喷雾热解法制备SrAl_2O_4:Eu~（2+），Dy~（3+）及其性能表征
摘要
本文综述了稀土离子激活的碱土铝酸盐蓄光材料的研究现状,特别是铕镝共激活的碱土铝酸锶长余辉材料的发展历程、研究现状、制备方法以及发光机理。采用喷雾热解法合成了球形SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,研究了不同制备工艺条件对SrAl_2O_4:Eu~(2+),Dy~(3+)发光材料的结构、形貌、粒度分布、余辉性能及光谱性能的影响,并与高温固相法所制备的SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料进行了对比。实验结果表明:
采用高温固相法制备了SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,SrAl_2O_4:Eu~(2+),Dy~(3+)的晶体结构与ɑ-SrAl_2O_4磷石英晶体结构相同,掺杂Eu、Dy对晶体结构的影响很小。助熔剂硼酸的使用不但能降低合成温度,还能增强发光材料的余辉性能。硼酸用量的变化对SrAl_2O_4:Eu~(2+),Dy~(3+)发射光谱特征峰位的影响不大。对于SrAl_2O_4:Eu~(2+)体系的发光材料,其最佳辅助激活剂是Dy~(3+),Dy~(3+)的引入能显著增强发光材料的余辉性能,但不会改变发射光谱的形状和特征峰位,当Eu~(2+)与Dy~(3+)的比值为0.01:0.02时,可获得余辉性能较好的SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料。高温固相法制备SrAl_2O_4:Eu~(2+),Dy~(3+)的还原温度在1350℃,还原时间为3h时,可获得余辉性能较好的长余辉发光材料。
采用喷雾热解两段法制备了球形SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,SrAl_2O_4:Eu~(2+),Dy~(3+)的晶体结构与ɑ-SrAl_2O_4磷石英晶体结构相同,掺杂Eu、Dy对晶体结构的影响很小。前驱体溶液浓度、热解温度和还原温度对产物的形貌、粒度分布、发光性能有较大影响。随着还原温度的升高,产物的发射主峰位置发生红移。
助熔剂H_3BO_3的引入不但能降低合成温度,还能有效地提高发光材料的余辉性能,当硼酸的用量为3.5mol%时,可以形成较好的SrAl_2O_4晶体,且发光材料具有好的余辉性能和形貌。随着硼酸用量的增加,长余辉发光材料的激发光谱出现“蓝移”现象。
添加剂的使用能明显改善和修饰材料的形貌、增强材料的初始亮度、延长材料的余辉时间(柠檬酸的使用会缩短材料的余辉时间)。柠檬酸的加入有助于获得实心球形颗粒,乙醇除了良好的分散性,还能有效的增大颗粒的球形度,但无法获得实心颗粒,PEG能够起到分散剂和稳定剂的作用。当三种添加剂同时使用时可获得初始亮度高、余辉时间长、分散性好、粒度小、粒径分布窄(2μm～5μm)的实心球形颗粒。它们的最佳加入量为:柠檬酸为0.3g/L;PEG为0.03mol/L;乙醇为40ml/L。
喷雾热解法制备的SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,较之高温固相法所制备的具有合成温度低、分散性好、粒度小、粒径分布窄(2μm～5μm)、形貌规则(实心球形)、发光亮度高、余辉时间长(>65h)等优点。
In this paper,the development course,research status,preparation method and the emitting mechanism of rare earth ions actived alkaline aluminates salt light-storing materials,especially of SrAl_2O_4:Eu~(2+),Dy~(3+) long afterglow luminescence materials were summarized.The spherical SrAl_2O_4:Eu~(2+),Dy~(3+) was synthesized by a two-step spray pyrolysis process.The structure,morphology,luminous performances and Spectral properties of SrAl_2O_4:Eu~(2+),Dy~(3+) at different preparation technology conditions were studied.and compared with the preparation methods of solid state reaction at a high temperature.The results showed that:
The SrAl_2O_4:Eu~(2+),Dy~(3+) prepared by solid state reaction at a high temperature belongs to theɑ-SrAl2O4 phosphor crystal structure . Small amount of Eu、Dy introduced into the mixture did not affect the crystal structure of SrAl2O4.The flux H3BO3 could not only reduce the synthesis temperature, but also enhance the afterlow performance. The shape of the emission spectrum of SrAl_2O_4:Eu~(2+),Dy~(3+) did not be changed by the use of flux H3BO3. Dy3+ was the best auxiliary activators for SrA12O4:Eu2+ luminescence materials, Dy3+ could enhance the afterlow performance and won't change the peak location of its emission spectrum. The best composition of the prepared material with better afterlow performance was Sr0.97Al2O4:Eu0.01,Dy0.02. The SrAl_2O_4:Eu,Dy luminescence materials with better afterlow performance could be obtained by solid state reaction method when reduction temperature was 1350℃and reduction time was 3h .
