农药—类水滑石纳米杂化物的合成及性能研究
|
摘要
我国是世界上第二大农药生产国,但与发达国家相比,长期存在剂型结构不合理,制剂质量差等问题。目前我国的农药制剂仍以传统的粉剂、乳油和悬浮剂为主,技术落后,药效差,且对环境污染严重。近年来,以安全、经济、环保为目标的农药新剂型研制日益受到重视,其中农药控释剂型已成农药剂型领域的研究热点。
类水滑石(Hydrotalcite-like compounds,简称HTlc)是由两种或两种以上金属元素组成的具有水滑石层状晶体结构的氢氧化物,层片带结构正电荷,层间存在可交换的阴离子。HTlc层间可作为微型储存器,将农药分子插入其中制成农药-HTlc纳米杂化物,因空间位阻效应和农药分子与层板间的相互作用可实现对农药分子的控释。近期,农药-HTlc纳米杂化物的制备及在农药控释剂型中的应用备受关注。
本文分别选取阴离子型水溶性农药吲哚丁酸(Indole-3-bytric acid,简称IBA)、非离子型水溶性农药吡虫啉(Imidacloprid,简称IM)和非离子型水难溶性农药阿维菌素(Avermectin,简称AVM)为客体分子,以HTlc为主体,分别采用离子交换法、二次组装法和二次组装蒸发溶剂促进插层法制备了三种农药/HTlc纳米杂化物,考察了其释放行为,探讨了释放机理。以期掌握农药-HTlc纳米杂化物的关键制备技术,了解其农药控释规律,为进一步的实际应用奠定基础。
本文研究的主要内容和结论归纳如下。
1、吲哚丁酸-Mg_2Al HTlc纳米杂化物的制备及其缓释性能研究
(1)研究了阴离子型水溶性农药吲哚丁酸(IBA)在Mg_2Al类水滑石上的吸附,考察了固液比(或HTlc浓度)、IBA浓度、温度及pH等因素的影响。结果表明,其吸附动力学和吸附等温线分别符合准二级吸附动力学方程和Langmiur方程;在所研究条件下,随固液比和温度增加,准二级吸附动力学速率常数(k_2)和初始吸附速率(h)均增大;pH在6.5-10.5间有利于吸附;饱和吸附量随固液比增大而降低,随温度升高而增大;由Arrhenius方程得出其吸附活化能为10.1 kJ/mol。
(2)分别采用离子交换法和结构重建法合成了IBA-HTlc纳米杂化物,并进行了表征:研究了农药释放行为,考察了温度和电解质等因素的影响。根据纳米杂化物通道高度和农药分子大小推测,IBA分子在HTlc层间呈双层排列。IBA-HTlc纳米杂化物具有良好的缓释性能,其释放动力学符合准二级动力学方程;温度越高,离子强度越大,其释放速率越快。由不同温度下的准二级释放动力学速率常数(k_2),依据Arrhenius方程得出其释放过程的活化能为16 kJ/mol。
2、吡虫啉-SDS-Zn_2Al HTlc纳米杂化物合成及其释放性能研究
(1)以非离子型水溶性农药吡虫啉(IM)为客体分子,以Zn_2Al HTlc为主体,采用二次组装法合成了IM-SDS-Zn_2Al HTlc纳米杂化物,并进行了表征。首先,用十二烷基硫酸钠(SDS)修饰HTlc,SDS分子插入HTlc层间将其层间距增大,形成SDS-HTlc纳米杂化物;然后,再将吡虫啉分子插入HTlc层间形成IM-SDS-HTlc纳米杂化物,其驱动力可能是浓度差。根据SDS-HTlc纳米杂化物通道高度和SDS分子大小推测,SDS分子在HTlc层间呈垂直单层排列。研究发现,吡虫啉分子的插入使SDS-HTlc纳米杂化物的层间距略有降低,可能是由于IM分子与SDS分子相互作用使SDS链弯曲所致。
(2)研究了IM-SDS-HTlc纳米杂化物的释放行为,考察了电解质和pH等因素的影响。结果表明,所合成的纳米杂化物具有良好的缓释效果,其释放动力学符合准二级动力学方程;电解质的存在和低pH可增大释放速率。纳米杂化物中SDS含量(A_(SDS))增加使IM的释放速率增大,可能与IM的亲水性有关。
3、阿维菌素-SDS-Mg_2Al HTlc纳米杂化物合成及其释放性能研究
(1)以非离子型水难溶性农药阿维菌素(AVM)为客体分子,以Mg_2Al HTlc为主体,采用二次组装蒸发溶剂促进插层(evaporating solvent enhancedintercalation method)法制备了AVM-SDS-HTlc纳米杂化物,并进行了表征。首先,将十二烷基硫酸钠(SDS)插入HTlc层间制备SDS-HTlc纳米杂化物,SDS在HTlc层间形成疏水区;其次,将SDS-HTlc纳米杂化物分散到阿维菌素的乙醇溶液中,逐渐蒸发溶剂(乙醇),迫使疏水性的阿维菌素插入HTlc层间的疏水区,形成AVM-SDS-HTlc纳米杂化物。根据SDS-HTlc纳米杂化物通道高度和SDS分子大小推测,SDS分子在HTlc层间呈垂直单层排列,其通道高度随SDS插入量的增大略有降低。阿维菌素的插入可使SDS-HTlc纳米杂化物通道高度略有增加。
(2)研究了AVM-SDS-HTlc纳米杂化物的释放行为,考察了温度、电解质和pH等因素的影响。结果表明,所合成的纳米杂化物具有良好的缓释效果,其释放动力学符合准一级动力学方程:电解质的存在、低pH和温度升高均可增大其释放速率。纳米杂化物中SDS含量增大,其阿维菌素释放速率有降低趋势,这是因为SDS含量越大,HTlc层间疏水性越强,与阿维菌素的相互作用越大。由不同温度下的准一级释放动力学速率常数(k_1)和Arrhenius方程,得出其释放过程的活化能为279 kJ/mol。
Nowadays in china,the second biggest country of pesticide producing, preparations forms are mainly powder,oil concentrate and suspension concentrate, which are irrational and large application.Pesticide has brought many ignorant effects such as air pollutions,environmental destroy,food safety and so on,which has baffled agricultural sustainable development.Now the hit research trends of pesticide forms in the world are focused on controlled-release formulations.
Hydtrotalcite-like compounds(HTlc),also called Layered double hydroxides (LDHs),consisting of divalent and trivalent metal ions and with the same layered crystal structure as hydrotalcite,are a class of layered materials which has been paid a great of attention in recent years.The interlayer region of HTlc may be considered as a microvessle,some pesticide and drug molecules may be intercalated into the gallery of HTlc to form pesticide/drug-HTlc nanohybrids.The nanohybrids may evidently inhibit the release of moleculars in the interlayer.So pesticide/drug-HTlc nanohybrids are greatly potential controlled-release formulations.
HTlc was chosen as host material and some pesticides as guest species, Indole-3-buytric acid(IBA),Avermectin(AVM) and Imidacloprid(IM) have been successfully intercalated into HTlc using different methods to obtain a series of pesticide-HTlc nanohybrids.
The synthesis strategy and the properties of nanohybrids,released behavior, released mechanism and the relationship between structures and released behavior of nanohybrids were systematically studied.
The main contents of this paper are as follows.
1、Synthesis and characterization of IBA-HTlc nanohybrids
(1) The adsorption of IBA on HTlc was studied,and some fators were investigated,for example,solid/liquid ratio(HTlc concentration),initial concentrations,temperature and pH.It was found that the adsorption kinetics and isotherms was well fitted by pseudo-second order kinetic equation and Langmiur isotherms equation.And with the increase of HTlc concentration and temperature, the constant(k_2) of pseudo-second order kinetics and the initial adsorption rate both increase;The adsorption amount arrived maxium at pH 6.5-10.5;The adsorption capacity will decrease with the increase of solid/liquid ratio;The activation energy was calculated by Arrhenius equation.
(2) IBA-HTlc nanohybrids were synthesized by exchange method and reconstruction method,which were also characterized.The release behavior was studied.The effect of temperature and electrolyte were investigated.According to the dimensions of pesticide structure and the gallery height of nanohybrids,a possible arrangement(vertical-arranging overlapped bilayer) of indole-3-buytric acid in the interlayer of nanohybrids was proposed.IBA-HTlc nanohybrids was a good controlled release pesticide formulation.And the release kinetics was well analyzed by pesudo-second-order kinetic equation.Higher temperature and electrolyte concentration,higher the release rate.According to the different values of k_2 at different temperatures and Arrhenius equation,the activation energy of release process was calculated to be 16 kJ/mol.
2、Synthesis and characterization of IM-SDS-Zn_2Al HTlc nanohybrids
(1) Non-ionic and water-soluble imidacloprid was chosen as pesticide guest, and Zn_2Al HTlc was the host.IM-SDS-Zn_2Al HTlc nanohybrids were synthesized by Second Assembling Intercalation method,which were also characterized. Firstly,HTlc was modified by SDS,and the basal spacing increased with the intercalation of SDS,then SDS-HTlc nanohybrids were obtained.Secondly, imidacloprid would be intercalated into the gallery of SDS-HTlc to form IM-SDS-Zn_2Al HTlc nanohybrids.The driving force may be the concentration difference.According to the gallery height of SDS-HTlc and SDS molecular structure,the possible arrangement may be vertical-arranging monolayer.It was found that the intercalation of imidacloprid induced the decrease of basal spacing of SDS-HTlc,which may be caused by the interaction of pesticide and SDS.The hydrophobic chain of SDS was distorted.
(2) The release behavior was studied,and the effect of pH and electrolyte was also investigated.It was indicated that the synthesized nanohybrids could well control the release of imidacloprid.And pseudo-second order kinetic equation was satisfactory for describing the release behavior.The presence of electrolyte and lower pH would increase the release rate.The release rate will increase with the increase of SDS loading(Asps),which may be caused by the hydrophilic property of imidacloprid.
3、Synthesis and characterization of AVM-SDS-Mg_2Al HTlc nanohybrids
(1) Non-ionic and poorly water-soluble avermectin(AVM) was chosen as pesticide guest,and Mg_2Al HTlc was the host.AVM-SDS-HTlc nanohybrids were synthesized by Second Assembling Intercaltion method(enhanced intercalation by evaporating solvent).Firstly,SDS-HTlc nanohybrids were synthesized by the intercalation of SDS into the gallery of HTlc,and hydrophobic region was formed. Secondly,SDS-HTlc nanohybrids were dispersed into ethanol solution containing avermectin.Then the solvent(ethanol) was gradually evaporated out,avermetin will be forced to intercalate into the hydrophobic region of HTlc to form AVM-SDS-HTlc nanohybrids.According to the gallery height of SDS-HTlc and SDS molecular structure,the possible arrangement may be vertical-arranging monolayer.The gallery height will slightly decrease with the increase SDS loading (A_(SDS)).The intercaltion of avermectin slightly induced the increase of gallery height.
(2) The release behavior of nanohybrids was studied,and effect of temperature,electrolyte and pH was investigated.It was found that the obtained nanohybrids were a good controlled release pesticide formulation.Its releae kinetics was better fitted by pseudo-first order kinetic equation.The presence of electrolyte,lower pH and higher temperature all increase the relase rate.The release rate will decrease with the increase of SDS loading(A_(SDS)),which was interpreted that higher A_(SDS),stonger hydrophobicity of HTlc gallery,and the interaction between avermectin and SDS will be enhanced.Using the pseudo-first order kinetic constant with different temperatures and Arrhenius equation,the acitivation energy of release process was calculated to be 279 kJ/mol.
类水滑石(Hydrotalcite-like compounds,简称HTlc)是由两种或两种以上金属元素组成的具有水滑石层状晶体结构的氢氧化物,层片带结构正电荷,层间存在可交换的阴离子。HTlc层间可作为微型储存器,将农药分子插入其中制成农药-HTlc纳米杂化物,因空间位阻效应和农药分子与层板间的相互作用可实现对农药分子的控释。近期,农药-HTlc纳米杂化物的制备及在农药控释剂型中的应用备受关注。
本文分别选取阴离子型水溶性农药吲哚丁酸(Indole-3-bytric acid,简称IBA)、非离子型水溶性农药吡虫啉(Imidacloprid,简称IM)和非离子型水难溶性农药阿维菌素(Avermectin,简称AVM)为客体分子,以HTlc为主体,分别采用离子交换法、二次组装法和二次组装蒸发溶剂促进插层法制备了三种农药/HTlc纳米杂化物,考察了其释放行为,探讨了释放机理。以期掌握农药-HTlc纳米杂化物的关键制备技术,了解其农药控释规律,为进一步的实际应用奠定基础。
本文研究的主要内容和结论归纳如下。
1、吲哚丁酸-Mg_2Al HTlc纳米杂化物的制备及其缓释性能研究
(1)研究了阴离子型水溶性农药吲哚丁酸(IBA)在Mg_2Al类水滑石上的吸附,考察了固液比(或HTlc浓度)、IBA浓度、温度及pH等因素的影响。结果表明,其吸附动力学和吸附等温线分别符合准二级吸附动力学方程和Langmiur方程;在所研究条件下,随固液比和温度增加,准二级吸附动力学速率常数(k_2)和初始吸附速率(h)均增大;pH在6.5-10.5间有利于吸附;饱和吸附量随固液比增大而降低,随温度升高而增大;由Arrhenius方程得出其吸附活化能为10.1 kJ/mol。
(2)分别采用离子交换法和结构重建法合成了IBA-HTlc纳米杂化物,并进行了表征:研究了农药释放行为,考察了温度和电解质等因素的影响。根据纳米杂化物通道高度和农药分子大小推测,IBA分子在HTlc层间呈双层排列。IBA-HTlc纳米杂化物具有良好的缓释性能,其释放动力学符合准二级动力学方程;温度越高,离子强度越大,其释放速率越快。由不同温度下的准二级释放动力学速率常数(k_2),依据Arrhenius方程得出其释放过程的活化能为16 kJ/mol。
2、吡虫啉-SDS-Zn_2Al HTlc纳米杂化物合成及其释放性能研究
(1)以非离子型水溶性农药吡虫啉(IM)为客体分子,以Zn_2Al HTlc为主体,采用二次组装法合成了IM-SDS-Zn_2Al HTlc纳米杂化物,并进行了表征。首先,用十二烷基硫酸钠(SDS)修饰HTlc,SDS分子插入HTlc层间将其层间距增大,形成SDS-HTlc纳米杂化物;然后,再将吡虫啉分子插入HTlc层间形成IM-SDS-HTlc纳米杂化物,其驱动力可能是浓度差。根据SDS-HTlc纳米杂化物通道高度和SDS分子大小推测,SDS分子在HTlc层间呈垂直单层排列。研究发现,吡虫啉分子的插入使SDS-HTlc纳米杂化物的层间距略有降低,可能是由于IM分子与SDS分子相互作用使SDS链弯曲所致。
(2)研究了IM-SDS-HTlc纳米杂化物的释放行为,考察了电解质和pH等因素的影响。结果表明,所合成的纳米杂化物具有良好的缓释效果,其释放动力学符合准二级动力学方程;电解质的存在和低pH可增大释放速率。纳米杂化物中SDS含量(A_(SDS))增加使IM的释放速率增大,可能与IM的亲水性有关。
3、阿维菌素-SDS-Mg_2Al HTlc纳米杂化物合成及其释放性能研究
(1)以非离子型水难溶性农药阿维菌素(AVM)为客体分子,以Mg_2Al HTlc为主体,采用二次组装蒸发溶剂促进插层(evaporating solvent enhancedintercalation method)法制备了AVM-SDS-HTlc纳米杂化物,并进行了表征。首先,将十二烷基硫酸钠(SDS)插入HTlc层间制备SDS-HTlc纳米杂化物,SDS在HTlc层间形成疏水区;其次,将SDS-HTlc纳米杂化物分散到阿维菌素的乙醇溶液中,逐渐蒸发溶剂(乙醇),迫使疏水性的阿维菌素插入HTlc层间的疏水区,形成AVM-SDS-HTlc纳米杂化物。根据SDS-HTlc纳米杂化物通道高度和SDS分子大小推测,SDS分子在HTlc层间呈垂直单层排列,其通道高度随SDS插入量的增大略有降低。阿维菌素的插入可使SDS-HTlc纳米杂化物通道高度略有增加。
(2)研究了AVM-SDS-HTlc纳米杂化物的释放行为,考察了温度、电解质和pH等因素的影响。结果表明,所合成的纳米杂化物具有良好的缓释效果,其释放动力学符合准一级动力学方程:电解质的存在、低pH和温度升高均可增大其释放速率。纳米杂化物中SDS含量增大,其阿维菌素释放速率有降低趋势,这是因为SDS含量越大,HTlc层间疏水性越强,与阿维菌素的相互作用越大。由不同温度下的准一级释放动力学速率常数(k_1)和Arrhenius方程,得出其释放过程的活化能为279 kJ/mol。
Nowadays in china,the second biggest country of pesticide producing, preparations forms are mainly powder,oil concentrate and suspension concentrate, which are irrational and large application.Pesticide has brought many ignorant effects such as air pollutions,environmental destroy,food safety and so on,which has baffled agricultural sustainable development.Now the hit research trends of pesticide forms in the world are focused on controlled-release formulations.
