分离高碳脂肪酸分子蒸馏工艺技术研究
|
摘要
通过采用高压水解法研究高芥酸菜籽油水解制备芥酸的工艺技术条件,分别对反应温度、时间、催化剂浓度和加水量进行单因素试验,优化确定了制备芥酸的工艺条件,芥酸制备工艺参数：反应温度150℃,时间9小时,催化剂浓度0.06g/ml,剂水比2：3。
通过对芥酸分子蒸馏小试工艺技术参数进行分析,研究了芥酸分子蒸馏装置结构形式、内部构件和装置辅助系统,分别对蒸馏温度、系统真空度、刮膜转速、进料速率及预热温度进行试验研究,试验确定了分离提纯芥酸的工艺技术参数：蒸馏温度210℃,系统真空度9Pa,刮膜转速85rpm,进料速率110g/h,预热温度80℃。
在小试实验工艺技术参数优化研究基础上,对分子蒸馏提纯芥酸中试蒸馏器及装置进行了设计和试验,推导计算出液膜厚度0.25mm,平均停留时间18s,分子蒸馏器的内径和高度分别为350mm和1200mm,加热蒸发面和内冷面面积分别为0.8m2和2.5m2,用导热油来进行加热,所选用导热油泵的流量为3m3/h。预热器换热面积为1m2；真空系统设计选用JZJ2X系列罗茨泵-旋片泵真空机组,抽气量70L/s。试验结果：芥酸收率可达52%,纯度高达92%。
The process technology conditions of preparation of erucic acid were studied by using high-pressure hydrolysis of erucic acid colza oil, and we did the single factor experiment of reaction temperature, time and amount of catalyst, amount of water to determine optimal conditions for erucic acid preparation. Erucic acid preparation process parameters were that: temperature was 150℃, the time was 9 hours, catalyst concentration was 0.06g/ml, agent water ratio was 2:3.
Technical parameters of erucic acid molecular distillation in the small scale were analyzed, we studied the structure of erucic acid in the form of molecular distillation, the internal components and devices support system and researched the distillation temperature, system vacuum, wiper speed, feed rate and preheat temperature, and determined acid technology parameters of the separation and purification of erucic:the distillation temperature 210℃, vacuum 9Pa, agitating speed 85rpm, the feed rate 110g/h, preheating temperature 80℃.
On the basis of optimization study of technical parameters in small scale, distiller and device were designed and tested in the molecular distillation pilot plant test for purification of erucic, the film thickness was designed 0.25mm, mean residence time was 18s, the inner diameter and height of molecular distiller were 350mm and 1200mm, the heated evaporation surface of molecular distiller and inner cold area were 0.8m2 and 2.5m2, conduction oil was used heated, the heat flow pump was 3m3/h, the heat transfer area of preheater was 1m2; JZJ2X series Roots pumps-Rotary Vane vacuum pump unit was designed and selected with the exhaust volume 70L/s. Test result was that:erucic acid yield was 52% and purity was up to 92%.
通过对芥酸分子蒸馏小试工艺技术参数进行分析,研究了芥酸分子蒸馏装置结构形式、内部构件和装置辅助系统,分别对蒸馏温度、系统真空度、刮膜转速、进料速率及预热温度进行试验研究,试验确定了分离提纯芥酸的工艺技术参数：蒸馏温度210℃,系统真空度9Pa,刮膜转速85rpm,进料速率110g/h,预热温度80℃。
在小试实验工艺技术参数优化研究基础上,对分子蒸馏提纯芥酸中试蒸馏器及装置进行了设计和试验,推导计算出液膜厚度0.25mm,平均停留时间18s,分子蒸馏器的内径和高度分别为350mm和1200mm,加热蒸发面和内冷面面积分别为0.8m2和2.5m2,用导热油来进行加热,所选用导热油泵的流量为3m3/h。预热器换热面积为1m2；真空系统设计选用JZJ2X系列罗茨泵-旋片泵真空机组,抽气量70L/s。试验结果：芥酸收率可达52%,纯度高达92%。
The process technology conditions of preparation of erucic acid were studied by using high-pressure hydrolysis of erucic acid colza oil, and we did the single factor experiment of reaction temperature, time and amount of catalyst, amount of water to determine optimal conditions for erucic acid preparation. Erucic acid preparation process parameters were that: temperature was 150℃, the time was 9 hours, catalyst concentration was 0.06g/ml, agent water ratio was 2:3.
