Structures, and Magnetic Properties.Inorg. Chem.[J]2002, 41,(13):3410-3422.
[26] Grirrane, A.; Pastor, A.;álvarez, E.; Mealli, C.; Ienco, A.; Rosa, P.; Montilla, F.; Galindo, A.Manganese Oxydiacetate Complexes: Synthesis, Structure and Magnetic Properties Eur. J. Inorg. Chem.[J]2004,(4):707-717.
[27] Fromm, K. M.A Logical Concept of Structure Prediction Derived from Supramolecular Polymers of Alkaline Earth Metal Halides Formed by Hydrogen Bonding and Complexation of the Metal Ion Chem. Eur. J.[J]2001, 7,(10):2236-2244.
[28] Evans, O. R.; Lin, W.Crystal Engineering of NLO Materials Based on Metal-Organic Coordination Networks.Acc. Chem. Res.[J]2002, 35,(7):511-522.
[29] Hou, H.; Meng, X.; Song, Y.; Fan, Y.; Zhu, Y.; Lu, H.; Du, C.; Shao, W.Two-Dimensional Rhombohedral Grid Coordination Polymers [M(bbbt)_2(NCS)_2]n (M = Co, Mn, or Cd; bbbt = 1,1‘-(1,4-butanediyl) bis-1H-benzotriazole): Synthesis, Crystal Structures, and Third-Order Nonlinear Optical Properties.Inorg. Chem.[J]2002, 41,(15):4068-4075.
[30] Dong, Y.-B.; Geng, Y.; Ma, J.-P.; Huang, R.-Q.Organometallic Silver(I) Supramolecular Complexes Generated from Multidentate Furan-Containing Symmetric and Unsymmetric Fulvene Ligands and Silver(I) Salts.Inorg. Chem.[J]2005, 44,(6):1693-1703.
[31] Suh, M. P.; Cheon, Y. E.; Lee, E. Y.Syntheses and functions of porous metallosupramolecular networks.Coordination Chemistry Reviews[J]2008, 252:1007-1026.
[32] Navarro, J. A. R.; Barea, E.; Salas, J. M.; Masciocchi, N.; Galli, S.; Sironi, A.; Ania, C. O.; Parra, J. B.H_2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers.Inorg. Chem.[J]2006, 45:2397-2399.
[33] Gu, J.-Z.; Lu, W.-G.; Jiang, L.; Zhou, H.-C.; Lu, T.-B.3D Porous Metal-Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents.Inorg. Chem. 2007, 46, 5835-5837[J] 2007, 46:5835-5837.
[34] Li, Y.-M.; Kwong, F.-Y.; Yu, W.-Y.; Chan, A. S. C.Recent advances in developing new axially chiralphosphine ligands for asymmetric catalysis.Coordination Chemistry Reviews[J]2007, 251:2119-2144.
[35] Rasappan, R.; Laventine, D.; Reiser, O.Metal-bis(oxazoline) complexes: From coordination chemistry to asymmetric catalysis.Coordination Chemistry Reviews[J]2008, 252:702-714.
[36] Liu, J.; Wu, X.; Iggo, J. A.; Xiao, J.Half-sandwich iridium complexes—Synthesis and applications in catalysis.Coordination Chemistry Reviews[J]2008, 252:782-809.
[37] Kitagawa, S.; Noro., S.Comprehensive Coordination Chemistry [M].Vol.7.2004:231-261.
[38] Desiraju, G. R.Supramolecular Synthons in Crystal Engineering - A New Organic Synthesis.Angew. Chem. Int. Ed.[J]1995, 34,(21):2311-2327.
[39] Müller, A.; Reuter, H.; Dillinger, S.Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts.Angew. Chem. Int. Ed.[J]1995, 34,(21):2328-2361.
[40] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schroder, M.Supramolecular design of one-dimensional coordination polymers based on silver(I) complexes of aromatic nitrogen-donor ligands.Coordination Chemistry Reviews[J]2001, 222:155-192.
[41] Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.Silver(I)–hexamethylenetetramine molecular architectures: from self-assembly to designed assembly.Coordination Chemistry Reviews[J]2003, 246:185-202.
[42] Fujita, M.Self-Assembly of [2]Catenanes Containing Metals in Their Backbones.Acc. Chem. Res.[J]1999, 32,(1):53-61.
[43] Caulder, D. L.; Raymond, K. N.Supermolecules by Design.Acc. Chem. Res.[J]1999, 32,(11):975-982.
[44] Pschirer, N. G.; Ciurtin, D. M.; Smith, M. D.; Bunz, U. H. F.; Loye, H.-C. z.Noninterpenetrating Square-Grid Coordination Polymers With Dimensions of 25×25 ?2 Prepared by Using N,N-Type Ligands: The First Chiral Square-Grid Coordination Polymer Angew. Chem. Int. Ed.[J]2002, 41,(4):583-585.
[45] Roesky, H. W.; Andruh, M.The interplay of coordinative, hydrogen bonding and p-/p stacking interactions in sustaining supramolecular solid-state architectures. A study case of bis(4-pyridyl)- and bis(4-pyridyl-N-oxide) tectons.Coordination Chemistry Reviews[J]2003, 236:91-119.
[46] Yuan, R.-X.; Xiong, R.-G.; Xie, Y.-L.; You, X.-Z.; Peng, S.-M.; Lee, G.-H.A novel 1D CdII coordination polymer with 4-sulfobenzoate and 2, 2' -bipyridine containing an approximate rectangularmolecular box unit with blue fluorescent emission.Inorganic Chemistry Communications[J]2001, 4:384-387.
[47] Yang, C. T.; Moubaraki, B.; Murray, K. S.; Ranford, J. D.; Vittal, J. J.Interconversion of a Monomer and Two Coordination Polymers of a Copper(II)-Reduced Schiff Base Ligand-1,10-Phenanthroline Complex Based on Hydrogen- and Coordinative-Bonding.Inorg. Chem.[J]2001, 40,(23):5934-5941.
