两种外围修饰的含硫四氮杂卟啉金属配合物的合成与性能研究
摘要
引文
[1] Karaoglu H.R., Gul A.,Kocak M.B., Synthesis and Characterization of a New Tetracationic Phthalocyanine, Dyes and Pigments, 2008, 76 : 231-235.
[2] Durmus M., Nyokong T., The Synthesis Fluorescence Behaviour and Singlet Oxygen Studies of New Water-soluble Cationic Gallium(III) Phthalocyanines, Inorg. Chem. Commum., 2007, 10 : 332-338.
[3] Koca A., Bayar S., Dincer H., Gonca E., Voltammetric in-situ Spectroelectro- chemical and in-situ Electrocolorimetric Characterization of Phthalocyanines, Electrochimica Acta, 2009, 54 : 2684-2692.
[4] Khelevina O.G., Chizhova N.V., Stuzhin P.A., Modification of b-positions in Porphyrazines by Substitution Reactions, J. Porphyr. Phthalocya., 2000, 4 : 555–563.
[5] Chen J., Poon C., Photocatalytic Construction and Building Materials:From Fundamentals to Applications, Building and Environment, 2009, 44 (9) : 1899-1906.
[6] Durmus M., Erdogmus A., Ogunsipe A., Nyokong T., The Synthesis and Photophysicochemical Behaviour of Novel Water-soluble Cationic Indium(III) Phthalocyanine, Dyes and Pigments, 2009, 82 : 244-250.
[7] Sorokin A., Meunier B., Oxidation of Pollutants Catalyzed by Metallo- phthalocyanines, Acc. Chem. Res., 1997, 30 : 470-476.
[8] Kobayashi N., Miwa H., Isago H., et al., An Adjacent Dibenzotetraazaporphyrin: A Structural Intermediate between Tetraazaporphyrin and Phthalocyanine, Inorg. Chem., 1999, 38 : 479-485.
[9] Ishii K., Itoya H., Miwa H., et al., Relationship between Symmetry of Porphyrinicπ-Conjugated Systems and Singlet Oxygen Yields: Low-Symmetry Tetraazaporphyrin Derivatives, J. Phys. Chem. A, 2005, 109 : 5781-5787.
[10] Hammer N.D., Lee S., Vesper B.J., et al.,Charge Dependence of Cellular Uptake and Selective Antitumor Activity of Porphyrazines, J. Med. Chem., 2005, 48 :8125-8133.
[11] Thamae M., Nyokong T., Cobalt(II) Porphyrazine Catalysed Reduction of Nitrite, J. Electro. Chem., 1999, 470 : 126-135.
[12] Sekota M., Nyokong T., Palladium(II) and Platinum(II) Tetramethyltetra- pyridinoporphyrazine Complexes: Redox Properties and Interactions with Cysteine and Histidine, J. Porphyr. Phthalocya., 1999, 3 : 477-487.
[13] Nyokong T., Gasyna Z., Stillman M., Phthalocyanineπ-Cation-Radical Species: Photochemical and Electrochemical Preparation of [ZnPc(-1)]+ in solution, Inorg. Chem, 1994, 26 : 548-553.
[14] Cook A.H., Linstead R.P., Phthalocyanines Part XI. The Preparation of Octaphenyl- porphyrazines from Diphenylmaleinitrile, J. Chem. Soc, 1937 : 929-933.
[15] Linstead R.P., Whalley M., Conjugated Macrocylces Part XXII. Tetrazaporphin and its Metallic Derivatives, J. Chem. Soc, 1952 : 4839-4846.
[16]刘涌洲,硫代四代杂卟啉及其过渡金属配合物的合成与功能研究,武汉大学博士学位论文, 2004 : 1-25.
[17] B?hr G., Schleitzer G., Beitr?ge zur Chemie des Schwefelkohlenstoffs und Selenkohlenstoffs, I. Mitteil.: Salze der Cyan-dithioameisens?ure, Chem. Ber, 1955, 88 (11) : 1771-1777.