Technical parameters of erucic acid molecular distillation in the small scale were analyzed, we studied the structure of erucic acid in the form of molecular distillation, the internal components and devices support system and researched the distillation temperature, system vacuum, wiper speed, feed rate and preheat temperature, and determined acid technology parameters of the separation and purification of erucic:the distillation temperature 210℃, vacuum 9Pa, agitating speed 85rpm, the feed rate 110g/h, preheating temperature 80℃.
On the basis of optimization study of technical parameters in small scale, distiller and device were designed and tested in the molecular distillation pilot plant test for purification of erucic, the film thickness was designed 0.25mm, mean residence time was 18s, the inner diameter and height of molecular distiller were 350mm and 1200mm, the heated evaporation surface of molecular distiller and inner cold area were 0.8m2 and 2.5m2, conduction oil was used heated, the heat flow pump was 3m3/h, the heat transfer area of preheater was 1m2; JZJ2X series Roots pumps-Rotary Vane vacuum pump unit was designed and selected with the exhaust volume 70L/s. Test result was that:erucic acid yield was 52% and purity was up to 92%.
引文
[1].吴关庭,郎春秀,陈锦清.芥酸的生产及其衍生产品开发[J].中国油脂,2007,32(6)：27-31.
[2].田跃信,王金顺,王红梅.四号溶剂提纯芥酸酰胺工艺[J].精细化工,2003,20(9)：541-542.
[3].杨鑫莉,胡生泳.芥酸酰胺的研制[J].精细石油化工,2009,5(3)：7-9.
[4].周茂洪,赵肖为,吴蓉蓉,等.反胶束酶水解法生产芥酸的工艺研究[J].科技通报,2006,22(3)：367-371.
[5].梁成满,黄少烈,朱宝璋.分子蒸馏法提纯芥酸酰胺[J].精细化工,2005,22(4)：272-274.
[6].周远.菜油脚提取芥酸方法的研究[J].粮油食品科技,2002,10(4)：11-13.
[7]. Nadson Murilo Nascimento Lima, Lamia Zuniga Linan, Flavio Manenti, et al. Fuzzy cognitive approach of a molecular distillation process[J]. Chemical Engineering Research and Design,2010,76 (3): 171-180.
[8]. L.V. Fregolente, P.B.L. Fregolente, A.M. Chicuta, et al. Effect of operating conditions on the concentration of monoglycerides using molecular distillation[J]. Chemical Engineering Research and Design,2007,85 (11):1524-1528.
[9].杨村,冯武文,于宏奇.分子蒸馏技术与绿色精细化工[J].精细化工,2005,22(5)：321-324.
[10].王虎,刘吉平,马超,等.分子蒸馏技术及应用[J].现代化工,2008,28(1)：132-135.
[11]. Fang Chen, Tongyi Cai, Guanghua Zhao, et al. Optimizing conditions for the purification of crude octacosanol extract from rice bran wax by molecular distillation analyzed using response surface methodology[J]. Journal of Food Engineering,2005,70 (1):47-53.
[12]. Luidy Rodriguez Posada, John Shi, Yukio Kakuda, et al. Extraction of tocotrienols from palm fatty acid distillates using molecular distillation[J]. Separation and Purification Technology,2007,57 (2): 220-229.
[13].于建华,李庆生,卢长兰.刮膜式分子蒸馏器流场特性的数值模拟研究[J].食品与机械,2008,24(2)：73-76.