The SrAl_2O_4:Eu~(2+),Dy~(3+) prepared by spray pyrolysis belongs to theɑ-SrAl2O4 phosphor crystal structure and small amount of Eu、Dy introduced into the mixture did not affect the crystal structure of SrAl2O4. The morphology,size distribution and luminous performances of the phosphors could be affected with synthesizing conditions, such as precursor concentration, sintering temperature, reduction temperature etc. As the reduction temperature rised, red shift of the main peak position in the emission spectrum had occurred (move to longer wavelengths).
H3BO3 could not only reduce the synthesis temperature, but also enhance the afterlow performance.The SrAl_2O_4:Eu~(2+),Dy~(3+) with better crystals,good luminous performance and morphology was syshtesised when the adding quantity of H3BO3 was 3.5mol%.As the add amount of H3BO3 increased,(2.5mol%～5mol%),the long afterlow material inspire spectra appear "blue shift" phenomenon.
Additives caould obviously improve the morphology,reinforce the initial brightness,enlarge the afterlow time (citric acid would shorten the afterlow time).Citric acid could help to obtain solid spherical particle. Ethanol was not only a good dispersant but also increased the sphericity of particle, howerve, solid spherical particles couldn't be gotten in this condition. PEG played the role of dispersant and stabilizer. The solid spherical SrAl_2O_4:Eu~(2+),Dy~(3+) particles with high initial brightness, long twilight time, good dispersion, small particle size and narrow particle size distribution (2μm~5μm) when these additives used at the same time.Their best addition amount were citric acid of 0.3g/L, PEG of 0.03mol/L, ethanol of 40ml/L.
Compared with solid state method,the SrAl_2O_4:Eu~(2+),Dy~(3+) with more regular morphology,smaller particle size, narrower particle size distribution and more excellent luminescent properties could be prepared by spray pyrolysis, and the synthesis temperature can be significantly reduced.
