基于煤气化的IGCC-甲醇多联产系统的模拟与优化
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摘要
本文利用Aspen Plus软件模拟子IGCC-甲醇多联产系统,并对该系统进行子节能分析。对气化炉建立了一维修正模型,分析了煤种、颗粒粒径、颗粒停留时间分布对气化炉出口的组成、温度和碳转化率的影响。
考察的IGCC-甲醇多联产系统配置方案中气化工艺分别采用废锅流程和激冷流程,IGCC和甲醇合成组合方式分别采用串联和并联。以相对节能率作为指标,对多联产系统进行了能耗分析。结果表明：废锅流程节能效果优于激冷流程。废锅并联组合通往甲醇侧的合成气比例增大时,相对节能率增大；废锅串联组合甲醇合成圈循环比增加时,相对节能率增大。本文采用分摊算法分别计算了废锅并联多联产系统发电和甲醇合成的煤耗。结果显示,随着通往甲醇合成侧的合成气量的增加,供电煤耗显著减少,甲醇合成煤耗略有减少。
本文在考虑颗粒停留时间分布和反应动力学的基础上,建立气化炉的一维修正模型,该模型包含煤粒脱挥发份和挥发份燃烧子程序、气化子程序和传热子程序。通过该模型计算得到了气化炉出口气相组成和总碳转化率,以及颗粒相在气化炉中的温度分布和不同粒径的颗粒的碳转化率,考察了煤种动力学参数等对气化炉出口的组成、温度和碳转化率的影响。
The IGCC-methanol polygeneration systems were simulated using Aspen Plus software. Energy saving of IGCC-methanol polygeneration system was analysed.An improved one-dimensional steady-state model for an entrained flow coal gasifier was developed in this thesis.
In order to evaluate the configurations of the IGCC-methanol polygeneration system based on entrained-bed pulverized coal gasification, the polygeneration systems were simulated using Aspen Plus software. Different configurations, including waste heat boiler process/quench process and series/parallel combination of IGCC and methanol synthesis were evaluated by caculating the relative energy saving ratio.The results show that the waste heat boiler process is more energy-efficient than the quench process. For the parallel polygeneration systems with waste heat boiler process, the relative energy saving ratio increases when the proportion of the synthesis gas to methanol side increases. For the series polygeneration systems with waste heat boiler process, the relative energy saving ratio increases when the proportion of cycle gas increases in the methanol synthesis process. Based on allocation of energy, coal consumption of methanol synthesis and power generation of the IGCC-methanol parallel system with waste heat boiler process were calculated respectively.
Because the one-dimensional model is reasonable simplified and its computing speed is very fast,it is suited to be used in the simulation study of polygeneration systems.In this study, an improved one-dimensional model for entrained flow coal gasifier was built by considering kinetics of heterogeneous and homogeneous reactions and residence time distribution of particles. This model includes the coal pyrolysis and volatile combustion subroutine, gasification subroutine and heat balances subroutine.The temperature and composition of the syngas of the coal gasifier, the distribution of gas composition,temperature and carbon conversion of particles was caculated by using the model. The effect of coal type and particle diameter on the the distribution of gas composition,temperature and carbon conversion was analysed.
考察的IGCC-甲醇多联产系统配置方案中气化工艺分别采用废锅流程和激冷流程,IGCC和甲醇合成组合方式分别采用串联和并联。以相对节能率作为指标,对多联产系统进行了能耗分析。结果表明：废锅流程节能效果优于激冷流程。废锅并联组合通往甲醇侧的合成气比例增大时,相对节能率增大；废锅串联组合甲醇合成圈循环比增加时,相对节能率增大。本文采用分摊算法分别计算了废锅并联多联产系统发电和甲醇合成的煤耗。结果显示,随着通往甲醇合成侧的合成气量的增加,供电煤耗显著减少,甲醇合成煤耗略有减少。
本文在考虑颗粒停留时间分布和反应动力学的基础上,建立气化炉的一维修正模型,该模型包含煤粒脱挥发份和挥发份燃烧子程序、气化子程序和传热子程序。通过该模型计算得到了气化炉出口气相组成和总碳转化率,以及颗粒相在气化炉中的温度分布和不同粒径的颗粒的碳转化率,考察了煤种动力学参数等对气化炉出口的组成、温度和碳转化率的影响。
The IGCC-methanol polygeneration systems were simulated using Aspen Plus software. Energy saving of IGCC-methanol polygeneration system was analysed.An improved one-dimensional steady-state model for an entrained flow coal gasifier was developed in this thesis.
In order to evaluate the configurations of the IGCC-methanol polygeneration system based on entrained-bed pulverized coal gasification, the polygeneration systems were simulated using Aspen Plus software. Different configurations, including waste heat boiler process/quench process and series/parallel combination of IGCC and methanol synthesis were evaluated by caculating the relative energy saving ratio.The results show that the waste heat boiler process is more energy-efficient than the quench process. For the parallel polygeneration systems with waste heat boiler process, the relative energy saving ratio increases when the proportion of the synthesis gas to methanol side increases. For the series polygeneration systems with waste heat boiler process, the relative energy saving ratio increases when the proportion of cycle gas increases in the methanol synthesis process. Based on allocation of energy, coal consumption of methanol synthesis and power generation of the IGCC-methanol parallel system with waste heat boiler process were calculated respectively.
Because the one-dimensional model is reasonable simplified and its computing speed is very fast,it is suited to be used in the simulation study of polygeneration systems.In this study, an improved one-dimensional model for entrained flow coal gasifier was built by considering kinetics of heterogeneous and homogeneous reactions and residence time distribution of particles. This model includes the coal pyrolysis and volatile combustion subroutine, gasification subroutine and heat balances subroutine.The temperature and composition of the syngas of the coal gasifier, the distribution of gas composition,temperature and carbon conversion of particles was caculated by using the model. The effect of coal type and particle diameter on the the distribution of gas composition,temperature and carbon conversion was analysed.
引文
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