[48] Yang, C.-T.; Moubaraki, B.; Murray, K. S.; Vittal, J. J.Synthesis, characterization and properties of ternary copper(II) complexes containing reduced Schiff base N-(2-hydroxybenzyl)-a- amino acids and 1,10-phenanthroline.Dalton Trans.[J]2003:880-889.
[49] Sun, D.; Cao, R.; Liang, Y.; Shi, Q.; Su, W.; Hong, M.Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures.J. Chem. Soc., Dalton Trans.[J]2001:2335-2340.
[50] Dalai, S.; Mukherjee, P. S.; Rogez, G.; Mallah, T.; Drew, M. G. B.; Chaudhuri, N. R.Synthesis, Crystal Structures, and Magnetic Properties of Two New 1D Copper(II) Coordination Polymers Containing Fumarate(-2) and Chelating N, N-Donor as Ligands.Eur. J. Inorg. Chem.[J]2002, 2002,(12):3292-3297.
[51] Chadjistamatis, I.; Terzis, A.; Raptopoulou, C. P.; Perlepes, S. P.First use of the succinamate(-1) ligand in 3d-metal chemistry: dinuclear copper(II) complexes with the rare [Cu2(η1:μ2-O2CR)_2(η1:η1:μ2-O2CR)]+, [Cu2(η1:η1:μ2-O2CR)_2]2+ and [Cu2(μ-OH)(μ-OH_2)(η1:η1:μ2-O2CR)]2+ cores, and a novel one-dimensional polymerization of two different dimers (R=CH_2CH_2CONH_2).Inorganic Chemistry Communications[J]2003, 6:1365-1371.
[52] Marinescu, G.; Andruh, M.; ze, R. L.; Munoz, M. C.; Cano, J.; Lloretb, F.; Julve, M.[ Cr(phen)(ox)_2]-: a versatile bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of AsPh4 [ Cr(phen)(ox)_2].H_2O, [NaCr(phen)(ox)_2(H_2O)] . 2H_2O and { [Cr(phen)(ox)_2 ] 2 [Mn2(bpy)_2(H_2O)_2(ox) ] }.6H_2O.New J. Chem.[J]2000, 24:527-536.
[53] Zhua, L.-H.; Zeng, M.-H.; Yea, B.-H.; Chen, X.-M.Hydrothermal Synthesis and Crystal Structure of a New Oxalato-bridged Lead(II) Polymer: {[Pb(phen)_2(ox)]·5H_20}n (phen=1,10-phenanthroline,ox=oxalate).Z. Anorg. Allg. Chem.[J]2004, 630:952-955.
[54] Wan, Y.; Zhang, L.; Jin, L.; Gao, S.; Lu, S.High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions with Benzenedicarboxylates and 1,10-Phenanthroline.Inorg. Chem.[J]2003, 42,(16):4985-4994.
[55] Wan, Y.-H.; Zhang, L.-P.; Jin, L.-P.Three new lanthanide coordination polymers containing isophthalate and 1,10-phenanthroline.Journal of Molecular Structure[J]2003, 658:253-260.
[56] Li, Y.; Hao, N.; Lu, Y.; Wang, E.; Kang, Z.; Hu, C.New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands.Inorg. Chem.[J]2003, 42,(9):3119-3124.
[57] Fei, B.-L.; Sun, W.-Y.; Okamura, T.-a.; Tang, W.-X.; Ueyamab, N.Synthesis and crystal structure of a luminescent inDnite 2D brick-wall network with two- and three-coordinate silver(I) atoms and ligand-unsupported silver-silver interactions.New J. Chem.[J]2001, 25:210-212.
[58] Liu, G.-F.; Qiao, Z.-P.; Wang, H.-Z.; Chen, X.-M.; Yang, G.Synthesis, structures and photoluminescence of three terbium(III) dicarboxylate coordination polymers.New J. Chem.[J]2002, 26:791-795.
[59] Vishnyakov, A.; Ravikovitch, P. I.; Neimark, A. V.; Blow, M.; Wang, Q. M.Nanopore Structure and Sorption Properties of Cu-BTC Metal?Organic Framework.Nano Letters[J]2003, 3,(6):713-718.
[60] Skoulidas, A. I.Molecular Dynamics Simulations of Gas Diffusion in Metal-Organic Frameworks: Argon in CuBTC.J. Am. Chem. Soc.[J]2004, 126,(5):1356-1357.
[61] Wang, J.; Lin, Z.; Ou, Y.-C.; Yang, N.-L.; Zhang, Y.-H.; Tong, M.-L.Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)-Hydroxide Clusters or Zinc(II)-Carboxylate Layers.Inorg. Chem.[J]2008, 47:190-199.
[62] Shi, X.; Zhu, G.; Wang, X.; Li, G.; Fang, Q.; Wu, G.; Tian, G.; Xue, M.; Zhao, X.; Wang, R.; Qiu, S.From a 1-D Chain, 2-D Layered Network to a 3-D Supramolecular Framework Constructed from a Metal-Organic Coordination Compound.Crystal Growth & Design[J]2005, 5,(1):207-213.
[63]计亮年;莫庭焕.生物无机化学导论[M].Vol.第一版.中山大学出版社:广州:1992:39-61, 84-85,258-295.
[64] Glasner, M. E.; Bergman, N. H.; Bartel, D. P.Metal Ion Requirements for Structure and Catalysis of an RNA Ligase Ribozyme.Biochemistry[J]2002, 41:8103-8112.
[65] Kluge, S.; Weston, J.Can a Hydroxide Ligand Trigger a Change in the Coordination Number of Magnesium Ions in Biological Systems?Biochemistry[J]2005, 44:4877-4885.
[66] Cowan, J. A.Metal Activation of Enzymes in Nucleic Acid Biochemistry.Chem. Rev.[J]1998, 98:1067-1087.
[67] Ellis-Davies, G. C. R.Neurobiology with Caged Calcium.Chem. Rev.[J]2008, 108:1603-1613.
[68] Wang, L.; Nancollas, G. H.Calcium Orthophosphates: Crystallization and Dissolution.Chem. Rev.[J]2008, 108,(11):4628-4669.
[69] Zhang, D.-J.; Song, T.-Y.; Zhang, P.; Shi, J.; Wang, Y.; Wang, L.; Ma, K.-R.; Yin, W.-R.; Zhao, J.; Fan, Y.; Xu, J.-N.Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3-D magnesium metal–organic framework Mg1.5(m5-btec)(H_2O)_2][H_2N(CH3)_2]H_2O.Inorganic Chemistry Communications[J]2007, 10:876-879.
[70] He, X.; Allan, J. F.; Noll, B. C.; Kennedy, A. R.; Henderson, K. W.Stereoselective Enolizations Mediated by Magnesium and Calcium Bisamides: Contrasting Aggregation Behavior in Solution and in the Solid State.J. Am. Chem. Soc.[J]2005, 127,(19):6920-6921.
[71]张必松.新型邻菲咯啉镁(II)配合物[Mg(H_2O)_4(phen)](phen)[C6H4(COO)_2]?H_2O的水热合成和晶体结构.结构化学[J]2004, 23:1411-1415.
[72] He, X.; Noll, B. C.; Beatty, A.; Mulvey, R. E.; Henderson, K. W.Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases: Structural Characterization of Potassium, Calcium, and Mixed Potassium-Calcium Enolates.J. Am. Chem. Soc.[J]2004, 126,(24):7444-7445.
[73]陈鹏刚;邓兆鹏;高山.三元混配的钙配合物[Ca(NO_3)(Phen)_2(H_2O)_2](NO_3)的合成与晶体结构研究.黑龙江大学自然科学学报[J]2006, 123:806-809.
[74] Murugavel, R.; Baheti, K.; Anantharaman, G.Reactions of 2-Mercaptobenzoic Acid with DivalentAlkaline Earth Metal Ions: Synthesis, Spectral Studies, and Single-Crystal X-ray Structures of Calcium, Strontium, and Barium Complexes of 2,2′-Dithiobis(benzoic acid).Inorg. Chem. [J]2001, 40:6870-6878.
[75] Murugavel, R.; Banerjee, S.First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)_2(H_2O)_2]n assembly.Inorganic Chemistry Communications[J]2003, 6:810-814.
[76] Murugavel, R.; Karambelkar, V. V.; Anantharaman, G.; Walawalkar, M. G.Synthesis, Spectral Characterization, and Structural Studies of 2-Aminobenzoate Complexes of Divalent Alkaline Earth Metal Ions: X-ray Crystal Structures of [Ca(2-aba)_2(OH_2)_3], [{Sr(2-aba)_2(OH_2)_2}H_2O], and [Ba(2-aba)_2(OH_2)] (2-abaH )= 2-NH_2C6H4COOH).Inorg. Chem.[J]2000, 39:1381-1390.
[77] Murugavel, R.; Korah, R.Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-Phenanthroline and 4, 4′-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands.Inorg. Chem. [J]2007, 46:11048-11062.
[78] Murugavel, R.; Kumar, P.; Walawalkar, M. G.; Mathialagan, R.A Double Helix Is the Repeating Unit in a Luminescent Calcium 5-Aminoisophthalate Supramolecular Edifice with Water-Filled Hexagonal Channels.Inorg. Chem.[J]2007, 46:6828-6830.
[79] Murugavel, R.; Kuppuswamy, S.; Randoll, S.Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal-Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline.Inorg. Chem.[J]2008, 47:6028-6039.
[80] J.Baier; U.Thewalt.Darstellung und Strukturen von Mg-Komplexen mit a,w-Dicarboxylato-Liganden (Dicarboxylat = Succinat, Glutarat und Suberat).Z.Anorg.Allg.Chem.[J]2002, 628,(1):315-321.
[81] Aliouane, K.; Djeghri, A.; Guehria-Laidoudi, A.; Dahaoui, S.; Lecomte, C.Synthesis, structure and thermal behaviour of a barium-glutarate framework.Journal of Molecular Structure[J]2007, 832:150-155.
[82] Groeneman, R. H.; Atwood, J. L.Terephthlate bridged coordination polymers based upon group two metals.Crystal Engineering[J]1999, 2:241-249.
[83] Davies, R. P.; Less, R. J.; Lickiss, P. D.; White, A. J. P.Framework materials assembled from magnesium carboxylate building units.Dalton Trans.[J]2007:2528-2535.
[84] Shuai, Q.; Chen, S.; Gao, S.Structural and thermal properties of three novel alkaline earth metalcoordination polymers based on 5-hydroxyisophthalate ligand.Inorganica Chimica Acta[J]2007, 360:1381-1387.
[85] Yang, Y.; Jiang, G.; Li, Y.-Z.; Bai, J.; Pan, Y.; You, X.-Z.Synthesis, structures and properties of alkaline earth metal benzene-1,4-dioxylacetates with three-dimensional hybrid networks.Inorganica Chimica Acta[J]2006, 359:3257-3263.
[86] Senkovska, I.; Kaskel, S.Solvent-Induced Pore-Size Adjustment in the Metal-Organic Framework [Mg3(ndc)_3(dmf)_4] (ndc = naphthalenedicarboxylate).Eur. J. Inorg. Chem.[J]2006:4564-4569.
[87] Volkringer, C.; Marrot, J.; Férey, G.; Loiseau, T.Hydrothermal Crystallization of Three Calcium-Based Hybrid Solids with 2,6-Naphthalene- or 4,4'-Biphenyl-Dicarboxylates.Cryst. Growth Des.[J]2008, 8:685-689.
[88] Williams, C. A.; Blake, A. J.; Wilson, C.; Hubberstey, P.; Schr?der, M.Novel Metal-Organic Frameworks Derived from Group II Metal Cations and Aryldicarboxylate Anionic Ligands.Cryst. Growth Des.[J]2008, 8:911-922.
[89] Plater, M. J.; Roberts, A. J.; Marr, J.; Lachowski, E. E.; Howie, R. A.Hydrothermal synthesis and characterisation of alkaline-earth metal salts of benzene-1,3,5-tricarboxylic acid.J. Chem. Soc., Dalton Trans.[J]1998:797-802.