采用高温固相法制备了SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,SrAl_2O_4:Eu~(2+),Dy~(3+)的晶体结构与ɑ-SrAl_2O_4磷石英晶体结构相同,掺杂Eu、Dy对晶体结构的影响很小。助熔剂硼酸的使用不但能降低合成温度,还能增强发光材料的余辉性能。硼酸用量的变化对SrAl_2O_4:Eu~(2+),Dy~(3+)发射光谱特征峰位的影响不大。对于SrAl_2O_4:Eu~(2+)体系的发光材料,其最佳辅助激活剂是Dy~(3+),Dy~(3+)的引入能显著增强发光材料的余辉性能,但不会改变发射光谱的形状和特征峰位,当Eu~(2+)与Dy~(3+)的比值为0.01:0.02时,可获得余辉性能较好的SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料。高温固相法制备SrAl_2O_4:Eu~(2+),Dy~(3+)的还原温度在1350℃,还原时间为3h时,可获得余辉性能较好的长余辉发光材料。
采用喷雾热解两段法制备了球形SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,SrAl_2O_4:Eu~(2+),Dy~(3+)的晶体结构与ɑ-SrAl_2O_4磷石英晶体结构相同,掺杂Eu、Dy对晶体结构的影响很小。前驱体溶液浓度、热解温度和还原温度对产物的形貌、粒度分布、发光性能有较大影响。随着还原温度的升高,产物的发射主峰位置发生红移。
助熔剂H_3BO_3的引入不但能降低合成温度,还能有效地提高发光材料的余辉性能,当硼酸的用量为3.5mol%时,可以形成较好的SrAl_2O_4晶体,且发光材料具有好的余辉性能和形貌。随着硼酸用量的增加,长余辉发光材料的激发光谱出现“蓝移”现象。
添加剂的使用能明显改善和修饰材料的形貌、增强材料的初始亮度、延长材料的余辉时间(柠檬酸的使用会缩短材料的余辉时间)。柠檬酸的加入有助于获得实心球形颗粒,乙醇除了良好的分散性,还能有效的增大颗粒的球形度,但无法获得实心颗粒,PEG能够起到分散剂和稳定剂的作用。当三种添加剂同时使用时可获得初始亮度高、余辉时间长、分散性好、粒度小、粒径分布窄(2μm～5μm)的实心球形颗粒。它们的最佳加入量为:柠檬酸为0.3g/L;PEG为0.03mol/L;乙醇为40ml/L。
喷雾热解法制备的SrAl_2O_4:Eu~(2+),Dy~(3+)长余辉发光材料,较之高温固相法所制备的具有合成温度低、分散性好、粒度小、粒径分布窄(2μm～5μm)、形貌规则(实心球形)、发光亮度高、余辉时间长(>65h)等优点。
In this paper,the development course,research status,preparation method and the emitting mechanism of rare earth ions actived alkaline aluminates salt light-storing materials,especially of SrAl_2O_4:Eu~(2+),Dy~(3+) long afterglow luminescence materials were summarized.The spherical SrAl_2O_4:Eu~(2+),Dy~(3+) was synthesized by a two-step spray pyrolysis process.The structure,morphology,luminous performances and Spectral properties of SrAl_2O_4:Eu~(2+),Dy~(3+) at different preparation technology conditions were studied.and compared with the preparation methods of solid state reaction at a high temperature.The results showed that:
The SrAl_2O_4:Eu~(2+),Dy~(3+) prepared by solid state reaction at a high temperature belongs to theɑ-SrAl2O4 phosphor crystal structure . Small amount of Eu、Dy introduced into the mixture did not affect the crystal structure of SrAl2O4.The flux H3BO3 could not only reduce the synthesis temperature, but also enhance the afterlow performance. The shape of the emission spectrum of SrAl_2O_4:Eu~(2+),Dy~(3+) did not be changed by the use of flux H3BO3. Dy3+ was the best auxiliary activators for SrA12O4:Eu2+ luminescence materials, Dy3+ could enhance the afterlow performance and won't change the peak location of its emission spectrum. The best composition of the prepared material with better afterlow performance was Sr0.97Al2O4:Eu0.01,Dy0.02. The SrAl_2O_4:Eu,Dy luminescence materials with better afterlow performance could be obtained by solid state reaction method when reduction temperature was 1350℃and reduction time was 3h .
The SrAl_2O_4:Eu~(2+),Dy~(3+) prepared by spray pyrolysis belongs to theɑ-SrAl2O4 phosphor crystal structure and small amount of Eu、Dy introduced into the mixture did not affect the crystal structure of SrAl2O4. The morphology,size distribution and luminous performances of the phosphors could be affected with synthesizing conditions, such as precursor concentration, sintering temperature, reduction temperature etc. As the reduction temperature rised, red shift of the main peak position in the emission spectrum had occurred (move to longer wavelengths).