Hydtrotalcite-like compounds(HTlc),also called Layered double hydroxides (LDHs),consisting of divalent and trivalent metal ions and with the same layered crystal structure as hydrotalcite,are a class of layered materials which has been paid a great of attention in recent years.The interlayer region of HTlc may be considered as a microvessle,some pesticide and drug molecules may be intercalated into the gallery of HTlc to form pesticide/drug-HTlc nanohybrids.The nanohybrids may evidently inhibit the release of moleculars in the interlayer.So pesticide/drug-HTlc nanohybrids are greatly potential controlled-release formulations.
HTlc was chosen as host material and some pesticides as guest species, Indole-3-buytric acid(IBA),Avermectin(AVM) and Imidacloprid(IM) have been successfully intercalated into HTlc using different methods to obtain a series of pesticide-HTlc nanohybrids.
The synthesis strategy and the properties of nanohybrids,released behavior, released mechanism and the relationship between structures and released behavior of nanohybrids were systematically studied.
The main contents of this paper are as follows.
1、Synthesis and characterization of IBA-HTlc nanohybrids
(1) The adsorption of IBA on HTlc was studied,and some fators were investigated,for example,solid/liquid ratio(HTlc concentration),initial concentrations,temperature and pH.It was found that the adsorption kinetics and isotherms was well fitted by pseudo-second order kinetic equation and Langmiur isotherms equation.And with the increase of HTlc concentration and temperature, the constant(k_2) of pseudo-second order kinetics and the initial adsorption rate both increase;The adsorption amount arrived maxium at pH 6.5-10.5;The adsorption capacity will decrease with the increase of solid/liquid ratio;The activation energy was calculated by Arrhenius equation.
(2) IBA-HTlc nanohybrids were synthesized by exchange method and reconstruction method,which were also characterized.The release behavior was studied.The effect of temperature and electrolyte were investigated.According to the dimensions of pesticide structure and the gallery height of nanohybrids,a possible arrangement(vertical-arranging overlapped bilayer) of indole-3-buytric acid in the interlayer of nanohybrids was proposed.IBA-HTlc nanohybrids was a good controlled release pesticide formulation.And the release kinetics was well analyzed by pesudo-second-order kinetic equation.Higher temperature and electrolyte concentration,higher the release rate.According to the different values of k_2 at different temperatures and Arrhenius equation,the activation energy of release process was calculated to be 16 kJ/mol.
2、Synthesis and characterization of IM-SDS-Zn_2Al HTlc nanohybrids
(1) Non-ionic and water-soluble imidacloprid was chosen as pesticide guest, and Zn_2Al HTlc was the host.IM-SDS-Zn_2Al HTlc nanohybrids were synthesized by Second Assembling Intercalation method,which were also characterized. Firstly,HTlc was modified by SDS,and the basal spacing increased with the intercalation of SDS,then SDS-HTlc nanohybrids were obtained.Secondly, imidacloprid would be intercalated into the gallery of SDS-HTlc to form IM-SDS-Zn_2Al HTlc nanohybrids.The driving force may be the concentration difference.According to the gallery height of SDS-HTlc and SDS molecular structure,the possible arrangement may be vertical-arranging monolayer.It was found that the intercalation of imidacloprid induced the decrease of basal spacing of SDS-HTlc,which may be caused by the interaction of pesticide and SDS.The hydrophobic chain of SDS was distorted.
(2) The release behavior was studied,and the effect of pH and electrolyte was also investigated.It was indicated that the synthesized nanohybrids could well control the release of imidacloprid.And pseudo-second order kinetic equation was satisfactory for describing the release behavior.The presence of electrolyte and lower pH would increase the release rate.The release rate will increase with the increase of SDS loading(Asps),which may be caused by the hydrophilic property of imidacloprid.
3、Synthesis and characterization of AVM-SDS-Mg_2Al HTlc nanohybrids
(1) Non-ionic and poorly water-soluble avermectin(AVM) was chosen as pesticide guest,and Mg_2Al HTlc was the host.AVM-SDS-HTlc nanohybrids were synthesized by Second Assembling Intercaltion method(enhanced intercalation by evaporating solvent).Firstly,SDS-HTlc nanohybrids were synthesized by the intercalation of SDS into the gallery of HTlc,and hydrophobic region was formed. Secondly,SDS-HTlc nanohybrids were dispersed into ethanol solution containing avermectin.Then the solvent(ethanol) was gradually evaporated out,avermetin will be forced to intercalate into the hydrophobic region of HTlc to form AVM-SDS-HTlc nanohybrids.According to the gallery height of SDS-HTlc and SDS molecular structure,the possible arrangement may be vertical-arranging monolayer.The gallery height will slightly decrease with the increase SDS loading (A_(SDS)).The intercaltion of avermectin slightly induced the increase of gallery height.
(2) The release behavior of nanohybrids was studied,and effect of temperature,electrolyte and pH was investigated.It was found that the obtained nanohybrids were a good controlled release pesticide formulation.Its releae kinetics was better fitted by pseudo-first order kinetic equation.The presence of electrolyte,lower pH and higher temperature all increase the relase rate.The release rate will decrease with the increase of SDS loading(A_(SDS)),which was interpreted that higher A_(SDS),stonger hydrophobicity of HTlc gallery,and the interaction between avermectin and SDS will be enhanced.Using the pseudo-first order kinetic constant with different temperatures and Arrhenius equation,the acitivation energy of release process was calculated to be 279 kJ/mol.
引文
[1]E.L.Griffin,C H.Richardson,R C.Burdette,Globule size of emulsions and toxicity to aphids[J].J.Agric.Res.,1927,34:727
[2]L.L.English,Globule size of emulsions and toxicity[J].Nat.Hist.Surv.Bull.,1928,17:235.
[3]S.E Chiu,Particle size and toxicity of silica dusts[J].J.Econ.Entom.,1939,32:240.
[4]L.M.Bertholf,J E.Pilson,Particle size and stomach toxicity of lead arsenate[J].J.Econ.Entom.,1941,34:24-33.
[5]H.P.Burchfield,G L.McNew Mechanism of particle size effects of fungicides on plant protection[J].Boyce.Thompson.Inst.,1950,16:131-161
[6]G.S.Hartley,I.J.Graham-Bryce,Physical Principles of Pesticide Behaviour[A].The Dynamics of Applied Pesticides in the Local Environment in Relation to Biological Response[C].Academic Press,London/New York,1980,2:722-723
[7]王以燕,刘绍仁,宗伏霖,等.中华人民共和国国家标准—农药利型名称及代码[S].农业部农药检定所:中华人民共和国国家质量监督检验检疫总局,2003.
[8]凌世海主编.农药剂型加工丛书.液体制剂[M].北京:化学工业出版社2003
[9]崔福德主编.药剂学[M].北京:人民卫生出版社,2003.
[10]A.Michael.Non-aqueous suspension concentrate[P]United States Patent:6,165,940.December 26,2000.
[11]H.E.Agbaje,D.H.Carter,Powers Tracy A.Stable concentrated pesticide suspension[P]United States Patent:6,451,731.September 17,2002.
[12]Y.Shimura,T.Asano,S.Shimono,Insecticide composition and production process thereof[P]United States Patent:5,733,561.March 31,1998.
[13]A.Kisuno,T.Ansai,A.S.Aizawa Composite particle aqueous suspension and process for producing same[P]United States Patent:5,889,088.March 30,1999.
[14]M.G.Ochomogo,M.A.Deleo,Selbach Hanneliese S.Suspoemulsion system for delivery of actives[P]United States Patent:6,358,909.March 19,2002.
[15]H.Rochling,J.Kocur,K.Albrecht.Water-dispersible glufosinate granules[P]United States Patent:5,543,385.August 6,1996.
[16]R.J.Lo,J.L Chen,H.B Scher,Dhy water-dispersible compositions of micro-encapsulated pesticides[P]United States Patent:6,358,520.March 19,2002.
[17]R.J.Lo,J.L Chen,H.B Scher,Dry water-dispersible compositions of microencapsulated pesticides[P]United States Patent:6,419,942.July 16,2002.
[18]H.Rochling,B.Joachim,Water-dispersible granules of suspoemulsions[P]United States Patent:6,410,481.June 25,2002.
[19]W.L.Geigle,L.S.Sandell,R.D.Wysong,Water-dispersible or water-soluble pesticide grandules from heat-activated binders[P]United States Patent:5,372,989.December 13,1994.
[20]陈福良,王仪,郑斐能.农药微乳剂及其浊点问题的探讨和初步研究[J].农药,1999,38(3):9-10.
[21]吴春江.微乳液的形成和微乳剂的制备原理[J]浙江化工,2003 1:1-2.
[22]凌世海.农药剂型进展评述[J].农药,1998,37(8):6-9.
[23]梁文平,郑斐能,王仪.21世纪农药发展的趋势:绿色农药与绿色农药制剂[J].农药,1999,38(9):1-2.
[24]I.Domingo,D.I.Prettypaul,Water-dilutable,microemulsion concentrate and pour-on formulations thereof[P]United States Patent:5968990,1999-10-19.
[25]H.Rudolf,Slective herbicidal compositions in the form of concentrated microemulsions[P],United States Patent:5733847,1998-03-01.
[26]S.J.Barcay,.Water powder as a synergist in pest baits[P],United States Patent:5820855,1998-10-13.
[27]P.M.Murali,Process of preparing purified azadirachtin in powder form from neem seeds and storage stable aqueous composition containing azadirachtin[P].United States Patent:6193974,2001-02-27.
[28]T.D Nelson,Granular pest bait[P].United States Patent:6153181,2000-11-28.
[29]H.Rochling.Concentrated aqueous microemulsions[P].United States Patent:5227402,1993-07-13.
[30]吴秀华,陈蔚林,王飞.农药微乳液物理稳定性的探讨[J].化学通报,1999(3):36-38.
[31]R.F.Stewart,L.C.Greene,R.K.Bhaskar,Microcapsule having temperature-dependent permeability profile[P]United States Patent:5.120.349.June 9.1992.
[32]J.E.Van Koppenhagen,,H.B.Scher,K.-S.S.Lee,Acid triggered release microcapsules[P]United States Patent:6,337,130.January 8,2002.
[33]J.E.Van Koppenhagen,,H.B.Scher,K.-S.S.Lee,Acid-triggered microcapsules[P]United States Patent Application 20020068169.June 6,2002
[34]S.T Wellinghoff,J.J Kampa,S.A.Barenberg,Silicate-containing powders providing controlled,sustained gas release[P]United States Patent:6,605,304.August 12,2003.
[35]O.Benjamin,P.J..Frank,C.Mark.,Stabilized controlled release substrate having a coating derived from an aqueous dispersion of hydrophobic polymer[P]United States Patent:6,316,031.November 13,2001.
[36]C.C.Yang,I.H.Pan.,Preparation of pesticide microcapsule[P]United States Patent:5,576,008.November 19,1996.
[37]R.Celis,M.C.Hermosian,M.J.Carrizosa,J.Cornejo,Inorganic and Organic Clays as Carriers for Controlled Release of the Herbicide Hexazinone[J]J.Agric.Food Chem.2002,50:2324-2330
[38]M C.Hermosin,M J.Calderon,J.-P.Aguer and J.Cornejo,Organoclays for controlled release of the herbicide fenuron[J]Pest Manag Sci 2001,57:803-809
[39]M.Fernandez-Perez,E.Gonzalez-Pradas,M.Villafranca-Sanchez,F.Flores-Cespedes,Mobility of isoproturon from an alginate-bentonite controlledrelease formulation in layered soil[J]Chemosphere 2000,41:1495-1501
[40]E Gonzalez-Pradas,M Fernandez-Perez,M Villafranca-Sanchez,F Martmez-Lopez and F Flores-Cespedes,Use of bentonite and humic acid as modifying agents in alginate-based controlled-release formulations of imidacloprid[J]Pest Manag Sci 1999,55:546-552
[41]M Villafranca-Sanchez,E Gonzalez-Pradas,M Fernandez-Perez,F Martinez-Lopez,Flores-Cespedes and MD Urena-Amate,Controlled release of isoproturon from an alginate-bentonite formulation:water release kinetics and soil mobility[J]Pest Manag Sci 2000,56:749-756
[42]E Gonzalez-Pradas,M Fernandez-Perez,M Villafranca-Sanchez and F Flores-Cespedes,Mobility of imidacloprid from alginate-bentonite controlled-release formulations in greenhouse soils[J]Pest Manag Sci,1999,55:1109-1115
[43]M.F.Nnez-Pearez,M.Villafranca-Saa Nchez,F.Flores-Cea Spedes,F.J. Garrido-Herrera,S.Pea Rez-Garciaa,Use of Bentonite and Activated Carbon in Controlled Release Formulations of Carbofuran[J]J.Agric.Food Chem.2005,53:6697-6703
[44]Z.Gerstl,A.Nasser,and U.Mingelgrin Controlled Release of Pesticides into Soils from Clay-Polymer Formulations[J]J.Agric.Food Chem.1998,46:3797-3802
[45]F.Cavani,F.Trifiro,A.Vaccari.Hydrotalcite-type anionic clays:preparation,properties and applications[J].Catal.Today,1991,11(2):173-301.
[46]V.Angelo,Preparation and catalytic properties of cationic and anionic clays[J]Catal.Today,1998,41(1-3):53-71.
[47]W.Feitknecht,Doppelhydroxyden zwischen zwei-und dreiwertigen metallen[J]Helv.Chim.Acta,1942,25:555-569
[48]侯万国,张春光,孙德军,梁晓丽,王果庭,氢氧化铝镁正电溶胶制备及性能研究[J]高等学校化学学报,1995,16(8):1292-1294.
[49]张春光,徐同台,侯万国,正电胶钻井液[M],石油工业出版社,2000,第1版.
[50]J.Perez-Ramirez,G.Mul,F.Kapteijn,J.A.Moulijn,In-situ investigation of the thermal decomposition of Co-Al hydrotalcite in different atmospheres[J]J.Mater.Chem.,2001,11:821-830.
[51]V.Rives,A.U.Marya.Layered double hydroxides(HTlc) intercalated with metal coordination compounds and oxometalates[J].Coordin.Chem.Rev.,1999,181:61-120.
[52]H.C.B.Hansen,R.M.Taylor,Formation of synthetic analogues of double metal-hydroxycarbonate minerals under controlled pH conditions:The synthesis of desautelsite[J]Clay Miner.1991,26:507-525.
[53]J.M.Fernandez,C.Barriga,M.-A.Ulibarri,F.M.Labajos,V.Rives,Preparation and thermal stability of manganese-containing hydrotalcite,[Mg_(0.75)Mn_(0.04)~ⅡMn_(0.21)~Ⅲ(OH)_2](CO_3)_(0.11)·nH_2O[J]J.Mater.Chem.,1994,4:1117-1122.
[54]V.Prevot,C.Forano,J.E Besse,Hydrolysis in polyol:new route for hybrid-layered double hydroxides preparation[J]Chem.Mater.2005,17:6695-6701
[55]W.T.Reichle,Kang S.Y.and Everhardt D.S.,The nature of the thermal decomposition of a catalytically active anionic clay mineral[J]J.Catal.,1986,101:352-359.
[56]S.Miyata,The syntheses of hydrotalcite-like compound and their structures[J]Clays Clay Miner.,1975,23:369-373.
[57]S.Miyata,A.Okada,Synthesis of Hydrotalcite-like system of Mg~(2+)-Al~(3+)-SO_4~(2-)and Mg~(2+)-Al~(3+)-CrO_4~(2-)[J]Clays Clay Miner,1977,25:14-18.
[58]S.Miyata,Physico-chemical properties of hydrotalcite-like compounds[J]Clays Clay Miner,1980,28:50-56.
[59]S.K.Yun,T.J.Pinnavaia,Water Content and Particle Texture of Synthetic Hydrotalcite-like Layered Double Hydroxides[J]Chem.Mater,1995,7(2):348-354.
[60]M.Sychev,R.Prihod'ko,K.Erdmann.Hydrotalcites:relation between structural features,basicity and activity in the Wittig reaction[J]Appl.ClaySci.2001,18:103-110.
[61]N.S.Puttaswamy,P.V.Kamath,Reversible thermal behaviour of layered double hydroxides:a thermogravimetric study[J]J.Mater.Chem.,1997,7:1941-1946.
[62]J.Rocha,M.del Arco,V.Rives,M.A.Ulibarri,Reconstruction of layered double hydroxides from calcined precursors:a powder XRD and ~(27)Al MAS NMR study[J]J.Mater.Chem.,1999,9:2499-2504.
[63]S.K.Pramod,S.V.Jaime,C.F.Fran,Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]Chem.Commun.,1998,1091-1092.
[64]M.Rajamathi,G.D.Nataraja,S.Ananthamurthy,P.Vishnu Kamath,Reversible thermal behavior of the layered double hydroxide of Mg with Al:mechanistic studies[J]J.Mater.Chem.,2000,10:2754-2757.
[65]H.P.Boehm,J.Steinle,C.Vieweger,[Zn_2Cr(OH)_6]X 2H_2O(X=F~-,Cl~-,Br~-,I~-,ect),new layer compounds capable of anion exchange and intracystalline swelling[J]Angew Chem.Int.Ed.Engl,1977,16:265-270.
[66]T.Lopez,P.Bosch,E.Ramos,R.Gomez,O.Novaro,D.Acosta,F.Figueras,Synthesis and Characterization of Sol-Gel Hydrotalcites.Structure and Texture[J]Langmuir,1996,12(1):189-192.
[67]P.Federica,G.Giovanna,G.Patrick.Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples[J]Micropor.Mesopor.Mater.,2000,39:229-247.
[68]I.Di Cosimo,V.K.Diez,C.R.Apesteguia,Synthesis of α,β-unsaturated ketones over thermally activated Mg-Al hydrotalcites[J]Appl.Clay Sci.,1998,13:433-449.
[69]J.S.Valente,M.S.Cantu,Preparation and Characterization of Sol-Gel MgAl Hydrotalcites with Nanocapsular Morphology[J]J.Phys.Chem.C 2007,111:642-651
[70]H.C.Xu,Zeng,Thermal evolution of cobalt hydroxides:a comparative study of their various structural phases[J]J.Mater Chem.,1998,8:2499-2506.
[71]M.Ogawa,S.Asai.Hydrothermal Synthesis of Layered Double Hydroxide-Deoxycholate Intercalation Compounds[J]Chem.Mater,2000,12(11):3253-3255.
[72]M.Ogawa,H.Kaiho.Homogeneous Precipitation of Uniform Hydrotalcite Particles[J].Langmuir,2002,18:4240-4242.
[73]谢晖,矫庆泽,段雪.镁铝型水滑石水热合成[J]应用化学,2001,18(1):70-72.
[74]段雪,矫庆泽,李蕾,均分散超细阴离子层状材料的新合成方法[P]CN99119385.7.
[75]段雪,李殿卿,何俊玲,张法智,一种以卤水为原料制备纳米级镁铝水滑石的方法[P]CN03150037.4.
[76]Y.Zhao,F.Li,Zhang R,Evans D.G,Duan X,Preparation of layered double-hydroxide nanomaterials with a uniform crystallite size using a new method involving separate nucleation and aging steps[J]Chem.Mater,2002,14(10):4286-4291.
[77]杜一波,何静,李峰,等,微波技术在制备水滑石和柱撑水滑石中的应用[J]应用科学学报,1998,16(3):349-354.
[78]G.Fetter,.F H.Andez,A.M.Maubert,et al.Microwave irradiation effect on hydrotalcite synthesis[J].J.Porous Mater.,1997,4:27-30.
[79]X.M.Xie,X.R.Ren,J.P.Li,et al.Preparation of ZnAl_2 HTLcs with small particle size by ultrasonic crystallization[J]J.Nat.Gas Chem.,2006,15:100-104.
[80]杜以波,北京化工大学硕士学位论文(1995).
[81]郭军,孙铁,沈剑平,等.硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J]高等化学学报,1995,3:346-350.
[82]刘继广,郭军,杂多阴离子组成水滑石类层柱材料中层柱相互作用研究[J]高等化学学报,1995,9:1329-1333.
[83]C.P.Kelkar,A.A.Schutz,Ni-,Mg- and Co-containing hydrotalcite-like materials with a sheet-like morphology:synthesis and characterization[J]Micropor.Mater,1997,10:163-172.
[84]F.Kooli,K.Kosuge,T.Hibino,A.Tsunashima,Synthesis and Properties of Mg-Zn-Al-SO_4 Hydrotalcite-like Compounds[J]J.Mater Sci.,1993,28:2769-2773.
[85]胡长文,刘彦勇,型微孔材料-杂多阴离子柱撑Zn-Al型阴离子粘土的 合成、表征及其催化反应活性的研究[J]中国科学(B),1995,15:916-922.
[86]J.T.Kloprogge,R.L.Frost,Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Zn/Al-hydrotalcites[J]Phys.Chem.Chem.Phys.,1999,1:1641-1647.
[87]J.Twu,P.K.Dutta,Raman spectroscopic study of intercalated molybdate ions in layered metal hydroxides[J]Chem.Mater.1992,4:398-401.
[88]刘继广,矫庆泽,张鹏,钨磷杂多化合物嵌入ZnAl类水滑石层间及其酸碱催化活性的研究[J]高等学校化学学报,1994,15:275-278.
[89]陈涛,周明华,王岚,詹正坤,锌铬水滑石的合成及表征[J]合成化学,2002,10:45-48。
[90]陈涛,周明华,王岚,詹正坤,钴铬水滑石的合成及表征[J]化学研究及应用,2002,14:44-47.
[91]V.A.Drits,New Members of the Hydrotalcite-Manasseite Group[J]Clays Clay Miner,1987,35:401-417.
[92]G.Hu,D.O'Hare,Unique Layered double hydroxide morphologies using reverse microemulsion synthesis[J]J.Am.Chem.Soc.2005,127:17808-17813.
[93]H.Cai,A.C.Hillier,K.R.Franklin,C.C.Nunn,M.D.Ward,Nanoscale Imaging of Molecular Adsorption Science[J]Science,1994,266:1551-1555.
[94]R.V.Prikhodko,M.V.Sychev,I.M.Astrelin,K.Erdmann,A.Mangel,R.A.van Santen Synthesis and Structural Transformations of Hydrotalcite-like Materials Mg-Al and Zn-Al[J]Russian J.Appl.Chem.,2001,74:231.
[95]D.Tichit,M.N.Bennani,F.Figueras,J.R.Ruiz,Decomposition Processes and Characterization of the Surface Basicity of Cl~- and CO_3~(2-)Hydrotalcites[J]Langmuir,1998,14:2086-2091.
[96]A M Fogg,J S Dunn,S-G Shyu.Selective Ion-Exchange Intercalation of Isomeric Dicarboxylate Anions into the Layered Double Hydroxide[J][LiAl_2(OH)_6]Cl·H_2O[J],Chem Mater,1998,10(1):351-355.
[97]S.Kohjiyo,T.Sato,T.Nakayama,Hydrotalcite-like compounds[J]Makromol Chem.Rapid Commun.,1981,2:231-236.
[98]W.T.Reiehle,Pulse microreactor examination of the vapor-phase aldol condensation of acetone[J]J.Catal.,1980,63:295-306.
[99]M.A.Drezdon,Synthesis of Isopolymetalate-Pillared Hydrotalcite Via Organic-Anion-Pillared Precursors[J]Inorg.Chem.,1988,27:4628-4632.
[100]吕亮,吾国强,段雪,李峰,杜以波,水滑石的制备、表征及其在酯 交换反应中的应用[J]精细石油化工,2001,1:9-12.
[101]S.Pramod,J.Kumbhar,V.Sanchez,F.Francois,Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]J.Chem.Soc.Chemical Commun.,1998,39:1091-1092.
[102]B.M.Choudary,M.L.Kantam,C.R.Reddy,K.K.Rao,F.Figueras,Michael addition catalyzed by modified Mg-Al Hydrotalcite[J]J Mol.Catal.A,1999,146:279-284.
[103]J.Perez-Ramirez,G.Mul,F.Kapteijn and J.A.Moulijn,In situ investigation of the thermal decomposition of Co-Al hydrotalcite in different atmospheres[J]J.Mater.Chem.,2001,11:821-830
[104]P.S.Kumbhar,J.Sanchez-Valente,F.Figueras.Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]Chem Commun,1998,10:1091-1092.
[105]S.Amin,G.G.Jayson.Humic substance uptake by hydrotalcites and pilcs [J],Water Res.,1996,30(2):299-306.
[106]M.A.Ulibarri,I.Pavlovic,M.C.Hermosin,J.Cornejo,Hydrotalcite-like compounds as potential sorbents of phenols from water[J]Appl.Clay Sci.,1995,10:131-145.
[107]A.Sood,Process for removing heavy metal ions from solutions using adsorbents containing activated hydrotalcite[P]US Patent 4,752,397,Jan,1988
[108]苏延磊,侯万国,孙德军,刘尚营,张春光,Mg-Fe-LMHs纳米颗粒的合成及其阴离子交换容量的研究[J]高等学校化学学报,1999,20(7):1012-1016.
[109]夏春友,侯万国,孙德军,王果庭,铝镁混合金属氢氧化物溶胶阴离子交换性能研究[J]无机化学学报,1996,12(4):368-371.
[110]李丽芳,侯万国,贾春晓,焦燕妮,金属元素对类水滑石物质阴离子交换性能影响的研究[J]山东大学学报,2004,39(2):90-94.
[111]包玉敏,李连生,焦磷酸根嵌入后形成的交联水滑石的研究[J]化学通报,2002,3:194-197.
[112]V.L.Constantino,T.J.Pinnavaia,Basic Properties of Mg-Al layered double hydroxides intercalated by carbonate,hydroxide,chloride,and sulfate anions[J]Inorg,chem.,1995,34:883-892.
[113]U.Costantino,Intercalation and grafting of hydrogen phosphates and phosphonates into synthetic hydrotalcites and a.c.-conductivity of the compounds thereby obtained[J]Solid State lonic,1997,97:203-212.
[114]V.Rives,A.U.Marya.Layered double hydroxides(HTlc) intercalated with metal coordination compounds and oxometalates[J] Coordin. Chem. Rev., 1999,181:61-120.
[115] T. K. Duta,, M. Puri, Anion exchange in lithium aluminate hydroxides[J] J. Phys.Chem.,1989, 93: 37 6-381.
[116] H. Nijs, A. Clearfield, E. F. Vansant, The intercalation of phenylphosphonic acid in layered double hydroxides[J] Micropor. Mesopor. Mater., 1998, 23: 97-108.
[117] E. Kanezaki, Intercalation of N26DS between layers of Mg/Al double hydroxide: preparaton, powder X-ray diffraction, fourier transform infrared spectra and X-ray photoelectron spectra[J] Mater. Res. Bull., 1999, 34(9): 1435-1440.
[118] S. P. Rey, J. E. M. Robles, K.-S. Han, Liliane, G. Demourgues, C. Delmas, E. Duguet, Acrylate intercalation and in situ polymerization in iron substituted nickel hydroxides[J] Polym Int, 1999, 48: 277-282.
[119] F. Millange, R.I. Walton, L. Lei, D. O'Hare, Efficient Separation of Terephthalate and Phthalate Anions by Selective Ion-Exchange Intercalation in the Layered Double Hydroxide Ca_2Al(OH)_6·NO_3·2H_2O[J] Chem. Mater., 2000, 12(7): 1990-1994.
[120] V. Prevot, C. Forano, J. P. Besse, Hybrid derivatives of layered double hydroxides[J] Appl. Clay Sci., 2001, 18: 3-15.
[121] E. L. Crepaldi, P. C. Pavan, J. B. Valim, Anion exchange in layered double hydroxides by surfactant salt formation[J] J. Mater. Chem., 2000, 1337-1343.
[122] S. Abend, N. Bonnke, U. Gutschner, G. Lagaly, Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides[J] Colloid Polym. Sci., 1998, 276: 730-737
[123] J. M. R. Genin, Thermodynamic equilibria in aqueous suspersions of synthesisand natural (Fe)(II)-Fe(III) green rusts: occurrences of the mineral inhydromorphic soils[J] Environ. Sci. Tech., 1998, 32: 1058-1068.
[124] K. A. Baltpurvins, R. C. Burns, G. A. Lawrance, A. D. Stuart, Effect of Ca~(2+), Mg~(2+) and anion type on the aging of iron(III)Hydroxide precipitates[J] Environ. Sci. Technol., 1997, 31: 1024-1032.
[125] M. Meyn, K. Beneke, Anion-exchange reactions of layered double hydroxides[J] Inorg. Chem. 1990, 29: 5201-5207.
[126] H.T. Zhao, G.F. Vance, Intercalation of carboxymethyl-a-cyclodextrin into magnesium-aluminum layered double hydroxide[J] J. Chem. Soc., Dalton Trans., 1997, 1961-1965
[127] W.-Y. Tseng, J.-T. Lin, C.-Y. Mou, S. Cheng, S.-B. Liu, P. P. Chu, and H.-W. Liu, Incorporation of C60 in Layered Double Hydroxide[J] J. Am. Chem. Soc. 1996, 118: 4411-4418
[128] S. Carlino, The intercalation of carboxylic acids into layered double hydroxides: a critical evaluation and review of the different methods[J] Solid State Ionics 1997, 98: 73-84
[129] S. Sasaki , S. Aisawa , H. Hirahara, A. Sasaki, H. Nakayam, E. Narit, Synthesis of p-sulfonated calix[4]arene-intercalated layered double hydroxides and their adsorption properties for organic molecules[J] J. Eur. Ceram. Soc. 2006, 26: 655-659
[130] A. Clearfield, M. Kieke, J. Kwan, J. L. Colon and R.-C. Wang, Intercalation of Dodecyl Sulfate into Layered Double Hydroxides[J] J. Inch Phenom. Mole. Recog. Chem. 1991,11: 361-378.
[131] M. Borja and P. K. Dutta, Fatty Acids in Layered Metal Hydroxides: Membrane-iike Structure and Dynamlcs[J] J. Phys. Chem., 1992, 96: 5434-5444.
[132] H.Y. Chen, F.Z. Zhang, S.S. Fu, and X. Duan, In Situ Microstructure Control of Oriented Layered Double Hydroxide Monolayer Films with Curved Hexagonal Crystals as Superhydrophobic Materials[J] Adv. Mater. 2006,18:3089-3093
[133] T. Kanoh, T. Shichi, and K. Takagi, Mono- and Bilayer Equilibria of Stearate Self-Assembly Formed in Hydrotalcite Interlayers by Changing the Intercalation Temperature [J] Chem. Lett. 1999, 117-118
[134] F. Wypych, G. G. C. Arizag, J. E. F. C. Gardolinski, Intercalation and functionalization of zinc hydroxide nitrate with monoand dicarboxylic acids[J] J. Colloid Interf. Sci. 2005, 283: 130-138
[135] L. Mohanambe and S. Vasudevan, Aromatic Molecules in Restricted Geometries: Photophysics of Naphthalene Included in a Cyclodextrin Functionalized Layered Solid[J] J. Phys. Chem. B 2005, 109: 22523-22529
[136] L. Mohanambe and S. Vasudevan, Inclusion of Ferrocene in a Cyclodextrin-Functionalized Layered Metal Hydroxide: A New Organometallic-Organic-LDH Nanohybrid[J] Inorg. Chem. 2005, 44: 2128-2130
[137] L Mmohanambe and S Vasudevan, Inclusion of poly-aromatic hydrocarbon (PAH) molecules in a functionalized layered double hydroxide[J] J. Chem. Sci., 2006, 118: 105-115.
[138] L. Mohanambe and S. Vasudevan, Orientational Dynamics of Anthracene in a Cyclodextrin Functionalized Layered Solid[J] J. Phys. Chem. B, 2005, 109(24):11865-11869.
[139]L.Mohanambe and S.Vasudevan,Insertion of Iodine in a Functionalized Inorganic Layered Solid[J]Inorg.Chem.2004,43:6421-6425
[140]J.Wang,M.Wei,G.Y.Rao,D.G.Evans,and X.Duan,Structure and thermal decomposition of sulfated β-cyclodextrin intercalated in a layered double hydroxide[J]J.Solid State Chem.2004,177:366-371
[141]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organohydrotalcite[J]Appl.Clay Sci.2006,33:116-124
[142]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.2004,274:613-624
[143]Y.W.You,H.T.Zhao,G.F.Vance,Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]Colloid and Surface A,2002,205:161-172.
[144]P.K.Dutta and D.S.Robins,Pyrene Sorption in Organic-Layered Double-Metal Hydroxides[J]Langmuir 1994,10:1851-1856
[145]M.Ogawa,K.Kuroda,Photofunctions of intercalation compounds[J]Chem.Rev.,1995,95:399-438.
[146]H.Tagaya,S.Ogata,S.Nakano,J.Kadokawa,M.Karasu,K.Chiba,Intercalation of Azo-Compounds into Layered Aluminium Dihydrogentriphosphate and a Layered Double Hydroxide[J]J.Incl.Phenom.Mol.Recog.Chem.,1998,31:231-241.
[147]D.S.Robins,P.K.Dutta Examination of fatty acid exchanged layered double hydroxides as supports for photochemical assemblies[J]Langmuir,1996,12:402-408.
[148]H.Nakajima,S.Ishino,H.Masuda,T.Shimosaka,T.Nakagama,T.Hobo,K.Uchiyama,Photochemical Immobilization of Protein on Inner Wall of Microchannel[J]Chem.Lett.,2005,34(3):358-359.
[149]K.Itaya,H.C.Chang,L.Uchida,Anion-exchanged hydrotalcite-like-clay modified electrodes[J]Inorg.Chem.,1987,26:624-625.
[150]C.Mousty,S.Therias,C.Forano,J.P.Besse,Anion-exchanging clay-modified electrodes:synthetic layered double hydroxides intercalated with electroactive organic anions[J]J.Electroanal.Chem.,1994,374:63-69.
[151]刘俊杰,李峰,D.G.Evans,段雪,由Mg-Fe(Ⅱ)-Fe(Ⅲ)HTlc层状前体制备MgFe_2O_4尖晶石的研究[J]化学学报,2003,61:51-57.
[152]J.J.Liu,F.Li,D.G.Evans,X.Duan,Stoichiometric synthesis of a pure ferrite from a tailored layered double hydroxide(hydrotalcite-like)precursor[J]Chem.Commun.,2003,4:542-543.
[153]L.Lei,F.Millange,R.I.Walton,D.O'Hare,Efficient Separation of Pyridinedicarboxylates by Preferential Anion Exchange Intercalation in [LiAl_2(OH)_6]C1.H_2O[J]J.Mater Chem,2000,10:1881-1886.
[154]L.Lei,R.P.Vijayan,D.O'Hare,Preferential Anion Exchange Intercalation of Pyridinecarboxylates and Toluates Isomers in the Layered Double Hydroxide[LiAl_2(OH)_6]Cl·H_2O[J]J.Mater.Chem.,2001,11:3276-3280.
[155]J.L.Burba,Laboratory and field evaluation of novel inorganic drilling fluid additive[C]IADC/SPE 17198,presented at the IADC/SPE Drilling Conference,Dallas,Texas,USA,February 28-March 2,1988.
[156]韩书华,侯万国,孙德军,张春光,王果庭,MMH的结构与提粘提切机理研究[J]油田化学,1997,14(4):299-303.
[157]侯万国,李东祥,孙德军,韩书华,张春光,盐对粘土/氢氧化铝镁/甘油胶体性能的影响[J]应用化学,1997,14(01):29-32.
[158]李淑萍,侯万国,孙德军,张春光,Fe-Al-Mg-MMH/钠质蒙脱土分散体系触变性研究[J]高等学校化学学报,2001,22(07):1173-1176.
[159]W.G.Hou,C.G.Zhang,Studies on colloidal properties of mixed metal hydroxide-clay aqueous suspension[J]Chem.Res.Chinese U.,1995,11(4):316-322.
[160]W.G.Hou,D.J.Sun,S.H.Han,Study on the thixotropy of aluminum magnesium hydroxide-Na-montmorillonite suspension[J]Colloid Polym Sci,1998,276:274-277.
[161]任庆利,张赞锋,罗强.纳米晶镁铝水滑石的制备及其热分解机理[J]物理化学学报,2004,20:318-322
[162]N.Kobayashi,T.Honmyo,T.Katamoto,et al.Mg-Al based hydrotalcitetype particles,chlorine containing resin stabilizer and p rocess for p roducing the particles[P]US:6413639,2002-07-02.
[163]N.Kobayashi,T.Honmyo,T.Katamoto,et al,Mg-Al-based hydrotalcitetype particles,chlorine containing resin composition and process for producing the particles[P]US:200313951 1,2003-07-21.
[164]V.Ambrogi,G.Fardella,G.Grandolini,M.Nocchetti,L.Perioli,Effect of hydrotalcite-like compounds on the aqueous solubility of some poorly watersoluble drugs[J]J.Pharm.Sci.,2003,92(7):1407-1418.
[165]K.M.Tyner,S.R.Schiffman,E.P.Giannelis,Nanobiohybrids as delivery vehicles for camptothecin[J]J.Control.Release,2004,95(3):501-514
[166]孙辉,张慧,D.G.Evans,段雪,磁性药物.无机纳米复合材料的结构设计 与表征[J]科学通报,2004,49:2525-2530.
[167]M.Z.bin Hussein,Z.Zainal,A.H.Yahaya,D.W.V.Foo.Controlled release of a plant growth regulator,a-naphthaleneacetate from the lamella of Zn-Al-layered double hydroxide nanocomposite[J]J.Control.Release 2002,82:417-427
[168]孟锦宏,张慧,David G.Evans,段雪,新型层状农药缓/控释材料—草甘膦插层双金属 氢氧化物的超分子结构与缓释性能[J]科学通报,2005,50(3):208-214
[169]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.,2007,19:2679-2685
[170]杨巧珍,层状前驱体制备尖晶石铁氧体及其应用性能研究,博士论文2005,17-18.
[171]M.V.Villa,M.J.Sanchez-Martin and M.Sanchez-Camazano,Hydrotalcites and organo-hydrotalcites as sorbents for removing pesticides from water[J]J.Environ.Sci.Health,1999,34:509-525
[172]Cockett ect,Adsorption of materials[P]European Patent,0541358,May,1993
[173]R.Celis,W.C.Koskinen,A.M.Cecchi,G.A.Bresnahan,M.J.Carrisoza,M.A.Ulibarri,I.Pavlovic and M.C.Hermosin,Sorption of the ionizable pesticide imazamox by organo-clays and orgno-hydrotalcites[J]J.Environ.Sci.Health,1999,34:929-941
[174]R.Celis,W.C.Koskinen,M.C.Hermosin,M.A.Ulibarri,and J.Cornejo,Triadimefon Interactions with Organoclays and Organohydrotalcites[J]Soil Sci.Soc.Am.J.2000,64:36-43
[175]J.Inacio,C.Taviot-Gueho,C.Forano,J.P.Besse,Adsorption of MCPA pesticide by MgAl-layered double hydroxides[J]Appl.Clay Sci.2001,18:255-264
[176]F.Bruna,R.Celis,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Layered double hydroxides as adsorbents and carriers of the herbicide (4-chloro-2-methylphenoxy)acetic acid(MCPA):Systems Mg-Al,Mg-Fe and Mg-Al-Fe[J]J.Hazard.Mater.doi:10.1016/j.jhazmat.2009.03.038
[177]Y.H.Guo,D.F.Li,C.W.Hua,Y.H.Wang,E.B.Wang,Y.C.Zhou,S.H.Feng,Photocatalytic degradation of aqueous organocholorine pesticide on the layered double hydroxide pillared by Paratungstate Anion,Mg_(12)Al_6(OH)_(36)(W_7O_(24))·4H_2O[J]Appl.Catal.B:Environ.2001,30:337-349
[178]Y.W.You,H.T.Zhao,G.F.Vance,Adsorption of dicamba (3,6-dichloro-2-methoxy benzoic acid) in aqueous solution by calcined-layered double hydroxide[J]Appl.Clay Sci.2002,21:217-226
[179]M.Z.bin Hussein,C.W.Long,Synthesis of organo-mineral nanohybrid material:indole-2-carboxylate in the lamella of Zn-Al-layered double hydroxide[J]Mater.Chem.Phys.2004,85:427-431
[180]J.H.Meng,H.Zhang,D.G.Evans,X.Duan,Novel layered pesticide slow/controlled release materials-supramolecular structure and slow release property of glyphosate intercalated layered double hydroxides[J]Chinese Sci.Bull.2005,50:745-751
[181]F.Li,Y.F.Wang,Q.Z.Yang,D.G.Evans,C.Forano,X.Duan,Study on adsorption of glyphosate(N-phosphonomethyl glycine) pesticide on MgAl-layered double hydroxides in aqueous solution[J]J.Hazard.Mate.2005,125:89-95
[182]M.Lakraimi,A.Legrouri,A.Barroug,A.De Roy and J.P.Besse,Preparation of a new stable hybrid material by chloride-2,4-dichlorophenoxyacetate ion exchange into the zinc-aluminium-chloride layered double hydroxide[J]J.Mater.Chem.,2000,10:1007-1011
[183]I.Pavlovic,C.Barriga,M.C.Hermosin,J.Cornejo,M.A.Ulibarri,Adsorption of acidic pesticides 2,4-D,Clopyralid and Picloram on calcined hydrotalcite[J]Appl.Clay Sci.2005,30:125-133
[184]A.Legrouri,M.Lakraimi,A.Barroug,A.De Royc,J.P.Besse,Removal of the herbicide 2,4-dichlorophenoxyacetate from water to zinc-aluminium-chloride layered double hydroxides[J]Water Res.2005,39:3441-3448
[185]M.Z.bin Hussein,A.H.Yahay,Z.Zainal,L.H.Kian,Nanocomposite based controlled release formulation of an herbicide,2,4-dichlorophenoxyacetate incapsulated in zinc-aluminium-layered double hydroxide[J]Sci.Technol.Adv.Mater.2005,6:956-962
[186]Y.F.Chao,P.C.Chen,S.L.Wang,Adsorption of 2,4-D on Mg/Al-NO_3layered double hydroxides with varying layer charge density[J]Appl.Clay Sci.2008,40:193-200
[187]L.P.Cardoso,R.Celis,J.Cornejo,J.Valim,Layered Double Hydroxides as Supports for the Slow Release of Acid Herbicides[J]J.Agric.Food Chem.2006,54:5968-5975
[188]L.P.Cardoso,J.B.Valim,Study of acids herbicides removal by calcined Mg-Al-CO_3-LDH[J]J.Phys.Chem.Solids 2006,67:987-993
[189] M. A. Khan, C.-L. Choi, D.-H. Lee, M. Park, B.-K. Lim, J.-Y. Lee, J. Choi, Synthesis and properties of mecoprop-intercalated layered double hydroxide[J] J. Phys. Chem. Solids 2007, 68: 1591-1597
[190] F. Bruna, I. Pavlovic, R. Celis, C. Barriga, J. Cornejo, M.A. Ulibarri, Organohydrotalcites as novel supports for the slow release of the herbicide terbuthylazine[J] Appl. Clay Sci.2008, 42: 194-200
[191] Cockett ect, Adsorption of materials[P] U.S. Patent, 5,256,300, November, 1993
[192] Cockett ect, Sorbing agents[P] U.S. Patent, 5,360,547, Nov., 1994
[193] Bonora, Michela, Polyolefin or olefin copolymer films having improved light stabilitiy and pesticide resistance[P] European Patent, EP0690094(Al) Jan., 1996.
[194] Bonora, Michela, Polyolefin or olefin copolymer films having improved light stabilitiy and pesticide resistance, Canadian Patent, 2,152,580, Dec, 1995.
[195] Kuroda ect, Slow-releasing compositions containing hydrotalcites which have been intercalated with an organic anion and method of controlling insects and protecting fabric from insects[P] U.S. Patent, 5,595,747, Jan., 1997.
[196] Bonora, Stabilizer combination for synthetic organic polymers[P] U.S. Patent, 5,948,836, Sep., 1999.
[197] Bonora, Polyolefin or olefin copolymer films having improved light stability and pesticide resistance[P] U.S. Patent, 5,977,218, Nov., 1999
[198] Bonora, Use of sterically hindered amines in combination with a metal oxide or hydroxide to improve the light stabilitiy and pesticide resistance of polyolefin or olefin copolymer films[P] European Patent, EP0690094(Bl), Aug., 2002.
[1]L.Desigaux,M.B.Belkacem,P.Richard,J.Cellier,P.Leone,L.Cario,F.Leroux,C.Taviot-Gueho,and B.Pitard,Self-Assembly and Characterization of Layered Double Hydroxide/DNA Hybrids[J]Nano Letters 2006,16:199-204.
[2]J.-H.Choy,S.-Y.Kwak,J.-S.Park,Y.-J.Jeong,and J.Portier,Intercalative Nanohybrids of Nucleoside Monophosphates and DNA in Layered Metal Hydroxide[J]J.Am.Chem.Soc.1999,121:1399-1400.
[3]H.T.Zhao and G.F.Vance,Intercalation of carboxymethyl-α-cyclodextrin into magnesium-aluminum layered double hydroxide[J]J.Chem.Soc.Dalton.Trans.1997,1961-1965.
[4]U.Costantino,N.Coletti,M.Nocchetti,Anion Exchange of Methyl Orange into Zn-Al Synthetic Hydrotalcite and Photophysical Characterization of the Intercalates Obtained[J]Langmuir 1999,15:4454-4460.
[5]L.Perioli,V.Ambrogi,B.Bertini,M.Ricci,M.Nocchetti,L.Latterini,C.Rossi,Anionic clays for sunscreen agent safe use:Photoprotection,photostability and prevention of their skin penetration[J]Eur.J.Pharm.Biopharm.2006,62:185-193.
[6]H.Nakayama,N.Wada,M.Tsuhako,Intercalation of amino acids and peptides into Mg-Al layered double hydroxide by reconstruction method[J]Int.J.Pharm.2004,269:469-478.
[7]J.Inacio,C.Taviot-Gue'ho,C.Forano,J.P.Besse,Adsorption of MCPA pesticide by MgAl-layered double hydroxides[J]Appl.Clay Sci.2001,18:255-264
[8]S.B.Haderlein,K.W.Weissmahr,R.P.Schwazenbach,Specific adsorption of nitroaromatic explosives and pesticides to clays minerals[J]Environ.Sci.Technol.1996,30:612-622.
[9]Y.J.Li,B.Y.Gao,T.Wu,W.S.Chen,X.Li,B.Wang,Adsorption kinetics for removal of thiocyanate from aqueous solution by calcined hydrotalcite[J]Colloid Surface A 2008,325:38-43
[10]Y.S.Ho,AE.Ofomaja,Pseudo-second-order model for lead ion sorption from aqueous solutions onto palm kernel fiber[J]J.Hazard.Mater.2006,129:137-142
[11]Y.S.Ho,DAJ Wase,Forster CF,Batch nickel removal from aqueous solution by sphagnum moss peat[J]Water Res.1995,29:1327-1332
[12]Y.S.Ho,C.C.Wang,Pseudo-isotherms for the sorption of cadmium ion onto tree fern[J]Process.Biochem.2004,39:761-765
[13]X.F.Wu,Y.L.Hu,F.Zhao,Z.Z.Huang,D.Lei,Ion adsorption components in liquid/solid systems[J]J.Environ.Sci.2006,18:1167-1175
[14]T.C.Voice.,W.J.J.Weber,Sorbent concentration effects in liquid/solid partitioning[J]Environ.Sci.Technol.1985,19:789-796
[15]S.H.Han,W.G.Hou,Structure and the point of zero charge of magnesium aluminium hydroxide[J]J.Chem.Soc.,Faraday Trans.1998,94:915-918
[16]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.2007,19:2679-2685.
[17]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf Sci.2004,274,613-624.
[18]M.J.S.Dewar,E.G.Zoebisch,E.F.Healy,J.P.Stewart,Development and use of quantum mechanical molecular models.76.AM1:a new general purpose quantum mechanical molecular model[J]J.Am.Chem.Soc.1985,107,3902-3909.
[19]S.Carlino,The intercalation of carboxylic acids into layered double hydroxides:a critical evaluation and review of the different methods[J]Solid State Ionics 1997,98:73-84.
[1]M.Fernandez-Perez,E.Gonzalez-Pradas,M.D.Urena-Amate,Controlled Release of Imidacloprid from a Lignin Matrix:Water Release Kinetics and Soil Mobility Study[J]J.Agric.Food Chem.1998,46:3828-3834
[2]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.2004,274:613-624
[3]C.X.Liu,W.G.Hou,L.F.Li,Y.Li,S.J.Liu,Synthesis and characterization of 5-fluorocytosine intercalated Zn-Al layered double hydroxide[J]J.Solid State Chem.2008,181(8):1792-1797
[4]程丽鸿,赵静,吡虫啉/羧甲基壳聚糖凝胶球的制备及释放性能[J]精细化工2005,22:653-657
[5]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organo hydrotalcite[J]Appl.Clay Sci.2006,33:116-124
[6]M.C.Hermosin,M J.Calderon,J.-P.Aguer and J.Cornejo,Organoclays for controlled release of the herbicide fenuron[J]Pest.Manag.Sci.2001,57:803-809.
[7]M.Z.bin Hussein,Z.Zainal,A.H.Yahaya,D.W.V.Foo.Controlled release of a plant growth regulator,a-naphthaleneacetate from the lamella of Zn-Al-layered double hydroxide nanocomposite[J]J.Control.Release 2002,82:417-427
[1]L.Y.Wang,C.Li,M.Liu,D.G.Evans and X.Duan,Large continuous,transparent and oriented self-supporting films of layered double hydroxides with tunable chemical composition[J]Chem.Commun.,2007,123-125.
[2]L.Desigaux,M.B.Belkacem,P.Richard,J.Cellier,P.Leone,L.Cario,F.Leroux,C.Taviot-Gueho,and B.Pitard,Self-Assembly and Characterization of Layered Double Hydroxide/DNA Hybrids[J]Nano Letters,2006,16:199-204.
[3]J.-H.Choy,S.-Y.Kwak,J.-S.Park,Y.-J.Jeong,and J.Portier,Intercalative Nanohybrids of Nucleoside Monophosphates and DNA in Layered Metal Hydroxide[J]J.Am.Chem.Soc.,1999,121:1399-1400.
[4]L.Perioli,V.Ambrogi,B.Bertini,M.Ricci,M.Nocchetti,L.Latterini,C.Rossi,Anionic clays for sunscreen agent safe use:Photoprotection,photostability and prevention of their skin penetration[J]Eur.J.Pharm.Biopharm.,2006,62:185-193.
[5]L.Lv,J.He,M.Wei,D.G.Evans,X.Duan,Uptake of chloride ion from aqueous solution by calcined layered double hydroxides:Equilibrium and kinetic studies[J]Water Res.,2006,40:735-743.
[6]H.Morioka,H.Tagaya,M.Karasu,J.Kadokawa,and K.Chiba,Preparation of New Useful Mterials by Surface Modification of Inorganic Layered Compound[J]J.Solid State Chem.,1995,117:337-342.
[7]L.Mohanambe and S.Vasudevan,Insertion of Iodine in a Functionalized Inorganic Layered Solid[J]Inorg.Chem.,2004,43:6421-6425.
[8]W.-Y.Tseng,J.-T.Lin,C.-Y.Mou,S.Cheng,S.-B.Liu,P.P.Chu,and H.-W.Liu,Incorporation of C60 in Layered Double Hydroxide[J]J.Am.Chem.Soc.,1996,118:4411-4418
[9]Y.W.You,H.T.Zhao,G.F.Vance,Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]Colloid Surfaces A 2002,205:161-172
[10]Y.W.You,H.T.Zhao and G.F.Vance,Hybrid organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate:Preparation and adsorption characteristics[J]J.Mater.Chem.,2002,12:907-912
[11]M.Fernandez-Perez,E.Gonzalez-Pradas,and M.D.Urena-Amate,Controlled Release of Imidacloprid from a Lignin Matrix:Water Release Kinetics and Soil Mobility Study[J]J.Agric.Food Chem.,1998,46:3828-3834.
[12]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organohydrotalcite[J]Appl.Clay Sci.,2006,33:116-124
[13]Z.Z.Li,L.X.Wen,F.Liu,A.Q.Liu,Q.Wang,J.F.Chen,Fabrication of Novel Avermectin-porous Hollow Silica Nanoparticles(Av-PHSN)Carrier and Its Properties[J]Chinese J.Pest.Sci.,2005,7:275-281.
[14]H.T.Zhao,G.F.Vance,Intercalation of carboxymethyl-α-cyclodextrin into magnesium-aluminum layered double hydroxide[J]J.Chem.Soc.Dalton.Trans.,1997,1961-1965.
[15]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.,2004,274:613-624.
[16]M.J.S.Dewar,E.G.Zoebisch,E.F.Healy,J.P.P.Stewart,Development and use of quantum mechanical molecular models.AM1:a new general purpose quantum mechanical molecular model[J]J.Am.Chem.Soc.,1985,107(13):3902-3907.
[17]K.Esumi,S.Yamamoto,Adsorption of sodium dodecyl sulfate on hydrotalcite and adsolubilization of 2-naphthol[J]Colloid Surface A,1998,137:385-388.
[18]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.,2007,19:2679-2685.
[1]张百臻,农药分析第三版[M]1988,202-203.
[2]郑华华,广西大学硕士学位论文,2006.
[3]王书瑞,山东大学硕士学位论文,2001.
[2]L.L.English,Globule size of emulsions and toxicity[J].Nat.Hist.Surv.Bull.,1928,17:235.
[3]S.E Chiu,Particle size and toxicity of silica dusts[J].J.Econ.Entom.,1939,32:240.
[4]L.M.Bertholf,J E.Pilson,Particle size and stomach toxicity of lead arsenate[J].J.Econ.Entom.,1941,34:24-33.
[5]H.P.Burchfield,G L.McNew Mechanism of particle size effects of fungicides on plant protection[J].Boyce.Thompson.Inst.,1950,16:131-161
[6]G.S.Hartley,I.J.Graham-Bryce,Physical Principles of Pesticide Behaviour[A].The Dynamics of Applied Pesticides in the Local Environment in Relation to Biological Response[C].Academic Press,London/New York,1980,2:722-723
[7]王以燕,刘绍仁,宗伏霖,等.中华人民共和国国家标准—农药利型名称及代码[S].农业部农药检定所:中华人民共和国国家质量监督检验检疫总局,2003.
[8]凌世海主编.农药剂型加工丛书.液体制剂[M].北京:化学工业出版社2003
[9]崔福德主编.药剂学[M].北京:人民卫生出版社,2003.
[10]A.Michael.Non-aqueous suspension concentrate[P]United States Patent:6,165,940.December 26,2000.
[11]H.E.Agbaje,D.H.Carter,Powers Tracy A.Stable concentrated pesticide suspension[P]United States Patent:6,451,731.September 17,2002.
[12]Y.Shimura,T.Asano,S.Shimono,Insecticide composition and production process thereof[P]United States Patent:5,733,561.March 31,1998.
[13]A.Kisuno,T.Ansai,A.S.Aizawa Composite particle aqueous suspension and process for producing same[P]United States Patent:5,889,088.March 30,1999.
[14]M.G.Ochomogo,M.A.Deleo,Selbach Hanneliese S.Suspoemulsion system for delivery of actives[P]United States Patent:6,358,909.March 19,2002.
[15]H.Rochling,J.Kocur,K.Albrecht.Water-dispersible glufosinate granules[P]United States Patent:5,543,385.August 6,1996.
[16]R.J.Lo,J.L Chen,H.B Scher,Dhy water-dispersible compositions of micro-encapsulated pesticides[P]United States Patent:6,358,520.March 19,2002.
[17]R.J.Lo,J.L Chen,H.B Scher,Dry water-dispersible compositions of microencapsulated pesticides[P]United States Patent:6,419,942.July 16,2002.
[18]H.Rochling,B.Joachim,Water-dispersible granules of suspoemulsions[P]United States Patent:6,410,481.June 25,2002.
[19]W.L.Geigle,L.S.Sandell,R.D.Wysong,Water-dispersible or water-soluble pesticide grandules from heat-activated binders[P]United States Patent:5,372,989.December 13,1994.
[20]陈福良,王仪,郑斐能.农药微乳剂及其浊点问题的探讨和初步研究[J].农药,1999,38(3):9-10.
[21]吴春江.微乳液的形成和微乳剂的制备原理[J]浙江化工,2003 1:1-2.
[22]凌世海.农药剂型进展评述[J].农药,1998,37(8):6-9.
[23]梁文平,郑斐能,王仪.21世纪农药发展的趋势:绿色农药与绿色农药制剂[J].农药,1999,38(9):1-2.
[24]I.Domingo,D.I.Prettypaul,Water-dilutable,microemulsion concentrate and pour-on formulations thereof[P]United States Patent:5968990,1999-10-19.
[25]H.Rudolf,Slective herbicidal compositions in the form of concentrated microemulsions[P],United States Patent:5733847,1998-03-01.
[26]S.J.Barcay,.Water powder as a synergist in pest baits[P],United States Patent:5820855,1998-10-13.
[27]P.M.Murali,Process of preparing purified azadirachtin in powder form from neem seeds and storage stable aqueous composition containing azadirachtin[P].United States Patent:6193974,2001-02-27.
[28]T.D Nelson,Granular pest bait[P].United States Patent:6153181,2000-11-28.
[29]H.Rochling.Concentrated aqueous microemulsions[P].United States Patent:5227402,1993-07-13.
[30]吴秀华,陈蔚林,王飞.农药微乳液物理稳定性的探讨[J].化学通报,1999(3):36-38.
[31]R.F.Stewart,L.C.Greene,R.K.Bhaskar,Microcapsule having temperature-dependent permeability profile[P]United States Patent:5.120.349.June 9.1992.
[32]J.E.Van Koppenhagen,,H.B.Scher,K.-S.S.Lee,Acid triggered release microcapsules[P]United States Patent:6,337,130.January 8,2002.
[33]J.E.Van Koppenhagen,,H.B.Scher,K.-S.S.Lee,Acid-triggered microcapsules[P]United States Patent Application 20020068169.June 6,2002
[34]S.T Wellinghoff,J.J Kampa,S.A.Barenberg,Silicate-containing powders providing controlled,sustained gas release[P]United States Patent:6,605,304.August 12,2003.
[35]O.Benjamin,P.J..Frank,C.Mark.,Stabilized controlled release substrate having a coating derived from an aqueous dispersion of hydrophobic polymer[P]United States Patent:6,316,031.November 13,2001.
[36]C.C.Yang,I.H.Pan.,Preparation of pesticide microcapsule[P]United States Patent:5,576,008.November 19,1996.
[37]R.Celis,M.C.Hermosian,M.J.Carrizosa,J.Cornejo,Inorganic and Organic Clays as Carriers for Controlled Release of the Herbicide Hexazinone[J]J.Agric.Food Chem.2002,50:2324-2330
[38]M C.Hermosin,M J.Calderon,J.-P.Aguer and J.Cornejo,Organoclays for controlled release of the herbicide fenuron[J]Pest Manag Sci 2001,57:803-809
[39]M.Fernandez-Perez,E.Gonzalez-Pradas,M.Villafranca-Sanchez,F.Flores-Cespedes,Mobility of isoproturon from an alginate-bentonite controlledrelease formulation in layered soil[J]Chemosphere 2000,41:1495-1501
[40]E Gonzalez-Pradas,M Fernandez-Perez,M Villafranca-Sanchez,F Martmez-Lopez and F Flores-Cespedes,Use of bentonite and humic acid as modifying agents in alginate-based controlled-release formulations of imidacloprid[J]Pest Manag Sci 1999,55:546-552
[41]M Villafranca-Sanchez,E Gonzalez-Pradas,M Fernandez-Perez,F Martinez-Lopez,Flores-Cespedes and MD Urena-Amate,Controlled release of isoproturon from an alginate-bentonite formulation:water release kinetics and soil mobility[J]Pest Manag Sci 2000,56:749-756
[42]E Gonzalez-Pradas,M Fernandez-Perez,M Villafranca-Sanchez and F Flores-Cespedes,Mobility of imidacloprid from alginate-bentonite controlled-release formulations in greenhouse soils[J]Pest Manag Sci,1999,55:1109-1115
[43]M.F.Nnez-Pearez,M.Villafranca-Saa Nchez,F.Flores-Cea Spedes,F.J. Garrido-Herrera,S.Pea Rez-Garciaa,Use of Bentonite and Activated Carbon in Controlled Release Formulations of Carbofuran[J]J.Agric.Food Chem.2005,53:6697-6703
[44]Z.Gerstl,A.Nasser,and U.Mingelgrin Controlled Release of Pesticides into Soils from Clay-Polymer Formulations[J]J.Agric.Food Chem.1998,46:3797-3802
[45]F.Cavani,F.Trifiro,A.Vaccari.Hydrotalcite-type anionic clays:preparation,properties and applications[J].Catal.Today,1991,11(2):173-301.
[46]V.Angelo,Preparation and catalytic properties of cationic and anionic clays[J]Catal.Today,1998,41(1-3):53-71.
[47]W.Feitknecht,Doppelhydroxyden zwischen zwei-und dreiwertigen metallen[J]Helv.Chim.Acta,1942,25:555-569
[48]侯万国,张春光,孙德军,梁晓丽,王果庭,氢氧化铝镁正电溶胶制备及性能研究[J]高等学校化学学报,1995,16(8):1292-1294.
[49]张春光,徐同台,侯万国,正电胶钻井液[M],石油工业出版社,2000,第1版.
[50]J.Perez-Ramirez,G.Mul,F.Kapteijn,J.A.Moulijn,In-situ investigation of the thermal decomposition of Co-Al hydrotalcite in different atmospheres[J]J.Mater.Chem.,2001,11:821-830.
[51]V.Rives,A.U.Marya.Layered double hydroxides(HTlc) intercalated with metal coordination compounds and oxometalates[J].Coordin.Chem.Rev.,1999,181:61-120.
[52]H.C.B.Hansen,R.M.Taylor,Formation of synthetic analogues of double metal-hydroxycarbonate minerals under controlled pH conditions:The synthesis of desautelsite[J]Clay Miner.1991,26:507-525.
[53]J.M.Fernandez,C.Barriga,M.-A.Ulibarri,F.M.Labajos,V.Rives,Preparation and thermal stability of manganese-containing hydrotalcite,[Mg_(0.75)Mn_(0.04)~ⅡMn_(0.21)~Ⅲ(OH)_2](CO_3)_(0.11)·nH_2O[J]J.Mater.Chem.,1994,4:1117-1122.
[54]V.Prevot,C.Forano,J.E Besse,Hydrolysis in polyol:new route for hybrid-layered double hydroxides preparation[J]Chem.Mater.2005,17:6695-6701
[55]W.T.Reichle,Kang S.Y.and Everhardt D.S.,The nature of the thermal decomposition of a catalytically active anionic clay mineral[J]J.Catal.,1986,101:352-359.
[56]S.Miyata,The syntheses of hydrotalcite-like compound and their structures[J]Clays Clay Miner.,1975,23:369-373.
[57]S.Miyata,A.Okada,Synthesis of Hydrotalcite-like system of Mg~(2+)-Al~(3+)-SO_4~(2-)and Mg~(2+)-Al~(3+)-CrO_4~(2-)[J]Clays Clay Miner,1977,25:14-18.
[58]S.Miyata,Physico-chemical properties of hydrotalcite-like compounds[J]Clays Clay Miner,1980,28:50-56.
[59]S.K.Yun,T.J.Pinnavaia,Water Content and Particle Texture of Synthetic Hydrotalcite-like Layered Double Hydroxides[J]Chem.Mater,1995,7(2):348-354.
[60]M.Sychev,R.Prihod'ko,K.Erdmann.Hydrotalcites:relation between structural features,basicity and activity in the Wittig reaction[J]Appl.ClaySci.2001,18:103-110.
[61]N.S.Puttaswamy,P.V.Kamath,Reversible thermal behaviour of layered double hydroxides:a thermogravimetric study[J]J.Mater.Chem.,1997,7:1941-1946.
[62]J.Rocha,M.del Arco,V.Rives,M.A.Ulibarri,Reconstruction of layered double hydroxides from calcined precursors:a powder XRD and ~(27)Al MAS NMR study[J]J.Mater.Chem.,1999,9:2499-2504.
[63]S.K.Pramod,S.V.Jaime,C.F.Fran,Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]Chem.Commun.,1998,1091-1092.
[64]M.Rajamathi,G.D.Nataraja,S.Ananthamurthy,P.Vishnu Kamath,Reversible thermal behavior of the layered double hydroxide of Mg with Al:mechanistic studies[J]J.Mater.Chem.,2000,10:2754-2757.
[65]H.P.Boehm,J.Steinle,C.Vieweger,[Zn_2Cr(OH)_6]X 2H_2O(X=F~-,Cl~-,Br~-,I~-,ect),new layer compounds capable of anion exchange and intracystalline swelling[J]Angew Chem.Int.Ed.Engl,1977,16:265-270.
[66]T.Lopez,P.Bosch,E.Ramos,R.Gomez,O.Novaro,D.Acosta,F.Figueras,Synthesis and Characterization of Sol-Gel Hydrotalcites.Structure and Texture[J]Langmuir,1996,12(1):189-192.
[67]P.Federica,G.Giovanna,G.Patrick.Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples[J]Micropor.Mesopor.Mater.,2000,39:229-247.
[68]I.Di Cosimo,V.K.Diez,C.R.Apesteguia,Synthesis of α,β-unsaturated ketones over thermally activated Mg-Al hydrotalcites[J]Appl.Clay Sci.,1998,13:433-449.
[69]J.S.Valente,M.S.Cantu,Preparation and Characterization of Sol-Gel MgAl Hydrotalcites with Nanocapsular Morphology[J]J.Phys.Chem.C 2007,111:642-651
[70]H.C.Xu,Zeng,Thermal evolution of cobalt hydroxides:a comparative study of their various structural phases[J]J.Mater Chem.,1998,8:2499-2506.
[71]M.Ogawa,S.Asai.Hydrothermal Synthesis of Layered Double Hydroxide-Deoxycholate Intercalation Compounds[J]Chem.Mater,2000,12(11):3253-3255.
[72]M.Ogawa,H.Kaiho.Homogeneous Precipitation of Uniform Hydrotalcite Particles[J].Langmuir,2002,18:4240-4242.
[73]谢晖,矫庆泽,段雪.镁铝型水滑石水热合成[J]应用化学,2001,18(1):70-72.
[74]段雪,矫庆泽,李蕾,均分散超细阴离子层状材料的新合成方法[P]CN99119385.7.
[75]段雪,李殿卿,何俊玲,张法智,一种以卤水为原料制备纳米级镁铝水滑石的方法[P]CN03150037.4.
[76]Y.Zhao,F.Li,Zhang R,Evans D.G,Duan X,Preparation of layered double-hydroxide nanomaterials with a uniform crystallite size using a new method involving separate nucleation and aging steps[J]Chem.Mater,2002,14(10):4286-4291.
[77]杜一波,何静,李峰,等,微波技术在制备水滑石和柱撑水滑石中的应用[J]应用科学学报,1998,16(3):349-354.
[78]G.Fetter,.F H.Andez,A.M.Maubert,et al.Microwave irradiation effect on hydrotalcite synthesis[J].J.Porous Mater.,1997,4:27-30.
[79]X.M.Xie,X.R.Ren,J.P.Li,et al.Preparation of ZnAl_2 HTLcs with small particle size by ultrasonic crystallization[J]J.Nat.Gas Chem.,2006,15:100-104.
[80]杜以波,北京化工大学硕士学位论文(1995).
[81]郭军,孙铁,沈剑平,等.硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J]高等化学学报,1995,3:346-350.
[82]刘继广,郭军,杂多阴离子组成水滑石类层柱材料中层柱相互作用研究[J]高等化学学报,1995,9:1329-1333.
[83]C.P.Kelkar,A.A.Schutz,Ni-,Mg- and Co-containing hydrotalcite-like materials with a sheet-like morphology:synthesis and characterization[J]Micropor.Mater,1997,10:163-172.
[84]F.Kooli,K.Kosuge,T.Hibino,A.Tsunashima,Synthesis and Properties of Mg-Zn-Al-SO_4 Hydrotalcite-like Compounds[J]J.Mater Sci.,1993,28:2769-2773.
[85]胡长文,刘彦勇,型微孔材料-杂多阴离子柱撑Zn-Al型阴离子粘土的 合成、表征及其催化反应活性的研究[J]中国科学(B),1995,15:916-922.
[86]J.T.Kloprogge,R.L.Frost,Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Zn/Al-hydrotalcites[J]Phys.Chem.Chem.Phys.,1999,1:1641-1647.
[87]J.Twu,P.K.Dutta,Raman spectroscopic study of intercalated molybdate ions in layered metal hydroxides[J]Chem.Mater.1992,4:398-401.
[88]刘继广,矫庆泽,张鹏,钨磷杂多化合物嵌入ZnAl类水滑石层间及其酸碱催化活性的研究[J]高等学校化学学报,1994,15:275-278.
[89]陈涛,周明华,王岚,詹正坤,锌铬水滑石的合成及表征[J]合成化学,2002,10:45-48。
[90]陈涛,周明华,王岚,詹正坤,钴铬水滑石的合成及表征[J]化学研究及应用,2002,14:44-47.
[91]V.A.Drits,New Members of the Hydrotalcite-Manasseite Group[J]Clays Clay Miner,1987,35:401-417.
[92]G.Hu,D.O'Hare,Unique Layered double hydroxide morphologies using reverse microemulsion synthesis[J]J.Am.Chem.Soc.2005,127:17808-17813.
[93]H.Cai,A.C.Hillier,K.R.Franklin,C.C.Nunn,M.D.Ward,Nanoscale Imaging of Molecular Adsorption Science[J]Science,1994,266:1551-1555.
[94]R.V.Prikhodko,M.V.Sychev,I.M.Astrelin,K.Erdmann,A.Mangel,R.A.van Santen Synthesis and Structural Transformations of Hydrotalcite-like Materials Mg-Al and Zn-Al[J]Russian J.Appl.Chem.,2001,74:231.
[95]D.Tichit,M.N.Bennani,F.Figueras,J.R.Ruiz,Decomposition Processes and Characterization of the Surface Basicity of Cl~- and CO_3~(2-)Hydrotalcites[J]Langmuir,1998,14:2086-2091.
[96]A M Fogg,J S Dunn,S-G Shyu.Selective Ion-Exchange Intercalation of Isomeric Dicarboxylate Anions into the Layered Double Hydroxide[J][LiAl_2(OH)_6]Cl·H_2O[J],Chem Mater,1998,10(1):351-355.
[97]S.Kohjiyo,T.Sato,T.Nakayama,Hydrotalcite-like compounds[J]Makromol Chem.Rapid Commun.,1981,2:231-236.
[98]W.T.Reiehle,Pulse microreactor examination of the vapor-phase aldol condensation of acetone[J]J.Catal.,1980,63:295-306.
[99]M.A.Drezdon,Synthesis of Isopolymetalate-Pillared Hydrotalcite Via Organic-Anion-Pillared Precursors[J]Inorg.Chem.,1988,27:4628-4632.
[100]吕亮,吾国强,段雪,李峰,杜以波,水滑石的制备、表征及其在酯 交换反应中的应用[J]精细石油化工,2001,1:9-12.
[101]S.Pramod,J.Kumbhar,V.Sanchez,F.Francois,Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]J.Chem.Soc.Chemical Commun.,1998,39:1091-1092.
[102]B.M.Choudary,M.L.Kantam,C.R.Reddy,K.K.Rao,F.Figueras,Michael addition catalyzed by modified Mg-Al Hydrotalcite[J]J Mol.Catal.A,1999,146:279-284.
[103]J.Perez-Ramirez,G.Mul,F.Kapteijn and J.A.Moulijn,In situ investigation of the thermal decomposition of Co-Al hydrotalcite in different atmospheres[J]J.Mater.Chem.,2001,11:821-830
[104]P.S.Kumbhar,J.Sanchez-Valente,F.Figueras.Modified Mg-Al hydrotalcite:a highly active heterogeneous base catalyst for cyanoethylation of alcohols[J]Chem Commun,1998,10:1091-1092.
[105]S.Amin,G.G.Jayson.Humic substance uptake by hydrotalcites and pilcs [J],Water Res.,1996,30(2):299-306.
[106]M.A.Ulibarri,I.Pavlovic,M.C.Hermosin,J.Cornejo,Hydrotalcite-like compounds as potential sorbents of phenols from water[J]Appl.Clay Sci.,1995,10:131-145.
[107]A.Sood,Process for removing heavy metal ions from solutions using adsorbents containing activated hydrotalcite[P]US Patent 4,752,397,Jan,1988
[108]苏延磊,侯万国,孙德军,刘尚营,张春光,Mg-Fe-LMHs纳米颗粒的合成及其阴离子交换容量的研究[J]高等学校化学学报,1999,20(7):1012-1016.
[109]夏春友,侯万国,孙德军,王果庭,铝镁混合金属氢氧化物溶胶阴离子交换性能研究[J]无机化学学报,1996,12(4):368-371.
[110]李丽芳,侯万国,贾春晓,焦燕妮,金属元素对类水滑石物质阴离子交换性能影响的研究[J]山东大学学报,2004,39(2):90-94.
[111]包玉敏,李连生,焦磷酸根嵌入后形成的交联水滑石的研究[J]化学通报,2002,3:194-197.
[112]V.L.Constantino,T.J.Pinnavaia,Basic Properties of Mg-Al layered double hydroxides intercalated by carbonate,hydroxide,chloride,and sulfate anions[J]Inorg,chem.,1995,34:883-892.
[113]U.Costantino,Intercalation and grafting of hydrogen phosphates and phosphonates into synthetic hydrotalcites and a.c.-conductivity of the compounds thereby obtained[J]Solid State lonic,1997,97:203-212.
[114]V.Rives,A.U.Marya.Layered double hydroxides(HTlc) intercalated with metal coordination compounds and oxometalates[J] Coordin. Chem. Rev., 1999,181:61-120.
[115] T. K. Duta,, M. Puri, Anion exchange in lithium aluminate hydroxides[J] J. Phys.Chem.,1989, 93: 37 6-381.
[116] H. Nijs, A. Clearfield, E. F. Vansant, The intercalation of phenylphosphonic acid in layered double hydroxides[J] Micropor. Mesopor. Mater., 1998, 23: 97-108.
[117] E. Kanezaki, Intercalation of N26DS between layers of Mg/Al double hydroxide: preparaton, powder X-ray diffraction, fourier transform infrared spectra and X-ray photoelectron spectra[J] Mater. Res. Bull., 1999, 34(9): 1435-1440.
[118] S. P. Rey, J. E. M. Robles, K.-S. Han, Liliane, G. Demourgues, C. Delmas, E. Duguet, Acrylate intercalation and in situ polymerization in iron substituted nickel hydroxides[J] Polym Int, 1999, 48: 277-282.
[119] F. Millange, R.I. Walton, L. Lei, D. O'Hare, Efficient Separation of Terephthalate and Phthalate Anions by Selective Ion-Exchange Intercalation in the Layered Double Hydroxide Ca_2Al(OH)_6·NO_3·2H_2O[J] Chem. Mater., 2000, 12(7): 1990-1994.
[120] V. Prevot, C. Forano, J. P. Besse, Hybrid derivatives of layered double hydroxides[J] Appl. Clay Sci., 2001, 18: 3-15.
[121] E. L. Crepaldi, P. C. Pavan, J. B. Valim, Anion exchange in layered double hydroxides by surfactant salt formation[J] J. Mater. Chem., 2000, 1337-1343.
[122] S. Abend, N. Bonnke, U. Gutschner, G. Lagaly, Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides[J] Colloid Polym. Sci., 1998, 276: 730-737
[123] J. M. R. Genin, Thermodynamic equilibria in aqueous suspersions of synthesisand natural (Fe)(II)-Fe(III) green rusts: occurrences of the mineral inhydromorphic soils[J] Environ. Sci. Tech., 1998, 32: 1058-1068.
[124] K. A. Baltpurvins, R. C. Burns, G. A. Lawrance, A. D. Stuart, Effect of Ca~(2+), Mg~(2+) and anion type on the aging of iron(III)Hydroxide precipitates[J] Environ. Sci. Technol., 1997, 31: 1024-1032.
[125] M. Meyn, K. Beneke, Anion-exchange reactions of layered double hydroxides[J] Inorg. Chem. 1990, 29: 5201-5207.
[126] H.T. Zhao, G.F. Vance, Intercalation of carboxymethyl-a-cyclodextrin into magnesium-aluminum layered double hydroxide[J] J. Chem. Soc., Dalton Trans., 1997, 1961-1965
[127] W.-Y. Tseng, J.-T. Lin, C.-Y. Mou, S. Cheng, S.-B. Liu, P. P. Chu, and H.-W. Liu, Incorporation of C60 in Layered Double Hydroxide[J] J. Am. Chem. Soc. 1996, 118: 4411-4418
[128] S. Carlino, The intercalation of carboxylic acids into layered double hydroxides: a critical evaluation and review of the different methods[J] Solid State Ionics 1997, 98: 73-84
[129] S. Sasaki , S. Aisawa , H. Hirahara, A. Sasaki, H. Nakayam, E. Narit, Synthesis of p-sulfonated calix[4]arene-intercalated layered double hydroxides and their adsorption properties for organic molecules[J] J. Eur. Ceram. Soc. 2006, 26: 655-659
[130] A. Clearfield, M. Kieke, J. Kwan, J. L. Colon and R.-C. Wang, Intercalation of Dodecyl Sulfate into Layered Double Hydroxides[J] J. Inch Phenom. Mole. Recog. Chem. 1991,11: 361-378.
[131] M. Borja and P. K. Dutta, Fatty Acids in Layered Metal Hydroxides: Membrane-iike Structure and Dynamlcs[J] J. Phys. Chem., 1992, 96: 5434-5444.
[132] H.Y. Chen, F.Z. Zhang, S.S. Fu, and X. Duan, In Situ Microstructure Control of Oriented Layered Double Hydroxide Monolayer Films with Curved Hexagonal Crystals as Superhydrophobic Materials[J] Adv. Mater. 2006,18:3089-3093
[133] T. Kanoh, T. Shichi, and K. Takagi, Mono- and Bilayer Equilibria of Stearate Self-Assembly Formed in Hydrotalcite Interlayers by Changing the Intercalation Temperature [J] Chem. Lett. 1999, 117-118
[134] F. Wypych, G. G. C. Arizag, J. E. F. C. Gardolinski, Intercalation and functionalization of zinc hydroxide nitrate with monoand dicarboxylic acids[J] J. Colloid Interf. Sci. 2005, 283: 130-138
[135] L. Mohanambe and S. Vasudevan, Aromatic Molecules in Restricted Geometries: Photophysics of Naphthalene Included in a Cyclodextrin Functionalized Layered Solid[J] J. Phys. Chem. B 2005, 109: 22523-22529
[136] L. Mohanambe and S. Vasudevan, Inclusion of Ferrocene in a Cyclodextrin-Functionalized Layered Metal Hydroxide: A New Organometallic-Organic-LDH Nanohybrid[J] Inorg. Chem. 2005, 44: 2128-2130
[137] L Mmohanambe and S Vasudevan, Inclusion of poly-aromatic hydrocarbon (PAH) molecules in a functionalized layered double hydroxide[J] J. Chem. Sci., 2006, 118: 105-115.
[138] L. Mohanambe and S. Vasudevan, Orientational Dynamics of Anthracene in a Cyclodextrin Functionalized Layered Solid[J] J. Phys. Chem. B, 2005, 109(24):11865-11869.
[139]L.Mohanambe and S.Vasudevan,Insertion of Iodine in a Functionalized Inorganic Layered Solid[J]Inorg.Chem.2004,43:6421-6425
[140]J.Wang,M.Wei,G.Y.Rao,D.G.Evans,and X.Duan,Structure and thermal decomposition of sulfated β-cyclodextrin intercalated in a layered double hydroxide[J]J.Solid State Chem.2004,177:366-371
[141]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organohydrotalcite[J]Appl.Clay Sci.2006,33:116-124
[142]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.2004,274:613-624
[143]Y.W.You,H.T.Zhao,G.F.Vance,Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]Colloid and Surface A,2002,205:161-172.
[144]P.K.Dutta and D.S.Robins,Pyrene Sorption in Organic-Layered Double-Metal Hydroxides[J]Langmuir 1994,10:1851-1856
[145]M.Ogawa,K.Kuroda,Photofunctions of intercalation compounds[J]Chem.Rev.,1995,95:399-438.
[146]H.Tagaya,S.Ogata,S.Nakano,J.Kadokawa,M.Karasu,K.Chiba,Intercalation of Azo-Compounds into Layered Aluminium Dihydrogentriphosphate and a Layered Double Hydroxide[J]J.Incl.Phenom.Mol.Recog.Chem.,1998,31:231-241.
[147]D.S.Robins,P.K.Dutta Examination of fatty acid exchanged layered double hydroxides as supports for photochemical assemblies[J]Langmuir,1996,12:402-408.
[148]H.Nakajima,S.Ishino,H.Masuda,T.Shimosaka,T.Nakagama,T.Hobo,K.Uchiyama,Photochemical Immobilization of Protein on Inner Wall of Microchannel[J]Chem.Lett.,2005,34(3):358-359.
[149]K.Itaya,H.C.Chang,L.Uchida,Anion-exchanged hydrotalcite-like-clay modified electrodes[J]Inorg.Chem.,1987,26:624-625.
[150]C.Mousty,S.Therias,C.Forano,J.P.Besse,Anion-exchanging clay-modified electrodes:synthetic layered double hydroxides intercalated with electroactive organic anions[J]J.Electroanal.Chem.,1994,374:63-69.
[151]刘俊杰,李峰,D.G.Evans,段雪,由Mg-Fe(Ⅱ)-Fe(Ⅲ)HTlc层状前体制备MgFe_2O_4尖晶石的研究[J]化学学报,2003,61:51-57.
[152]J.J.Liu,F.Li,D.G.Evans,X.Duan,Stoichiometric synthesis of a pure ferrite from a tailored layered double hydroxide(hydrotalcite-like)precursor[J]Chem.Commun.,2003,4:542-543.
[153]L.Lei,F.Millange,R.I.Walton,D.O'Hare,Efficient Separation of Pyridinedicarboxylates by Preferential Anion Exchange Intercalation in [LiAl_2(OH)_6]C1.H_2O[J]J.Mater Chem,2000,10:1881-1886.
[154]L.Lei,R.P.Vijayan,D.O'Hare,Preferential Anion Exchange Intercalation of Pyridinecarboxylates and Toluates Isomers in the Layered Double Hydroxide[LiAl_2(OH)_6]Cl·H_2O[J]J.Mater.Chem.,2001,11:3276-3280.
[155]J.L.Burba,Laboratory and field evaluation of novel inorganic drilling fluid additive[C]IADC/SPE 17198,presented at the IADC/SPE Drilling Conference,Dallas,Texas,USA,February 28-March 2,1988.
[156]韩书华,侯万国,孙德军,张春光,王果庭,MMH的结构与提粘提切机理研究[J]油田化学,1997,14(4):299-303.
[157]侯万国,李东祥,孙德军,韩书华,张春光,盐对粘土/氢氧化铝镁/甘油胶体性能的影响[J]应用化学,1997,14(01):29-32.
[158]李淑萍,侯万国,孙德军,张春光,Fe-Al-Mg-MMH/钠质蒙脱土分散体系触变性研究[J]高等学校化学学报,2001,22(07):1173-1176.
[159]W.G.Hou,C.G.Zhang,Studies on colloidal properties of mixed metal hydroxide-clay aqueous suspension[J]Chem.Res.Chinese U.,1995,11(4):316-322.
[160]W.G.Hou,D.J.Sun,S.H.Han,Study on the thixotropy of aluminum magnesium hydroxide-Na-montmorillonite suspension[J]Colloid Polym Sci,1998,276:274-277.
[161]任庆利,张赞锋,罗强.纳米晶镁铝水滑石的制备及其热分解机理[J]物理化学学报,2004,20:318-322
[162]N.Kobayashi,T.Honmyo,T.Katamoto,et al.Mg-Al based hydrotalcitetype particles,chlorine containing resin stabilizer and p rocess for p roducing the particles[P]US:6413639,2002-07-02.
[163]N.Kobayashi,T.Honmyo,T.Katamoto,et al,Mg-Al-based hydrotalcitetype particles,chlorine containing resin composition and process for producing the particles[P]US:200313951 1,2003-07-21.
[164]V.Ambrogi,G.Fardella,G.Grandolini,M.Nocchetti,L.Perioli,Effect of hydrotalcite-like compounds on the aqueous solubility of some poorly watersoluble drugs[J]J.Pharm.Sci.,2003,92(7):1407-1418.
[165]K.M.Tyner,S.R.Schiffman,E.P.Giannelis,Nanobiohybrids as delivery vehicles for camptothecin[J]J.Control.Release,2004,95(3):501-514
[166]孙辉,张慧,D.G.Evans,段雪,磁性药物.无机纳米复合材料的结构设计 与表征[J]科学通报,2004,49:2525-2530.
[167]M.Z.bin Hussein,Z.Zainal,A.H.Yahaya,D.W.V.Foo.Controlled release of a plant growth regulator,a-naphthaleneacetate from the lamella of Zn-Al-layered double hydroxide nanocomposite[J]J.Control.Release 2002,82:417-427
[168]孟锦宏,张慧,David G.Evans,段雪,新型层状农药缓/控释材料—草甘膦插层双金属 氢氧化物的超分子结构与缓释性能[J]科学通报,2005,50(3):208-214
[169]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.,2007,19:2679-2685
[170]杨巧珍,层状前驱体制备尖晶石铁氧体及其应用性能研究,博士论文2005,17-18.
[171]M.V.Villa,M.J.Sanchez-Martin and M.Sanchez-Camazano,Hydrotalcites and organo-hydrotalcites as sorbents for removing pesticides from water[J]J.Environ.Sci.Health,1999,34:509-525
[172]Cockett ect,Adsorption of materials[P]European Patent,0541358,May,1993
[173]R.Celis,W.C.Koskinen,A.M.Cecchi,G.A.Bresnahan,M.J.Carrisoza,M.A.Ulibarri,I.Pavlovic and M.C.Hermosin,Sorption of the ionizable pesticide imazamox by organo-clays and orgno-hydrotalcites[J]J.Environ.Sci.Health,1999,34:929-941
[174]R.Celis,W.C.Koskinen,M.C.Hermosin,M.A.Ulibarri,and J.Cornejo,Triadimefon Interactions with Organoclays and Organohydrotalcites[J]Soil Sci.Soc.Am.J.2000,64:36-43
[175]J.Inacio,C.Taviot-Gueho,C.Forano,J.P.Besse,Adsorption of MCPA pesticide by MgAl-layered double hydroxides[J]Appl.Clay Sci.2001,18:255-264
[176]F.Bruna,R.Celis,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Layered double hydroxides as adsorbents and carriers of the herbicide (4-chloro-2-methylphenoxy)acetic acid(MCPA):Systems Mg-Al,Mg-Fe and Mg-Al-Fe[J]J.Hazard.Mater.doi:10.1016/j.jhazmat.2009.03.038
[177]Y.H.Guo,D.F.Li,C.W.Hua,Y.H.Wang,E.B.Wang,Y.C.Zhou,S.H.Feng,Photocatalytic degradation of aqueous organocholorine pesticide on the layered double hydroxide pillared by Paratungstate Anion,Mg_(12)Al_6(OH)_(36)(W_7O_(24))·4H_2O[J]Appl.Catal.B:Environ.2001,30:337-349
[178]Y.W.You,H.T.Zhao,G.F.Vance,Adsorption of dicamba (3,6-dichloro-2-methoxy benzoic acid) in aqueous solution by calcined-layered double hydroxide[J]Appl.Clay Sci.2002,21:217-226
[179]M.Z.bin Hussein,C.W.Long,Synthesis of organo-mineral nanohybrid material:indole-2-carboxylate in the lamella of Zn-Al-layered double hydroxide[J]Mater.Chem.Phys.2004,85:427-431
[180]J.H.Meng,H.Zhang,D.G.Evans,X.Duan,Novel layered pesticide slow/controlled release materials-supramolecular structure and slow release property of glyphosate intercalated layered double hydroxides[J]Chinese Sci.Bull.2005,50:745-751
[181]F.Li,Y.F.Wang,Q.Z.Yang,D.G.Evans,C.Forano,X.Duan,Study on adsorption of glyphosate(N-phosphonomethyl glycine) pesticide on MgAl-layered double hydroxides in aqueous solution[J]J.Hazard.Mate.2005,125:89-95
[182]M.Lakraimi,A.Legrouri,A.Barroug,A.De Roy and J.P.Besse,Preparation of a new stable hybrid material by chloride-2,4-dichlorophenoxyacetate ion exchange into the zinc-aluminium-chloride layered double hydroxide[J]J.Mater.Chem.,2000,10:1007-1011
[183]I.Pavlovic,C.Barriga,M.C.Hermosin,J.Cornejo,M.A.Ulibarri,Adsorption of acidic pesticides 2,4-D,Clopyralid and Picloram on calcined hydrotalcite[J]Appl.Clay Sci.2005,30:125-133
[184]A.Legrouri,M.Lakraimi,A.Barroug,A.De Royc,J.P.Besse,Removal of the herbicide 2,4-dichlorophenoxyacetate from water to zinc-aluminium-chloride layered double hydroxides[J]Water Res.2005,39:3441-3448
[185]M.Z.bin Hussein,A.H.Yahay,Z.Zainal,L.H.Kian,Nanocomposite based controlled release formulation of an herbicide,2,4-dichlorophenoxyacetate incapsulated in zinc-aluminium-layered double hydroxide[J]Sci.Technol.Adv.Mater.2005,6:956-962
[186]Y.F.Chao,P.C.Chen,S.L.Wang,Adsorption of 2,4-D on Mg/Al-NO_3layered double hydroxides with varying layer charge density[J]Appl.Clay Sci.2008,40:193-200
[187]L.P.Cardoso,R.Celis,J.Cornejo,J.Valim,Layered Double Hydroxides as Supports for the Slow Release of Acid Herbicides[J]J.Agric.Food Chem.2006,54:5968-5975
[188]L.P.Cardoso,J.B.Valim,Study of acids herbicides removal by calcined Mg-Al-CO_3-LDH[J]J.Phys.Chem.Solids 2006,67:987-993
[189] M. A. Khan, C.-L. Choi, D.-H. Lee, M. Park, B.-K. Lim, J.-Y. Lee, J. Choi, Synthesis and properties of mecoprop-intercalated layered double hydroxide[J] J. Phys. Chem. Solids 2007, 68: 1591-1597
[190] F. Bruna, I. Pavlovic, R. Celis, C. Barriga, J. Cornejo, M.A. Ulibarri, Organohydrotalcites as novel supports for the slow release of the herbicide terbuthylazine[J] Appl. Clay Sci.2008, 42: 194-200
[191] Cockett ect, Adsorption of materials[P] U.S. Patent, 5,256,300, November, 1993
[192] Cockett ect, Sorbing agents[P] U.S. Patent, 5,360,547, Nov., 1994
[193] Bonora, Michela, Polyolefin or olefin copolymer films having improved light stabilitiy and pesticide resistance[P] European Patent, EP0690094(Al) Jan., 1996.
[194] Bonora, Michela, Polyolefin or olefin copolymer films having improved light stabilitiy and pesticide resistance, Canadian Patent, 2,152,580, Dec, 1995.
[195] Kuroda ect, Slow-releasing compositions containing hydrotalcites which have been intercalated with an organic anion and method of controlling insects and protecting fabric from insects[P] U.S. Patent, 5,595,747, Jan., 1997.
[196] Bonora, Stabilizer combination for synthetic organic polymers[P] U.S. Patent, 5,948,836, Sep., 1999.
[197] Bonora, Polyolefin or olefin copolymer films having improved light stability and pesticide resistance[P] U.S. Patent, 5,977,218, Nov., 1999
[198] Bonora, Use of sterically hindered amines in combination with a metal oxide or hydroxide to improve the light stabilitiy and pesticide resistance of polyolefin or olefin copolymer films[P] European Patent, EP0690094(Bl), Aug., 2002.
[1]L.Desigaux,M.B.Belkacem,P.Richard,J.Cellier,P.Leone,L.Cario,F.Leroux,C.Taviot-Gueho,and B.Pitard,Self-Assembly and Characterization of Layered Double Hydroxide/DNA Hybrids[J]Nano Letters 2006,16:199-204.
[2]J.-H.Choy,S.-Y.Kwak,J.-S.Park,Y.-J.Jeong,and J.Portier,Intercalative Nanohybrids of Nucleoside Monophosphates and DNA in Layered Metal Hydroxide[J]J.Am.Chem.Soc.1999,121:1399-1400.
[3]H.T.Zhao and G.F.Vance,Intercalation of carboxymethyl-α-cyclodextrin into magnesium-aluminum layered double hydroxide[J]J.Chem.Soc.Dalton.Trans.1997,1961-1965.
[4]U.Costantino,N.Coletti,M.Nocchetti,Anion Exchange of Methyl Orange into Zn-Al Synthetic Hydrotalcite and Photophysical Characterization of the Intercalates Obtained[J]Langmuir 1999,15:4454-4460.
[5]L.Perioli,V.Ambrogi,B.Bertini,M.Ricci,M.Nocchetti,L.Latterini,C.Rossi,Anionic clays for sunscreen agent safe use:Photoprotection,photostability and prevention of their skin penetration[J]Eur.J.Pharm.Biopharm.2006,62:185-193.
[6]H.Nakayama,N.Wada,M.Tsuhako,Intercalation of amino acids and peptides into Mg-Al layered double hydroxide by reconstruction method[J]Int.J.Pharm.2004,269:469-478.
[7]J.Inacio,C.Taviot-Gue'ho,C.Forano,J.P.Besse,Adsorption of MCPA pesticide by MgAl-layered double hydroxides[J]Appl.Clay Sci.2001,18:255-264
[8]S.B.Haderlein,K.W.Weissmahr,R.P.Schwazenbach,Specific adsorption of nitroaromatic explosives and pesticides to clays minerals[J]Environ.Sci.Technol.1996,30:612-622.
[9]Y.J.Li,B.Y.Gao,T.Wu,W.S.Chen,X.Li,B.Wang,Adsorption kinetics for removal of thiocyanate from aqueous solution by calcined hydrotalcite[J]Colloid Surface A 2008,325:38-43
[10]Y.S.Ho,AE.Ofomaja,Pseudo-second-order model for lead ion sorption from aqueous solutions onto palm kernel fiber[J]J.Hazard.Mater.2006,129:137-142
[11]Y.S.Ho,DAJ Wase,Forster CF,Batch nickel removal from aqueous solution by sphagnum moss peat[J]Water Res.1995,29:1327-1332
[12]Y.S.Ho,C.C.Wang,Pseudo-isotherms for the sorption of cadmium ion onto tree fern[J]Process.Biochem.2004,39:761-765
[13]X.F.Wu,Y.L.Hu,F.Zhao,Z.Z.Huang,D.Lei,Ion adsorption components in liquid/solid systems[J]J.Environ.Sci.2006,18:1167-1175
[14]T.C.Voice.,W.J.J.Weber,Sorbent concentration effects in liquid/solid partitioning[J]Environ.Sci.Technol.1985,19:789-796
[15]S.H.Han,W.G.Hou,Structure and the point of zero charge of magnesium aluminium hydroxide[J]J.Chem.Soc.,Faraday Trans.1998,94:915-918
[16]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.2007,19:2679-2685.
[17]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf Sci.2004,274,613-624.
[18]M.J.S.Dewar,E.G.Zoebisch,E.F.Healy,J.P.Stewart,Development and use of quantum mechanical molecular models.76.AM1:a new general purpose quantum mechanical molecular model[J]J.Am.Chem.Soc.1985,107,3902-3909.
[19]S.Carlino,The intercalation of carboxylic acids into layered double hydroxides:a critical evaluation and review of the different methods[J]Solid State Ionics 1997,98:73-84.
[1]M.Fernandez-Perez,E.Gonzalez-Pradas,M.D.Urena-Amate,Controlled Release of Imidacloprid from a Lignin Matrix:Water Release Kinetics and Soil Mobility Study[J]J.Agric.Food Chem.1998,46:3828-3834
[2]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.2004,274:613-624
[3]C.X.Liu,W.G.Hou,L.F.Li,Y.Li,S.J.Liu,Synthesis and characterization of 5-fluorocytosine intercalated Zn-Al layered double hydroxide[J]J.Solid State Chem.2008,181(8):1792-1797
[4]程丽鸿,赵静,吡虫啉/羧甲基壳聚糖凝胶球的制备及释放性能[J]精细化工2005,22:653-657
[5]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organo hydrotalcite[J]Appl.Clay Sci.2006,33:116-124
[6]M.C.Hermosin,M J.Calderon,J.-P.Aguer and J.Cornejo,Organoclays for controlled release of the herbicide fenuron[J]Pest.Manag.Sci.2001,57:803-809.
[7]M.Z.bin Hussein,Z.Zainal,A.H.Yahaya,D.W.V.Foo.Controlled release of a plant growth regulator,a-naphthaleneacetate from the lamella of Zn-Al-layered double hydroxide nanocomposite[J]J.Control.Release 2002,82:417-427
[1]L.Y.Wang,C.Li,M.Liu,D.G.Evans and X.Duan,Large continuous,transparent and oriented self-supporting films of layered double hydroxides with tunable chemical composition[J]Chem.Commun.,2007,123-125.
[2]L.Desigaux,M.B.Belkacem,P.Richard,J.Cellier,P.Leone,L.Cario,F.Leroux,C.Taviot-Gueho,and B.Pitard,Self-Assembly and Characterization of Layered Double Hydroxide/DNA Hybrids[J]Nano Letters,2006,16:199-204.
[3]J.-H.Choy,S.-Y.Kwak,J.-S.Park,Y.-J.Jeong,and J.Portier,Intercalative Nanohybrids of Nucleoside Monophosphates and DNA in Layered Metal Hydroxide[J]J.Am.Chem.Soc.,1999,121:1399-1400.
[4]L.Perioli,V.Ambrogi,B.Bertini,M.Ricci,M.Nocchetti,L.Latterini,C.Rossi,Anionic clays for sunscreen agent safe use:Photoprotection,photostability and prevention of their skin penetration[J]Eur.J.Pharm.Biopharm.,2006,62:185-193.
[5]L.Lv,J.He,M.Wei,D.G.Evans,X.Duan,Uptake of chloride ion from aqueous solution by calcined layered double hydroxides:Equilibrium and kinetic studies[J]Water Res.,2006,40:735-743.
[6]H.Morioka,H.Tagaya,M.Karasu,J.Kadokawa,and K.Chiba,Preparation of New Useful Mterials by Surface Modification of Inorganic Layered Compound[J]J.Solid State Chem.,1995,117:337-342.
[7]L.Mohanambe and S.Vasudevan,Insertion of Iodine in a Functionalized Inorganic Layered Solid[J]Inorg.Chem.,2004,43:6421-6425.
[8]W.-Y.Tseng,J.-T.Lin,C.-Y.Mou,S.Cheng,S.-B.Liu,P.P.Chu,and H.-W.Liu,Incorporation of C60 in Layered Double Hydroxide[J]J.Am.Chem.Soc.,1996,118:4411-4418
[9]Y.W.You,H.T.Zhao,G.F.Vance,Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]Colloid Surfaces A 2002,205:161-172
[10]Y.W.You,H.T.Zhao and G.F.Vance,Hybrid organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate:Preparation and adsorption characteristics[J]J.Mater.Chem.,2002,12:907-912
[11]M.Fernandez-Perez,E.Gonzalez-Pradas,and M.D.Urena-Amate,Controlled Release of Imidacloprid from a Lignin Matrix:Water Release Kinetics and Soil Mobility Study[J]J.Agric.Food Chem.,1998,46:3828-3834.
[12]F.Bruna,I.Pavlovic,C.Barriga,J.Cornejo,M.A.Ulibarri,Adsorption of pesticides Carbetamide and Metamitron on organohydrotalcite[J]Appl.Clay Sci.,2006,33:116-124
[13]Z.Z.Li,L.X.Wen,F.Liu,A.Q.Liu,Q.Wang,J.F.Chen,Fabrication of Novel Avermectin-porous Hollow Silica Nanoparticles(Av-PHSN)Carrier and Its Properties[J]Chinese J.Pest.Sci.,2005,7:275-281.
[14]H.T.Zhao,G.F.Vance,Intercalation of carboxymethyl-α-cyclodextrin into magnesium-aluminum layered double hydroxide[J]J.Chem.Soc.Dalton.Trans.,1997,1961-1965.
[15]H.T.Zhao and K.L.Nagy,Dodecyl sulfate-hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water[J]J.Colloid Interf.Sci.,2004,274:613-624.
[16]M.J.S.Dewar,E.G.Zoebisch,E.F.Healy,J.P.P.Stewart,Development and use of quantum mechanical molecular models.AM1:a new general purpose quantum mechanical molecular model[J]J.Am.Chem.Soc.,1985,107(13):3902-3907.
[17]K.Esumi,S.Yamamoto,Adsorption of sodium dodecyl sulfate on hydrotalcite and adsolubilization of 2-naphthol[J]Colloid Surface A,1998,137:385-388.
[18]J.-H.Yang,Y.-S.Han,M.Park,T.Park,S.-J.Hwang,and J.-H.Choy,New Inorganic-Based Drug Delivery System of Indole-3-Acetic Acid-Layered Metal Hydroxide Nanohybrids with Controlled Release Rate[J]Chem.Mater.,2007,19:2679-2685.
[1]张百臻,农药分析第三版[M]1988,202-203.
[2]郑华华,广西大学硕士学位论文,2006.
[3]王书瑞,山东大学硕士学位论文,2001.