[14].王淑华.分子蒸馏过程稀薄气体的流动及天然产物提纯的研究[D]：[硕士学位论文].天津：天津大学,2005.
[15].任艳奎.分子蒸馏技术提纯高沸点物系及数学模型的研究[D]：[硕士学位论文].天津：天津大学,2005.
[16].郑弢.分子蒸馏提纯三种天然产物及理论模型的研究[D]：[硕士学位论文].天津：天津大学,2004.
[17].应安国.刮膜分子蒸馏技术的应用及其过程模型的研究[D]:[硕士学位论文].天津：天津大学,2005.
[18].周冉.卤虾油营养成分的分子蒸馏法提取[D]:[硕士学位论文].天津：天津大学,2005.
[19].任艳君.深海鱼油和海狗油的分子蒸馏提纯研究[D]：[硕士学位论文].天津：天津大学,2006.
[20].林涛.分子蒸馏提纯合成维生素E的工艺及过程模型的研究[D]:[硕士学位论文].天津：天津大学,2009.
[21].梁峥,胡雪芳,赵航,等.分子蒸馏纯化姜精油工艺的响应面法优化[J].食品科学,2010,31(2)：67-71.
[22].王毅,张旭斌,李淑芬.惰性气体对分子蒸馏过程的影响[J].天津化工,2010,21(4)：30-32.
[23].黄蕾,李君.分子蒸馏技术[J].科技信息,2010,25(6)：23-24.
[24].栾礼侠.分子蒸馏分离上艺研究及其在物料分离中的应用[D]:[硕士学位论文].天津：天津大学,2005.
[25].闫广.分子蒸馏传热与传质过程数值模拟及实验研究[D]：[硕士学位论文].江苏：南京工业大学,2004.
[26].耿中峰.基于gPROMS的分子蒸馏过程研究[D]:[硕士学位论文].天津：天津大学,2007.
[27].朱宝璋,刘松,冯志豪.分子蒸馏在石油化工中的应用[J].化工进展,2009,28：41-44.
[28]. Shurong Wang, Yueling Gu, Qian Liu, et al. Separation of bio-oil by molecular distillation[J]. Fuel Processing Technology,2009,90(5):738-745.
[29].王珊珊.分子蒸馏法从脱臭馏出物中提取VE的研究[D]：[硕士学位论文].江苏：江南大学,2008.
[30]. E. B. Moraes, C. B. Batistella, M. E. Torres Alvarez, et al. Evaluation of Tocopherol Recovery Through Simulation of Molecular Distillation Process[J]. Applied Biochemistry and Biotechnology,2004,114(3): 689-711.
[31]. Xiujuan Guo, Shurong Wang, Zuogang Guo, et al. Pyrolysis characteristics of bio-oil fractions separated by molecular distillation[J]. Applied Energy,2010,87 (9):2892-2898.
[32].P.F. Martins, V.M. Ito, C.B. Batistella, et al. Free fatty acid separation from vegetable oil deodorizer distillate using molecular distillation process[J]. Separation and Purification Technology,2006,487(1): 78-84.
[33]. Moraes E B, Batistella C B, Alvarez M E, et al. Evaluation of tocopherol recovery thorough simulation of molecular fistillation process[J]. Applied Biochemistry and Biotechnolgy,2004,114(3):689-711.
[34]. David L. Compton, Joseph A. Laszlo, Fred J. Eller, et al. Purification of 1,2-diacylglycerols from vegetable oils:Comparison of molecular distillation and liquid CO2 extraction[J]. Industrial Crops and Products,2008,28(2):113-121.
[35].李红,王爱辉,刘延奇.分子蒸馏在油脂工业中的应用[J].中国油脂,2009,33(10)：57-59.
[36]. COMPTON D L, LASZLO J A, ELLER F J, et al. Purification of 1,2-diacylglycerols fromvegetable oils: comparison of molecular distillation and liquid CO2 extraction[J]. Industrial Crops and Products,2008, 28(2):113-121.
[37].连锦花,孙果宋,雷福厚.分子蒸馏技术及其应用[J].化工技术与开发,2010,39(7)：32-38.
[38].张旭斌,许春建,周明.降膜分子蒸馏过程模型研究[J].高校化学工程学报,2004,18(5)：558-563.
[39].李国兵,许春建,周明DBP-DBS刮膜分子蒸馏过程数值模拟[J].天津大学学报,2004,37(3)：196-202.
[40].翟志勇.离心式分子蒸馏器加热装置的研究[D]：[硕士学位论文].辽宁：大连理工大学,2001.
[41]. Yong Wang, Mourning Zhao, Keke Song, et al. Separation of diacylglycerols from enzymatically hydrolyzed soybean oil by molecular distillation[J]. Separation and Purification Technology,2010,75 (2):114-120.
[42]. Steven C. Cermak, Amber L. John, Roque L. Evangelista. Enrichment of decanoic acid in cuphea fatty acidsby molecular distillation[J]. Industrial Crops and Product,2007,26 (1):93-99.
[43]. Miriam Martinello, Gonzalo Hecker, Mariadel Carmen Pramparo. Grape seed oil deacidification by molecular distillation:Analysis ofoperative variables influence using the response surface methodology[J]. Journal of Food Engineering,2007,81 (1):60-64..
[44]. POSADA L R, SHI J, KAKUDA Y, et al. Extraction of tocotrienols from palm fatty acid distillates using molecular distillation[J]. Separation and Purification Technology,2007,57(2):220-229.
[45].毕艳红.分子蒸馏技术分离提纯大蒜精油的研究[D]:[硕士学位论文].山东：山东农业大学,2007.
[46].刘颖.功能性油脂分子蒸馏分离及其化学成分分析研究[D]：[硕十学位论文].天津：天津大学, 2006.
[47].向爱双.刮膜式分子蒸馏精制3-羟基丙腈及其蒸发液膜流场的CFD模拟[D]：[硕士学位论文].天津：天津大学,2004.
[48].王昌禄,吴志建,郭剑霞,等.分子蒸馏纯化亚油酸的工艺条件优化[J].天津科技大学学报,2010,25(5)：17-20.
[49].白宇,张炳南,高昌保,等.分子蒸馏过程技术研究及其应用进展[J].化工装备技术,2009,30(1)：9-12.
[50].车怀智,魏冰.分子蒸馏法亚麻酸乙酯的中试制备[J].陕西科技大学学报,2009,27(5)：68-71
[51].王丽华,丁红军,李尔春,等.分子蒸馏技术在食品工业中的应用[J].食品与药品,2007,9(10)：72-73.
[52].周松锐.短程蒸馏传热传质研究及其在废润滑油再生中的应用[D]：[硕士学位论文].四川：四川大学工程学院,2007.
[53].吴斌,阮孟法.利用分子蒸馏技术再生废旧轧制油[J].广东化工,2008,35(8)：78-80.
[54].Zuogang Guo, Shurong Wang, Yueling Gu, et al. Separation characteristics of biomass pyrolysis oil in molecular distillation[J]. Separation and Purification Technology,2010,76(1):52-57.
[55].谢静,阚建全.分子蒸馏技术纯化花椒籽油中α-亚麻酸的研究[J].食品工业科技,2010,(10)：294-299.
[56].曾世祥,唐成志.应用分子蒸馏中试设备进行肉桂油提纯的研究[J].广西轻工业,2010,(9)：5-7.
[57].肖斌,朱雪莲.菜籽油馏出物中维生素E的分子蒸馏工艺研究[J].广州化工,2010,38(6)：133-135.
[58].Moraes E B, Batistella C B, Alvarez M E, et al. Evaluation of tocopherol recovery thorough simulation of molecular fistillation process[J]. Applied Biochemistry and Biotechnolgy,2004,114(3):689-711.
[59]. Osamu M, Ikukazu T, Masamil B. Method of concentrateing minor ingredients in oily matters obtained from plant tissue[J]. Journal of the American Oil Chemists'Society,2006,78(4):477-484.
[60]. Patricia Bogalhos Lucente Fregolente, Glaucia Maria F. Pinto, Rubens Maciel Filho, et al. Monoglyceride and Diglyceride Production Through Lipase-Catalyzed Glycerolysis and Molecular Distillation[J]. Applied Biochemistry and Biotechnology,2010,160(7):1879-1887.
[61].陈必,郭晓东,许志杰,等.分子蒸馏及其在多不饱和脂肪酸中的应用[J].食品工程,2007,15(3)：14-16.
[62].王燕飞,许松林.分子蒸馏过程的计算流体力学模拟[J].化学工程,2010,38(1)：30-34.
[63].陈志刚,李月兰.分子蒸馏技术研究进展[J].广东化工,2007,34(8)：48-54.
[64].周本杰,冯丽娟.分子蒸馏技术筛选退热止痛散镇痛活性部位研究[J].中国药房,2008,19(3)：2326-2327.
[65].苏小建,方健,陈孟林,等.分子蒸馏八角茴香油微波催化氧化茴香脑制备茴香醛[J].精细化工,2009,26(4)：386-390.
[66].呼晓姝,王建中.响应面法优化分子蒸馏提纯神经酸要艺的研究[J].中国粮油学报,2009,24(6)：123-127.
[67].郭永来,吕传润,赵杰,等.利用分子蒸馏技术提取玫瑰油的工艺研究[J].香料香精化妆品,2010,(4)：11-13.
[68].王文渊,张芸兰,龙红萍,等.分子蒸馏技术分离纯化橘皮油中柠檬烯[J].食品研究与开发,2010,31(10)：59-62.
[69].王丽华,丁红军,李尔春,等.分子蒸馏技术在食品工业中的应用[J].食品与药品,2007,9(10)：72-73.
[70].王成章,叶建中,郑光耀,等.分子短程蒸馏和重结晶分离银杏叶甾醇类化合物的研[J].林产化学与工业,2008,28(2)：43-47.
[71].翟淑红,黄少烈,顾志伟.茶树油的分子蒸馏精制及其GC/MS分析[J].广州化工,2008,35(1)：97-100.
[72].许松林,郭凯.刮膜式分子蒸馏装置中的液膜状态实验[J].天津大学学报,2010,43(6)：544-548.
[73].陈光尧,王国槐.高芥酸油菜利用与研究[J].作物研究,2004,20(5)：366-368.
[74].江勇,王兴国,孙继平.芥酸及其衍生物制取[J].粮食与油脂,2002,22(3)：30-32.
[75].陈媛,陈智斌.菜籽油脂肪酸中芥酸提取浅议[J].中国油脂,2000,25(6)：157-158.
[2].田跃信,王金顺,王红梅.四号溶剂提纯芥酸酰胺工艺[J].精细化工,2003,20(9)：541-542.
[3].杨鑫莉,胡生泳.芥酸酰胺的研制[J].精细石油化工,2009,5(3)：7-9.
[4].周茂洪,赵肖为,吴蓉蓉,等.反胶束酶水解法生产芥酸的工艺研究[J].科技通报,2006,22(3)：367-371.
[5].梁成满,黄少烈,朱宝璋.分子蒸馏法提纯芥酸酰胺[J].精细化工,2005,22(4)：272-274.
[6].周远.菜油脚提取芥酸方法的研究[J].粮油食品科技,2002,10(4)：11-13.
[7]. Nadson Murilo Nascimento Lima, Lamia Zuniga Linan, Flavio Manenti, et al. Fuzzy cognitive approach of a molecular distillation process[J]. Chemical Engineering Research and Design,2010,76 (3): 171-180.
[8]. L.V. Fregolente, P.B.L. Fregolente, A.M. Chicuta, et al. Effect of operating conditions on the concentration of monoglycerides using molecular distillation[J]. Chemical Engineering Research and Design,2007,85 (11):1524-1528.
[9].杨村,冯武文,于宏奇.分子蒸馏技术与绿色精细化工[J].精细化工,2005,22(5)：321-324.
[10].王虎,刘吉平,马超,等.分子蒸馏技术及应用[J].现代化工,2008,28(1)：132-135.
[11]. Fang Chen, Tongyi Cai, Guanghua Zhao, et al. Optimizing conditions for the purification of crude octacosanol extract from rice bran wax by molecular distillation analyzed using response surface methodology[J]. Journal of Food Engineering,2005,70 (1):47-53.
[12]. Luidy Rodriguez Posada, John Shi, Yukio Kakuda, et al. Extraction of tocotrienols from palm fatty acid distillates using molecular distillation[J]. Separation and Purification Technology,2007,57 (2): 220-229.
[13].于建华,李庆生,卢长兰.刮膜式分子蒸馏器流场特性的数值模拟研究[J].食品与机械,2008,24(2)：73-76.
[14].王淑华.分子蒸馏过程稀薄气体的流动及天然产物提纯的研究[D]：[硕士学位论文].天津：天津大学,2005.
[15].任艳奎.分子蒸馏技术提纯高沸点物系及数学模型的研究[D]：[硕士学位论文].天津：天津大学,2005.
[16].郑弢.分子蒸馏提纯三种天然产物及理论模型的研究[D]：[硕士学位论文].天津：天津大学,2004.
[17].应安国.刮膜分子蒸馏技术的应用及其过程模型的研究[D]:[硕士学位论文].天津：天津大学,2005.
[18].周冉.卤虾油营养成分的分子蒸馏法提取[D]:[硕士学位论文].天津：天津大学,2005.
[19].任艳君.深海鱼油和海狗油的分子蒸馏提纯研究[D]：[硕士学位论文].天津：天津大学,2006.
[20].林涛.分子蒸馏提纯合成维生素E的工艺及过程模型的研究[D]:[硕士学位论文].天津：天津大学,2009.
[21].梁峥,胡雪芳,赵航,等.分子蒸馏纯化姜精油工艺的响应面法优化[J].食品科学,2010,31(2)：67-71.
[22].王毅,张旭斌,李淑芬.惰性气体对分子蒸馏过程的影响[J].天津化工,2010,21(4)：30-32.
[23].黄蕾,李君.分子蒸馏技术[J].科技信息,2010,25(6)：23-24.
[24].栾礼侠.分子蒸馏分离上艺研究及其在物料分离中的应用[D]:[硕士学位论文].天津：天津大学,2005.
[25].闫广.分子蒸馏传热与传质过程数值模拟及实验研究[D]：[硕士学位论文].江苏：南京工业大学,2004.
[26].耿中峰.基于gPROMS的分子蒸馏过程研究[D]:[硕士学位论文].天津：天津大学,2007.
[27].朱宝璋,刘松,冯志豪.分子蒸馏在石油化工中的应用[J].化工进展,2009,28：41-44.
[28]. Shurong Wang, Yueling Gu, Qian Liu, et al. Separation of bio-oil by molecular distillation[J]. Fuel Processing Technology,2009,90(5):738-745.
[29].王珊珊.分子蒸馏法从脱臭馏出物中提取VE的研究[D]：[硕士学位论文].江苏：江南大学,2008.
[30]. E. B. Moraes, C. B. Batistella, M. E. Torres Alvarez, et al. Evaluation of Tocopherol Recovery Through Simulation of Molecular Distillation Process[J]. Applied Biochemistry and Biotechnology,2004,114(3): 689-711.
[31]. Xiujuan Guo, Shurong Wang, Zuogang Guo, et al. Pyrolysis characteristics of bio-oil fractions separated by molecular distillation[J]. Applied Energy,2010,87 (9):2892-2898.