H3BO3 could not only reduce the synthesis temperature, but also enhance the afterlow performance.The SrAl_2O_4:Eu~(2+),Dy~(3+) with better crystals,good luminous performance and morphology was syshtesised when the adding quantity of H3BO3 was 3.5mol%.As the add amount of H3BO3 increased,(2.5mol%～5mol%),the long afterlow material inspire spectra appear "blue shift" phenomenon.
Additives caould obviously improve the morphology,reinforce the initial brightness,enlarge the afterlow time (citric acid would shorten the afterlow time).Citric acid could help to obtain solid spherical particle. Ethanol was not only a good dispersant but also increased the sphericity of particle, howerve, solid spherical particles couldn't be gotten in this condition. PEG played the role of dispersant and stabilizer. The solid spherical SrAl_2O_4:Eu~(2+),Dy~(3+) particles with high initial brightness, long twilight time, good dispersion, small particle size and narrow particle size distribution (2μm~5μm) when these additives used at the same time.Their best addition amount were citric acid of 0.3g/L, PEG of 0.03mol/L, ethanol of 40ml/L.
Compared with solid state method,the SrAl_2O_4:Eu~(2+),Dy~(3+) with more regular morphology,smaller particle size, narrower particle size distribution and more excellent luminescent properties could be prepared by spray pyrolysis, and the synthesis temperature can be significantly reduced.
引文
[1]肖志国，罗昔贤.蓄光型发光材料及其制品.北京：化学工业出版社，2005
[2]张中泰，张俊英.无机光致发光材料.北京：化学工业出版社，2005
[3] Jorma H ls ,Taneli Laamanen,Mika Lastusaari1, et al.Electronic structure of the SrAl2O4：Eu2+persistent luminescence materi．Rare Earths. 1 December 2008．
[4]徐晓.超长余辉发光材料的制备及其性能表征：[硕士学位论文].上海，华东师范大学，2008
[5] Jia D D,Wang Y,Cuo Y,Li K,Zou Y K,Jia W Y.Synthesis and characterization of YAG:Ce3+ LEDnanophosphors.Journal of the Electrochemical Society, 2007，154(1):J 1.
[6] Haranath D, Harish Chander,Pooja Shanna,Singh S.Enhanced luminescence of Y3Al5O12:Ce3+nanophosphor for white light-emitting diodes.Applied Physics Letters, 2006, 89:173118.
[7] Kasuya R,Isohe T, Kuma H. Glycothennal synthesis and pho-toluminescence of YAG: Ce3+，nanophosphors.Journal of Alloys and Compounds, 2006, 408～412: 820.
[8] Jorma H.ls.,Taneli Laamanen,Mika Lastusaari,et.al.Electronic structure of the SrAl2O4:Eu2+Persistent luminescence material.Jouranal of Rare Eartha, 2009,Vol.27,No.4, p.550.
[9]邱东.长余辉发光材料的制备与性能研究：[硕士学位论文].安徽，合肥工业大学，2009
[10]常素玲，曹立新，高英俊等.掺杂硼对铝酸锶体系长余辉材料制备及发光性能影响的研究进展．发光学报，2007，Vo1.59 No.4．
[11] Lv Hao,Liu Aimei,Xiong Pingfan,et al.Preparation and Luminescence Properties ofSr1-xBaxAl2O4:Eu2+,Dy3+.Chin. J. Lumin. 2009,30(3) (in Chinese).
[12] Liao Feng,Wang Yinhai,Hu Yihua,et al. Temperature Impact on Luminescence Performances ofLong-lasting Afterglow Glass.Chin. J. Lumin. 2009,30(4) (in Chinese).
[13]邓新荣，胡国荣，彭忠东等.喷雾热解法合成球形(Y,Gd)BO3：Eu荧光粉的研究.中国稀土学报，2007，Vo1.25 No.2
[14]戚发鑫.喷雾热解法制备稀土YAG荧光粉：[硕士学位论文].南京，南京工业大学，2006
[15] Hyuan Sook Bae,Woo Joon Chuang,Ki-Woong.Effect of barrier rib height variation on theluminous characteristics of ac plasma display panel.of Applied Physics,2004,95(1):30～34.
[16] Marchal Julien,John Tyrone,Baranwal Rita,et al.Yttrium aluminum garnet nanopowders producedby liquid-feed flame spray pyrolysis(LF-FSP) of metalloorganic precursors Chem.Mater.2004, 16:822
[17]井艳军，王海波，黄如喜等.喷雾热解法制备红色发光粉LiEu ( SiO2)1/6 W2O8的研究.发光学报，2007，Vo1.28 No.5
[18]黎学明，李武林，孔令峰等.YAG:Ce荧光粉的喷雾干燥热解二步法合成与表征.中国稀土学报，2007，Vol.25 No.4
[19]陈伟.三基色PDP荧光粉的喷雾热解法合成及其表征：[硕士学位论文].广东，中山大学，2007
[20] Kyeong Youl Jung,Yun Chan Kang,Preparation of BaMgAll0OtT:Eu blue phosphor by flameassisted spray pyrolysis:photoluminesoence properties of powder and film under VUVexcitation,Materials Letters,2004,58:2161～2165
[21] Jung H,Lee D,Jung K Y,et a1.Fabrication of Dense BaMgAl10O17:Eu2+ Phosphor Particles bySpray Pymlysis,J.Alloys Comp.2005,390:189～193[1]肖志国,罗昔贤.蓄光型发光材料及其制品.北京:化学工业出版社,2005
[22]曹雁冰,胡国荣,彭忠东等.喷雾热解法合成球形(Y,Gd)BO3:Eu荧光粉.功能材料,2007,(增刊)38
[23]胡国荣,曹雁冰,邓新荣等.喷雾热解法制备PDP用(Y,Gd)BO3:Eu球形荧光粉.化工新型材料,2008,Vo1.36 No.1
[24] Froelich H C.Strontium Aluminate Phosphor.US 2392814,l946
[25] Palilla FC,Lecine AK,Tomkus MR.Huorescent propeies of alkMine earth aluminates of the type MAI204:activated by divalent europium.J Electroehem.Sec.1968,115(5):642
[26] G.Blasse.New Luminescent Materials.Chemistry of Materials.1989,1,294～301
[27]伊藤佑敏等.窑业协会志,1978,87(1):345
[28]宋庆梅,黄锦斐,吴茂钧等.铝酸锶铕的合成与发光的研究.发光学报,1991,2:144.
[29]松尺隆嗣等.日本第248回荧光粉学会演讲预稿.1993,7～13
[30]唐明道,李长宽,高志武.SrAl2O4:Eu的长余辉发光特性的研究.发光学报,1995,16(1):51
[31]宋庆梅,陈暨耀,吴中亚.掺镁的铝酸锶铕磷光体的特性.复旦学报(自然科学版),1995,34(1):103
[32] Yoshi yama,et al.Spring Proceeding in physics,1989,38:48
[33] T.Matsuzawa,Y.Aoki,N.Takeuchi,Y.Murayama,J.Electrochem.Soc,1996,143:2670.
[34] Hajime Yamamoto,International Conference on luminescence,1996,8:131
[35] Weiyi Jia.J.Luminescence.1989,76﹠77:424～428
[36]张天之,苏锵.MAl2O4:Eu,RE长余辉发光性质的研究.发光学报,1999,20(2):170
[37] Purwanto A,Lenggoro I W,Chang H,et a1.Journal of Chemical Engineering of Japan,2006,39(1):68～76
[38] Byung Woo Jeoung,Gun Young Hong,Won Tae Yoo,et a1.Journal of the Electrochemical Society,2004,151(10):H213～H216
[39]李沉英,彭明立.微波热效应合成(Y,Gd) BO3:Eu3+荧光体.发光学报,1995,16(3):261～264
[40]刘文芳.铝酸锶铕发光材料的微波合成和性能研究.河南师范大学硕士学位论文,2007
[41]翟永清,刘元红,李常娥等.微波场作用下Y2O2S:Tb绿色荧光粉.稀有金属材料与工程,2007,Vol.36 No.9
[42] T.Matsuzawa,YAoki,N.Takeuchi and Y.Murayama,A New long Phosphorescent Phosphor with High Brightness,J.Electrochem.Soc,143,2670(1996) 2670～2673
[43] Jia W Y,Yuan H B,Lu L H,et J.Lumines.1998,76～77,424～428
[44] J.Qiu, K.Hirao,Long lasting phosphorescence in Eu2+-doped calcium aluminoborate glasseso Solid state communicationsa 1998,106(12):795～798
[45]苏锵,张夭之,王淑彬.MAl2O4:Eu2+,RE3+长余辉发光性质的研究.发光学报,1999,20(2) :170～175
[46]宋庆梅,黄锦斐,吴茂均.铝酸锶铕的合成与发光的研究.发光学报,1991,12(2):145～150
[47] Chen Xuehua,HuYihua,Wang Yinhai,et al.Valence-change of Eu and Its Effect on the Luminescent Properties of Long Afterglow Phosphor SrAl2 O4:Eu,Dy.Chin.J.Lumin.2009,30(1) (in Chinese)
[48] Yamamoto H,Matsuzawa T.Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+and CaAl2O4:Eu2+, Nd3+.International Conference Luminescenc.1996,8:131
[49]周传仓,卢忠远,戴亚堂.共沉淀法制备超细长余辉发光材料铝酸锶铕镝的研究.稀有金属,2005,29(1):20～24
[50]李涛,沈明荣,袁小芳.柠檬酸为配位剂对Pr3+掺杂CaTiO3薄膜发光性能的影响.苏州大学学报(自然科学版), Vo1.24 No.4
[51]张晏清,张雄.空心微珠铁氧体复合粉体的改性与吸波性能.无机材料学报,2009,Vo1.24 No.4
[52]陈庆春,邓慧宇,马燕明.聚乙二醇在新材料制备中的作用及其机理.日用化学工业,2002, Vo1.32 No.5
[53]薛红伟,崔彩娥,郝虎在等.硼酸对蓝色铝酸锶长余辉材料的物相及发光特性的影响.功能材料与器件学报,2010,Vo1.16 No.1
[54]杨志平,徐小岭,熊志军等.B2O3对SrA12O4:Eu,Dy材料热释光谱和长余辉性能的影响.功能材料与器件学报,2007,Vo1.13 No.2
[2]张中泰，张俊英.无机光致发光材料.北京：化学工业出版社，2005
[3] Jorma H ls ,Taneli Laamanen,Mika Lastusaari1, et al.Electronic structure of the SrAl2O4：Eu2+persistent luminescence materi．Rare Earths. 1 December 2008．
[4]徐晓.超长余辉发光材料的制备及其性能表征：[硕士学位论文].上海，华东师范大学，2008
[5] Jia D D,Wang Y,Cuo Y,Li K,Zou Y K,Jia W Y.Synthesis and characterization of YAG:Ce3+ LEDnanophosphors.Journal of the Electrochemical Society, 2007，154(1):J 1.
[6] Haranath D, Harish Chander,Pooja Shanna,Singh S.Enhanced luminescence of Y3Al5O12:Ce3+nanophosphor for white light-emitting diodes.Applied Physics Letters, 2006, 89:173118.
[7] Kasuya R,Isohe T, Kuma H. Glycothennal synthesis and pho-toluminescence of YAG: Ce3+，nanophosphors.Journal of Alloys and Compounds, 2006, 408～412: 820.
[8] Jorma H.ls.,Taneli Laamanen,Mika Lastusaari,et.al.Electronic structure of the SrAl2O4:Eu2+Persistent luminescence material.Jouranal of Rare Eartha, 2009,Vol.27,No.4, p.550.
[9]邱东.长余辉发光材料的制备与性能研究：[硕士学位论文].安徽，合肥工业大学，2009
[10]常素玲，曹立新，高英俊等.掺杂硼对铝酸锶体系长余辉材料制备及发光性能影响的研究进展．发光学报，2007，Vo1.59 No.4．
[11] Lv Hao,Liu Aimei,Xiong Pingfan,et al.Preparation and Luminescence Properties ofSr1-xBaxAl2O4:Eu2+,Dy3+.Chin. J. Lumin. 2009,30(3) (in Chinese).
[12] Liao Feng,Wang Yinhai,Hu Yihua,et al. Temperature Impact on Luminescence Performances ofLong-lasting Afterglow Glass.Chin. J. Lumin. 2009,30(4) (in Chinese).
[13]邓新荣，胡国荣，彭忠东等.喷雾热解法合成球形(Y,Gd)BO3：Eu荧光粉的研究.中国稀土学报，2007，Vo1.25 No.2
[14]戚发鑫.喷雾热解法制备稀土YAG荧光粉：[硕士学位论文].南京，南京工业大学，2006
[15] Hyuan Sook Bae,Woo Joon Chuang,Ki-Woong.Effect of barrier rib height variation on theluminous characteristics of ac plasma display panel.of Applied Physics,2004,95(1):30～34.
[16] Marchal Julien,John Tyrone,Baranwal Rita,et al.Yttrium aluminum garnet nanopowders producedby liquid-feed flame spray pyrolysis(LF-FSP) of metalloorganic precursors Chem.Mater.2004, 16:822
[17]井艳军，王海波，黄如喜等.喷雾热解法制备红色发光粉LiEu ( SiO2)1/6 W2O8的研究.发光学报，2007，Vo1.28 No.5
[18]黎学明，李武林，孔令峰等.YAG:Ce荧光粉的喷雾干燥热解二步法合成与表征.中国稀土学报，2007，Vol.25 No.4
[19]陈伟.三基色PDP荧光粉的喷雾热解法合成及其表征：[硕士学位论文].广东，中山大学，2007
[20] Kyeong Youl Jung,Yun Chan Kang,Preparation of BaMgAll0OtT:Eu blue phosphor by flameassisted spray pyrolysis:photoluminesoence properties of powder and film under VUVexcitation,Materials Letters,2004,58:2161～2165
[21] Jung H,Lee D,Jung K Y,et a1.Fabrication of Dense BaMgAl10O17:Eu2+ Phosphor Particles bySpray Pymlysis,J.Alloys Comp.2005,390:189～193[1]肖志国,罗昔贤.蓄光型发光材料及其制品.北京:化学工业出版社,2005
[22]曹雁冰,胡国荣,彭忠东等.喷雾热解法合成球形(Y,Gd)BO3:Eu荧光粉.功能材料,2007,(增刊)38
[23]胡国荣,曹雁冰,邓新荣等.喷雾热解法制备PDP用(Y,Gd)BO3:Eu球形荧光粉.化工新型材料,2008,Vo1.36 No.1
[24] Froelich H C.Strontium Aluminate Phosphor.US 2392814,l946
[25] Palilla FC,Lecine AK,Tomkus MR.Huorescent propeies of alkMine earth aluminates of the type MAI204:activated by divalent europium.J Electroehem.Sec.1968,115(5):642
[26] G.Blasse.New Luminescent Materials.Chemistry of Materials.1989,1,294～301
[27]伊藤佑敏等.窑业协会志,1978,87(1):345
[28]宋庆梅,黄锦斐,吴茂钧等.铝酸锶铕的合成与发光的研究.发光学报,1991,2:144.