[18] Wolf W., Degener E., Peteersen S., Dicyano-dithia-cyclohexen, einneues neterocycl isches Dinitril Zur Herstellung Van Phthalocyaninen, Angew. Chem. Int. Ed., 1960, 72 (24) : 963-966.
[19] Manecke V.G., W?hrle D., Synthese und halbleitereigenschaften einiger komplexe und der aus ihnen hergestellten polymeren. Teil. Polymere mitphthalocyaninartige und triazinartiger stuktur, Die Makromolekulare Chem., 1968, 120 (1) : 176-191.
[20] Schramm C.J., Hoffman B.M., Octakis(alkylthio) Tertrazzaporphyrins, Irorg. Chem, 1980, 19 : 383-385.
[21]沈永嘉,酞菁的合成与应用,第一版,北京,化学工业出版社, 2000 : 137-138.
[22]孙杰,韩耑壮,邓克俭等,干熔法合成四(对-二硫杂环己烯)四氮杂卟啉铁,合成化学, 2006, 14 : 552-555.
[23] Haeg W., Yao C., Rate Constants for Reaction of Hydroxyl Radicals with Several Drinking Water Contaminants, Environ. Sci. Technol., 1992, 26 : 1005.
[24] Szaci?owski K., Macyk W., Drzewiecka-Matuszek A., Brindell M., Stochel G., Bioinorganic Photochemistry: Frontiers and Mechanisms, Chem. Rev. 2005, 105 : 2647-2694.
[25]马万红,籍宏伟,李静,赵进才,活化和分子氧的光催化氧化反应,科学通报, 2004, 49 (18) : 1821-1829.
[26] Hill C L., Controlled Green Oxidation, Nature, 1999, 401 : 436-437.
[27] Collins T J., Toward Sustainable Chemistry, Science, 2001, 291 : 1899-1900.
[28] Wao I., Reductive Dioxygen Action by use of Artifical P450 Systems, Coord. Chem. Rev., 1988, 86 : 1-42.
[29] Parra S., Guasaquillo I., Enea O., et al, Abatement of an Azo Dye on Structured C-Nafion/Fe-Ion Surfaces by Photo-Fenton Reactions Leading to Carboxylate Intermediates with a Remarkable Biodegradability Increase of the Treated Solution, J. Phys. Chem. B, 2003, 107 : 7026-7035.
[30] Meunier B., Metalloporphyrins as Versatile Catalysts for Oxidation Reactions and Oxidative DNA Cleavage, Chem. Rev., 1992, 92 (6) : 1411-1456.
[31] Sorokin A., Suzzoni Dezard S. D., Meunier B., CO2 as the Ultimate Degradation Product in the H2O2 Oxidation of 2,4,6-trichlorophnol Ctalyzed by Iron Tetrasulfophalocyanine, J. Am. Chem. Soc., 1996, 118 (31) : 7401-7411.
[32] Sorokin A., Seris J. L., Meunier B., Effect of Arterially Infused Catecholamines and Insulin on Plasma Glucose and Free Fatty Acids in Carp, Science, 1995, 268 : 1163-1166.
[33] Tao X., Ma W., Zhang T., et al, Efficient Oxidative Degradation of Organic Pollutants in the presence of Iron Tetrasulfophthalayanine under Visible Irradiation, Angew. Chem. Int. Ed., 2001, 113 : 3013-3016.
[34] Tao X., Ma W., Zhang T., et al, A Novel Approach for the Oxidative Degradation of Organic Pollutants in Aqueous Solutions Mediated by Iron Tetrasulfophthalayanine under Visible Light Irradiation, Chem. Eur. J., 2002, 6 :1321-1326.
[35] Gupta S. S., Stadler M., Collins T. J., Rapid Total Destraction Chlorophenols by Activated Hydrogen Peroxide, Science, 2002, 296 : 326-328.
[36] Collins T. J., A New Approach to Activation Hydrogen Peroxide for Environmentally Significant Problems, Acc. Chem. Res., 2002, 35 (9) : 782-790.
[37] Barton D. H. R., Gastiger M. J., Motherwell W. B., A New Prodedure for the Oxidationof Saturated Hydrocarbons, J. Chem. Soc. Chem. Commun., 1983, (1) : 4143.
