杂环稀土配合物的合成与催化性能研究
|
摘要
本文首次合成了两种新型含噻唑和吡啶杂环的希夫碱化合物及其稀土金属配合物,表征了其结构,并将其应用于环状单体和烯烃类单体催化均聚合和共聚合;另外还合成了一类杂环稀土金属有机胺化合物,将其应用与极性烯烃类单体MMA的均聚合。系统讨论了稀土种类、聚合溶剂、聚合条件等对聚合反应的影响,表征了聚合物的结构与性能,并探讨了聚合反应的机理。
在所合成的噻唑希夫碱稀土配合物中,其均配物Nd(DBTP)_3·2THF可以单组分催化ε-己内酯开环聚合,通过聚合行为的研究得到了聚合的最优条件为[CL]/[Nd]=1600,[CL]=2.26mol/L,50℃,1h,聚合反应的单体转化率可以达到94%,所得聚己内酯的数均分子量可以达到5.4万;通过GPC、DSC、~1H NMR及偏光显微镜表征了聚合物的结构和热性能,对聚合产物的GPC表征,发现该聚合反应存在较明显的酯交换反应,通过改变聚合条件可以在一定范围内调节聚合物的分子量及分子量分布;通过用异丙醇终止低分子量聚合物的端基分析确证了该配合物引发CL聚合的过程为“酰氧键断裂开环的配位阴离子聚合机理”
而其带氯的配合物Nd(DBTP)_2Cl_3在助催化剂Al(iBu)_3的作用下,可以用来高活性催化异戊二烯均聚,聚合物转化率可达95%,数均分子量最高可达到58万;该Nd(DBTP)_2Cl_3/Al(iBu)_3双组份体系催化聚合产物PIP具有高顺式(95%cis-1,4)结构及少量3,4链节,不含反式链节;通过对聚合条件研究和聚合产物GPC表征详细讨论了Al/Nd摩尔比、聚合温度对聚合体系活性中心的影响,证明该双组份催化体系中存在向烷基铝的链转移反应,在高的Al/Nd比和高温下加快链转移反应使得聚合产物分子量减小及分子量分布变宽。
吡啶希夫碱稀土配合物可以高活性的催化环状单体如己内酯(CL)、环碳酸酯及丙交酯开环聚合。其中配合物Y(DBPP)_2Cl·3THF可以有效地催化L-丙交酯(LLA)均聚合及CL和LLA的共聚合,在较温和的条件下(60℃)即可催化L-丙交酯开环聚合,~1H NMR和~(13)C NMR谱图证明用该吡啶希夫碱稀土配合物催化的PLLA在聚合过程中不会发生L-构型向D-构型的转变,即聚合过程中不存在手性中心的翻转;通过DSC和偏光显微镜表征了PLLA的热性能和结晶性能,与文献报道的纯PLLA各项性能一致;通过端基分析研究了该吡啶希夫碱稀土配合物催化LLA聚合的机理,得出LLA开环的方式应该为酰氧基断裂,聚合的机理类似于己内酯,为配位阴离子机理。通过和CL的共聚合,所得共聚物PCL-b-PLLA的数均分子量最高可以达13.5万,分子量分布只有1.23;系统讨论了聚合加料顺序、催化剂浓度、嵌段长度、聚合温度及时间对聚合反应的影响,发现只有按一定的顺序(先CL后LLA),催化剂浓度为1.9×10~(-3)mol/L,较多CL单体和少量LLA共聚,较低温度和较长时间下才能得到分子量大于10万的PCL-b-PLLA共聚物;研究了不同PCL与PLLA嵌段长度对聚合反应以及聚合物的热性能和结晶性能的影响,实验发现PCL与PLLA会相互干扰对方的结晶性,使PCL和PLLA链段都不易结晶。
首次合成了吡啶氮硅烷稀士配合物Ln(PyNSiMe_3)_2Cl·THF,该类配合物可以单组分引发MMA聚合,聚合活性高,所得PMMA间规立构含量较高(＞70%),粘均分子量最高可以达到12.9×10~5;系统讨论了稀土元素种类、聚合溶剂、单体浓度、单体引发剂比例以及温度、时间对聚合的影响和对产物立构规整度的影响;研宂了配合物Sm(PyNSiMe_3)_2Cl·THF催化MMA聚合反应在聚合前期的反应动力学,结果表明该聚合反应在前期有活性聚合的特征;通过端基分析的方法研究了该聚合反应的机理,并推测出可能的机理路线图。
In this paper, two novel heterocycle schiff base derivatives and a pyridine amino deravative have been synthesized, then its rare earth complexes have also been prepared as a polmerization catalyst for ring opening polymerization of cyclic ester and coordination polymerization of olefin. These complexes have characterized by 1H NMR and element analysis, and also their catalytic behaviour has been researched. The structure and property of the polymer and copolymer initiated by these complexes have also been characterized, and the postulated mechanism of polymerization has been proposed.
An aromatic heterocyclic Schiff base neodymium complex bearing thiazole was synthesized and its activity in the ring opening polymerization ofε-caprolactone (CL) was examined. The conditions of the CL/Nd molar ratio, monomer concentration, polymerization time and temperature were investigated. Activities of ca.171kg/Nd·h were obtained under the optimum condition (CL/Nd=1600(molar ratio), [CL]=2.26mol L~(-1), 1h at 50℃), giving a polycaprolactone(PCL) of number molecular weight Mn=5.4×10~4 and molecular weight distribution MWD=1.96. The conversion of CL monomer as high as 94% was observed after polymerized for one hour. The mechanism of coordination polymerization has also been investigated.
Neodymium based thiazole heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high c/s-1,4 stereo specificity (ca.95%) and high molecular weight (ca.10~5) in the presence of the tri-isobutyl aluminum(AI(iBu)_3) as cocatalyst. The microstructure of obtained polyisoprene was investigated by FTIR, 1H NMR. Two different kinds of active centers in the catalyst system were examined by GPC method.
Pyriding Schiff base rare earth complex(Y(DBPP)_2Cl·3THF) can be used as an efficient catalyst for ring opening polymerizaiton of cyclic ester such asε-caprolactone(CL), cyclic carbonic ester and lactide etc. The polymerizaiton of L-lactide under the condition of [LLA]/[Y]=500, 60℃, 40min produced poly(L-lactide) without the convert of chiral center of LLA monomer. The thermal behaviour and crystallinity are coinciding with the reported reference. Through the copolymerization of LLA with CL monomer, the molecualr weight has been increased to 13.5×10~4 with narrow distribution (1.23). The block copolymer can only be obtained by the sequence of polymerization which initiated CL first. The thermal behaviour and crystallinity of different length of block have been charaterized and the interference of each block has been confirmed.
The rare earth samarium complex of N-(trimethylsilyl)pyridin-2-amine is an efficient catalyst of polymerization of polar olefin monomer MMA, giving a syndiotactic PMMA with molecular weight of 12.9×10~5. Its catalytic behaviour has been researched and the kinetic research proved that the polymerization of MMA in the very beginning (<40min) has a certain character of living polymerization. Through terminal group analysis, a postulated mechanism has been proposed.
在所合成的噻唑希夫碱稀土配合物中,其均配物Nd(DBTP)_3·2THF可以单组分催化ε-己内酯开环聚合,通过聚合行为的研究得到了聚合的最优条件为[CL]/[Nd]=1600,[CL]=2.26mol/L,50℃,1h,聚合反应的单体转化率可以达到94%,所得聚己内酯的数均分子量可以达到5.4万;通过GPC、DSC、~1H NMR及偏光显微镜表征了聚合物的结构和热性能,对聚合产物的GPC表征,发现该聚合反应存在较明显的酯交换反应,通过改变聚合条件可以在一定范围内调节聚合物的分子量及分子量分布;通过用异丙醇终止低分子量聚合物的端基分析确证了该配合物引发CL聚合的过程为“酰氧键断裂开环的配位阴离子聚合机理”
而其带氯的配合物Nd(DBTP)_2Cl_3在助催化剂Al(iBu)_3的作用下,可以用来高活性催化异戊二烯均聚,聚合物转化率可达95%,数均分子量最高可达到58万;该Nd(DBTP)_2Cl_3/Al(iBu)_3双组份体系催化聚合产物PIP具有高顺式(95%cis-1,4)结构及少量3,4链节,不含反式链节;通过对聚合条件研究和聚合产物GPC表征详细讨论了Al/Nd摩尔比、聚合温度对聚合体系活性中心的影响,证明该双组份催化体系中存在向烷基铝的链转移反应,在高的Al/Nd比和高温下加快链转移反应使得聚合产物分子量减小及分子量分布变宽。
吡啶希夫碱稀土配合物可以高活性的催化环状单体如己内酯(CL)、环碳酸酯及丙交酯开环聚合。其中配合物Y(DBPP)_2Cl·3THF可以有效地催化L-丙交酯(LLA)均聚合及CL和LLA的共聚合,在较温和的条件下(60℃)即可催化L-丙交酯开环聚合,~1H NMR和~(13)C NMR谱图证明用该吡啶希夫碱稀土配合物催化的PLLA在聚合过程中不会发生L-构型向D-构型的转变,即聚合过程中不存在手性中心的翻转;通过DSC和偏光显微镜表征了PLLA的热性能和结晶性能,与文献报道的纯PLLA各项性能一致;通过端基分析研究了该吡啶希夫碱稀土配合物催化LLA聚合的机理,得出LLA开环的方式应该为酰氧基断裂,聚合的机理类似于己内酯,为配位阴离子机理。通过和CL的共聚合,所得共聚物PCL-b-PLLA的数均分子量最高可以达13.5万,分子量分布只有1.23;系统讨论了聚合加料顺序、催化剂浓度、嵌段长度、聚合温度及时间对聚合反应的影响,发现只有按一定的顺序(先CL后LLA),催化剂浓度为1.9×10~(-3)mol/L,较多CL单体和少量LLA共聚,较低温度和较长时间下才能得到分子量大于10万的PCL-b-PLLA共聚物;研究了不同PCL与PLLA嵌段长度对聚合反应以及聚合物的热性能和结晶性能的影响,实验发现PCL与PLLA会相互干扰对方的结晶性,使PCL和PLLA链段都不易结晶。
首次合成了吡啶氮硅烷稀士配合物Ln(PyNSiMe_3)_2Cl·THF,该类配合物可以单组分引发MMA聚合,聚合活性高,所得PMMA间规立构含量较高(＞70%),粘均分子量最高可以达到12.9×10~5;系统讨论了稀土元素种类、聚合溶剂、单体浓度、单体引发剂比例以及温度、时间对聚合的影响和对产物立构规整度的影响;研宂了配合物Sm(PyNSiMe_3)_2Cl·THF催化MMA聚合反应在聚合前期的反应动力学,结果表明该聚合反应在前期有活性聚合的特征;通过端基分析的方法研究了该聚合反应的机理,并推测出可能的机理路线图。
In this paper, two novel heterocycle schiff base derivatives and a pyridine amino deravative have been synthesized, then its rare earth complexes have also been prepared as a polmerization catalyst for ring opening polymerization of cyclic ester and coordination polymerization of olefin. These complexes have characterized by 1H NMR and element analysis, and also their catalytic behaviour has been researched. The structure and property of the polymer and copolymer initiated by these complexes have also been characterized, and the postulated mechanism of polymerization has been proposed.
An aromatic heterocyclic Schiff base neodymium complex bearing thiazole was synthesized and its activity in the ring opening polymerization ofε-caprolactone (CL) was examined. The conditions of the CL/Nd molar ratio, monomer concentration, polymerization time and temperature were investigated. Activities of ca.171kg/Nd·h were obtained under the optimum condition (CL/Nd=1600(molar ratio), [CL]=2.26mol L~(-1), 1h at 50℃), giving a polycaprolactone(PCL) of number molecular weight Mn=5.4×10~4 and molecular weight distribution MWD=1.96. The conversion of CL monomer as high as 94% was observed after polymerized for one hour. The mechanism of coordination polymerization has also been investigated.
Neodymium based thiazole heterocyclic Schiff base complex was prepared and applied for the coordination polymerization of isoprene. This complex polymerized isoprene to afford products featuring high c/s-1,4 stereo specificity (ca.95%) and high molecular weight (ca.10~5) in the presence of the tri-isobutyl aluminum(AI(iBu)_3) as cocatalyst. The microstructure of obtained polyisoprene was investigated by FTIR, 1H NMR. Two different kinds of active centers in the catalyst system were examined by GPC method.
Pyriding Schiff base rare earth complex(Y(DBPP)_2Cl·3THF) can be used as an efficient catalyst for ring opening polymerizaiton of cyclic ester such asε-caprolactone(CL), cyclic carbonic ester and lactide etc. The polymerizaiton of L-lactide under the condition of [LLA]/[Y]=500, 60℃, 40min produced poly(L-lactide) without the convert of chiral center of LLA monomer. The thermal behaviour and crystallinity are coinciding with the reported reference. Through the copolymerization of LLA with CL monomer, the molecualr weight has been increased to 13.5×10~4 with narrow distribution (1.23). The block copolymer can only be obtained by the sequence of polymerization which initiated CL first. The thermal behaviour and crystallinity of different length of block have been charaterized and the interference of each block has been confirmed.
The rare earth samarium complex of N-(trimethylsilyl)pyridin-2-amine is an efficient catalyst of polymerization of polar olefin monomer MMA, giving a syndiotactic PMMA with molecular weight of 12.9×10~5. Its catalytic behaviour has been researched and the kinetic research proved that the polymerization of MMA in the very beginning (<40min) has a certain character of living polymerization. Through terminal group analysis, a postulated mechanism has been proposed.
引文
[1]陶治,杂环及希夫碱类化合物的合成及晶体结构表征,分析化学.2005,青岛科技大学:硕士学位论文.
[2]P Pfeiffer,E Bucholz,O Hauer,Synthesis and Chareacter of Some Metal Complex of Schiff Base Ligand.J Parkt Chem,1931.129:163-167.
[3]Pier Giorgio Cozzi,Metal-Salen Schiff base complexes in catalysis:practical aspects.Chemical Society Reviews,2004.33:410-421.
[4]P Guerrio,U Casellato,S.Tamburini,Inorg.Chim.Acta,1987.129:127.
[5]姚克敏,李冬成,沈联芳,化学学报,1993.51:677.
[6]Sunirban Das,Samudranil Pal,Copper(Ⅱ)complexes with tridentate N-(benzoyl)-N'-(salicylidene)-hydrazine and monodentate N-heterocycles:Investigations of intermolecular interactions in the solid state.Journal of Molecular Structure,2005.753(1-3):68-79.
[7]Sunirban Das,Samudranil Pal,Self-assembly of copper(Ⅱ)complexes with a dibasic tridentate ligand and monodentate N-heterocycles:structural,magnetic and EPR studies.Journal of Molecular Structure,2005.741(1-3):183-192.
[8]Sunirban Das,G.P.Muthukrumaragopal,Satyanarayan Pal,Samudranil Pal,A one-dimensional assembly of a square-planar copper(Ⅱ)complex with alternating short and long Cu...Cu distances.Metal ion spin-exchange via p-p interactions.New Journal of Chemistry,2003.27(7):1102-1107.
[9]M.Saidul Islam,Motahera Begum,Harendra Math Roy,Mixed-ligand complexes of cobalt(Ⅱ)and nickel(Ⅱ)with a tridentate schiff base and heterocyclic amines.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1995.23(2):293-306.
[10]R.N.Patel,Nripendra Singh,V.L.N.Gundla,Synthesis,structure and properties of ternary copper(Ⅱ)complexes of ONO donor Schiff base,imidazole,2,2 '-bipyridine and 1,10-phenanthroline.Polyhedron,2006.25(17):3312-3318.
[11]Jonathan L.Sessler,Elisa Tomat,Tarak D.Mody,Vincent M.Lynch,et al.,A Schiff Base Expanded Porphyrin Macrocycle that Acts as a Versatile Binucleating Ligand for Late First-Row Transition Metals.Inorganic Chemistry,2005.44(7):2125-2127.
[12]Valeria Amendola,Luigi Fabbrizzi,Luca Gianelli,Cristina Maggi,et al.,Electrochemical Assembling/Disassembling of Helicates with Hysteresis.Inorganic Chemistry,2001.40(14):3579-3587.
[13]David A.Bardwell,John C.Jeffery,Peter L.Jones,Jon A.McCleverty,et al.,Lanthanide complexes of the tetradentate N-donor ligand dihydrobis [3-(2-pyridyl)pyrazolyl]borate and the terdentate N-donor ligand 2,6-bis(1H-pyrazol3-yl)pyridine:syntheses,crystal structures and solution structures based on luminescence lifetime studies.J.Chem.Soc.,Dalton Trans.,,1997:2079.
[14]B.D.Chandler,D.T.Cramb,G.K.H.Shimizu,Microporous Metal-Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks.J.Am.Chem.Soc.,2006.128(32):10403-10412.
[15]H.S.Wang,B.Zhao,B.Zhai,W.Shi,et al.,Syntheses,Structures,and Photoluminescence of One-Dimensional Lanthanide Coordination Polymers with 2,4,6-Pyridinetricarboxylic Acid.Cryst.Growth Des.,2007.7(9):1851-1857.
[16]Zheng Wang,Joseph Reibenspies,Arthur E.Martell,Design,Synthesis,and X-ray Structural Characterization of New Dinucleating Macrocyclic Ligands and a Novel Phenolate-Bridged Dilanthanum(Ⅲ)Complex.Inorganic Chemistry,1997.36(4):629-636.
[17]M.Seitz,A.G.Oliver,K.N.Raymond,The Lanthanide Contraction Revisited.J.Am.Chem.Sot.,2007.129(36):11153-11160.
[18]Michael Barz,Monika Rauch,Werner R.Thiel,New Schiffbases derived from trans-pyrazolylcyclohexanol:synthesis,co-ordination chemistry and structural features.Journal of the Chemical Society,Dalton Transactions:Inorganic Chemistry,1997(12):2155-2161.
[19]Angel Garcia-Raso,Juan J.Fiol,Adela Lopez-Zafra,Andres Tasada,et al.,Different ways of interaction between binary copper(Ⅱ)-Schiff bases (Cu-N-salicylideneserinato)and pyrimidine derivatives.Polyhedron,2006.25(11):2295-2302.
[20]Kerim Serbest,Ismail Degirmencioglu,Yasemin Unver,Mustafa Er,et al.,Microwave-assisted synthesis and characterization and theoretical calculations of the first example of free and metallophthalocyanines from salen type Schiff base derivative bearing thiophen and triazole heterocyclic rings.Journal of Organometallic Chemistry,2007.692(25):5646-5654.
[21]T.R.Rao,P.A.Kumar,Studies of some lanthanide(Ⅲ)complexes of heterocyclic ligands.Part Ⅲ.Eight-coordinated complexes of an unsymmetrical tetradentate Schiff base.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1995.25(6):1011-26.
[22]Ramalingam Balamurugan,Mallayan Palaniandavar,Malcolm A.Halcrow,Copper(Ⅱ)complexes of sterically hindered Schiff base ligands:Synthesis,structure,spectra and electrochemistry.Polyhedron,2006.25:1077-1088.
[23]N.E.Borisova,V.V.Roznyatovskii,M.D.Reshetova,Yu.A.Ustynyuk,Synthesis of New Polydentate Acyclic Schiff Bases by Reaction of 2,3-Diaminomaleodinitrile with Dicarbonyl Compounds.Russian Journal of Organic Chemistry,2005.41(7):1005-1010.
[24]Farba Bouyagui Tamboura,Pepe Marcel Haba,Mohamed Gaye,Abdou Salam Sall,et al.,Structural studies of bis-(2,6-diacetylpyridine-bis-(phenylhydrazone))and X-ray structure of its Y(Ⅲ),Pr(Ⅲ),Sm(Ⅲ)and Er(Ⅲ)complex.Polyhedron,2004.23(7):1191-1197.
[25]F.Benetollo,G.Bombieri,W.A.Gootee,K.K.Fonda,et al.,Constitutional isomers and stereoisomers of lanthanum(Ⅲ)complexes of the dimethyl-substituted six-nitrogen-donor ligand C24H30N6 and crystal structure of [La(C_(24)H_(30)N_6)(NCS)_3(H_2O)].O.5H_2O.Polyhedron,1998.17(20):3633-3642.
[26]Wanda Radecka-Paryzek,Violetta Patroniak,Maciej Kubicki,The template synthesis and characterization of pentaaza macrocyclic complexes of rare earth elements.The crystal structure of the 2,14-dimethyl-3,6,10,13,19-pentaazabicyclo [13.3.1]nonadeca-1(19),2,13,15,17-pentaene-dichlorolutetium(Ⅲ)perchlorate.Polyhedron,2003.22(20):2773-2779.
[27]Harry Adams,Rufina Bastida,David E.Fenton,Alejandro Macias,et al.,Zinc and cadmium complexes of an 18-membered N_4O_2 oxaaza-Schiff base macrocycle and the corresponding reduced form.Journal of the Chemical Society,Dalton Transactions:Inorganic Chemistry,1999(23):4131-4137.
[28]Lorenzo Tei,Alexander J.Blake,Claire Wilson,Martin Schroder,Lanthanide complexes of new nonadentate imino-phosphonate ligands derived from 1,4,7-triazacyclononane:synthesis,structural characterisation and NMR studies.Dalton Transactions,2004(13):1945-1952.
[29]C K Bhaskare,P P Hankare,Cobalt-,nickel- and copper(Ⅱ)complexes of schiffbases with Nor S donor sites.J Indian Chem.Soc.,1995.72(9):585-587.
[30]A.Proto,C.Capacchione,V.Venditto,J Okuda,Macromolecules,2003.36:9249.
[31]Har Lal Singh,A.K.Varshney,Synthetic,structural,and biochemical studies of organotin(Ⅳ)with Schiff bases having nitrogen and sulphur donor ligands.Bioinorganic Chemistry and Applications,2006:1-7.
[32]H.L.Singh,M.Shama,A.K.Vaeshney,Studies on coordination compounds of organotin(Ⅳ)with schiff base of amino acids.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000.30(3):445-456.
[33]戴晴,王志,刘燕,张以群,一种新型含硫杂环的金属配合物的合成与表征.东北师大学报自然科学版,2005.37(3):135-137.
[34]Daniel T.Thangadurai,Son-Ki Ihm,Ruthenium(Ⅱ)carbonyl complexes containingNS andNNSS donor atoms.Wuji Huaxue Xuebao,2006.22(6):1055-1061.
[35]Agnete la Cour,Matthias Findeisen,Alan Hazell,Rita Hazell,et al.,Metal(Ⅱ)N_2S_2 Schiff-base complexes incorporating pyrazole or isoxazole(M = Ni,Cu or Zn).Spin states,racemization kinetics and electrochemistry.J.Chem.Soc.,Dalton Trans.,,1997:121-128.
[36]Alaaddin Cukurovali,Ibrahim Ylimaz,Habibe Ozmen,Antimicrobial activity studies of the metal complexes derives from substituted cyclibutane substituted thiazole schiff base ligands.Transition Metal Chemistry(Dordrecht,Netherlands),2001.26:619-624.
[37]Kalagouda B.Gudasi,Siddappa A.Patil,Ramesh S.Vadavi,Rashmi V.Shenoy,et al.,Synthesis and Spectral Characterization of Some Transition Metal Complexes Containing Pentadentate SNNNS Donor Heterocyclic Schiff Base Ligands.Transition Metal Chemistry(Dordrecht,Netherlands),2005.30(8):1014-1019.
[38]Christian Muller,Zoraida Freixa,Martin Lutz,Anthony L.Spek,et al.,Wide-Bite-Angle Diphosphinines:Design,Synthesis,and Coordination Properties.Organometallics,2008.27(5):834-838.
[39]Zahid H.Chohan,Humayun Pervez,A.Rauf,Khalid M.Khan,et al.,Antibacterial and Antifugal Mono- and Di-substituted Symmertrical and Unsymmetrical Triazine-derived Schiff-base and their Transition Metal Complexes.Journal of Enzyme Inhibition and Medicinal Chemistry,2004.19(2):161-168.
[40]Shanta Dhar,Munirathinam Nethaji,Akhil R.Chakravarty,DNA Cleavage on Photoexposure at the d-d Band in Ternary Copper(Ⅱ)Complexes Using Red-Light Laser.Inorganic Chemistry,2006.45(26):11043-11050.
[41]Shanta Dhar,Munirathinam Nethaji,Akhil R.Chakravarty,Synthesis,crystal structure and photo-induced DNA cleavage activity of ternary copper(Ⅱ)complexes of NSO-donor Schiff bases and NN-donor heterocyclic ligands.Inorganica Chimica Acta,2005.358(7):2437-2444.
[42]Pattubala A.N.Reddy,Munirathinam Nethaji,Akhil R.Chakravarty,Hydrolytic cleavage of DNA by ternary amino acid Schiff base copper(Ⅱ)complexes having planar heterocyclic ligands.European Journal of Inorganic Chemistry,2004(7):1440-1446.
[43]Pattubala A.N.Reddy,Bidyut K.Santra,Munirathinam Nethaji,Akhil R.Chakravarty,Metal-assisted light-induced DNA cleavage activity of 2-(methylthio)phenylsalicylaldimine Schiff base copper(Ⅱ)complexes having planar heterocyclic bases.Journal of Inorganic Biochemistry,2004.98(2):377-386.
[44]Shanta Dhar,Dulal Senapati,Puspendu K.Das,Pabitra Chattopadhyay,et al.,Ternary Copper Complexes for Photocleavage of DNA by Red Light:Direct Evidence for Sulfur-to-Copper Charge Transfer and d-d Band Involvement.Journal of the American Chemical Society,2003.125(40):12118-12124.
[45]Kiran Singh,Manjeet Singh Barwa,Parikshit Tyagi,Synthesis,characterization and biological studies of Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)and Zn(Ⅱ)complexes with bidentate Schiff bases derived by heterocyclic ketone.European Journal of Medicinal Chemistry,2006.41(1):147-153.
[46]J.Patole,S.Dutta,S.Padhye,E.Sinn,Tuning up superoxide dismutase activity of copper complex of salicylaldehyde semicarbazone by heterocyclic bases pyridine and N-methylimidazole.Inorganica Chimica Acta,2001.318(1,2):207-211.
[47]Angel Garcia-Raso,Juan J.Fiol,Adela Lopez-Zafra,Jose A.Castro,et al.,Crystal structure of the copper(Ⅱ)ternary complex of N-salicylidene-L-serinato with 2,6-diaminopyridine.Toxicity studies against Drosophila melanogaster.Polyhedron,2003.22(3):403-409.
[48]Jose S.Casas,Alfonso Castineiras,Felix Condori,Maria D.Couce,et al.,Diorganotin(Ⅳ)-promoted deamination of amino acids by pyridoxal:SnR_2~(2+)complexes of pyridoxal 5'-phosphate and of the Schiff base pyridoxal-pyridoxamine (PLPM),and antibacterial activities of PLPM and[SnR_2(PLPM-2H)](R = Me,Et,Bu,Ph).Polyhedron,2003.22(1):53-65.
[49]M.Praveen Zahid H.Chohan,Synthesis,characterization and antibacterial properties of symmetric 1,1'-ferrocene derived Schiff-base ligands and their Co(Ⅱ),Cu(Ⅱ),Ni(Ⅱ)and Zn(Ⅱ)chelates.Applied Organometallic Chemistry,2000.14:376-382.
[50]M.Praveen Zahid H.Chohan,Synthesis,characterization,coordination and antibacterial properties of novel asymmetric 1,1'-disubstituted ferrocene-derives schiff-base ligands and their Co(Ⅱ),Cu(Ⅱ),Ni(Ⅱ)and Zn(Ⅱ)complexes.Applied Organometallic Chemistry,2001.15:617-625.
[51]林明丽,刘醒民,崔秀兰,洪海龙,稀土与苯并咪唑甲基酮缩二乙三胺schiff碱配合物的合成、表征及生物活性.稀土,2004.25(6):38-40.
[52]Yin Yang Zheng,Ru Dong Yang,Fa Shen Li,Kai Bei Yu,Crystal structure and antitumor activity of some rare earth metal complexes with Schiff base.Polyhedron,2000.19(26-27):2599-2604.
[53]Kalagouda B.Gudasi,Rashmi V.Shenoy,Ramesh S.Vadavi,Manjula S.Patil,et aL,Lanthanide(Ⅲ)and Yttrium(Ⅲ)Complexes of Benzimidazole-2-Acetic Acid:Synthesis,Characterisation and Effect of La(Ⅲ)Complex on Germination of Wheat. Bioinorganic Chemistry and Applications,2006:1-8.
[54]A.Th Chaviara,P.J.Cox,K.H.Repana,R.M.Papi,et al.,Copper(Ⅱ)Schiff base coordination compounds of dien with heterocyclic aldehydes and 2-amino-5-methyl-thiazole:synthesis,characterization,antiproliferative and antibacterial studies.Crystal structure of CudienOOCl_2.Journal of Inorganic Biochemistry,2004.98(8):1271-1283.
[55]Zahid H.Chohan,Biologically active transition metal chelates of Ni(Ⅱ),Cu(Ⅱ)and Zn(Ⅱ)with 2-aminothiazole derives schiff bases:their synthesis,charecterization and the role of anions(NO_3~-,SO_4~(2-),C_2O_4~(2-)and CH_3CO~(2-))on their antibacterial properties.Met-Based Drugs,1999.6(3):187-192.
[56]梁芳珍,徐克花,任建新,2-氨基噻唑取代水杨醛Zn(Ⅱ)配合物的合成、表征及抑菌活性.合成化学,1999.7(2):121-124.
[57]梁芳珍,江崇球,黄汝骐,新型荧光试剂N-2-噻唑基水杨醛亚胺Schiff碱的合成及荧光性质.合成化学,1999.7(2):170-174.
[58]唐波,刘阳,梁芳珍,β-CD-Schiff碱铜(Ⅱ)配合物模拟酶催化光度法的研究.化学学报,2000.58(8):1031-1036.
[59]M.M.Omar,G.G.Mohamed,A.M.M.Hindy,TRANSITION METAL COMPLEXES OF HETEROCYCLIC SCHIFF BASE:Biological activity,spectroscopic and thermal characterization.Journal of Thermal Analysis and Calorimetry,2006.86(2):315-325.
[60]D.Shanker,R.K.Sharma,J.Sharma,A.K.Rai,et al.,Metal-induced rearrangement of benzothiazoline ring:synthesis and characterization of some new organoantimony(Ⅴ)derivatives of N,O,and S atom containing Schiff base ligands.Heteroatom Chemistry,2007.18(1):70-75.
[61]Martin E.Bluhm,Michael Ciesielski,Helmar Goerls,Olaf Walter,et al.,Complexes of Schiff Bases and Intermediates in the Copper-Catalyzed Oxidative Heterocyclization by Atmospheric Oxygen.Inorganic Chemistry,2003.42(26):8878-8885.
[62]Jingjun Yin,Matthew M.Zhao,Mark A.Huffman,James M.Mcnamara,Pd-Catalyzed N-Arylation of Heteroarylamines.Organic Letters,2002.4(20):3481-3484.
[63]Galmari Venkatachalam,Rengan Ramesh,Ruthenium(Ⅲ)Schiff base complexes of[ONNO]-type mediated transfer hydrogenation of ketones.Inorganic Chemistry Communications,2005.8(11):1009-1013.
[64]H.Takeda,K.Koike,H.Inoue,O.Ishitani,Development of an Efficient Photocatalytic System for CO2 Reduction Using Rhenium(Ⅰ)Complexes Based on Mechanistic Studies.J.Am.Chem.Sot.,2008.130(6):2023-2031.
[65]N.C.Bhardwaj,K.K.Chaturvedi,R.V.Singh,Coordination compounds of heterocyclic hydrazinecarboxamides with trivalent indium.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1996.26(3):455-471.
[66]E.Smolensky,M.Kapon,M.S.Eisen,Catalytic Intermolecular Hydroamination of Methylenecyclopropanes.Organometallics,2005.24(23):5495-5498.
[67]G.G.Skvortsov,G.K.Fukin,A.A.Trifonov,A.Noor,et al.,Intramolecular (sp3-hybridized)C-H Activation:Yttrium Alkyls versus Transient Yttrium Hydrides. Organometallics,2007.26(24):5770-5773.
[68]Ashot S.Saghiyan,Luisa L.Manasyan,Arpine V.Geolchanyan,Anahit M.Hovhannisyan,et al.,Asymmetric synthesis of anti-diastereoisomers of b-heterocycle substituted(S)-a-aminobutyric acids.Tetrahedron:Asymmetry,2006.17(19):2743-2753.
[69]A.S.Saghiyan,A.V.Geolchanyan,S.G.Petrosyan,T.V.Ghochikyan,et al.,Asymmetric synthesis of b-heterocycle substituted L-a-amino acids.Tetrahedron:Asymmetry,2004.15(4):705-711.
[70]A.S.Sagiyan,A.V.Geolchanyan,A.A.Grigoryan,N.R.Martirosyan,et al.,Asymmetric synthesis of(R)-S-[5-(2'-methoxyphenyl)triazol-3-yl]cysteine and (R)-S-[5-(2'-chlorophenyl)-4-allyl-1,2,4-triazol-3-yl]cysteine.Hayastani Kimiakan Handes,2004.57(1-2):85-92.
[71]A.S.Sagiyan,A.V.Geolchanyan,N.R.Martirosyan,S.A.Dadayan,et al.,Asymmetric synthesis of(R)-S-5-(3-hydroxy-4-isoamyloxy)butyl-4-phenyl-1,2,4-triazol-3-ylcysteine and(R)-S-5-(3-hydroxy)propyl-4-phenyl- 1,2,4-triazol-3-ylcysteine.Hayastani Kimiakan Handes,2002.55(4):84-91.
[72]M.Thirumavalavan,P.Akilan,M.Kandaswamy,Lateral macrobicyclic compartmental mono and binuclear nickel(Ⅱ)complexes derived from phenolate ligands:Synthesis,spectral,electrochemical and kinetic studies.Polyhedron,2005.24(13):1781-1791.
[73]Jens Hartung,Simone Drees,Marco Greb,Philipp Schmidt,et al.,(Schiff-base)vanadium(Ⅴ)complex-catalyzed oxidations of substituted bis(homoallylic)alcohols-stereoselective synthesis of functionalized tetrahydrofurans.European Journal of Organic Chemistry,2003(13):2388-2408.
[74]Joerg Wagler,Uwe Boehme,Gerhard Roewer,Activation of a Si-Si Bond by Hypercoordination:Cleavage of a Disilane and Formation of a Si-C Bond Organometallics,2004.23(25):6066-6069.
[75]Dominique Agustin,Ghassoub Rima,Heinz Gornitzka,Jacques Barrau,Stable heterocyclic(Schiff base)divalent Group 14 element species M-O-Schiff base-O(M =Ge,Sn,Pb).Journal of Organometallic Chemistry,1999.592(1):1-10.
[76]M Peter,Zeimentz,Jun Okuda,Cationic Aryl Complexes of the Rare-Earth Metals.Organometallics,2007.26:6388-6396.
[77]Dominique Robert,Alexander A Trifonov,Peter Voth,Jun Okuda,"Constrained geometry"catalysts of the rare-earth metals for the hydrosilylation of olefins.Journal of Organometallic Chemistry,2006.691:4393-4399.
[78]Shaozhong Ge,Victor F.Quiroga Norambuena,Bart Hessen,Highly Efficient Regio- and Stereoselective Dimerization of(Hetero)aromatic Terminal Alkynes by Organo Rare-Earth Metal Catalysts.Organometallics,2007.26(26):6508-6510.
[79]B.J.He,W.L.Sun,M.Wang,Z.Q.Shen,New magnetic phenomena of rare earth ions-modified carbon nanotubes.Materials Chemistry and Physics,2005.95(2-3):202-205.
[80]S.Liu,W.L.Sun,B.J.He,Z.Q.Shen,Synthesis and properties of oligomers containing substituted bithiazole rings.European Polymer Journal,2004.40(9):2043-2051.
[81]W.L.Sun,L.M.Jiang,J.Weng,B.J.He,et al.,A novel bithiazole-tetrathiapentalene polymer and its metal complexes.Reactive & Functional Polymers,2003.55(3):249-254.
[82]Gopalakrishnan Karthikeyan,Ponnuchamy Pitchaimani,Synthesis,characterization and electrochemical studies of ruthenium(Ⅲ)heterocyclic Schiff bases.Transition Metal Chemistry(Dordrecht,Netherlands),2003.28(4):482-486.
[83]Salih Ilhan,Hamdi Temel,Ismail Yilmaz,Memet Sekerci,Synthesis,structural characterization and electrochemical studies of new macrocyclic Schiff base containing pyridine head and its metal complexes.Journal of Organometallic Chemistry,2007.692:3855-3865.
[84]Sheba D.Bergman,Israel Goldberg,Carla Caefagna,Luca Mosca,et al.,Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Coolymerization.Organometallics,2006.25:6014-6018.
[85]Stegano Milione,Valerio Bertolasi,Tomas Cuenca,Alfonso Grassi,Titanium Complexes Bearing a Hemilabile Heteroscorpionate Ligand:Synthesis,Reactivity,and Olefin Polymerization Activity.Organometallics,2005.24:4915-4925.
[86]Christopher T.Burns,Richard F.Jordan,Ethylene Dimerization by Cationic Palladium(Ⅱ)Alkyl Complexes that Contain Bis(heterocycle)methane Ligands.Organometallics,2007.26(27):6726-6736.
[87]Daniel J.Arriola,Edmund M.Carnahan,Phillip D.Hustad,Roger L.Kuhlman,et al.,Catalytic Production of Olefin Block Copolymers via Chain Shuttling Polymerization.Science,2006.312(5774):714-719.
[88]Antonio F.Bella,Aurora Ruiz,Carmen Claver,Francisco Sepulveda,et al.,Pyrazolyl-pyrimidine based ligands in palladium catalyzed copolymerization and terpolymerization of CO/olefins.Journal of Organometallic Chemistry,2008.693:1269-1275.
[89]Vernon C.Gibson,Sergio Mastroianni,Claire Newton,Carl Redshaw,et al.,A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands.J.Chem.Soc.,Dalton Trans.,2000:1969-1971.
[90]Junji Saito,Makoto Mitani,Shigekazu Matsui,Yasushi Tohi,et al.,A New Titanium Complex Having Two Phenoxy-Imine Chelate Ligands for Ethylene Polymerization.Macromol.Chem.Phys.,2002.203(1):59-65.
[91]苏碧云,赵建设,单亚胺吡啶化合物、其制备方法和含有该化合物的催化剂及其应用,发明专利申请公开说明书CN 1660810A
[92]孙文华,王乐勇,韩玲芹,胡友良,et al.,乙烯齐聚和聚合后过渡金属配位催化剂,发明专利申请公开说明书CN 1401666A
[93]Y.Yang,S.Li,D.Cui,X.Chen,et al.,Pyrrolide-Ligated Organoyttrium Complexes.Synthesis,Characterization,and Lactide Polymerization Behavior.Organometallics,2007.26(3):671-678.
[94]Dun Wang,Dongmei Cui,Wei Miao,Shihui Li,et al.,Rare earth metal complexes bearing thiophene-amido ligand:Synthesis and structural characterization.Dalton.Trans,2007.2007:4576-4581.
[95]Xinli Liu,Xiaomin Shang,Tao Tang,Ninghai Hu,et al.,Achiral Lanthanide Alkyl Complexes Bearing N,O Multidentate Ligands.Synthesis and Catalysis of Highly Heteroselective Ring-Opening Polymerization of rac-Lactide.Organometallics,2007.26:2747-2757.
[96]L.Xiang,Q.Wang,H.Song,G.Zi,Synthesis,Structural Characterization,and Reactivity of Organolanthanides Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,1'-binaphthyl.Organometallics,2007.26(22):5323-5329.
[97]Qiuwen Wang,Li Xiang,Guofu Zi,Synthesis,structural characterization,and reactivity of organolanthanides derived from a new chiral ligand(S)-2-(pyrrol2-ylmethyleneamino)-2'-hydroxy-1,1 '-binaphthyl.Journal of Organometallic Chemistry,2008.693(1):68-76.
[98]Eiji Ihara,Shiro Yoshioka,Masahito Furo,Hajime Yasuda,et al.,Synthesis and Olefin Polymerization Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging Bis(cyclopentadienyl)Ligands.Organometallics,2001.20:1752-1761.
[99]Shojiro Kaita,Michiko Yamanaka,Akira C.Horiuchi,Yasuo Wakatsuki,Butadiene Polymerization Catalyzed by Lanthanide Metallocene-Alkylaluminum Complexes with Cocatalysts:Metal-Dependent Control of 1,4-Cis/Trans Stereoselectivity and Molecular Weight.Macromolecules,2006.39:1359-1363.
[100]Chun Ji Wu,Sang Hoon Lee,Hoseop Yun,Bun Yeoul Lee,Ortho Lithiation of Tetrahydroquinoline Derivatives and Its Use for the Facile Construction of Polymerization Catalysts.Organometallics,2007.26(27):6685-6687.
[101]Tom Opstal,Francis Verpoort,Atom transfer radical addition and enol-ester synthesis catalyzed by Ru-vinylidene complexes.Tetrahedron Letters,2002.43:9259-9263.
[102]W.Li,H.Sun,M.Chen,Z.Wang,et al.,Synthesis of Salicylaldiminato-Functionalized N-Heterocyclic Carbene Complex of Nickel(Ⅱ)and Its Catalytic Activity for Styrene Polymerization.Organometallies,2005.24(24):5925-5928.
[103]Mu-Zi Chen,Hong-Mei Sun,Wan-Fei Li,Zhing-Guo Wang,et al.,Synthesis,structure of functionalized N-heterocyclic carbene complexes of Fe(Ⅱ)and their catalytic activity for ring-opening polymerization of[epsilon]-caprolactone.Journal of Organometallic Chemistry,2006.691(11):2489-2494.
[104]A.Michrowska,K.Mennecke,U.Kunz,A.Kirschning,et al.,A New Concept for the Noncovalent Binding of a Ruthenium-Based Olefin Metathesis Catalyst to Polymeric Phases:Preparation of a Catalyst on Raschig Rings.J.Am.Chem.Soc.,2006.128(40):13261-13267.
[105]Lipika Ray,Vimal Katiyar,Samir Barman,Mustafa J.Raihan,et al.,Gold(Ⅰ)N-heterocyclic carbene based initiators for bulk ring-opening polymerization of l-lactide.Journal of Organometallic Chemistry,2007.692(20):4259-4269.
[106]B.Wang,D.Wang,D.Cui,W.Gao,et al.,Synthesis of the First Rare Earth Metal Bis(alkyl)s Bearing an Indenyl Functionalized N-Heterocyclic Carbene.Organometallics,2007.26(13):3167-3172.
[107]Z.G.Wang,H.M.Sun,H.S.Yao,Q.Shen,et al.,Mono- and Tris-Phenoxo-Tethered N-Heterocyclic Carbene Yttrium Complexes:Syntheses and Molecular Structures.Organometallics,2006.25(19):4436-4438.
[108]Zhi-Guo Wang,Hong-Mei Sun,Hai-Sheng Yao,Ying-Ming Yao,et al.,Bis-aryloxo-functionalized NHC complexes of ytterbium(Ⅲ):Syntheses and structures of Yb[O-4,6-tBu_2-C_6H_2-2-CH_2{C(RNCHCHN)}]_2N(iPr)_2(R=Pr,Me).Journal of Organometallic Chemistry,2006.691(15):3383-3390.
[109]P.L.Arnold,S.Y.Liddle,J.McMaster,C.Jones,et al.,A Lanthanide-Gallium Complex Stabilized by the N-Heterocyclic Carbene Group.J.Am.Chem.Soc.,2007.129(17):5360-5361.
[110]Min Ying,Ruo Yuan,Zhi-Qiang Li,You-Qiang Song et al.,Thiocyanate-selective electrode based on cobalt(Ⅱ)complexes of pyrazolone heterocyclic Schiff bases.Fresenius' Journal of Analytical Chemistry,1998.361(5):437-441.
[111]Jeon Woo Jeong,Younghwan Kwon,Synthesis and Electroluminescent Properties of Polyazomethine-type Conjugates Polymers Contianing Heterocyclic Phenothiazine and Carbazole Moiety.Journal of Nonlinear Optical Physics &Materials,2005.14(4):545-553.
[112]Ruiqing Fan,Dongsheng Zhu,Hong Ding,Ying Mu,et al.,Blue luminescent zinc(Ⅱ)complexes of 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine and 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine.Synthetic Metals,2005.149:135-141.
[113]Gountchev T.I.,Tilley T.D.,Organometallics,1999.18(2896).
[114]Cloke F.G.N.,Elvidge B.R.,Hitchcock P.B.,Lamarche V.M.E.,J.Chem.Soc.,Dalton Trans.,2002:2413.
[115]Shah A.A.S.,Dorn H.,Roesky H.W.,Lubini P.,et al.,Inorganic Chemistry,1997.36:1102.
[116]Sakinner M.E.G.,Tyrrel B.R.,Ward B.D.,Mountford P.,J.Organomet.Chem,2002.647:145.
[117]Skinner M.E.G.,Miuntford P.,J.Chem.Soc.,Dalton Trans.,2002:1694.
[118]GrafD.D.,Davis W.M.,Schrock R.R.,Organometallics,1998.17:5820.
[119]Fryzuk M.D.,Yu P.,Patrick B.O.,Can.J.Chem,2001.1194.
[120]Lee L.,Berg D.J.,Bushnell G.W.,Inorganic Chemistry,1994.33:5302.
[121]Fryzuk M.D.,J.B.Love,Rettig S.J.,J.Am.Chem.Soc.,1997.119:9071.
[122]Fryzuk M.D.,Jafapour L.,Kerton F.M.,J.B.Love,et al.,Organometallics,2001.20(1387).
[123]R.E.Maginn,S Manastyrskyj,M.Dubeck,The Dicyclopentadienyl lanthanide Chlorides.Journal of the American Chemical Society,1963.85(6):672-676.
[124]Michel R Gagne,Tobin J.Marks,Organolanthanide-catalyzed hydroamination.Facile,regiospecific cyclization of unprotected amino olefins.Journal of the American Chemical Society,1989.111:4108.
[125]Qi Shen,Yingming Yao,Synthesis and reactivity of organolanthanoid complexes containing N and S ligands.Journal of Organometallic Chemistry,2002.647(1-2):180-189.
[126]Alexander A.Trifonov,Dmitrii M.Lyubov,Elena A.Fedorova,Georgy K.Fukin,et al.,Chloro,Alkyl and Aryl complexes of Rare Earth Metals Supported by Bulky Tetrasubstituted Guanidinate Ligands.European Journal of Inorganic Chemistry,2006:747-756.
[127]Frank T.Edelmann,Rare earth complexes with heteroallylic ligands and their use as precusors for lanthanide-based homogeneous catalysts.Journal of Alloys and Compounds,1994.207/208:182-188.
[128]Shihui Li,Wei Miao,Tao Tang,Weimin Dong,et al.,New Rare Earth Metal Bis(alkyl)s Bearing an Iminophosphonamido Ligand.Synthesis and Catalysis toward Highly 3,4-Selective Polymerization of Isoprene.Organometallics,2008.27(4):718-725.
[129]Yunjie Luo,Masayoshi Nishiura,Zhaomin Hou,Rare earth metal bis(alkyl)complexes bearing a monodentate arylamido ancillary ligand:Synthesis,structure,and Olefin polymerization catalysis.Journal of Organometallic Chemistry,2007.692(1-3):536-544.
[130]P.J.Shapiro,W.D.Cotter,W.P.Schaefer,J.A.Labinger,et al.,Journal of the American Chemical Society,1994.116:4623.
[131]S.Arndt,A.Trifonov,T.P.Spaniol,J.Okuda,et al.,Journal of Organometallic Chemistry,2002.647:158.
[132]S.Arndt,T.P.Spaniol,J.Okuda,European Journal of Inorganic Chemistry,2001:73.
[133]S.Arndt,T.P.Spaniol,J.Okuda,Organometallics,2003.22:775.
[134]Xin Xu,Xiaoyan Xu,Yaofeng Chen,Jie Sun,Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors.Organometallics,2008.27(4):758-763.
[135]Shihui Li,Wei Miao,Tao Tang,Dongmei Cui,et al.,Rare earth metal bis(alkyl)complexes bearing amino phosphine ligands:Synthesis and catalytic activity toward ethylene polymerization.Journal of Organometallic Chemistry,2007.692(22):4943-4952.
[136]Wei Miao,Shihui Li,Dongmei Cui,Baotong Huang,Rare earth metal alkyl complexes bearing N,O,P multidentate ligands:Synthesis,characterization and catalysis on the ring-opening polymerization of l-lactide.Journal of Organometallic Chemistry,2007.692(17):3823-3834.
[137]Koleske J.V.,Lundberg R.D.,Lactone polymers.Ⅱ.Viscosity-molecular weight relationships and unperturbed chain dimensions.Journal of Polymer Science Part A:Polymer Chemistry,1969.17(8):897-907.
[138]W.H.Beattie,C.Booth,Instrinsic viscosity-mol.wt,relation for cis-1,4-polyisoprene.Journal of Applied Polymer Science,1963.7:507.
[139]王文,王征,沈之荃,Nd(P_(204))_3-Al(i-Bu)_3-CCl_4催化体系聚合甲基丙烯酸甲酯.高分子材料科学与工程,1991(4):11-16.
[140]金鹰泰,林永华,金哲山,李凤富,[(CH_2)_3CCH_2O]_4Nd_2r的合成、晶体结构和催化聚合双烯烃的研究.中国稀土学报,1993.11(1):17.
[141]R K Kulkarrni,E G Moore,A F Hegyeli,L Fred,Biodegradable poly(lactic acid)polymres.Journal of Biomedical Materials Resaerch,1971.5(3):169-181.
[142]Toshio Kawato,Hiroyuki Koyama,Hajime Kanatomi,Makiko Isshiki,Photoisomerization and thermoisomerization Ⅰ:Unusual Photochromism of N-(3,5-Di-tert-Butyl-Salicylidene)amines.Journal of Photochemistry,1985.28:103-110.
[143]Stephen T.Liddle,William Clegg,Cation-induced structural variations in the alkali metal derivatives of 2-trimethylsilylaminopyridine:synthesis and X-ray structures of complexes for all five metals Li-Cs with 12-crown-4.J.Chem.Soc.,Dalton Trans.,2001:402-408.
[144]M.D.Taylor,C.P.Cartes,LnCl3.J.Inorg.Nucl.Chem.,1962.24:387.
[145]Jose E.Baez,Angel Marcos-Fernandez,Rosa Lebron-Aguilar,Antonio Martinez-Richa,A novel route to[alpha],[omega]-telechelic poly([var epsilon]-caprolactone)diols,precursors of biodegradable polyurethanes,using catalysis by decamolybdate anion.Polymer,2006.47(26):8420-8429.
[146]D Braun,H.Cherdron,M.Rehahn,H.Ritter,Polymer Synthesis:Theory and Practice.4th ed.2004,Berlin:Springer.
[147]樊玲,三(2,4,6-三甲基苯氧基)稀土配合物单组分催化环酯聚合与可控合成两亲性嵌段共聚物及其胶束的制备,高分子化学与物理.2006,浙江大学:博士学位论文.
[148]J.Ling,Z.Q.Shen,W.P.Zhu,Synthesis,characterization,and mechanism studies on novel rare-earth calixarene complexes initiating ring-opening polymerization of 2,2-dimethyltrimethylene carbonate.Journal of Polymer Science Part a-Polymer Chemistry,2003.41(9):1390-1399.
[149]J.Ling,Z.Q.Shen,Lanthanum tris(2,6-di-tert-butyl-4-methylphenolate)as a novel,versatile initiator for homo- and copolymerization of cyclic carbonates and lactones(vol 203,pg 735,2002).Macromolecular Chemistry and Physics,2002.203(12):1872-1872.
[150]Q.H.Huang,Z.Q.Shen,Y.F.Zhang,Y.Q.Shen,et al.,Ring-opening copolymerization of trimethylene carbonate and D,L-lactide by rare earth chloride.Polymer Journal,1998.30(3):168-170.
[151]Y.Q.Shen,Z.Q.Shen,Y.F.Zhang,Q.H.Huang,et al.,Random copolymerization of epsilon-caprolactone and trimethylene carbonate with rare earth catalysts.Journal of Applied Polymer Science,1997.64(11):2131-2139.
[152]Y.Q.Shen,Z.Q.Shen,Y.F.Zhang,G.H.Hang,A comparison of polymerization characteristics and mechanisms of epsilon-caprolactone and trimethylene carbonate with rare earth halides.Journal of Polymer Science Part A-Polymer Chemistry,1997.35(8):1339-1352.
[153]Jun Ling,Weipu Zhu,Zhiquan Shen,Controlling Ring-Opening Copolymerization of ε-Caprolactone with Trimethylene Carbonate by Scandium Tris(2,6-di-tert-butyl-4-methylphenolate).Macromolecules,2004.37:758-763.