[32].P.F. Martins, V.M. Ito, C.B. Batistella, et al. Free fatty acid separation from vegetable oil deodorizer distillate using molecular distillation process[J]. Separation and Purification Technology,2006,487(1): 78-84.
[33]. Moraes E B, Batistella C B, Alvarez M E, et al. Evaluation of tocopherol recovery thorough simulation of molecular fistillation process[J]. Applied Biochemistry and Biotechnolgy,2004,114(3):689-711.
[34]. David L. Compton, Joseph A. Laszlo, Fred J. Eller, et al. Purification of 1,2-diacylglycerols from vegetable oils:Comparison of molecular distillation and liquid CO2 extraction[J]. Industrial Crops and Products,2008,28(2):113-121.
[35].李红,王爱辉,刘延奇.分子蒸馏在油脂工业中的应用[J].中国油脂,2009,33(10)：57-59.
[36]. COMPTON D L, LASZLO J A, ELLER F J, et al. Purification of 1,2-diacylglycerols fromvegetable oils: comparison of molecular distillation and liquid CO2 extraction[J]. Industrial Crops and Products,2008, 28(2):113-121.
[37].连锦花,孙果宋,雷福厚.分子蒸馏技术及其应用[J].化工技术与开发,2010,39(7)：32-38.
[38].张旭斌,许春建,周明.降膜分子蒸馏过程模型研究[J].高校化学工程学报,2004,18(5)：558-563.
[39].李国兵,许春建,周明DBP-DBS刮膜分子蒸馏过程数值模拟[J].天津大学学报,2004,37(3)：196-202.
[40].翟志勇.离心式分子蒸馏器加热装置的研究[D]：[硕士学位论文].辽宁：大连理工大学,2001.
[41]. Yong Wang, Mourning Zhao, Keke Song, et al. Separation of diacylglycerols from enzymatically hydrolyzed soybean oil by molecular distillation[J]. Separation and Purification Technology,2010,75 (2):114-120.
[42]. Steven C. Cermak, Amber L. John, Roque L. Evangelista. Enrichment of decanoic acid in cuphea fatty acidsby molecular distillation[J]. Industrial Crops and Product,2007,26 (1):93-99.
[43]. Miriam Martinello, Gonzalo Hecker, Mariadel Carmen Pramparo. Grape seed oil deacidification by molecular distillation:Analysis ofoperative variables influence using the response surface methodology[J]. Journal of Food Engineering,2007,81 (1):60-64..
[44]. POSADA L R, SHI J, KAKUDA Y, et al. Extraction of tocotrienols from palm fatty acid distillates using molecular distillation[J]. Separation and Purification Technology,2007,57(2):220-229.
[45].毕艳红.分子蒸馏技术分离提纯大蒜精油的研究[D]:[硕士学位论文].山东：山东农业大学,2007.
[46].刘颖.功能性油脂分子蒸馏分离及其化学成分分析研究[D]：[硕十学位论文].天津：天津大学, 2006.
[47].向爱双.刮膜式分子蒸馏精制3-羟基丙腈及其蒸发液膜流场的CFD模拟[D]：[硕士学位论文].天津：天津大学,2004.
[48].王昌禄,吴志建,郭剑霞,等.分子蒸馏纯化亚油酸的工艺条件优化[J].天津科技大学学报,2010,25(5)：17-20.
[49].白宇,张炳南,高昌保,等.分子蒸馏过程技术研究及其应用进展[J].化工装备技术,2009,30(1)：9-12.
[50].车怀智,魏冰.分子蒸馏法亚麻酸乙酯的中试制备[J].陕西科技大学学报,2009,27(5)：68-71
[51].王丽华,丁红军,李尔春,等.分子蒸馏技术在食品工业中的应用[J].食品与药品,2007,9(10)：72-73.
[52].周松锐.短程蒸馏传热传质研究及其在废润滑油再生中的应用[D]：[硕士学位论文].四川：四川大学工程学院,2007.
[53].吴斌,阮孟法.利用分子蒸馏技术再生废旧轧制油[J].广东化工,2008,35(8)：78-80.
[54].Zuogang Guo, Shurong Wang, Yueling Gu, et al. Separation characteristics of biomass pyrolysis oil in molecular distillation[J]. Separation and Purification Technology,2010,76(1):52-57.
[55].谢静,阚建全.分子蒸馏技术纯化花椒籽油中α-亚麻酸的研究[J].食品工业科技,2010,(10)：294-299.
[56].曾世祥,唐成志.应用分子蒸馏中试设备进行肉桂油提纯的研究[J].广西轻工业,2010,(9)：5-7.
[57].肖斌,朱雪莲.菜籽油馏出物中维生素E的分子蒸馏工艺研究[J].广州化工,2010,38(6)：133-135.
[58].Moraes E B, Batistella C B, Alvarez M E, et al. Evaluation of tocopherol recovery thorough simulation of molecular fistillation process[J]. Applied Biochemistry and Biotechnolgy,2004,114(3):689-711.
[59]. Osamu M, Ikukazu T, Masamil B. Method of concentrateing minor ingredients in oily matters obtained from plant tissue[J]. Journal of the American Oil Chemists'Society,2006,78(4):477-484.
[60]. Patricia Bogalhos Lucente Fregolente, Glaucia Maria F. Pinto, Rubens Maciel Filho, et al. Monoglyceride and Diglyceride Production Through Lipase-Catalyzed Glycerolysis and Molecular Distillation[J]. Applied Biochemistry and Biotechnology,2010,160(7):1879-1887.
[61].陈必,郭晓东,许志杰,等.分子蒸馏及其在多不饱和脂肪酸中的应用[J].食品工程,2007,15(3)：14-16.
[62].王燕飞,许松林.分子蒸馏过程的计算流体力学模拟[J].化学工程,2010,38(1)：30-34.
[63].陈志刚,李月兰.分子蒸馏技术研究进展[J].广东化工,2007,34(8)：48-54.
[64].周本杰,冯丽娟.分子蒸馏技术筛选退热止痛散镇痛活性部位研究[J].中国药房,2008,19(3)：2326-2327.
[65].苏小建,方健,陈孟林,等.分子蒸馏八角茴香油微波催化氧化茴香脑制备茴香醛[J].精细化工,2009,26(4)：386-390.
[66].呼晓姝,王建中.响应面法优化分子蒸馏提纯神经酸要艺的研究[J].中国粮油学报,2009,24(6)：123-127.
[67].郭永来,吕传润,赵杰,等.利用分子蒸馏技术提取玫瑰油的工艺研究[J].香料香精化妆品,2010,(4)：11-13.
[68].王文渊,张芸兰,龙红萍,等.分子蒸馏技术分离纯化橘皮油中柠檬烯[J].食品研究与开发,2010,31(10)：59-62.
[69].王丽华,丁红军,李尔春,等.分子蒸馏技术在食品工业中的应用[J].食品与药品,2007,9(10)：72-73.
[70].王成章,叶建中,郑光耀,等.分子短程蒸馏和重结晶分离银杏叶甾醇类化合物的研[J].林产化学与工业,2008,28(2)：43-47.
[71].翟淑红,黄少烈,顾志伟.茶树油的分子蒸馏精制及其GC/MS分析[J].广州化工,2008,35(1)：97-100.
[72].许松林,郭凯.刮膜式分子蒸馏装置中的液膜状态实验[J].天津大学学报,2010,43(6)：544-548.
[73].陈光尧,王国槐.高芥酸油菜利用与研究[J].作物研究,2004,20(5)：366-368.
[74].江勇,王兴国,孙继平.芥酸及其衍生物制取[J].粮食与油脂,2002,22(3)：30-32.
[75].陈媛,陈智斌.菜籽油脂肪酸中芥酸提取浅议[J].中国油脂,2000,25(6)：157-158.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |