胶印润版液性能的研究
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摘要
非离子表面活性剂润版液是近几年发展起来的新型润版液,是用非离子表面活性剂取代酒精的低表面张力润版液。由于其表面张力低、润湿性能好,能减少润版液的用量,成为高速多色胶印机中理想的润版液。本课题研究的主要目的是选择合适的非离子表面活性剂作为润版液添加剂,配置出一种润湿效果好、抗硬水能力强、性能稳定的新型润版液。
本文以印刷工艺原理和印刷适性为理论依据,通过对表面活性剂结构和性能的关系分析,利用HLB值法对表面活性剂进行筛选,从众多表面活性剂中初步筛选出四种非离子表面活性剂,AEO_7、吐温-80、APG0810、聚醚L64。通过对所选的表面活性剂进行浊点、硬水中稳定性以及临界胶团浓度等基本性能的测定,筛选出浊点较高、硬水中稳定性好且表面张力合适的两种非离子表面活性剂作为润版液添加剂,吐温-80、聚醚L64。
对吐温-80、聚醚L64进行复配,测定复配体系的润湿性,运用非线性回归对实验数据进行处理,求出复配比例与润湿性的回归方程,再运用规划求解得出协同效应最好时的最佳比例,确定出润版液主要添加剂的用量。
油墨的乳化率和乳化油墨的稳定性是衡量润版液性能很重要的指标。极性有机物和水溶性高分子化合物与表面活性剂分子相互作用,形成“复合物”,增加了油水界面膜的强度,从而可以提高乳化油墨的稳定性。本文选择润湿性好且具有吸湿性的丙三醇和聚乙二醇200作为润版液添加剂。通过均匀实验设计,确定了丙三醇和聚乙二醇200的最佳添加量。
润版液的pH值对胶印油墨的转移效果影响很大,pH值过低或过高的润版液都不适宜用来润湿印版。因此润版液应具有酸碱之间的缓冲性能,以保持润版液pH值的稳定性。本文选择具有清洗作用并且副作用小的柠檬酸和柠檬酸钠组成缓冲对,配置缓冲溶液。最后本文还对所配置的润版液的一些基本性能进行了测定。
结果表明:所配置的润版液满足印刷使用的要求,具有抗硬水性强、润湿性能好、缓冲性能好等特点。
The nonionic surfactant fountain solution is low surface tension and new solution which use nonionic surfactant instead of alcohol. It has become perfect fountain solution owing to its low surface tension and good wetting and reducing the dosage. The purpose is to choose suitable nonionic surfactant as additives of fountain solution and configure a new one that has good wetting and anti-hard water, and stable performance.
This paper chooses AEO_7, Tween-80, APG0810, L64 from the numerous surfactants as additives according to printing technical principle and printability and the relation of configuration and character of surfactant and the value of HLB. Through measuring the cloud point and hard water stability and critical micelle concentration of surfactant the Tween-80 and L64 was chose as additives owing to its higher cloud point and stable in hard water and suitable surface tension.
Tween-80 was blended with L64 then the wetting of mixed system was measured. Nonlinear regression was used to deal with experimental data and the mixing ratio and wetting was obtained. Then programming method was used to obtain best ratio when the best synergy and the dosage of main additives was determined.
The emulsion rate and stability of emulsion ink is an important indicator to evaluate the character of fountain solution. Polar organic interacted with water-soluble polymers and come into complex, so the interfacial film of ink and water was strengthened and the stability of emulsion ink was improved. The glycerol and polyethylene glycol200 was chose as additive because of its good wetting and hygroscopic. The dosage of additives of glycerol and polyethylene glycol200 was determined by uniform experimental design.
The pH value of fountain solution has an important effect on transfer of offset ink which too low or high will not be suitable for wetting plate. Fountain solution should have pH buffer in order to maintain pH stability of fountain solution. Citric acid and sodium citrate that have cleaning performance and less side-effect was chose to make up of buffer solution. Finally, some of the basic properties of configuration solution were measured.
The results show that configuration solution has strong anti-hard water, better wetting and buffer and meets the requirements of printing.
本文以印刷工艺原理和印刷适性为理论依据,通过对表面活性剂结构和性能的关系分析,利用HLB值法对表面活性剂进行筛选,从众多表面活性剂中初步筛选出四种非离子表面活性剂,AEO_7、吐温-80、APG0810、聚醚L64。通过对所选的表面活性剂进行浊点、硬水中稳定性以及临界胶团浓度等基本性能的测定,筛选出浊点较高、硬水中稳定性好且表面张力合适的两种非离子表面活性剂作为润版液添加剂,吐温-80、聚醚L64。
对吐温-80、聚醚L64进行复配,测定复配体系的润湿性,运用非线性回归对实验数据进行处理,求出复配比例与润湿性的回归方程,再运用规划求解得出协同效应最好时的最佳比例,确定出润版液主要添加剂的用量。
油墨的乳化率和乳化油墨的稳定性是衡量润版液性能很重要的指标。极性有机物和水溶性高分子化合物与表面活性剂分子相互作用,形成“复合物”,增加了油水界面膜的强度,从而可以提高乳化油墨的稳定性。本文选择润湿性好且具有吸湿性的丙三醇和聚乙二醇200作为润版液添加剂。通过均匀实验设计,确定了丙三醇和聚乙二醇200的最佳添加量。
润版液的pH值对胶印油墨的转移效果影响很大,pH值过低或过高的润版液都不适宜用来润湿印版。因此润版液应具有酸碱之间的缓冲性能,以保持润版液pH值的稳定性。本文选择具有清洗作用并且副作用小的柠檬酸和柠檬酸钠组成缓冲对,配置缓冲溶液。最后本文还对所配置的润版液的一些基本性能进行了测定。
结果表明:所配置的润版液满足印刷使用的要求,具有抗硬水性强、润湿性能好、缓冲性能好等特点。
The nonionic surfactant fountain solution is low surface tension and new solution which use nonionic surfactant instead of alcohol. It has become perfect fountain solution owing to its low surface tension and good wetting and reducing the dosage. The purpose is to choose suitable nonionic surfactant as additives of fountain solution and configure a new one that has good wetting and anti-hard water, and stable performance.
This paper chooses AEO_7, Tween-80, APG0810, L64 from the numerous surfactants as additives according to printing technical principle and printability and the relation of configuration and character of surfactant and the value of HLB. Through measuring the cloud point and hard water stability and critical micelle concentration of surfactant the Tween-80 and L64 was chose as additives owing to its higher cloud point and stable in hard water and suitable surface tension.
Tween-80 was blended with L64 then the wetting of mixed system was measured. Nonlinear regression was used to deal with experimental data and the mixing ratio and wetting was obtained. Then programming method was used to obtain best ratio when the best synergy and the dosage of main additives was determined.
The emulsion rate and stability of emulsion ink is an important indicator to evaluate the character of fountain solution. Polar organic interacted with water-soluble polymers and come into complex, so the interfacial film of ink and water was strengthened and the stability of emulsion ink was improved. The glycerol and polyethylene glycol200 was chose as additive because of its good wetting and hygroscopic. The dosage of additives of glycerol and polyethylene glycol200 was determined by uniform experimental design.
The pH value of fountain solution has an important effect on transfer of offset ink which too low or high will not be suitable for wetting plate. Fountain solution should have pH buffer in order to maintain pH stability of fountain solution. Citric acid and sodium citrate that have cleaning performance and less side-effect was chose to make up of buffer solution. Finally, some of the basic properties of configuration solution were measured.
The results show that configuration solution has strong anti-hard water, better wetting and buffer and meets the requirements of printing.
引文
[1]刘昕.胶版印刷工艺原理[M].北京:印刷工业出版社,2005:1-71
[2]Dr.Wolfgang Rauh.Investigations into the Reduction or Replacement of 2-propanol in Dampening Solutions for Offset Printing.FOGRA[C],1999,(3)
[3]Bernard Pineaux,Alessandro Gandini,Michael Has.The Effect of Water Hardness of Dampening Solutions on Printing Quality in OffsetLithography[A].TAGA Proceedings[C],1997:844-860.
[4]Bernard Pineaux,Alessandro Gandini,and Michael Has.Further Investigation into the Effect of Dampening Solution Hardnesson Offset Lithography[A].TAGA Proceedings[C],1998:451-465.
[5]R.Bassemir,R.Krishnan.Optimizing Lithographic Performance-A Physical-Chemical Approach[A].TAGA Proceedings[C],1987:238-249.
[6]Dipl.-ing.Helmut wordel.Quick Dampening Solution Test for Operators in the Press Room.FOGRA[C],1999,(8)
[7]Bernd Renner.The future for solvent in the offset printing process[J].Pigment & Resin Technology,Volume 29,Numberl,2000:235-251.
[8]Ryszard Sprycha,Jean-Dominique Turgis.Effect of Polymer/Surfactant Interactions on Rheological Properties of Polymer/Surfactant Mixtures[A].TAGA Proceedings[C],1999:636-649.
[9]Dr.Richard,M.tiaPodhajny.What is the Role of Tack in Ptin-ting Inks[J].Paper,Film and Foil Converter,2002,76(10):327-342
[10]M.J.Thompson,M.R.Mackley.Lithographic Emulsion Rheology at Low and High Shear Rates[A].TAGA Proceedings[C]2000:634-649.
[11]Yang Xiang,Doug,W.Bousfield.Ink Gloss Dynamics:Effect of Ink Emuls- ification and Coating Structure.TAGA Proceedings[C],2000:680-695.
[12]P.Aurenty,J.F.Palierne,and A.Gandini.Viscoelasticity of Water/InkEmulsions at Low and High Frequency[A].TAGA Proceedings[C]1998:564-582.
[13]冯瑞乾.印刷原理及工艺[M].北京:印刷工业出版社,2005:101-105
[14]John Kreeh,Richard Durand,Jr.Dynamic Moitoring of Water During Lithographic Printing[A].TAGA Proceedings[C],1998:711-723.
[15]H.Juhola.用联机密度计控制水墨平衡[J].印刷科技情报,1989(1):33-39.
[16]王灵变.油墨乳化及影响[J].山西化工,2005(11):42-43
[17]李国宏.pH值在印刷工业中的应用[J].今日印刷,2000(4):93-94
[18]罗大林.润版液导电率的调整与控制[J].今日印刷,2002(2):64-65
[19]李小东.润版液中水的硬度研究[J].广东印刷,1999(5):31-32
[20]齐晓堃,方伟,高桂红.润版液性能与水硬度的影响研究[J].北京印刷学院学报,2005(3):17-20
[21]齐晓堃,杨永刚,丁瀚文.水的硬度对油墨乳化率的影响[J].包装工程,2007(10):39-41
[22]张印辉,张海燕.润版液自动控制装置[J].印刷世界,2004(2):28-29
[23]李素芬.一种应用于润版液的低成本pH监控仪的研究[J].现代电子技术(14):29-30
[24]管力明,陈梅.胶印润版液膜厚动态检测技术研究[J].包装工程,2007(1):58-60
[25]北京中科爱比西科技发展有限公司 http://www.ipcbeij.com.cn
[26]北京市华从经贸有限责任公司 http://www.bihuacong.com
[27]上海立德精细化工有限公司 http://www.li-de.com.cn
[28]上海新日光印刷材料有限公司 http://www.xrgprint.com
[29]张建青.硅表面活性剂润版液的研究和配置[D].中国人民解放军信息工程大学,2002
[30]杨永刚.环保非离子表面活性剂润版液的配方探讨[J].包装工程,2006(10):38-40
[31]中国知识产权网 http://211.157.104.86:8080/cnipr/zljs/index.jsp.
[32]庞礼军.润湿现象中的附着力与内聚力[J].贵州师范大学学报,2000(11):89-91
[33]颜肖慈.界面化学[M].北京:化学工业出版社,2005
[34]赵振国.接触角及其在表面化学研究中的应用[J].化学研究与应用,2000(8):370-374
[35]吉守祥.固体表面润湿问题的探讨[J].青海师专学报,2003(6):93-94
[36]赵国玺.表面活性剂作用原理[M].北京:中国轻工业出版社,2003
[37]杜巧云,葛红.表面活性剂基础及应用[M].北京:中国石化出版社,1996
[38]严群芳.非离子表面活性剂的性质及应用[J].贵州化工,2005(10):4-7
[39]李云雁.试验设计与数据处理[M].北京:化学工业出版社,2005
[40]王沫然.MATLAB与科学计算[M].北京:电子工业出版社,2003
[41]焦学瞬,贺明波.乳状液与乳化技术新应用[M].北京:化学工业出版社,2005
[2]Dr.Wolfgang Rauh.Investigations into the Reduction or Replacement of 2-propanol in Dampening Solutions for Offset Printing.FOGRA[C],1999,(3)
[3]Bernard Pineaux,Alessandro Gandini,Michael Has.The Effect of Water Hardness of Dampening Solutions on Printing Quality in OffsetLithography[A].TAGA Proceedings[C],1997:844-860.
[4]Bernard Pineaux,Alessandro Gandini,and Michael Has.Further Investigation into the Effect of Dampening Solution Hardnesson Offset Lithography[A].TAGA Proceedings[C],1998:451-465.
[5]R.Bassemir,R.Krishnan.Optimizing Lithographic Performance-A Physical-Chemical Approach[A].TAGA Proceedings[C],1987:238-249.
[6]Dipl.-ing.Helmut wordel.Quick Dampening Solution Test for Operators in the Press Room.FOGRA[C],1999,(8)
[7]Bernd Renner.The future for solvent in the offset printing process[J].Pigment & Resin Technology,Volume 29,Numberl,2000:235-251.
[8]Ryszard Sprycha,Jean-Dominique Turgis.Effect of Polymer/Surfactant Interactions on Rheological Properties of Polymer/Surfactant Mixtures[A].TAGA Proceedings[C],1999:636-649.
[9]Dr.Richard,M.tiaPodhajny.What is the Role of Tack in Ptin-ting Inks[J].Paper,Film and Foil Converter,2002,76(10):327-342
[10]M.J.Thompson,M.R.Mackley.Lithographic Emulsion Rheology at Low and High Shear Rates[A].TAGA Proceedings[C]2000:634-649.
[11]Yang Xiang,Doug,W.Bousfield.Ink Gloss Dynamics:Effect of Ink Emuls- ification and Coating Structure.TAGA Proceedings[C],2000:680-695.
[12]P.Aurenty,J.F.Palierne,and A.Gandini.Viscoelasticity of Water/InkEmulsions at Low and High Frequency[A].TAGA Proceedings[C]1998:564-582.
[13]冯瑞乾.印刷原理及工艺[M].北京:印刷工业出版社,2005:101-105
[14]John Kreeh,Richard Durand,Jr.Dynamic Moitoring of Water During Lithographic Printing[A].TAGA Proceedings[C],1998:711-723.
[15]H.Juhola.用联机密度计控制水墨平衡[J].印刷科技情报,1989(1):33-39.
[16]王灵变.油墨乳化及影响[J].山西化工,2005(11):42-43
[17]李国宏.pH值在印刷工业中的应用[J].今日印刷,2000(4):93-94
[18]罗大林.润版液导电率的调整与控制[J].今日印刷,2002(2):64-65
[19]李小东.润版液中水的硬度研究[J].广东印刷,1999(5):31-32
[20]齐晓堃,方伟,高桂红.润版液性能与水硬度的影响研究[J].北京印刷学院学报,2005(3):17-20
[21]齐晓堃,杨永刚,丁瀚文.水的硬度对油墨乳化率的影响[J].包装工程,2007(10):39-41
[22]张印辉,张海燕.润版液自动控制装置[J].印刷世界,2004(2):28-29
[23]李素芬.一种应用于润版液的低成本pH监控仪的研究[J].现代电子技术(14):29-30
[24]管力明,陈梅.胶印润版液膜厚动态检测技术研究[J].包装工程,2007(1):58-60
[25]北京中科爱比西科技发展有限公司 http://www.ipcbeij.com.cn
[26]北京市华从经贸有限责任公司 http://www.bihuacong.com
[27]上海立德精细化工有限公司 http://www.li-de.com.cn
[28]上海新日光印刷材料有限公司 http://www.xrgprint.com
[29]张建青.硅表面活性剂润版液的研究和配置[D].中国人民解放军信息工程大学,2002
[30]杨永刚.环保非离子表面活性剂润版液的配方探讨[J].包装工程,2006(10):38-40
[31]中国知识产权网 http://211.157.104.86:8080/cnipr/zljs/index.jsp.
[32]庞礼军.润湿现象中的附着力与内聚力[J].贵州师范大学学报,2000(11):89-91
[33]颜肖慈.界面化学[M].北京:化学工业出版社,2005
[34]赵振国.接触角及其在表面化学研究中的应用[J].化学研究与应用,2000(8):370-374
[35]吉守祥.固体表面润湿问题的探讨[J].青海师专学报,2003(6):93-94
[36]赵国玺.表面活性剂作用原理[M].北京:中国轻工业出版社,2003
[37]杜巧云,葛红.表面活性剂基础及应用[M].北京:中国石化出版社,1996
[38]严群芳.非离子表面活性剂的性质及应用[J].贵州化工,2005(10):4-7
[39]李云雁.试验设计与数据处理[M].北京:化学工业出版社,2005
[40]王沫然.MATLAB与科学计算[M].北京:电子工业出版社,2003
[41]焦学瞬,贺明波.乳状液与乳化技术新应用[M].北京:化学工业出版社,2005