[90] Zhu, H.-F.; Zhang, Z.-H.; Sun, W.-Y.; Okamura, T.-a.; Ueyama, N.Syntheses, Structures, and Properties of Two-Dimensional Alkaline Earth Metal Complexes with Flexible Tripodal Tricarboxylate Ligands.Crystal Growth & Design[J]2005, 5:177-182.
[91] Volkringer, C.; Loiseau, T.; Fe′rey, G. r.; Warren, J. E.; Wragg, D. S.; Morris, R. E.A new calcium trimellitate coordination polymer with a chain-like structure.Solid State Sciences[J]2007, 9:455-458.
[92]苏扬;臧双全;倪春林;李一志;孟庆金.过渡金属-碱土金属铜钙四核配合物Cu2Ca2L2(H_2O)6.2H_2O的合成和晶体结构.无机化学学报[J]2004, 20:845-849.
[93]高山;张竹艳;霍丽华;赵辉;赵经贵.一维链状2-氧-1(4H)-吡啶乙酸桥联钙配位聚合物[Ca(2-OPA)_2(H_2O)_2]n的合成!晶体结构及热稳定性研究.无机化学学报[J]2005, 21:771-776.
[94]高山;霍丽华;赵辉;谷长生;赵经贵.三维网状的4-羧基苯氧乙酸锶(II)配位聚合物[Sr_2(4-CPOA)_2(H_2O)5]n的合成、结构与热稳定性研究.无机化学学报[J]2005, 21:1245-1249.
[95]台夕市;冯一民;孔凡元;王大奇;谭民裕.一维链状配位聚合物[Ca(L)_2·(CH3OH)_2]n的合成、结构及热稳定性.无机化学学报[J]2008, 24:831-834.
[96] Fox, S.; Bu1sching, I.; Barklage, W.; Strasdeit, H.Coordination of Biologically Important r-Amino Acids to Calcium(II) at High pH: Insights from Crystal Structures of Calcium a-Aminocarboxylates.Inorg. Chem.[J]2007, 46:818-824.
[97] Gurunatha, K. L.; Uemura, K.; Maji, T. K.Temperature- and Stoichiometry-Controlled Dimensionality in a Magnesium 4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces.Inorg. Chem.[J]2008, 47,(15):6578-6580.
[98] Zhong, R.-Q.; Zou, R.-Q.; Du, M.; Takeichia, N.; Xu, Q.Observation of helical water chains reversibly inlayed in magnesium imidazole-4,5-dicarboxylate.CrystEngComm[J]2008, 10:1175-1179.
[99] Pan, L.; Frydel, T.; Sander, M. B.; Huang, X.; Li, J.The Effect of pH on the Dimensionality of Coordination Polymers.Inorg. Chem.[J]2001, 40:11271-1283.
[100]谈芸;唐智萍.为健康加镁[M].华东师范大学出版社:上海:2005:17-18.
[101] Sheldrick, G. M.Program for Solution and Refinement of Crystal Structures,Version 5.1; University of Gottingen: Germany, 1997.
[102]中本一雄.无机和配位化合物的红外和拉曼光谱[M].化学工业出版社:北京:1986:216-220.
[103]张中强.新型荧光材料的制备和性质[D].硕士论文,河北师范大学.石家庄, 2005:39-42.
[104] Deacon, G. B.; Phillips, R. J.Relationships between the carbon-oxygen stretching frequencies of carboxylexes and the type of carboxylate coordination.Coordination Chemistry Reviews[J]1980, 33:227-250.
[2] Ye, B.-H.; Tong, M.-L.; Chen, X.-M.Metal-organic molecular architectures with 2,2'-bipyridyl-like and carboxylate ligands.Coordination Chemistry Reviews[J]2005, 249:545-565.
[3] Hoskins, B. F.; Robson, R.Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments.J. Am. Chem. Soc.[J]1989, 111,(15):5962-5964.
[4] Batten, S. R.; Robson, R.Interpenetrating Nets: Ordered, Periodic Entanglement.Angew. Chem. Int. Ed.[J]1998, 37,(11):1460-1494.
[5] Leininger, S.; Olenyuk, B.; Stang, P. J.Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals.Chem. Rev.[J]2000, 100:853-908.
[6] Swiegers, G. F.; Malefetse, T. J.New Self-Assembled Structural Motifs in Coordination Chemistry.Chem. Rev.[J]2000, 100,(9):3488-3538.
[7] Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M.Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks.Acc. Chem. Res.[J]2001, 34,(4):319-330.
[8] Holliday, B. J.; Mirkin, C. A.Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry Angew. Chem. Int. Ed.[J]2001, 40:2022-2043.
[9] Moulton, B.; Zaworotko, M. J.From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids.Chem. Rev.[J]2001, 101:1629-1658.
[10] Chen, X.-M.; Tong, M.-L.Solvothermal in Situ Metal/Ligand Reactions: A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry.Acc. Chem. Res.[J]2007, 40,(2):162-170.
[11]徐筱杰;唐有祺.晶体工程及其在化学中的应用.无机化学学报[J]2000, 16:157-166.
[12]洪茂椿;陈荣;梁文平.21世纪的无机化学[M].Vol.281-312.科学出版社:北京:2006.
[13] Etter, M. C.Encoding and decoding hydrogen-bond patterns of organic compounds.Acc. Chem. Res.[J]1990, 23,(4):120-126.
[14] Zaworotko, M. J.Crystal engineering of diamondoid networks.Chem. Soc. Rev.[J]1994, 23:283-288.
[15] Copp, S. B.; Holman, K. T.; Sangster, J. O. S.; Subramanian, S.; Zaworotko, M. J.Supramolecular chemistry of [{M(CO)_3(μ3-OH)}4](M = Mn or Re): a modular approach to crystal engineering of superdiamondoid networks.J. Chem. Soc., Dalton Trans.[J]1995:2233-2244.
[16] Ruben, M.; Rojo, J.; Romero-Salguero, F. J.; Uppadine, L. H.; Lehn, J.-M.Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays Angew. Chem. Int. Ed.[J]2004, 43,(38):3644-3662.
[17] Blake, A. J.; Champness, N. R.; Hubberstey, P.; Li, W.-S.; Withersby, M. A.; Schroder, M.Inorganic crystal engineering using self-assembly of tailored building-blocks.Coordination Chemistry Reviews[J]1999, 183:117-138.
[18] Beatty, A. M.Open-framework coordination complexes from hydrogen-bonded networks: toward host/guest complexes.Coordination Chemistry Reviews[J]2003, 246:131-143.
[19] Robin, A. Y.; Fromm, K. M.Coordination polymer networks with O- and N-donors: What they are, why and how they are made.Coordination Chemistry Reviews[J]2006, 250:2127-2157.
[20] Zhao, Y.; Hong, M.; Liang, Y.; Cao, R.; Li, W.; Weng, J.; Lu, S.A paramagnetic lamellar polymer with a high semiconductivity.Chem. Commun.[J]2001:1020-1021.
[21] Xu, Z.A selective review on the making of coordination networks with potential semiconductive properties.Coordination Chemistry Reviews[J]2006, 250:2745-2757.
[22] Sun, D.; Cao, R.; Weng, J.; Hong, M.; Liang, Y.A novel luminescent 3D polymer containing silver chains formed by ligand unsupported Ag–Ag interactions and organic spacers.J. Chem. Soc., Dalton Trans.[J]2002:291-292.
[23] Batten, S. R.; Murray, K. S.Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide.Coordination Chemistry Reviews[J]2003, 246:103-130.
[24] Noro, S.-i.; Miyasaka, H.; Kitagawa, S.; Wada, T.; Okubo, T.; Yamashita, M.; Mitani, T.Framework Control by a Metalloligand Having Multicoordination Ability: New Synthetic Approach for Crystal Structures and Magnetic Properties.Inorg. Chem.[J]2005, 44,(1):133-146.
[25] Kumagai, H.; Kepert, C. J.; Kurmoo, M.Construction of Hydrogen-Bonded and Coordination-BondedNetworks of Cobalt(II) with Pyromellitate: Synthesis, Structures, and Magnetic Properties.Inorg. Chem.[J]2002, 41,(13):3410-3422.
[26] Grirrane, A.; Pastor, A.;álvarez, E.; Mealli, C.; Ienco, A.; Rosa, P.; Montilla, F.; Galindo, A.Manganese Oxydiacetate Complexes: Synthesis, Structure and Magnetic Properties Eur. J. Inorg. Chem.[J]2004,(4):707-717.
[27] Fromm, K. M.A Logical Concept of Structure Prediction Derived from Supramolecular Polymers of Alkaline Earth Metal Halides Formed by Hydrogen Bonding and Complexation of the Metal Ion Chem. Eur. J.[J]2001, 7,(10):2236-2244.
[28] Evans, O. R.; Lin, W.Crystal Engineering of NLO Materials Based on Metal-Organic Coordination Networks.Acc. Chem. Res.[J]2002, 35,(7):511-522.
[29] Hou, H.; Meng, X.; Song, Y.; Fan, Y.; Zhu, Y.; Lu, H.; Du, C.; Shao, W.Two-Dimensional Rhombohedral Grid Coordination Polymers [M(bbbt)_2(NCS)_2]n (M = Co, Mn, or Cd; bbbt = 1,1‘-(1,4-butanediyl) bis-1H-benzotriazole): Synthesis, Crystal Structures, and Third-Order Nonlinear Optical Properties.Inorg. Chem.[J]2002, 41,(15):4068-4075.
[30] Dong, Y.-B.; Geng, Y.; Ma, J.-P.; Huang, R.-Q.Organometallic Silver(I) Supramolecular Complexes Generated from Multidentate Furan-Containing Symmetric and Unsymmetric Fulvene Ligands and Silver(I) Salts.Inorg. Chem.[J]2005, 44,(6):1693-1703.
[31] Suh, M. P.; Cheon, Y. E.; Lee, E. Y.Syntheses and functions of porous metallosupramolecular networks.Coordination Chemistry Reviews[J]2008, 252:1007-1026.
[32] Navarro, J. A. R.; Barea, E.; Salas, J. M.; Masciocchi, N.; Galli, S.; Sironi, A.; Ania, C. O.; Parra, J. B.H_2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers.Inorg. Chem.[J]2006, 45:2397-2399.
[33] Gu, J.-Z.; Lu, W.-G.; Jiang, L.; Zhou, H.-C.; Lu, T.-B.3D Porous Metal-Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents.Inorg. Chem. 2007, 46, 5835-5837[J] 2007, 46:5835-5837.
[34] Li, Y.-M.; Kwong, F.-Y.; Yu, W.-Y.; Chan, A. S. C.Recent advances in developing new axially chiralphosphine ligands for asymmetric catalysis.Coordination Chemistry Reviews[J]2007, 251:2119-2144.
[35] Rasappan, R.; Laventine, D.; Reiser, O.Metal-bis(oxazoline) complexes: From coordination chemistry to asymmetric catalysis.Coordination Chemistry Reviews[J]2008, 252:702-714.
[36] Liu, J.; Wu, X.; Iggo, J. A.; Xiao, J.Half-sandwich iridium complexes—Synthesis and applications in catalysis.Coordination Chemistry Reviews[J]2008, 252:782-809.
[37] Kitagawa, S.; Noro., S.Comprehensive Coordination Chemistry [M].Vol.7.2004:231-261.
[38] Desiraju, G. R.Supramolecular Synthons in Crystal Engineering - A New Organic Synthesis.Angew. Chem. Int. Ed.[J]1995, 34,(21):2311-2327.
[39] Müller, A.; Reuter, H.; Dillinger, S.Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts.Angew. Chem. Int. Ed.[J]1995, 34,(21):2328-2361.
[40] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schroder, M.Supramolecular design of one-dimensional coordination polymers based on silver(I) complexes of aromatic nitrogen-donor ligands.Coordination Chemistry Reviews[J]2001, 222:155-192.
[41] Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.Silver(I)–hexamethylenetetramine molecular architectures: from self-assembly to designed assembly.Coordination Chemistry Reviews[J]2003, 246:185-202.
[42] Fujita, M.Self-Assembly of [2]Catenanes Containing Metals in Their Backbones.Acc. Chem. Res.[J]1999, 32,(1):53-61.
[43] Caulder, D. L.; Raymond, K. N.Supermolecules by Design.Acc. Chem. Res.[J]1999, 32,(11):975-982.
[44] Pschirer, N. G.; Ciurtin, D. M.; Smith, M. D.; Bunz, U. H. F.; Loye, H.-C. z.Noninterpenetrating Square-Grid Coordination Polymers With Dimensions of 25×25 ?2 Prepared by Using N,N-Type Ligands: The First Chiral Square-Grid Coordination Polymer Angew. Chem. Int. Ed.[J]2002, 41,(4):583-585.
[45] Roesky, H. W.; Andruh, M.The interplay of coordinative, hydrogen bonding and p-/p stacking interactions in sustaining supramolecular solid-state architectures. A study case of bis(4-pyridyl)- and bis(4-pyridyl-N-oxide) tectons.Coordination Chemistry Reviews[J]2003, 236:91-119.
[46] Yuan, R.-X.; Xiong, R.-G.; Xie, Y.-L.; You, X.-Z.; Peng, S.-M.; Lee, G.-H.A novel 1D CdII coordination polymer with 4-sulfobenzoate and 2, 2' -bipyridine containing an approximate rectangularmolecular box unit with blue fluorescent emission.Inorganic Chemistry Communications[J]2001, 4:384-387.
[47] Yang, C. T.; Moubaraki, B.; Murray, K. S.; Ranford, J. D.; Vittal, J. J.Interconversion of a Monomer and Two Coordination Polymers of a Copper(II)-Reduced Schiff Base Ligand-1,10-Phenanthroline Complex Based on Hydrogen- and Coordinative-Bonding.Inorg. Chem.[J]2001, 40,(23):5934-5941.
[48] Yang, C.-T.; Moubaraki, B.; Murray, K. S.; Vittal, J. J.Synthesis, characterization and properties of ternary copper(II) complexes containing reduced Schiff base N-(2-hydroxybenzyl)-a- amino acids and 1,10-phenanthroline.Dalton Trans.[J]2003:880-889.
[49] Sun, D.; Cao, R.; Liang, Y.; Shi, Q.; Su, W.; Hong, M.Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures.J. Chem. Soc., Dalton Trans.[J]2001:2335-2340.
[50] Dalai, S.; Mukherjee, P. S.; Rogez, G.; Mallah, T.; Drew, M. G. B.; Chaudhuri, N. R.Synthesis, Crystal Structures, and Magnetic Properties of Two New 1D Copper(II) Coordination Polymers Containing Fumarate(-2) and Chelating N, N-Donor as Ligands.Eur. J. Inorg. Chem.[J]2002, 2002,(12):3292-3297.
[51] Chadjistamatis, I.; Terzis, A.; Raptopoulou, C. P.; Perlepes, S. P.First use of the succinamate(-1) ligand in 3d-metal chemistry: dinuclear copper(II) complexes with the rare [Cu2(η1:μ2-O2CR)_2(η1:η1:μ2-O2CR)]+, [Cu2(η1:η1:μ2-O2CR)_2]2+ and [Cu2(μ-OH)(μ-OH_2)(η1:η1:μ2-O2CR)]2+ cores, and a novel one-dimensional polymerization of two different dimers (R=CH_2CH_2CONH_2).Inorganic Chemistry Communications[J]2003, 6:1365-1371.
[52] Marinescu, G.; Andruh, M.; ze, R. L.; Munoz, M. C.; Cano, J.; Lloretb, F.; Julve, M.[ Cr(phen)(ox)_2]-: a versatile bis-oxalato building block for the design of heteropolymetallic systems. Crystal structures and magnetic properties of AsPh4 [ Cr(phen)(ox)_2].H_2O, [NaCr(phen)(ox)_2(H_2O)] . 2H_2O and { [Cr(phen)(ox)_2 ] 2 [Mn2(bpy)_2(H_2O)_2(ox) ] }.6H_2O.New J. Chem.[J]2000, 24:527-536.
[53] Zhua, L.-H.; Zeng, M.-H.; Yea, B.-H.; Chen, X.-M.Hydrothermal Synthesis and Crystal Structure of a New Oxalato-bridged Lead(II) Polymer: {[Pb(phen)_2(ox)]·5H_20}n (phen=1,10-phenanthroline,ox=oxalate).Z. Anorg. Allg. Chem.[J]2004, 630:952-955.
[54] Wan, Y.; Zhang, L.; Jin, L.; Gao, S.; Lu, S.High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions with Benzenedicarboxylates and 1,10-Phenanthroline.Inorg. Chem.[J]2003, 42,(16):4985-4994.
[55] Wan, Y.-H.; Zhang, L.-P.; Jin, L.-P.Three new lanthanide coordination polymers containing isophthalate and 1,10-phenanthroline.Journal of Molecular Structure[J]2003, 658:253-260.
[56] Li, Y.; Hao, N.; Lu, Y.; Wang, E.; Kang, Z.; Hu, C.New Two-Dimensional Metal-Organic Networks Constructed from 1,2,4,5-Benzenetetracarboxylate and Chelate Ligands.Inorg. Chem.[J]2003, 42,(9):3119-3124.
[57] Fei, B.-L.; Sun, W.-Y.; Okamura, T.-a.; Tang, W.-X.; Ueyamab, N.Synthesis and crystal structure of a luminescent inDnite 2D brick-wall network with two- and three-coordinate silver(I) atoms and ligand-unsupported silver-silver interactions.New J. Chem.[J]2001, 25:210-212.
[58] Liu, G.-F.; Qiao, Z.-P.; Wang, H.-Z.; Chen, X.-M.; Yang, G.Synthesis, structures and photoluminescence of three terbium(III) dicarboxylate coordination polymers.New J. Chem.[J]2002, 26:791-795.
[59] Vishnyakov, A.; Ravikovitch, P. I.; Neimark, A. V.; Blow, M.; Wang, Q. M.Nanopore Structure and Sorption Properties of Cu-BTC Metal?Organic Framework.Nano Letters[J]2003, 3,(6):713-718.
[60] Skoulidas, A. I.Molecular Dynamics Simulations of Gas Diffusion in Metal-Organic Frameworks: Argon in CuBTC.J. Am. Chem. Soc.[J]2004, 126,(5):1356-1357.
[61] Wang, J.; Lin, Z.; Ou, Y.-C.; Yang, N.-L.; Zhang, Y.-H.; Tong, M.-L.Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)-Hydroxide Clusters or Zinc(II)-Carboxylate Layers.Inorg. Chem.[J]2008, 47:190-199.
[62] Shi, X.; Zhu, G.; Wang, X.; Li, G.; Fang, Q.; Wu, G.; Tian, G.; Xue, M.; Zhao, X.; Wang, R.; Qiu, S.From a 1-D Chain, 2-D Layered Network to a 3-D Supramolecular Framework Constructed from a Metal-Organic Coordination Compound.Crystal Growth & Design[J]2005, 5,(1):207-213.
[63]计亮年;莫庭焕.生物无机化学导论[M].Vol.第一版.中山大学出版社:广州:1992:39-61, 84-85,258-295.
[64] Glasner, M. E.; Bergman, N. H.; Bartel, D. P.Metal Ion Requirements for Structure and Catalysis of an RNA Ligase Ribozyme.Biochemistry[J]2002, 41:8103-8112.
[65] Kluge, S.; Weston, J.Can a Hydroxide Ligand Trigger a Change in the Coordination Number of Magnesium Ions in Biological Systems?Biochemistry[J]2005, 44:4877-4885.
[66] Cowan, J. A.Metal Activation of Enzymes in Nucleic Acid Biochemistry.Chem. Rev.[J]1998, 98:1067-1087.
[67] Ellis-Davies, G. C. R.Neurobiology with Caged Calcium.Chem. Rev.[J]2008, 108:1603-1613.
[68] Wang, L.; Nancollas, G. H.Calcium Orthophosphates: Crystallization and Dissolution.Chem. Rev.[J]2008, 108,(11):4628-4669.
[69] Zhang, D.-J.; Song, T.-Y.; Zhang, P.; Shi, J.; Wang, Y.; Wang, L.; Ma, K.-R.; Yin, W.-R.; Zhao, J.; Fan, Y.; Xu, J.-N.Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3-D magnesium metal–organic framework Mg1.5(m5-btec)(H_2O)_2][H_2N(CH3)_2]H_2O.Inorganic Chemistry Communications[J]2007, 10:876-879.
[70] He, X.; Allan, J. F.; Noll, B. C.; Kennedy, A. R.; Henderson, K. W.Stereoselective Enolizations Mediated by Magnesium and Calcium Bisamides: Contrasting Aggregation Behavior in Solution and in the Solid State.J. Am. Chem. Soc.[J]2005, 127,(19):6920-6921.
[71]张必松.新型邻菲咯啉镁(II)配合物[Mg(H_2O)_4(phen)](phen)[C6H4(COO)_2]?H_2O的水热合成和晶体结构.结构化学[J]2004, 23:1411-1415.
[72] He, X.; Noll, B. C.; Beatty, A.; Mulvey, R. E.; Henderson, K. W.Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases: Structural Characterization of Potassium, Calcium, and Mixed Potassium-Calcium Enolates.J. Am. Chem. Soc.[J]2004, 126,(24):7444-7445.
[73]陈鹏刚;邓兆鹏;高山.三元混配的钙配合物[Ca(NO_3)(Phen)_2(H_2O)_2](NO_3)的合成与晶体结构研究.黑龙江大学自然科学学报[J]2006, 123:806-809.
[74] Murugavel, R.; Baheti, K.; Anantharaman, G.Reactions of 2-Mercaptobenzoic Acid with DivalentAlkaline Earth Metal Ions: Synthesis, Spectral Studies, and Single-Crystal X-ray Structures of Calcium, Strontium, and Barium Complexes of 2,2′-Dithiobis(benzoic acid).Inorg. Chem. [J]2001, 40:6870-6878.
[75] Murugavel, R.; Banerjee, S.First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)_2(H_2O)_2]n assembly.Inorganic Chemistry Communications[J]2003, 6:810-814.
[76] Murugavel, R.; Karambelkar, V. V.; Anantharaman, G.; Walawalkar, M. G.Synthesis, Spectral Characterization, and Structural Studies of 2-Aminobenzoate Complexes of Divalent Alkaline Earth Metal Ions: X-ray Crystal Structures of [Ca(2-aba)_2(OH_2)_3], [{Sr(2-aba)_2(OH_2)_2}H_2O], and [Ba(2-aba)_2(OH_2)] (2-abaH )= 2-NH_2C6H4COOH).Inorg. Chem.[J]2000, 39:1381-1390.
[77] Murugavel, R.; Korah, R.Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-Phenanthroline and 4, 4′-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands.Inorg. Chem. [J]2007, 46:11048-11062.
[78] Murugavel, R.; Kumar, P.; Walawalkar, M. G.; Mathialagan, R.A Double Helix Is the Repeating Unit in a Luminescent Calcium 5-Aminoisophthalate Supramolecular Edifice with Water-Filled Hexagonal Channels.Inorg. Chem.[J]2007, 46:6828-6830.
[79] Murugavel, R.; Kuppuswamy, S.; Randoll, S.Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal-Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline.Inorg. Chem.[J]2008, 47:6028-6039.
[80] J.Baier; U.Thewalt.Darstellung und Strukturen von Mg-Komplexen mit a,w-Dicarboxylato-Liganden (Dicarboxylat = Succinat, Glutarat und Suberat).Z.Anorg.Allg.Chem.[J]2002, 628,(1):315-321.
[81] Aliouane, K.; Djeghri, A.; Guehria-Laidoudi, A.; Dahaoui, S.; Lecomte, C.Synthesis, structure and thermal behaviour of a barium-glutarate framework.Journal of Molecular Structure[J]2007, 832:150-155.
[82] Groeneman, R. H.; Atwood, J. L.Terephthlate bridged coordination polymers based upon group two metals.Crystal Engineering[J]1999, 2:241-249.
[83] Davies, R. P.; Less, R. J.; Lickiss, P. D.; White, A. J. P.Framework materials assembled from magnesium carboxylate building units.Dalton Trans.[J]2007:2528-2535.
[84] Shuai, Q.; Chen, S.; Gao, S.Structural and thermal properties of three novel alkaline earth metalcoordination polymers based on 5-hydroxyisophthalate ligand.Inorganica Chimica Acta[J]2007, 360:1381-1387.
[85] Yang, Y.; Jiang, G.; Li, Y.-Z.; Bai, J.; Pan, Y.; You, X.-Z.Synthesis, structures and properties of alkaline earth metal benzene-1,4-dioxylacetates with three-dimensional hybrid networks.Inorganica Chimica Acta[J]2006, 359:3257-3263.
[86] Senkovska, I.; Kaskel, S.Solvent-Induced Pore-Size Adjustment in the Metal-Organic Framework [Mg3(ndc)_3(dmf)_4] (ndc = naphthalenedicarboxylate).Eur. J. Inorg. Chem.[J]2006:4564-4569.
[87] Volkringer, C.; Marrot, J.; Férey, G.; Loiseau, T.Hydrothermal Crystallization of Three Calcium-Based Hybrid Solids with 2,6-Naphthalene- or 4,4'-Biphenyl-Dicarboxylates.Cryst. Growth Des.[J]2008, 8:685-689.
[88] Williams, C. A.; Blake, A. J.; Wilson, C.; Hubberstey, P.; Schr?der, M.Novel Metal-Organic Frameworks Derived from Group II Metal Cations and Aryldicarboxylate Anionic Ligands.Cryst. Growth Des.[J]2008, 8:911-922.
[89] Plater, M. J.; Roberts, A. J.; Marr, J.; Lachowski, E. E.; Howie, R. A.Hydrothermal synthesis and characterisation of alkaline-earth metal salts of benzene-1,3,5-tricarboxylic acid.J. Chem. Soc., Dalton Trans.[J]1998:797-802.
[90] Zhu, H.-F.; Zhang, Z.-H.; Sun, W.-Y.; Okamura, T.-a.; Ueyama, N.Syntheses, Structures, and Properties of Two-Dimensional Alkaline Earth Metal Complexes with Flexible Tripodal Tricarboxylate Ligands.Crystal Growth & Design[J]2005, 5:177-182.
[91] Volkringer, C.; Loiseau, T.; Fe′rey, G. r.; Warren, J. E.; Wragg, D. S.; Morris, R. E.A new calcium trimellitate coordination polymer with a chain-like structure.Solid State Sciences[J]2007, 9:455-458.
[92]苏扬;臧双全;倪春林;李一志;孟庆金.过渡金属-碱土金属铜钙四核配合物Cu2Ca2L2(H_2O)6.2H_2O的合成和晶体结构.无机化学学报[J]2004, 20:845-849.
[93]高山;张竹艳;霍丽华;赵辉;赵经贵.一维链状2-氧-1(4H)-吡啶乙酸桥联钙配位聚合物[Ca(2-OPA)_2(H_2O)_2]n的合成!晶体结构及热稳定性研究.无机化学学报[J]2005, 21:771-776.
[94]高山;霍丽华;赵辉;谷长生;赵经贵.三维网状的4-羧基苯氧乙酸锶(II)配位聚合物[Sr_2(4-CPOA)_2(H_2O)5]n的合成、结构与热稳定性研究.无机化学学报[J]2005, 21:1245-1249.
[95]台夕市;冯一民;孔凡元;王大奇;谭民裕.一维链状配位聚合物[Ca(L)_2·(CH3OH)_2]n的合成、结构及热稳定性.无机化学学报[J]2008, 24:831-834.
[96] Fox, S.; Bu1sching, I.; Barklage, W.; Strasdeit, H.Coordination of Biologically Important r-Amino Acids to Calcium(II) at High pH: Insights from Crystal Structures of Calcium a-Aminocarboxylates.Inorg. Chem.[J]2007, 46:818-824.
[97] Gurunatha, K. L.; Uemura, K.; Maji, T. K.Temperature- and Stoichiometry-Controlled Dimensionality in a Magnesium 4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces.Inorg. Chem.[J]2008, 47,(15):6578-6580.
[98] Zhong, R.-Q.; Zou, R.-Q.; Du, M.; Takeichia, N.; Xu, Q.Observation of helical water chains reversibly inlayed in magnesium imidazole-4,5-dicarboxylate.CrystEngComm[J]2008, 10:1175-1179.
[99] Pan, L.; Frydel, T.; Sander, M. B.; Huang, X.; Li, J.The Effect of pH on the Dimensionality of Coordination Polymers.Inorg. Chem.[J]2001, 40:11271-1283.
[100]谈芸;唐智萍.为健康加镁[M].华东师范大学出版社:上海:2005:17-18.
[101] Sheldrick, G. M.Program for Solution and Refinement of Crystal Structures,Version 5.1; University of Gottingen: Germany, 1997.
[102]中本一雄.无机和配位化合物的红外和拉曼光谱[M].化学工业出版社:北京:1986:216-220.
[103]张中强.新型荧光材料的制备和性质[D].硕士论文,河北师范大学.石家庄, 2005:39-42.
[104] Deacon, G. B.; Phillips, R. J.Relationships between the carbon-oxygen stretching frequencies of carboxylexes and the type of carboxylate coordination.Coordination Chemistry Reviews[J]1980, 33:227-250.