[38] Brink G., Arends I., Sheldon R. A., Green, Catalytic Oxidation of Alcohols in Water, Science, 2000, 287 : 1636-1639.
[39] Weber L., Hommel R., Behling J., et al, Photocatalytic Oxygenation of Hydrocarbons with (tetraaryphyrinato) Iron(Ⅲ) Complexes and Molecular Oxygen. Comparison with Microsomal Cytochrome P-450 Mediated Oxygenation Reaction, .J. Am. Chem. Soc., 1994, 116 (6) : 2400-2408.
[40] Iliev V., Mihaylova A., Bilyarska L., Photooxidation of Phenols in Aquous Solution, Catalyzed by Mononuclear and Polynuclear Metal Phthalocyanine Complexes, J. Mol. Catal. A: Chem., 2002, 184 : 121.
[41] Ozoemena K., Kuznetsova N., Nyokong T., Comparative Photosensitized Transformation of Polychlorophenols with Different Sulphonated Metallo- phthalocyanine Complexes in Aqueous Medium, J. Mol. Catal. A: Chem., 2001, 176 : 29-40.
[42] Hu M., Xu Y., Xiong Z., A Novel Photosensitizer of Palladium(Ⅱ) Phthalocyanine Tetrasulfonate for Chlorophenol Oxidation under Visible Light Irradiation, Chem. Lett., 2004, 33 (9) : 1092-1093.
[43] Hu M., Xu Y., Zhao J., Efficient Photosensitized Degradation of 4-chlorophenol over Immobilized Aluminum Tetrasulfophthalocyanine in the presence of Hydrogen Peroxide, Langmuir, 2004, 20 : 6302-6307.
[44] Ma W., Li J., Zhao J., et al, Efficient Degradation of Organic Pollutants using Dioxygen Activeate by Resin-exchanged Iron(Ⅱ) Bypyridine under VisibleIrradiation, Angew. Chem. Int. Ed., 2003, 42 (9) : 1029-1032.
[45]黄飞,伍明,韩端壮等.四氮杂卟啉铁( II)催化降解水中有机污染物.中南民族大学学报(自然科学版), 2003, 22 (3): 6-9.
[46]杨有清,蓝伟侦,邓克俭等.活化分子氧降解水中有机污染物的CODCr值测定.中南民族大学学报(自然科学版), 2004, 23 (2): 1-4.
[47]刘敏,韩端壮,邓克俭等.载体对含硫四氮杂卟啉铁(Ⅱ) /树脂催化剂降解水中有机污染物效率的影响.催化学报, 2004,25(10): 834-838.
[48] Deng K.J., Huang F. and Wang D.Y. et al. Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen. Chinese Chemical Letters, 2004, 15(10): 1223-1226.
[49] Deng K.J., Huang F. and Wang D.Y. et al. A Novel Catalyst Iron(II) Tetra(1,4-dithin) porphyrazine for Oxygenating Degradation of Organic Pollutants in Aqueous Solutions. Chemistry Letters, 2004, 33(1): 34-35.
[50] Lei Y.P., Sun J. and Yang C.J. et al. Preparation and properties of sulfur-Containing tetraazaporphyrin iron supported on anion-exchange resin. J. Porphyrins Phthalocya-nines, 2005, 9: 537-543.
[51] Sun J., Han D.Z. and Deng K.J. et al. A mechanism of simulating enzymes to activate dioxygen for degradation of organic pollutants. J. Porphyrins Phthalocyanines, 2006, 10: 440.
[52]彭正合,温丽丽,蔡萍等,四氮杂卟啉研究进展,化学通报, 2002, 65 : 58.
[53] Yamazaki I., Piette H., EPR pin-Trapping Study on the Oxidizing Species Formed in the Reaction of the Ferrous Ion with Hydrogen Peroxide, J. Am. Chem. Soc., 1991, 113 : 7588-7593.
[54] Wu K., Xie Y., Zhao J., Hidaka H., Photo-Fenton degradation of a dye under visible light irradiation, J. Mol. Catal., 1999, 144 : 77.
[55] Hadasch A., Sorokin A., Rabion A., Meunier B., Sequential addition of H2O2, pH and Solvent Effects as Key Factors in the Oxidation of 2,4,6-trichlorophenol Catalyzed by Iron Tetrasulfophthalocyanine, New J. Chem., 1998 : 45-51.
[56] Hoffmann M. R., Martin S.T., Choi W., Bahemann D.W., Environmental Applications of Semiconductor Photo Catalysis, Chem. Rev., 1995, 95 : 69.
[57] Ma W., Li J., Zhao J., et al, Efficient Degradation of Organic Pollutants using Dioxygen Activeate by Resin-exchanged Iron(Ⅱ) Bypyridine under Visible Irradiation, Angew. Chem. Int. Ed., 2003, 42 (9) : 1029-1032.
[58] Li J., Ma W., Zhao J., et al, Oxidative Degradation of Organic Pollutants Utilizing Molecular and Visible Light over A Supported Catalyst of Fe(bpy)3+ in Water, Appl. Catal. B: Environ., 2004, 48 (1) : 17-24.
[59] Sun J., Sun Y.P., Deng K.J., et al, Synthesis and Characterization of Iron Sulfo-or Chlorotetra(1,4-dithiin)-porphyrazine, J. Porphyr. Phthalocya., 2006, 10 : 604.
[60] Sun J., Sun Y.P. and Deng K.J. et al. Oxidative Degradation of Organic Pollutants by Hydrogen Peroxide in the Presence of FePz(dtnCl2)4 under Visible Irradiation. Chemistry Letters, 2007, 36(5): 2-3.
[61] Cha D., Liu M., Zeng Z., Cheng D., Zhan G., Analysis of Fatty Acids in Lung Tissues using Gas Chromatography–mass Spectrometry Preceded by Derivatization-solid-phase Microextraction with A Novel Fiber, Analy. Chimi. Acta, 2006, 572 : 47-54.
[62] Ishibashi K., Fujishima A., Watanabe T., Hashimoto K., Detection of Active Oxidative Species in Ti02 Photocatalysis using the Fluorescence Technique, Electrochem. Commum. 2000, 2 : 207-210.
[63] Guan H., Zhu L., Zhou H., Tang H., Rapid Probing of Photocatalytic Activity on Titania-based Self-cleaning Materials using 7-hydroxycoumarin Fluorescent probe, Analyt. Chim. Acta 2008, 608 : 73-78.
[64] Labat G., SetiS J.L., Meunier B., Oxidative Degradation of Aromaric Pollutants by Chemical Models of Ligninase Based on Porphyrin Complexes, Angew. Chem. Int. Ed. 1990, 29 : 1471-1473.
[65] Finkelstein E., Rosen G. M., Rauckman E. J., et al, Kinetics of the Reaction of Super Oxide and Hydroxyl Radicals with Nitrones, J. Am. Chem. Soc, 1980, 102 : 4994-4999.
[66] Feng J., Hu X., Yue P., et al, Degradation of Azo-dye Orange II by a Photoassisted Fenton Reaction using A Novel Composite of Iron Oxide and Silicate Nanoparticles as A Catalyst, Ind. Eng. Chem. Res., 2003, 42 :2058-2066.
[67] Yang C.J., Sun J., Deng K.J. , Wang D.Y., Synthesis and Photocatalytic Porperities of Iron(II)-tetra-methyl-tetra-(1,4-dithin)-porphyrazine, Catal. Commun., 2008, 9 : 321-326.
[68] Kwon B.G., Lee D.S., Kang N.G., Yoon J., Characteristics of P-chlorophenol Oxidation by Fenton Regent, Wat. Res., 1999, 33 (9) : 2110.
[69] Feng J., Hu X., Yue P., et al, Degradation of Azo-dye Orange II by a Photoassisted Fenton Reaction using A Novel Composite of Iron Oxide and Silicate Nanoparticles as A Catalyst, Ind. Eng. Chem. Res., 2003, 42 : 2058-2066.
[70] Cheng M., Ma W., Zhao J., et al, Visible-light-assisted Degradation of Dyes Pollutants over Fe(III)-loaded Resin in the presence of H2O2 at Neutral pH Values, Environ. Sci. Technol., 2004, 38 : 1569-1575.
[71] Dorfman L. M., Adams G. E., Reactivity of the Hydroxyl Radical in Aqueous Solutions, National Bureau of Standards, Washington, DC, 1973.
[2] Durmus M., Nyokong T., The Synthesis Fluorescence Behaviour and Singlet Oxygen Studies of New Water-soluble Cationic Gallium(III) Phthalocyanines, Inorg. Chem. Commum., 2007, 10 : 332-338.
[3] Koca A., Bayar S., Dincer H., Gonca E., Voltammetric in-situ Spectroelectro- chemical and in-situ Electrocolorimetric Characterization of Phthalocyanines, Electrochimica Acta, 2009, 54 : 2684-2692.
[4] Khelevina O.G., Chizhova N.V., Stuzhin P.A., Modification of b-positions in Porphyrazines by Substitution Reactions, J. Porphyr. Phthalocya., 2000, 4 : 555–563.
[5] Chen J., Poon C., Photocatalytic Construction and Building Materials:From Fundamentals to Applications, Building and Environment, 2009, 44 (9) : 1899-1906.
[6] Durmus M., Erdogmus A., Ogunsipe A., Nyokong T., The Synthesis and Photophysicochemical Behaviour of Novel Water-soluble Cationic Indium(III) Phthalocyanine, Dyes and Pigments, 2009, 82 : 244-250.
[7] Sorokin A., Meunier B., Oxidation of Pollutants Catalyzed by Metallo- phthalocyanines, Acc. Chem. Res., 1997, 30 : 470-476.
[8] Kobayashi N., Miwa H., Isago H., et al., An Adjacent Dibenzotetraazaporphyrin: A Structural Intermediate between Tetraazaporphyrin and Phthalocyanine, Inorg. Chem., 1999, 38 : 479-485.
[9] Ishii K., Itoya H., Miwa H., et al., Relationship between Symmetry of Porphyrinicπ-Conjugated Systems and Singlet Oxygen Yields: Low-Symmetry Tetraazaporphyrin Derivatives, J. Phys. Chem. A, 2005, 109 : 5781-5787.
[10] Hammer N.D., Lee S., Vesper B.J., et al.,Charge Dependence of Cellular Uptake and Selective Antitumor Activity of Porphyrazines, J. Med. Chem., 2005, 48 :8125-8133.
[11] Thamae M., Nyokong T., Cobalt(II) Porphyrazine Catalysed Reduction of Nitrite, J. Electro. Chem., 1999, 470 : 126-135.
[12] Sekota M., Nyokong T., Palladium(II) and Platinum(II) Tetramethyltetra- pyridinoporphyrazine Complexes: Redox Properties and Interactions with Cysteine and Histidine, J. Porphyr. Phthalocya., 1999, 3 : 477-487.
[13] Nyokong T., Gasyna Z., Stillman M., Phthalocyanineπ-Cation-Radical Species: Photochemical and Electrochemical Preparation of [ZnPc(-1)]+ in solution, Inorg. Chem, 1994, 26 : 548-553.
[14] Cook A.H., Linstead R.P., Phthalocyanines Part XI. The Preparation of Octaphenyl- porphyrazines from Diphenylmaleinitrile, J. Chem. Soc, 1937 : 929-933.
[15] Linstead R.P., Whalley M., Conjugated Macrocylces Part XXII. Tetrazaporphin and its Metallic Derivatives, J. Chem. Soc, 1952 : 4839-4846.
[16]刘涌洲,硫代四代杂卟啉及其过渡金属配合物的合成与功能研究,武汉大学博士学位论文, 2004 : 1-25.
[17] B?hr G., Schleitzer G., Beitr?ge zur Chemie des Schwefelkohlenstoffs und Selenkohlenstoffs, I. Mitteil.: Salze der Cyan-dithioameisens?ure, Chem. Ber, 1955, 88 (11) : 1771-1777.
[18] Wolf W., Degener E., Peteersen S., Dicyano-dithia-cyclohexen, einneues neterocycl isches Dinitril Zur Herstellung Van Phthalocyaninen, Angew. Chem. Int. Ed., 1960, 72 (24) : 963-966.
[19] Manecke V.G., W?hrle D., Synthese und halbleitereigenschaften einiger komplexe und der aus ihnen hergestellten polymeren. Teil. Polymere mitphthalocyaninartige und triazinartiger stuktur, Die Makromolekulare Chem., 1968, 120 (1) : 176-191.
[20] Schramm C.J., Hoffman B.M., Octakis(alkylthio) Tertrazzaporphyrins, Irorg. Chem, 1980, 19 : 383-385.
[21]沈永嘉,酞菁的合成与应用,第一版,北京,化学工业出版社, 2000 : 137-138.
[22]孙杰,韩耑壮,邓克俭等,干熔法合成四(对-二硫杂环己烯)四氮杂卟啉铁,合成化学, 2006, 14 : 552-555.
[23] Haeg W., Yao C., Rate Constants for Reaction of Hydroxyl Radicals with Several Drinking Water Contaminants, Environ. Sci. Technol., 1992, 26 : 1005.
[24] Szaci?owski K., Macyk W., Drzewiecka-Matuszek A., Brindell M., Stochel G., Bioinorganic Photochemistry: Frontiers and Mechanisms, Chem. Rev. 2005, 105 : 2647-2694.
[25]马万红,籍宏伟,李静,赵进才,活化和分子氧的光催化氧化反应,科学通报, 2004, 49 (18) : 1821-1829.
[26] Hill C L., Controlled Green Oxidation, Nature, 1999, 401 : 436-437.
[27] Collins T J., Toward Sustainable Chemistry, Science, 2001, 291 : 1899-1900.
[28] Wao I., Reductive Dioxygen Action by use of Artifical P450 Systems, Coord. Chem. Rev., 1988, 86 : 1-42.
[29] Parra S., Guasaquillo I., Enea O., et al, Abatement of an Azo Dye on Structured C-Nafion/Fe-Ion Surfaces by Photo-Fenton Reactions Leading to Carboxylate Intermediates with a Remarkable Biodegradability Increase of the Treated Solution, J. Phys. Chem. B, 2003, 107 : 7026-7035.
[30] Meunier B., Metalloporphyrins as Versatile Catalysts for Oxidation Reactions and Oxidative DNA Cleavage, Chem. Rev., 1992, 92 (6) : 1411-1456.
[31] Sorokin A., Suzzoni Dezard S. D., Meunier B., CO2 as the Ultimate Degradation Product in the H2O2 Oxidation of 2,4,6-trichlorophnol Ctalyzed by Iron Tetrasulfophalocyanine, J. Am. Chem. Soc., 1996, 118 (31) : 7401-7411.
[32] Sorokin A., Seris J. L., Meunier B., Effect of Arterially Infused Catecholamines and Insulin on Plasma Glucose and Free Fatty Acids in Carp, Science, 1995, 268 : 1163-1166.
[33] Tao X., Ma W., Zhang T., et al, Efficient Oxidative Degradation of Organic Pollutants in the presence of Iron Tetrasulfophthalayanine under Visible Irradiation, Angew. Chem. Int. Ed., 2001, 113 : 3013-3016.
[34] Tao X., Ma W., Zhang T., et al, A Novel Approach for the Oxidative Degradation of Organic Pollutants in Aqueous Solutions Mediated by Iron Tetrasulfophthalayanine under Visible Light Irradiation, Chem. Eur. J., 2002, 6 :1321-1326.
[35] Gupta S. S., Stadler M., Collins T. J., Rapid Total Destraction Chlorophenols by Activated Hydrogen Peroxide, Science, 2002, 296 : 326-328.
[36] Collins T. J., A New Approach to Activation Hydrogen Peroxide for Environmentally Significant Problems, Acc. Chem. Res., 2002, 35 (9) : 782-790.
[37] Barton D. H. R., Gastiger M. J., Motherwell W. B., A New Prodedure for the Oxidationof Saturated Hydrocarbons, J. Chem. Soc. Chem. Commun., 1983, (1) : 4143.
[38] Brink G., Arends I., Sheldon R. A., Green, Catalytic Oxidation of Alcohols in Water, Science, 2000, 287 : 1636-1639.
[39] Weber L., Hommel R., Behling J., et al, Photocatalytic Oxygenation of Hydrocarbons with (tetraaryphyrinato) Iron(Ⅲ) Complexes and Molecular Oxygen. Comparison with Microsomal Cytochrome P-450 Mediated Oxygenation Reaction, .J. Am. Chem. Soc., 1994, 116 (6) : 2400-2408.
[40] Iliev V., Mihaylova A., Bilyarska L., Photooxidation of Phenols in Aquous Solution, Catalyzed by Mononuclear and Polynuclear Metal Phthalocyanine Complexes, J. Mol. Catal. A: Chem., 2002, 184 : 121.
[41] Ozoemena K., Kuznetsova N., Nyokong T., Comparative Photosensitized Transformation of Polychlorophenols with Different Sulphonated Metallo- phthalocyanine Complexes in Aqueous Medium, J. Mol. Catal. A: Chem., 2001, 176 : 29-40.
[42] Hu M., Xu Y., Xiong Z., A Novel Photosensitizer of Palladium(Ⅱ) Phthalocyanine Tetrasulfonate for Chlorophenol Oxidation under Visible Light Irradiation, Chem. Lett., 2004, 33 (9) : 1092-1093.
[43] Hu M., Xu Y., Zhao J., Efficient Photosensitized Degradation of 4-chlorophenol over Immobilized Aluminum Tetrasulfophthalocyanine in the presence of Hydrogen Peroxide, Langmuir, 2004, 20 : 6302-6307.
[44] Ma W., Li J., Zhao J., et al, Efficient Degradation of Organic Pollutants using Dioxygen Activeate by Resin-exchanged Iron(Ⅱ) Bypyridine under VisibleIrradiation, Angew. Chem. Int. Ed., 2003, 42 (9) : 1029-1032.
[45]黄飞,伍明,韩端壮等.四氮杂卟啉铁( II)催化降解水中有机污染物.中南民族大学学报(自然科学版), 2003, 22 (3): 6-9.
[46]杨有清,蓝伟侦,邓克俭等.活化分子氧降解水中有机污染物的CODCr值测定.中南民族大学学报(自然科学版), 2004, 23 (2): 1-4.
[47]刘敏,韩端壮,邓克俭等.载体对含硫四氮杂卟啉铁(Ⅱ) /树脂催化剂降解水中有机污染物效率的影响.催化学报, 2004,25(10): 834-838.
[48] Deng K.J., Huang F. and Wang D.Y. et al. Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen. Chinese Chemical Letters, 2004, 15(10): 1223-1226.
[49] Deng K.J., Huang F. and Wang D.Y. et al. A Novel Catalyst Iron(II) Tetra(1,4-dithin) porphyrazine for Oxygenating Degradation of Organic Pollutants in Aqueous Solutions. Chemistry Letters, 2004, 33(1): 34-35.
[50] Lei Y.P., Sun J. and Yang C.J. et al. Preparation and properties of sulfur-Containing tetraazaporphyrin iron supported on anion-exchange resin. J. Porphyrins Phthalocya-nines, 2005, 9: 537-543.
[51] Sun J., Han D.Z. and Deng K.J. et al. A mechanism of simulating enzymes to activate dioxygen for degradation of organic pollutants. J. Porphyrins Phthalocyanines, 2006, 10: 440.
[52]彭正合,温丽丽,蔡萍等,四氮杂卟啉研究进展,化学通报, 2002, 65 : 58.
[53] Yamazaki I., Piette H., EPR pin-Trapping Study on the Oxidizing Species Formed in the Reaction of the Ferrous Ion with Hydrogen Peroxide, J. Am. Chem. Soc., 1991, 113 : 7588-7593.
[54] Wu K., Xie Y., Zhao J., Hidaka H., Photo-Fenton degradation of a dye under visible light irradiation, J. Mol. Catal., 1999, 144 : 77.
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