[154]沈之荃,龚仲元,欧阳均,高分子通讯,1965.7:193.
[155]钱长涛,杜灿屏,稀士金属有机化学.1st ed.2004,北京:化学工业出版社.第九章:267
[156]Jun Ling,Xufeng Ni,Yifeng Zhang,Zhiquan Shen,Monte Carlo simulation of gas phase polymerization of 1,3-butadiene Part Ⅰ.Modeling and programming.Polymrer,2000.41:8703-8707.
[157]Jun Ling,Xufeng Ni,Yifeng Zhang,Zhiquan Shen,Monte Carlo simulation of gas phase polymerization of 1,3-butadiene Part Ⅱ.Kinetics optimization and confirmation.Polymer International,2003.52:213-217.
[158]Junfei Li Yifeng Zhang Zhiquan Shen Xufeng Ni,Gas phase polymerization of 1,3-butadiene with supported neodymium-based catalyst:Investigation of molecular weight.Journal of Applied Polymer Science,2004.92(3):1945-1949.
[159]R.P.Quirka,A.M.Kells,K.Yunlu,J.P.Cuif,Polymer,2000.41:5903.
[160]张国栋,杨纪元,冯新德,聚乳酸的研究进展.化学进展,2000.12(1):89-102.
[161]Matthieu Jalabert,Carole Fraschini,Robert E.Prud Homme,Synthesis and Characterization of Poly(L-lactide)s and Poly(D-lactide)s of Controlled Molecular Weight.Journal of Polymer Science:Part A:Polymer Chemistry,2007.45:1944-1955.
[162]Barakat,Ph.Dubois,R.Jerome,Ph.Teyssie,Macromolecular Engineering of Polylactones and Polylactides.X.Selective End-Functionalization of Poly(D,L)-Lactide.Journal of Polymer Science Part A:Polymer Chemistry,1993.31:505-514.
[163]D.J.Darensbourg,W.Choi,C.P.Richers,Ring-Opening Polymerization of Cyclic Monomers by Biocompatible Metal Complexes.Production of Poly(lactide),Polycarbonates,and Their Copolymers.Macromolecules,2007.40(10):3521-3523.
[164]Sandor Keki,Janos Torok,Gyorgy Deak,Miklos Zsuga,Mechanism of ring-opening and elimination cooligomerization of cyclic carbonates and ε-caprolactone:Formation of cyclic cooligomers.European Polymer Journal,2005.41:1478-1483.
[165]J.R.Sarasua,R.E.Prud'homme,M.Wisniewski,A.Le Borgne,et al.,Crystallization and Melting Behavior of Polylactides.Macromolecules,1998.31(12):3895-3905.
[166]Jun Ling,Zhiquan Shen,Lanthanum tris(2,6-di-tert-butyl-4-methylphenolate)as a Novel,Versatile Initiator for Homo- and Copolymerization of Cyclic Carbonates and Lactones.Macromol.Chem.Phys.,2002.203:735-738.
[167]Fabienne Fay,Estelle Renard,Valerie Langlois,Isabelle Linossier,et al.,Development of poly(e-caprolactone-co-L-lactide)and poly(ε-caprolactone-eod-valerolactone)as new degradable binder used for antifouling paint.European Polymer Journal,2007.43:4800-4813.
[168]Changchun Min,Wenjin Cui,Jianzhong Bei,Shenguo Wang,Effect of comonomer on thermal/mechanical and shape memory property of L-lactide-based shape-memory copolymers.Polymers for Advanced Technologies,2007.18:299-305.
[169]Hiroshi Miyasako,Kazuya Yamamoto,Aiko Nakao,Takao Aoyagi,Preparation of Cross-Linked Poly[(e-caprolactone)-co-lactide]and Biocompatibility Studies for Tissue Engineering Materials.Macromolecular Bioscience,2007.7:76-83.
[170]Swapan Kumar Saha,Hideto Tsuji,Effect of rapid crystallization on hydrolytic degradation and mechanical properties of poly(L-lactide-co-ε-carprolactone).Reactive and Functional Polymers,2006.66:1362-1372.
[171]S.Ya.Knjazhanski,L.Elizalde,G.Cadenas,B.M.Bulychev b,Polymerization of methyl methacrylate with alane complexes of bivalent lanthanidocenes.Journal of Organometallic Chemistry,1998.568:33-40.
[172]Lisa S.Boffa,Bruce M.Novak,Bimetallic Samarium(Ⅲ)Initiators for the Living Polymerization of Methacrylates and Lactones.A New Route into Telechelic,Triblock,and "Link-Functionalized" Polymers.Macromolecules,1994.27:6993-6995.
[173]Eiji Ihara,Kouji Koyama,Hajime Yasuda,Nobuko Kanehisa,et al.,Catalytic activity of allyl-,azaallyl- and diaza-pentadienyllanthanide complexes for polymerization of methyl methacrylate.Journal of Organometallic Chemistry,1999.574:40-49.
[174]Hajime Yasuda,Hitoshi Yamamoto,Masahiro Yamashita,Synthesis of High Molecular Weight Poly(methyl methacrylate)with Extremely Low Polydispersity by the Unique Function of Organolanthanide(111)Complexes.Macromolecules,1993.26:7134-7143.
[175]Michael A.Giardello,Yoshihiro Yamamoto,Laurent Brard,Tobin J.Marks, Stereocontrol in the Polymerization of Methyl Methacrylate Mediated by Chiral Organolanthanide Metallocenes.J.Am.Chem.Soc.,1995.117:3276-3277.
[176]周利英,氨基配体的结构对氨基稀土化合物的合成、结构和反应性能的影响,有机化学.2007,苏州大学:博士学位论文.
[177]Shuang-L.Zhou,Shao-W.Wang,Gao-S.Yang,Xin-Y.Liu,et al.,Synthesis,structure,and catalytic activity of tetracoordinate lanthanide amides [(Me_3Si)_2N]_3Ln(μ-Cl)Li(THF)_3(Ln=Nd,Sm,Eu).Polyhedron,2003.22(7):1019-1024.
[178]C.Qian,W.Nie,J.Sun,Cs-Symmetric ansa-Lanthanocenes Designed for Stereospecific Polymerization of Methyl Methacrylate.Synthesis and Structural Characterization of Silylene-Bridged Fluorenyl Cyclopentadienyl Lanthanide Halides,Amides,and Hydrocarbyls.Organometallics,2000.19(20):4134-4140.
[179]T.J.Woodman,M.Schormann,D.L.Hughes,M.Bochmann,Sterically Hindered Lanthanide Allyl Complexes and Their Use as Single-Component Catalysts for the Polymerization of Methyl Methacrylate and ε-Caprolactone.Organometallics,2004.23(12):2972-2979.
[180]Da Li,Yumei Zhang,Huaping Wang,Jianzhong Tang,et al.,Effect of the Medium on the Stereostructure of Poly(methyl methacrylate)Synthesized in Ionic Liquids.Journal of Applied Polymer Science,2006.102:2199-2202.
[2]P Pfeiffer,E Bucholz,O Hauer,Synthesis and Chareacter of Some Metal Complex of Schiff Base Ligand.J Parkt Chem,1931.129:163-167.
[3]Pier Giorgio Cozzi,Metal-Salen Schiff base complexes in catalysis:practical aspects.Chemical Society Reviews,2004.33:410-421.
[4]P Guerrio,U Casellato,S.Tamburini,Inorg.Chim.Acta,1987.129:127.
[5]姚克敏,李冬成,沈联芳,化学学报,1993.51:677.
[6]Sunirban Das,Samudranil Pal,Copper(Ⅱ)complexes with tridentate N-(benzoyl)-N'-(salicylidene)-hydrazine and monodentate N-heterocycles:Investigations of intermolecular interactions in the solid state.Journal of Molecular Structure,2005.753(1-3):68-79.
[7]Sunirban Das,Samudranil Pal,Self-assembly of copper(Ⅱ)complexes with a dibasic tridentate ligand and monodentate N-heterocycles:structural,magnetic and EPR studies.Journal of Molecular Structure,2005.741(1-3):183-192.
[8]Sunirban Das,G.P.Muthukrumaragopal,Satyanarayan Pal,Samudranil Pal,A one-dimensional assembly of a square-planar copper(Ⅱ)complex with alternating short and long Cu...Cu distances.Metal ion spin-exchange via p-p interactions.New Journal of Chemistry,2003.27(7):1102-1107.
[9]M.Saidul Islam,Motahera Begum,Harendra Math Roy,Mixed-ligand complexes of cobalt(Ⅱ)and nickel(Ⅱ)with a tridentate schiff base and heterocyclic amines.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1995.23(2):293-306.
[10]R.N.Patel,Nripendra Singh,V.L.N.Gundla,Synthesis,structure and properties of ternary copper(Ⅱ)complexes of ONO donor Schiff base,imidazole,2,2 '-bipyridine and 1,10-phenanthroline.Polyhedron,2006.25(17):3312-3318.
[11]Jonathan L.Sessler,Elisa Tomat,Tarak D.Mody,Vincent M.Lynch,et al.,A Schiff Base Expanded Porphyrin Macrocycle that Acts as a Versatile Binucleating Ligand for Late First-Row Transition Metals.Inorganic Chemistry,2005.44(7):2125-2127.
[12]Valeria Amendola,Luigi Fabbrizzi,Luca Gianelli,Cristina Maggi,et al.,Electrochemical Assembling/Disassembling of Helicates with Hysteresis.Inorganic Chemistry,2001.40(14):3579-3587.
[13]David A.Bardwell,John C.Jeffery,Peter L.Jones,Jon A.McCleverty,et al.,Lanthanide complexes of the tetradentate N-donor ligand dihydrobis [3-(2-pyridyl)pyrazolyl]borate and the terdentate N-donor ligand 2,6-bis(1H-pyrazol3-yl)pyridine:syntheses,crystal structures and solution structures based on luminescence lifetime studies.J.Chem.Soc.,Dalton Trans.,,1997:2079.
[14]B.D.Chandler,D.T.Cramb,G.K.H.Shimizu,Microporous Metal-Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks.J.Am.Chem.Soc.,2006.128(32):10403-10412.
[15]H.S.Wang,B.Zhao,B.Zhai,W.Shi,et al.,Syntheses,Structures,and Photoluminescence of One-Dimensional Lanthanide Coordination Polymers with 2,4,6-Pyridinetricarboxylic Acid.Cryst.Growth Des.,2007.7(9):1851-1857.
[16]Zheng Wang,Joseph Reibenspies,Arthur E.Martell,Design,Synthesis,and X-ray Structural Characterization of New Dinucleating Macrocyclic Ligands and a Novel Phenolate-Bridged Dilanthanum(Ⅲ)Complex.Inorganic Chemistry,1997.36(4):629-636.
[17]M.Seitz,A.G.Oliver,K.N.Raymond,The Lanthanide Contraction Revisited.J.Am.Chem.Sot.,2007.129(36):11153-11160.
[18]Michael Barz,Monika Rauch,Werner R.Thiel,New Schiffbases derived from trans-pyrazolylcyclohexanol:synthesis,co-ordination chemistry and structural features.Journal of the Chemical Society,Dalton Transactions:Inorganic Chemistry,1997(12):2155-2161.
[19]Angel Garcia-Raso,Juan J.Fiol,Adela Lopez-Zafra,Andres Tasada,et al.,Different ways of interaction between binary copper(Ⅱ)-Schiff bases (Cu-N-salicylideneserinato)and pyrimidine derivatives.Polyhedron,2006.25(11):2295-2302.
[20]Kerim Serbest,Ismail Degirmencioglu,Yasemin Unver,Mustafa Er,et al.,Microwave-assisted synthesis and characterization and theoretical calculations of the first example of free and metallophthalocyanines from salen type Schiff base derivative bearing thiophen and triazole heterocyclic rings.Journal of Organometallic Chemistry,2007.692(25):5646-5654.
[21]T.R.Rao,P.A.Kumar,Studies of some lanthanide(Ⅲ)complexes of heterocyclic ligands.Part Ⅲ.Eight-coordinated complexes of an unsymmetrical tetradentate Schiff base.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1995.25(6):1011-26.
[22]Ramalingam Balamurugan,Mallayan Palaniandavar,Malcolm A.Halcrow,Copper(Ⅱ)complexes of sterically hindered Schiff base ligands:Synthesis,structure,spectra and electrochemistry.Polyhedron,2006.25:1077-1088.
[23]N.E.Borisova,V.V.Roznyatovskii,M.D.Reshetova,Yu.A.Ustynyuk,Synthesis of New Polydentate Acyclic Schiff Bases by Reaction of 2,3-Diaminomaleodinitrile with Dicarbonyl Compounds.Russian Journal of Organic Chemistry,2005.41(7):1005-1010.
[24]Farba Bouyagui Tamboura,Pepe Marcel Haba,Mohamed Gaye,Abdou Salam Sall,et al.,Structural studies of bis-(2,6-diacetylpyridine-bis-(phenylhydrazone))and X-ray structure of its Y(Ⅲ),Pr(Ⅲ),Sm(Ⅲ)and Er(Ⅲ)complex.Polyhedron,2004.23(7):1191-1197.
[25]F.Benetollo,G.Bombieri,W.A.Gootee,K.K.Fonda,et al.,Constitutional isomers and stereoisomers of lanthanum(Ⅲ)complexes of the dimethyl-substituted six-nitrogen-donor ligand C24H30N6 and crystal structure of [La(C_(24)H_(30)N_6)(NCS)_3(H_2O)].O.5H_2O.Polyhedron,1998.17(20):3633-3642.
[26]Wanda Radecka-Paryzek,Violetta Patroniak,Maciej Kubicki,The template synthesis and characterization of pentaaza macrocyclic complexes of rare earth elements.The crystal structure of the 2,14-dimethyl-3,6,10,13,19-pentaazabicyclo [13.3.1]nonadeca-1(19),2,13,15,17-pentaene-dichlorolutetium(Ⅲ)perchlorate.Polyhedron,2003.22(20):2773-2779.
[27]Harry Adams,Rufina Bastida,David E.Fenton,Alejandro Macias,et al.,Zinc and cadmium complexes of an 18-membered N_4O_2 oxaaza-Schiff base macrocycle and the corresponding reduced form.Journal of the Chemical Society,Dalton Transactions:Inorganic Chemistry,1999(23):4131-4137.
[28]Lorenzo Tei,Alexander J.Blake,Claire Wilson,Martin Schroder,Lanthanide complexes of new nonadentate imino-phosphonate ligands derived from 1,4,7-triazacyclononane:synthesis,structural characterisation and NMR studies.Dalton Transactions,2004(13):1945-1952.
[29]C K Bhaskare,P P Hankare,Cobalt-,nickel- and copper(Ⅱ)complexes of schiffbases with Nor S donor sites.J Indian Chem.Soc.,1995.72(9):585-587.
[30]A.Proto,C.Capacchione,V.Venditto,J Okuda,Macromolecules,2003.36:9249.
[31]Har Lal Singh,A.K.Varshney,Synthetic,structural,and biochemical studies of organotin(Ⅳ)with Schiff bases having nitrogen and sulphur donor ligands.Bioinorganic Chemistry and Applications,2006:1-7.
[32]H.L.Singh,M.Shama,A.K.Vaeshney,Studies on coordination compounds of organotin(Ⅳ)with schiff base of amino acids.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2000.30(3):445-456.
[33]戴晴,王志,刘燕,张以群,一种新型含硫杂环的金属配合物的合成与表征.东北师大学报自然科学版,2005.37(3):135-137.
[34]Daniel T.Thangadurai,Son-Ki Ihm,Ruthenium(Ⅱ)carbonyl complexes containingNS andNNSS donor atoms.Wuji Huaxue Xuebao,2006.22(6):1055-1061.
[35]Agnete la Cour,Matthias Findeisen,Alan Hazell,Rita Hazell,et al.,Metal(Ⅱ)N_2S_2 Schiff-base complexes incorporating pyrazole or isoxazole(M = Ni,Cu or Zn).Spin states,racemization kinetics and electrochemistry.J.Chem.Soc.,Dalton Trans.,,1997:121-128.
[36]Alaaddin Cukurovali,Ibrahim Ylimaz,Habibe Ozmen,Antimicrobial activity studies of the metal complexes derives from substituted cyclibutane substituted thiazole schiff base ligands.Transition Metal Chemistry(Dordrecht,Netherlands),2001.26:619-624.
[37]Kalagouda B.Gudasi,Siddappa A.Patil,Ramesh S.Vadavi,Rashmi V.Shenoy,et al.,Synthesis and Spectral Characterization of Some Transition Metal Complexes Containing Pentadentate SNNNS Donor Heterocyclic Schiff Base Ligands.Transition Metal Chemistry(Dordrecht,Netherlands),2005.30(8):1014-1019.
[38]Christian Muller,Zoraida Freixa,Martin Lutz,Anthony L.Spek,et al.,Wide-Bite-Angle Diphosphinines:Design,Synthesis,and Coordination Properties.Organometallics,2008.27(5):834-838.
[39]Zahid H.Chohan,Humayun Pervez,A.Rauf,Khalid M.Khan,et al.,Antibacterial and Antifugal Mono- and Di-substituted Symmertrical and Unsymmetrical Triazine-derived Schiff-base and their Transition Metal Complexes.Journal of Enzyme Inhibition and Medicinal Chemistry,2004.19(2):161-168.
[40]Shanta Dhar,Munirathinam Nethaji,Akhil R.Chakravarty,DNA Cleavage on Photoexposure at the d-d Band in Ternary Copper(Ⅱ)Complexes Using Red-Light Laser.Inorganic Chemistry,2006.45(26):11043-11050.
[41]Shanta Dhar,Munirathinam Nethaji,Akhil R.Chakravarty,Synthesis,crystal structure and photo-induced DNA cleavage activity of ternary copper(Ⅱ)complexes of NSO-donor Schiff bases and NN-donor heterocyclic ligands.Inorganica Chimica Acta,2005.358(7):2437-2444.
[42]Pattubala A.N.Reddy,Munirathinam Nethaji,Akhil R.Chakravarty,Hydrolytic cleavage of DNA by ternary amino acid Schiff base copper(Ⅱ)complexes having planar heterocyclic ligands.European Journal of Inorganic Chemistry,2004(7):1440-1446.
[43]Pattubala A.N.Reddy,Bidyut K.Santra,Munirathinam Nethaji,Akhil R.Chakravarty,Metal-assisted light-induced DNA cleavage activity of 2-(methylthio)phenylsalicylaldimine Schiff base copper(Ⅱ)complexes having planar heterocyclic bases.Journal of Inorganic Biochemistry,2004.98(2):377-386.
[44]Shanta Dhar,Dulal Senapati,Puspendu K.Das,Pabitra Chattopadhyay,et al.,Ternary Copper Complexes for Photocleavage of DNA by Red Light:Direct Evidence for Sulfur-to-Copper Charge Transfer and d-d Band Involvement.Journal of the American Chemical Society,2003.125(40):12118-12124.
[45]Kiran Singh,Manjeet Singh Barwa,Parikshit Tyagi,Synthesis,characterization and biological studies of Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)and Zn(Ⅱ)complexes with bidentate Schiff bases derived by heterocyclic ketone.European Journal of Medicinal Chemistry,2006.41(1):147-153.
[46]J.Patole,S.Dutta,S.Padhye,E.Sinn,Tuning up superoxide dismutase activity of copper complex of salicylaldehyde semicarbazone by heterocyclic bases pyridine and N-methylimidazole.Inorganica Chimica Acta,2001.318(1,2):207-211.
[47]Angel Garcia-Raso,Juan J.Fiol,Adela Lopez-Zafra,Jose A.Castro,et al.,Crystal structure of the copper(Ⅱ)ternary complex of N-salicylidene-L-serinato with 2,6-diaminopyridine.Toxicity studies against Drosophila melanogaster.Polyhedron,2003.22(3):403-409.
[48]Jose S.Casas,Alfonso Castineiras,Felix Condori,Maria D.Couce,et al.,Diorganotin(Ⅳ)-promoted deamination of amino acids by pyridoxal:SnR_2~(2+)complexes of pyridoxal 5'-phosphate and of the Schiff base pyridoxal-pyridoxamine (PLPM),and antibacterial activities of PLPM and[SnR_2(PLPM-2H)](R = Me,Et,Bu,Ph).Polyhedron,2003.22(1):53-65.
[49]M.Praveen Zahid H.Chohan,Synthesis,characterization and antibacterial properties of symmetric 1,1'-ferrocene derived Schiff-base ligands and their Co(Ⅱ),Cu(Ⅱ),Ni(Ⅱ)and Zn(Ⅱ)chelates.Applied Organometallic Chemistry,2000.14:376-382.
[50]M.Praveen Zahid H.Chohan,Synthesis,characterization,coordination and antibacterial properties of novel asymmetric 1,1'-disubstituted ferrocene-derives schiff-base ligands and their Co(Ⅱ),Cu(Ⅱ),Ni(Ⅱ)and Zn(Ⅱ)complexes.Applied Organometallic Chemistry,2001.15:617-625.
[51]林明丽,刘醒民,崔秀兰,洪海龙,稀土与苯并咪唑甲基酮缩二乙三胺schiff碱配合物的合成、表征及生物活性.稀土,2004.25(6):38-40.
[52]Yin Yang Zheng,Ru Dong Yang,Fa Shen Li,Kai Bei Yu,Crystal structure and antitumor activity of some rare earth metal complexes with Schiff base.Polyhedron,2000.19(26-27):2599-2604.
[53]Kalagouda B.Gudasi,Rashmi V.Shenoy,Ramesh S.Vadavi,Manjula S.Patil,et aL,Lanthanide(Ⅲ)and Yttrium(Ⅲ)Complexes of Benzimidazole-2-Acetic Acid:Synthesis,Characterisation and Effect of La(Ⅲ)Complex on Germination of Wheat. Bioinorganic Chemistry and Applications,2006:1-8.
[54]A.Th Chaviara,P.J.Cox,K.H.Repana,R.M.Papi,et al.,Copper(Ⅱ)Schiff base coordination compounds of dien with heterocyclic aldehydes and 2-amino-5-methyl-thiazole:synthesis,characterization,antiproliferative and antibacterial studies.Crystal structure of CudienOOCl_2.Journal of Inorganic Biochemistry,2004.98(8):1271-1283.
[55]Zahid H.Chohan,Biologically active transition metal chelates of Ni(Ⅱ),Cu(Ⅱ)and Zn(Ⅱ)with 2-aminothiazole derives schiff bases:their synthesis,charecterization and the role of anions(NO_3~-,SO_4~(2-),C_2O_4~(2-)and CH_3CO~(2-))on their antibacterial properties.Met-Based Drugs,1999.6(3):187-192.
[56]梁芳珍,徐克花,任建新,2-氨基噻唑取代水杨醛Zn(Ⅱ)配合物的合成、表征及抑菌活性.合成化学,1999.7(2):121-124.
[57]梁芳珍,江崇球,黄汝骐,新型荧光试剂N-2-噻唑基水杨醛亚胺Schiff碱的合成及荧光性质.合成化学,1999.7(2):170-174.
[58]唐波,刘阳,梁芳珍,β-CD-Schiff碱铜(Ⅱ)配合物模拟酶催化光度法的研究.化学学报,2000.58(8):1031-1036.
[59]M.M.Omar,G.G.Mohamed,A.M.M.Hindy,TRANSITION METAL COMPLEXES OF HETEROCYCLIC SCHIFF BASE:Biological activity,spectroscopic and thermal characterization.Journal of Thermal Analysis and Calorimetry,2006.86(2):315-325.
[60]D.Shanker,R.K.Sharma,J.Sharma,A.K.Rai,et al.,Metal-induced rearrangement of benzothiazoline ring:synthesis and characterization of some new organoantimony(Ⅴ)derivatives of N,O,and S atom containing Schiff base ligands.Heteroatom Chemistry,2007.18(1):70-75.
[61]Martin E.Bluhm,Michael Ciesielski,Helmar Goerls,Olaf Walter,et al.,Complexes of Schiff Bases and Intermediates in the Copper-Catalyzed Oxidative Heterocyclization by Atmospheric Oxygen.Inorganic Chemistry,2003.42(26):8878-8885.
[62]Jingjun Yin,Matthew M.Zhao,Mark A.Huffman,James M.Mcnamara,Pd-Catalyzed N-Arylation of Heteroarylamines.Organic Letters,2002.4(20):3481-3484.
[63]Galmari Venkatachalam,Rengan Ramesh,Ruthenium(Ⅲ)Schiff base complexes of[ONNO]-type mediated transfer hydrogenation of ketones.Inorganic Chemistry Communications,2005.8(11):1009-1013.
[64]H.Takeda,K.Koike,H.Inoue,O.Ishitani,Development of an Efficient Photocatalytic System for CO2 Reduction Using Rhenium(Ⅰ)Complexes Based on Mechanistic Studies.J.Am.Chem.Sot.,2008.130(6):2023-2031.
[65]N.C.Bhardwaj,K.K.Chaturvedi,R.V.Singh,Coordination compounds of heterocyclic hydrazinecarboxamides with trivalent indium.Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,1996.26(3):455-471.
[66]E.Smolensky,M.Kapon,M.S.Eisen,Catalytic Intermolecular Hydroamination of Methylenecyclopropanes.Organometallics,2005.24(23):5495-5498.
[67]G.G.Skvortsov,G.K.Fukin,A.A.Trifonov,A.Noor,et al.,Intramolecular (sp3-hybridized)C-H Activation:Yttrium Alkyls versus Transient Yttrium Hydrides. Organometallics,2007.26(24):5770-5773.
[68]Ashot S.Saghiyan,Luisa L.Manasyan,Arpine V.Geolchanyan,Anahit M.Hovhannisyan,et al.,Asymmetric synthesis of anti-diastereoisomers of b-heterocycle substituted(S)-a-aminobutyric acids.Tetrahedron:Asymmetry,2006.17(19):2743-2753.
[69]A.S.Saghiyan,A.V.Geolchanyan,S.G.Petrosyan,T.V.Ghochikyan,et al.,Asymmetric synthesis of b-heterocycle substituted L-a-amino acids.Tetrahedron:Asymmetry,2004.15(4):705-711.
[70]A.S.Sagiyan,A.V.Geolchanyan,A.A.Grigoryan,N.R.Martirosyan,et al.,Asymmetric synthesis of(R)-S-[5-(2'-methoxyphenyl)triazol-3-yl]cysteine and (R)-S-[5-(2'-chlorophenyl)-4-allyl-1,2,4-triazol-3-yl]cysteine.Hayastani Kimiakan Handes,2004.57(1-2):85-92.
[71]A.S.Sagiyan,A.V.Geolchanyan,N.R.Martirosyan,S.A.Dadayan,et al.,Asymmetric synthesis of(R)-S-5-(3-hydroxy-4-isoamyloxy)butyl-4-phenyl-1,2,4-triazol-3-ylcysteine and(R)-S-5-(3-hydroxy)propyl-4-phenyl- 1,2,4-triazol-3-ylcysteine.Hayastani Kimiakan Handes,2002.55(4):84-91.
[72]M.Thirumavalavan,P.Akilan,M.Kandaswamy,Lateral macrobicyclic compartmental mono and binuclear nickel(Ⅱ)complexes derived from phenolate ligands:Synthesis,spectral,electrochemical and kinetic studies.Polyhedron,2005.24(13):1781-1791.
[73]Jens Hartung,Simone Drees,Marco Greb,Philipp Schmidt,et al.,(Schiff-base)vanadium(Ⅴ)complex-catalyzed oxidations of substituted bis(homoallylic)alcohols-stereoselective synthesis of functionalized tetrahydrofurans.European Journal of Organic Chemistry,2003(13):2388-2408.
[74]Joerg Wagler,Uwe Boehme,Gerhard Roewer,Activation of a Si-Si Bond by Hypercoordination:Cleavage of a Disilane and Formation of a Si-C Bond Organometallics,2004.23(25):6066-6069.
[75]Dominique Agustin,Ghassoub Rima,Heinz Gornitzka,Jacques Barrau,Stable heterocyclic(Schiff base)divalent Group 14 element species M-O-Schiff base-O(M =Ge,Sn,Pb).Journal of Organometallic Chemistry,1999.592(1):1-10.
[76]M Peter,Zeimentz,Jun Okuda,Cationic Aryl Complexes of the Rare-Earth Metals.Organometallics,2007.26:6388-6396.
[77]Dominique Robert,Alexander A Trifonov,Peter Voth,Jun Okuda,"Constrained geometry"catalysts of the rare-earth metals for the hydrosilylation of olefins.Journal of Organometallic Chemistry,2006.691:4393-4399.
[78]Shaozhong Ge,Victor F.Quiroga Norambuena,Bart Hessen,Highly Efficient Regio- and Stereoselective Dimerization of(Hetero)aromatic Terminal Alkynes by Organo Rare-Earth Metal Catalysts.Organometallics,2007.26(26):6508-6510.
[79]B.J.He,W.L.Sun,M.Wang,Z.Q.Shen,New magnetic phenomena of rare earth ions-modified carbon nanotubes.Materials Chemistry and Physics,2005.95(2-3):202-205.
[80]S.Liu,W.L.Sun,B.J.He,Z.Q.Shen,Synthesis and properties of oligomers containing substituted bithiazole rings.European Polymer Journal,2004.40(9):2043-2051.
[81]W.L.Sun,L.M.Jiang,J.Weng,B.J.He,et al.,A novel bithiazole-tetrathiapentalene polymer and its metal complexes.Reactive & Functional Polymers,2003.55(3):249-254.
[82]Gopalakrishnan Karthikeyan,Ponnuchamy Pitchaimani,Synthesis,characterization and electrochemical studies of ruthenium(Ⅲ)heterocyclic Schiff bases.Transition Metal Chemistry(Dordrecht,Netherlands),2003.28(4):482-486.
[83]Salih Ilhan,Hamdi Temel,Ismail Yilmaz,Memet Sekerci,Synthesis,structural characterization and electrochemical studies of new macrocyclic Schiff base containing pyridine head and its metal complexes.Journal of Organometallic Chemistry,2007.692:3855-3865.
[84]Sheba D.Bergman,Israel Goldberg,Carla Caefagna,Luca Mosca,et al.,Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Coolymerization.Organometallics,2006.25:6014-6018.
[85]Stegano Milione,Valerio Bertolasi,Tomas Cuenca,Alfonso Grassi,Titanium Complexes Bearing a Hemilabile Heteroscorpionate Ligand:Synthesis,Reactivity,and Olefin Polymerization Activity.Organometallics,2005.24:4915-4925.
[86]Christopher T.Burns,Richard F.Jordan,Ethylene Dimerization by Cationic Palladium(Ⅱ)Alkyl Complexes that Contain Bis(heterocycle)methane Ligands.Organometallics,2007.26(27):6726-6736.
[87]Daniel J.Arriola,Edmund M.Carnahan,Phillip D.Hustad,Roger L.Kuhlman,et al.,Catalytic Production of Olefin Block Copolymers via Chain Shuttling Polymerization.Science,2006.312(5774):714-719.
[88]Antonio F.Bella,Aurora Ruiz,Carmen Claver,Francisco Sepulveda,et al.,Pyrazolyl-pyrimidine based ligands in palladium catalyzed copolymerization and terpolymerization of CO/olefins.Journal of Organometallic Chemistry,2008.693:1269-1275.
[89]Vernon C.Gibson,Sergio Mastroianni,Claire Newton,Carl Redshaw,et al.,A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands.J.Chem.Soc.,Dalton Trans.,2000:1969-1971.
[90]Junji Saito,Makoto Mitani,Shigekazu Matsui,Yasushi Tohi,et al.,A New Titanium Complex Having Two Phenoxy-Imine Chelate Ligands for Ethylene Polymerization.Macromol.Chem.Phys.,2002.203(1):59-65.
[91]苏碧云,赵建设,单亚胺吡啶化合物、其制备方法和含有该化合物的催化剂及其应用,发明专利申请公开说明书CN 1660810A
[92]孙文华,王乐勇,韩玲芹,胡友良,et al.,乙烯齐聚和聚合后过渡金属配位催化剂,发明专利申请公开说明书CN 1401666A
[93]Y.Yang,S.Li,D.Cui,X.Chen,et al.,Pyrrolide-Ligated Organoyttrium Complexes.Synthesis,Characterization,and Lactide Polymerization Behavior.Organometallics,2007.26(3):671-678.
[94]Dun Wang,Dongmei Cui,Wei Miao,Shihui Li,et al.,Rare earth metal complexes bearing thiophene-amido ligand:Synthesis and structural characterization.Dalton.Trans,2007.2007:4576-4581.
[95]Xinli Liu,Xiaomin Shang,Tao Tang,Ninghai Hu,et al.,Achiral Lanthanide Alkyl Complexes Bearing N,O Multidentate Ligands.Synthesis and Catalysis of Highly Heteroselective Ring-Opening Polymerization of rac-Lactide.Organometallics,2007.26:2747-2757.
[96]L.Xiang,Q.Wang,H.Song,G.Zi,Synthesis,Structural Characterization,and Reactivity of Organolanthanides Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,1'-binaphthyl.Organometallics,2007.26(22):5323-5329.
[97]Qiuwen Wang,Li Xiang,Guofu Zi,Synthesis,structural characterization,and reactivity of organolanthanides derived from a new chiral ligand(S)-2-(pyrrol2-ylmethyleneamino)-2'-hydroxy-1,1 '-binaphthyl.Journal of Organometallic Chemistry,2008.693(1):68-76.
[98]Eiji Ihara,Shiro Yoshioka,Masahito Furo,Hajime Yasuda,et al.,Synthesis and Olefin Polymerization Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging Bis(cyclopentadienyl)Ligands.Organometallics,2001.20:1752-1761.
[99]Shojiro Kaita,Michiko Yamanaka,Akira C.Horiuchi,Yasuo Wakatsuki,Butadiene Polymerization Catalyzed by Lanthanide Metallocene-Alkylaluminum Complexes with Cocatalysts:Metal-Dependent Control of 1,4-Cis/Trans Stereoselectivity and Molecular Weight.Macromolecules,2006.39:1359-1363.
[100]Chun Ji Wu,Sang Hoon Lee,Hoseop Yun,Bun Yeoul Lee,Ortho Lithiation of Tetrahydroquinoline Derivatives and Its Use for the Facile Construction of Polymerization Catalysts.Organometallics,2007.26(27):6685-6687.
[101]Tom Opstal,Francis Verpoort,Atom transfer radical addition and enol-ester synthesis catalyzed by Ru-vinylidene complexes.Tetrahedron Letters,2002.43:9259-9263.
[102]W.Li,H.Sun,M.Chen,Z.Wang,et al.,Synthesis of Salicylaldiminato-Functionalized N-Heterocyclic Carbene Complex of Nickel(Ⅱ)and Its Catalytic Activity for Styrene Polymerization.Organometallies,2005.24(24):5925-5928.
[103]Mu-Zi Chen,Hong-Mei Sun,Wan-Fei Li,Zhing-Guo Wang,et al.,Synthesis,structure of functionalized N-heterocyclic carbene complexes of Fe(Ⅱ)and their catalytic activity for ring-opening polymerization of[epsilon]-caprolactone.Journal of Organometallic Chemistry,2006.691(11):2489-2494.
[104]A.Michrowska,K.Mennecke,U.Kunz,A.Kirschning,et al.,A New Concept for the Noncovalent Binding of a Ruthenium-Based Olefin Metathesis Catalyst to Polymeric Phases:Preparation of a Catalyst on Raschig Rings.J.Am.Chem.Soc.,2006.128(40):13261-13267.
[105]Lipika Ray,Vimal Katiyar,Samir Barman,Mustafa J.Raihan,et al.,Gold(Ⅰ)N-heterocyclic carbene based initiators for bulk ring-opening polymerization of l-lactide.Journal of Organometallic Chemistry,2007.692(20):4259-4269.
[106]B.Wang,D.Wang,D.Cui,W.Gao,et al.,Synthesis of the First Rare Earth Metal Bis(alkyl)s Bearing an Indenyl Functionalized N-Heterocyclic Carbene.Organometallics,2007.26(13):3167-3172.
[107]Z.G.Wang,H.M.Sun,H.S.Yao,Q.Shen,et al.,Mono- and Tris-Phenoxo-Tethered N-Heterocyclic Carbene Yttrium Complexes:Syntheses and Molecular Structures.Organometallics,2006.25(19):4436-4438.
[108]Zhi-Guo Wang,Hong-Mei Sun,Hai-Sheng Yao,Ying-Ming Yao,et al.,Bis-aryloxo-functionalized NHC complexes of ytterbium(Ⅲ):Syntheses and structures of Yb[O-4,6-tBu_2-C_6H_2-2-CH_2{C(RNCHCHN)}]_2N(iPr)_2(R=Pr,Me).Journal of Organometallic Chemistry,2006.691(15):3383-3390.
[109]P.L.Arnold,S.Y.Liddle,J.McMaster,C.Jones,et al.,A Lanthanide-Gallium Complex Stabilized by the N-Heterocyclic Carbene Group.J.Am.Chem.Soc.,2007.129(17):5360-5361.
[110]Min Ying,Ruo Yuan,Zhi-Qiang Li,You-Qiang Song et al.,Thiocyanate-selective electrode based on cobalt(Ⅱ)complexes of pyrazolone heterocyclic Schiff bases.Fresenius' Journal of Analytical Chemistry,1998.361(5):437-441.
[111]Jeon Woo Jeong,Younghwan Kwon,Synthesis and Electroluminescent Properties of Polyazomethine-type Conjugates Polymers Contianing Heterocyclic Phenothiazine and Carbazole Moiety.Journal of Nonlinear Optical Physics &Materials,2005.14(4):545-553.
[112]Ruiqing Fan,Dongsheng Zhu,Hong Ding,Ying Mu,et al.,Blue luminescent zinc(Ⅱ)complexes of 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine and 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine.Synthetic Metals,2005.149:135-141.
[113]Gountchev T.I.,Tilley T.D.,Organometallics,1999.18(2896).
[114]Cloke F.G.N.,Elvidge B.R.,Hitchcock P.B.,Lamarche V.M.E.,J.Chem.Soc.,Dalton Trans.,2002:2413.
[115]Shah A.A.S.,Dorn H.,Roesky H.W.,Lubini P.,et al.,Inorganic Chemistry,1997.36:1102.
[116]Sakinner M.E.G.,Tyrrel B.R.,Ward B.D.,Mountford P.,J.Organomet.Chem,2002.647:145.
[117]Skinner M.E.G.,Miuntford P.,J.Chem.Soc.,Dalton Trans.,2002:1694.
[118]GrafD.D.,Davis W.M.,Schrock R.R.,Organometallics,1998.17:5820.
[119]Fryzuk M.D.,Yu P.,Patrick B.O.,Can.J.Chem,2001.1194.
[120]Lee L.,Berg D.J.,Bushnell G.W.,Inorganic Chemistry,1994.33:5302.
[121]Fryzuk M.D.,J.B.Love,Rettig S.J.,J.Am.Chem.Soc.,1997.119:9071.
[122]Fryzuk M.D.,Jafapour L.,Kerton F.M.,J.B.Love,et al.,Organometallics,2001.20(1387).
[123]R.E.Maginn,S Manastyrskyj,M.Dubeck,The Dicyclopentadienyl lanthanide Chlorides.Journal of the American Chemical Society,1963.85(6):672-676.
[124]Michel R Gagne,Tobin J.Marks,Organolanthanide-catalyzed hydroamination.Facile,regiospecific cyclization of unprotected amino olefins.Journal of the American Chemical Society,1989.111:4108.
[125]Qi Shen,Yingming Yao,Synthesis and reactivity of organolanthanoid complexes containing N and S ligands.Journal of Organometallic Chemistry,2002.647(1-2):180-189.
[126]Alexander A.Trifonov,Dmitrii M.Lyubov,Elena A.Fedorova,Georgy K.Fukin,et al.,Chloro,Alkyl and Aryl complexes of Rare Earth Metals Supported by Bulky Tetrasubstituted Guanidinate Ligands.European Journal of Inorganic Chemistry,2006:747-756.
[127]Frank T.Edelmann,Rare earth complexes with heteroallylic ligands and their use as precusors for lanthanide-based homogeneous catalysts.Journal of Alloys and Compounds,1994.207/208:182-188.
[128]Shihui Li,Wei Miao,Tao Tang,Weimin Dong,et al.,New Rare Earth Metal Bis(alkyl)s Bearing an Iminophosphonamido Ligand.Synthesis and Catalysis toward Highly 3,4-Selective Polymerization of Isoprene.Organometallics,2008.27(4):718-725.
[129]Yunjie Luo,Masayoshi Nishiura,Zhaomin Hou,Rare earth metal bis(alkyl)complexes bearing a monodentate arylamido ancillary ligand:Synthesis,structure,and Olefin polymerization catalysis.Journal of Organometallic Chemistry,2007.692(1-3):536-544.
[130]P.J.Shapiro,W.D.Cotter,W.P.Schaefer,J.A.Labinger,et al.,Journal of the American Chemical Society,1994.116:4623.
[131]S.Arndt,A.Trifonov,T.P.Spaniol,J.Okuda,et al.,Journal of Organometallic Chemistry,2002.647:158.
[132]S.Arndt,T.P.Spaniol,J.Okuda,European Journal of Inorganic Chemistry,2001:73.
[133]S.Arndt,T.P.Spaniol,J.Okuda,Organometallics,2003.22:775.
[134]Xin Xu,Xiaoyan Xu,Yaofeng Chen,Jie Sun,Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors.Organometallics,2008.27(4):758-763.
[135]Shihui Li,Wei Miao,Tao Tang,Dongmei Cui,et al.,Rare earth metal bis(alkyl)complexes bearing amino phosphine ligands:Synthesis and catalytic activity toward ethylene polymerization.Journal of Organometallic Chemistry,2007.692(22):4943-4952.
[136]Wei Miao,Shihui Li,Dongmei Cui,Baotong Huang,Rare earth metal alkyl complexes bearing N,O,P multidentate ligands:Synthesis,characterization and catalysis on the ring-opening polymerization of l-lactide.Journal of Organometallic Chemistry,2007.692(17):3823-3834.
[137]Koleske J.V.,Lundberg R.D.,Lactone polymers.Ⅱ.Viscosity-molecular weight relationships and unperturbed chain dimensions.Journal of Polymer Science Part A:Polymer Chemistry,1969.17(8):897-907.
[138]W.H.Beattie,C.Booth,Instrinsic viscosity-mol.wt,relation for cis-1,4-polyisoprene.Journal of Applied Polymer Science,1963.7:507.
[139]王文,王征,沈之荃,Nd(P_(204))_3-Al(i-Bu)_3-CCl_4催化体系聚合甲基丙烯酸甲酯.高分子材料科学与工程,1991(4):11-16.
[140]金鹰泰,林永华,金哲山,李凤富,[(CH_2)_3CCH_2O]_4Nd_2r的合成、晶体结构和催化聚合双烯烃的研究.中国稀土学报,1993.11(1):17.
[141]R K Kulkarrni,E G Moore,A F Hegyeli,L Fred,Biodegradable poly(lactic acid)polymres.Journal of Biomedical Materials Resaerch,1971.5(3):169-181.
[142]Toshio Kawato,Hiroyuki Koyama,Hajime Kanatomi,Makiko Isshiki,Photoisomerization and thermoisomerization Ⅰ:Unusual Photochromism of N-(3,5-Di-tert-Butyl-Salicylidene)amines.Journal of Photochemistry,1985.28:103-110.
[143]Stephen T.Liddle,William Clegg,Cation-induced structural variations in the alkali metal derivatives of 2-trimethylsilylaminopyridine:synthesis and X-ray structures of complexes for all five metals Li-Cs with 12-crown-4.J.Chem.Soc.,Dalton Trans.,2001:402-408.
[144]M.D.Taylor,C.P.Cartes,LnCl3.J.Inorg.Nucl.Chem.,1962.24:387.
[145]Jose E.Baez,Angel Marcos-Fernandez,Rosa Lebron-Aguilar,Antonio Martinez-Richa,A novel route to[alpha],[omega]-telechelic poly([var epsilon]-caprolactone)diols,precursors of biodegradable polyurethanes,using catalysis by decamolybdate anion.Polymer,2006.47(26):8420-8429.
[146]D Braun,H.Cherdron,M.Rehahn,H.Ritter,Polymer Synthesis:Theory and Practice.4th ed.2004,Berlin:Springer.
[147]樊玲,三(2,4,6-三甲基苯氧基)稀土配合物单组分催化环酯聚合与可控合成两亲性嵌段共聚物及其胶束的制备,高分子化学与物理.2006,浙江大学:博士学位论文.
[148]J.Ling,Z.Q.Shen,W.P.Zhu,Synthesis,characterization,and mechanism studies on novel rare-earth calixarene complexes initiating ring-opening polymerization of 2,2-dimethyltrimethylene carbonate.Journal of Polymer Science Part a-Polymer Chemistry,2003.41(9):1390-1399.
[149]J.Ling,Z.Q.Shen,Lanthanum tris(2,6-di-tert-butyl-4-methylphenolate)as a novel,versatile initiator for homo- and copolymerization of cyclic carbonates and lactones(vol 203,pg 735,2002).Macromolecular Chemistry and Physics,2002.203(12):1872-1872.
[150]Q.H.Huang,Z.Q.Shen,Y.F.Zhang,Y.Q.Shen,et al.,Ring-opening copolymerization of trimethylene carbonate and D,L-lactide by rare earth chloride.Polymer Journal,1998.30(3):168-170.
[151]Y.Q.Shen,Z.Q.Shen,Y.F.Zhang,Q.H.Huang,et al.,Random copolymerization of epsilon-caprolactone and trimethylene carbonate with rare earth catalysts.Journal of Applied Polymer Science,1997.64(11):2131-2139.
[152]Y.Q.Shen,Z.Q.Shen,Y.F.Zhang,G.H.Hang,A comparison of polymerization characteristics and mechanisms of epsilon-caprolactone and trimethylene carbonate with rare earth halides.Journal of Polymer Science Part A-Polymer Chemistry,1997.35(8):1339-1352.
[153]Jun Ling,Weipu Zhu,Zhiquan Shen,Controlling Ring-Opening Copolymerization of ε-Caprolactone with Trimethylene Carbonate by Scandium Tris(2,6-di-tert-butyl-4-methylphenolate).Macromolecules,2004.37:758-763.
[154]沈之荃,龚仲元,欧阳均,高分子通讯,1965.7:193.
[155]钱长涛,杜灿屏,稀士金属有机化学.1st ed.2004,北京:化学工业出版社.第九章:267
[156]Jun Ling,Xufeng Ni,Yifeng Zhang,Zhiquan Shen,Monte Carlo simulation of gas phase polymerization of 1,3-butadiene Part Ⅰ.Modeling and programming.Polymrer,2000.41:8703-8707.
[157]Jun Ling,Xufeng Ni,Yifeng Zhang,Zhiquan Shen,Monte Carlo simulation of gas phase polymerization of 1,3-butadiene Part Ⅱ.Kinetics optimization and confirmation.Polymer International,2003.52:213-217.
[158]Junfei Li Yifeng Zhang Zhiquan Shen Xufeng Ni,Gas phase polymerization of 1,3-butadiene with supported neodymium-based catalyst:Investigation of molecular weight.Journal of Applied Polymer Science,2004.92(3):1945-1949.
[159]R.P.Quirka,A.M.Kells,K.Yunlu,J.P.Cuif,Polymer,2000.41:5903.
[160]张国栋,杨纪元,冯新德,聚乳酸的研究进展.化学进展,2000.12(1):89-102.
[161]Matthieu Jalabert,Carole Fraschini,Robert E.Prud Homme,Synthesis and Characterization of Poly(L-lactide)s and Poly(D-lactide)s of Controlled Molecular Weight.Journal of Polymer Science:Part A:Polymer Chemistry,2007.45:1944-1955.
[162]Barakat,Ph.Dubois,R.Jerome,Ph.Teyssie,Macromolecular Engineering of Polylactones and Polylactides.X.Selective End-Functionalization of Poly(D,L)-Lactide.Journal of Polymer Science Part A:Polymer Chemistry,1993.31:505-514.
[163]D.J.Darensbourg,W.Choi,C.P.Richers,Ring-Opening Polymerization of Cyclic Monomers by Biocompatible Metal Complexes.Production of Poly(lactide),Polycarbonates,and Their Copolymers.Macromolecules,2007.40(10):3521-3523.
[164]Sandor Keki,Janos Torok,Gyorgy Deak,Miklos Zsuga,Mechanism of ring-opening and elimination cooligomerization of cyclic carbonates and ε-caprolactone:Formation of cyclic cooligomers.European Polymer Journal,2005.41:1478-1483.
[165]J.R.Sarasua,R.E.Prud'homme,M.Wisniewski,A.Le Borgne,et al.,Crystallization and Melting Behavior of Polylactides.Macromolecules,1998.31(12):3895-3905.
[166]Jun Ling,Zhiquan Shen,Lanthanum tris(2,6-di-tert-butyl-4-methylphenolate)as a Novel,Versatile Initiator for Homo- and Copolymerization of Cyclic Carbonates and Lactones.Macromol.Chem.Phys.,2002.203:735-738.
[167]Fabienne Fay,Estelle Renard,Valerie Langlois,Isabelle Linossier,et al.,Development of poly(e-caprolactone-co-L-lactide)and poly(ε-caprolactone-eod-valerolactone)as new degradable binder used for antifouling paint.European Polymer Journal,2007.43:4800-4813.
[168]Changchun Min,Wenjin Cui,Jianzhong Bei,Shenguo Wang,Effect of comonomer on thermal/mechanical and shape memory property of L-lactide-based shape-memory copolymers.Polymers for Advanced Technologies,2007.18:299-305.
[169]Hiroshi Miyasako,Kazuya Yamamoto,Aiko Nakao,Takao Aoyagi,Preparation of Cross-Linked Poly[(e-caprolactone)-co-lactide]and Biocompatibility Studies for Tissue Engineering Materials.Macromolecular Bioscience,2007.7:76-83.
[170]Swapan Kumar Saha,Hideto Tsuji,Effect of rapid crystallization on hydrolytic degradation and mechanical properties of poly(L-lactide-co-ε-carprolactone).Reactive and Functional Polymers,2006.66:1362-1372.
[171]S.Ya.Knjazhanski,L.Elizalde,G.Cadenas,B.M.Bulychev b,Polymerization of methyl methacrylate with alane complexes of bivalent lanthanidocenes.Journal of Organometallic Chemistry,1998.568:33-40.
[172]Lisa S.Boffa,Bruce M.Novak,Bimetallic Samarium(Ⅲ)Initiators for the Living Polymerization of Methacrylates and Lactones.A New Route into Telechelic,Triblock,and "Link-Functionalized" Polymers.Macromolecules,1994.27:6993-6995.
[173]Eiji Ihara,Kouji Koyama,Hajime Yasuda,Nobuko Kanehisa,et al.,Catalytic activity of allyl-,azaallyl- and diaza-pentadienyllanthanide complexes for polymerization of methyl methacrylate.Journal of Organometallic Chemistry,1999.574:40-49.
[174]Hajime Yasuda,Hitoshi Yamamoto,Masahiro Yamashita,Synthesis of High Molecular Weight Poly(methyl methacrylate)with Extremely Low Polydispersity by the Unique Function of Organolanthanide(111)Complexes.Macromolecules,1993.26:7134-7143.
[175]Michael A.Giardello,Yoshihiro Yamamoto,Laurent Brard,Tobin J.Marks, Stereocontrol in the Polymerization of Methyl Methacrylate Mediated by Chiral Organolanthanide Metallocenes.J.Am.Chem.Soc.,1995.117:3276-3277.
[176]周利英,氨基配体的结构对氨基稀土化合物的合成、结构和反应性能的影响,有机化学.2007,苏州大学:博士学位论文.
[177]Shuang-L.Zhou,Shao-W.Wang,Gao-S.Yang,Xin-Y.Liu,et al.,Synthesis,structure,and catalytic activity of tetracoordinate lanthanide amides [(Me_3Si)_2N]_3Ln(μ-Cl)Li(THF)_3(Ln=Nd,Sm,Eu).Polyhedron,2003.22(7):1019-1024.
[178]C.Qian,W.Nie,J.Sun,Cs-Symmetric ansa-Lanthanocenes Designed for Stereospecific Polymerization of Methyl Methacrylate.Synthesis and Structural Characterization of Silylene-Bridged Fluorenyl Cyclopentadienyl Lanthanide Halides,Amides,and Hydrocarbyls.Organometallics,2000.19(20):4134-4140.
[179]T.J.Woodman,M.Schormann,D.L.Hughes,M.Bochmann,Sterically Hindered Lanthanide Allyl Complexes and Their Use as Single-Component Catalysts for the Polymerization of Methyl Methacrylate and ε-Caprolactone.Organometallics,2004.23(12):2972-2979.
[180]Da Li,Yumei Zhang,Huaping Wang,Jianzhong Tang,et al.,Effect of the Medium on the Stereostructure of Poly(methyl methacrylate)Synthesized in Ionic Liquids.Journal of Applied Polymer Science,2006.102:2199-2202.