[29]松尺隆嗣等.日本第248回荧光粉学会演讲预稿.1993,7～13
[30]唐明道,李长宽,高志武.SrAl2O4:Eu的长余辉发光特性的研究.发光学报,1995,16(1):51
[31]宋庆梅,陈暨耀,吴中亚.掺镁的铝酸锶铕磷光体的特性.复旦学报(自然科学版),1995,34(1):103
[32] Yoshi yama,et al.Spring Proceeding in physics,1989,38:48
[33] T.Matsuzawa,Y.Aoki,N.Takeuchi,Y.Murayama,J.Electrochem.Soc,1996,143:2670.
[34] Hajime Yamamoto,International Conference on luminescence,1996,8:131
[35] Weiyi Jia.J.Luminescence.1989,76﹠77:424～428
[36]张天之,苏锵.MAl2O4:Eu,RE长余辉发光性质的研究.发光学报,1999,20(2):170
[37] Purwanto A,Lenggoro I W,Chang H,et a1.Journal of Chemical Engineering of Japan,2006,39(1):68～76
[38] Byung Woo Jeoung,Gun Young Hong,Won Tae Yoo,et a1.Journal of the Electrochemical Society,2004,151(10):H213～H216
[39]李沉英,彭明立.微波热效应合成(Y,Gd) BO3:Eu3+荧光体.发光学报,1995,16(3):261～264
[40]刘文芳.铝酸锶铕发光材料的微波合成和性能研究.河南师范大学硕士学位论文,2007
[41]翟永清,刘元红,李常娥等.微波场作用下Y2O2S:Tb绿色荧光粉.稀有金属材料与工程,2007,Vol.36 No.9
[42] T.Matsuzawa,YAoki,N.Takeuchi and Y.Murayama,A New long Phosphorescent Phosphor with High Brightness,J.Electrochem.Soc,143,2670(1996) 2670～2673
[43] Jia W Y,Yuan H B,Lu L H,et J.Lumines.1998,76～77,424～428
[44] J.Qiu, K.Hirao,Long lasting phosphorescence in Eu2+-doped calcium aluminoborate glasseso Solid state communicationsa 1998,106(12):795～798
[45]苏锵,张夭之,王淑彬.MAl2O4:Eu2+,RE3+长余辉发光性质的研究.发光学报,1999,20(2) :170～175
[46]宋庆梅,黄锦斐,吴茂均.铝酸锶铕的合成与发光的研究.发光学报,1991,12(2):145～150
[47] Chen Xuehua,HuYihua,Wang Yinhai,et al.Valence-change of Eu and Its Effect on the Luminescent Properties of Long Afterglow Phosphor SrAl2 O4:Eu,Dy.Chin.J.Lumin.2009,30(1) (in Chinese)
[48] Yamamoto H,Matsuzawa T.Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+and CaAl2O4:Eu2+, Nd3+.International Conference Luminescenc.1996,8:131
[49]周传仓,卢忠远,戴亚堂.共沉淀法制备超细长余辉发光材料铝酸锶铕镝的研究.稀有金属,2005,29(1):20～24
[50]李涛,沈明荣,袁小芳.柠檬酸为配位剂对Pr3+掺杂CaTiO3薄膜发光性能的影响.苏州大学学报(自然科学版), Vo1.24 No.4
[51]张晏清,张雄.空心微珠铁氧体复合粉体的改性与吸波性能.无机材料学报,2009,Vo1.24 No.4
[52]陈庆春,邓慧宇,马燕明.聚乙二醇在新材料制备中的作用及其机理.日用化学工业,2002, Vo1.32 No.5
[53]薛红伟,崔彩娥,郝虎在等.硼酸对蓝色铝酸锶长余辉材料的物相及发光特性的影响.功能材料与器件学报,2010,Vo1.16 No.1
[54]杨志平,徐小岭,熊志军等.B2O3对SrA12O4:Eu,Dy材料热释光谱和长余辉性能的影响.功能材料与器件学报,2007,Vo1.13 No.2
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |