辛烯基琥珀酸淀粉酯的制备、性质及应用研究
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摘要
以非晶颗粒态玉米淀粉和蜡质玉米淀粉为原料,采用热解、酶解方法,以及羟丙基改性的方法制备不同种类的低粘度辛烯基琥珀酸淀粉酯,并对其吸附和包埋性质及机理做了研究。具体可分为以下几个部分:
制备非晶颗粒态辛烯基琥珀酸淀粉酯的过程包括:以普通玉米淀粉原料,在醇-水相中制备非晶颗粒态玉米淀粉,采用酶解的方法低粘度制备非晶颗粒态辛烯基琥珀酸淀粉酯,其吸附性能比较强,吸油率原淀粉辛烯基琥珀酸淀粉酯的3倍多,最大吸油率可达到161%。最佳制备条件为:反应温度为35℃,反应的pH值为8.5,反应时间为2h,淀粉乳的浓度为0.25g/ml,得到产品的取代度为0.0166。
热解法制备蜡质玉米淀粉辛烯基琥珀酸淀粉酯的过程包括:以蜡质玉米淀粉为原料制备辛烯基琥珀酸淀粉酯,然后对其进行热解和微胶囊化处理。该产品的包埋能力比较强,最高的包埋率超过了98%,与国内产品相比,表面油降低最高可以达到71%。制备条件为:反应温度为165℃,反应时间5h,酸酐的加入量为淀粉(干基的)的5.2%,反应的pH为3.5。微胶囊化工艺的最佳工艺是:壁材和心材的比例是2:1,均质压力是30~40Mpa,均质次数为2~3次,进风温度为210℃,出风温度为80℃,通针为10次/min。
酶解法制备辛烯基琥珀酸淀粉酯的过程包括:以蜡质玉米淀粉为原料,采用高温α-淀粉酶制备低粘度辛烯基琥珀酸淀粉酯,产品的透明度比较高,包埋率偏低为90.3%。最佳制备条件为:酯化淀粉乳的浓度为20%(w/w),反应时间为10min,反应温度为95℃,反应pH为6.0,α-淀粉酶添加量的范围为10mL/g,此时的粘度为120maps左右。
热解制备羟丙基改性辛烯基琥珀酸淀粉酯的过程包括:以辛烯基琥珀酸淀粉酯为原料,采用羟丙基改性的方法制备低粘度的辛烯基琥珀酸淀粉酯,与改性前相比,产品的包埋能力更强,最高可以达到99.2%,表面油最高可以下降33.6%。工艺条件为:羟丙基酯化淀粉:淀粉酯的浓度是35%,环氧丙烷加入量为淀粉酯的10%(干基),常温维持30min,反应温度为50℃,时间为10h。
非晶颗粒态淀粉是吸水性比较强,以非晶颗粒态玉米为原料,经过辛烯基琥珀酸淀粉酯改性质后,可以大大改善吸附油脂的性能,拓宽了非晶颗粒态淀粉的应用范围。蜡质玉米淀粉制备的辛烯基琥珀酸淀粉酯的适合制备微胶囊,可以用来包埋易氧化的油脂如DHA,AA油和一些对身体有危害的食品添加剂,可以延长食品的货架保质期和降低食品添加剂的危害。
Octenyl succinic anhydride modified starch (SSOS) was prepared from non-crystal granular corn starch and waxy corn starch in this paper, then respectively dealed them withα-amylase or hot temperatuter, moreover using the products to prepare for different kinds of microcapsule.finally the embedding mechanism and reaction mechanisms were preliminarily studied.Including following several sections.
The process of preparing Non-crystal corn SSOS was:Non-crystal granular starch was prepared in ethanol-water system, low viscosity non-crystal granular SSOS was produced through enzymolysis and the properties of adsorption was very well, the maximal oil adsoption exceeded 161%,which was treble the adsorption of native SSOS,the optimum processcondition was: reactive temperature 35℃,pH8.5, reactive time 2h, the concentration of starch 0.25g/ml, the DS 0.0166..
The process of preparing waxy corn SSOS was: SSOS was prepared from waxy corn starch, then dealing it with pyrolysis and microcapsule, the embedding property of the product was very well, the rate of embedding oil exceeding 98%. Compared with home products, the surface oil was reduced 71%.The optimize condition was: the last temperature 165℃, reactive time 5h. The optimum technology of microcapsule was: the rate of the modified starch and oil 2:1, homogeneous pressure 30-40Mpa, homogeneous times 2-3, entering air temp 210℃, leaving air temp 80℃,nozzle cleaner 10 times/min.
The process of preparing SSOS including: SSOS was dealed with thermostable alphaα-amylase, taking apparent viscosity as index to decide the degree. The embedding property of product was not very well, the rate of embedding oil was 90.3%. The optimum condition was : the concentration of starch 20% (w/w), reactive temperature 95℃, pH 6.0, amylase added 10ml.
Hydroxypropyl modified SSOS was prepared from waxy corn starch, then dealing it with pyrolysis and microcapsule, the embedding property of the product is very well, themaximun rate of embedding oil 99.2%, the rudction of the surface oil was 33.6%. The preparing technics: the concentration of starch 35%, epoxy chloropropane addition 10%( dry basis of esterification), at 18℃reactive time half an hour, at 50℃reactive time 10h.
Non-crystal granular SSOS was hydrophilic, after modification, the abilty of oil obsorption was improved largely. Waxy corn starch is suit to prepare microcapsule, which could reduce the harm of food additive and prolong the shelf life of functional components of health product, such as DHA and AA oil.
制备非晶颗粒态辛烯基琥珀酸淀粉酯的过程包括:以普通玉米淀粉原料,在醇-水相中制备非晶颗粒态玉米淀粉,采用酶解的方法低粘度制备非晶颗粒态辛烯基琥珀酸淀粉酯,其吸附性能比较强,吸油率原淀粉辛烯基琥珀酸淀粉酯的3倍多,最大吸油率可达到161%。最佳制备条件为:反应温度为35℃,反应的pH值为8.5,反应时间为2h,淀粉乳的浓度为0.25g/ml,得到产品的取代度为0.0166。
热解法制备蜡质玉米淀粉辛烯基琥珀酸淀粉酯的过程包括:以蜡质玉米淀粉为原料制备辛烯基琥珀酸淀粉酯,然后对其进行热解和微胶囊化处理。该产品的包埋能力比较强,最高的包埋率超过了98%,与国内产品相比,表面油降低最高可以达到71%。制备条件为:反应温度为165℃,反应时间5h,酸酐的加入量为淀粉(干基的)的5.2%,反应的pH为3.5。微胶囊化工艺的最佳工艺是:壁材和心材的比例是2:1,均质压力是30~40Mpa,均质次数为2~3次,进风温度为210℃,出风温度为80℃,通针为10次/min。
酶解法制备辛烯基琥珀酸淀粉酯的过程包括:以蜡质玉米淀粉为原料,采用高温α-淀粉酶制备低粘度辛烯基琥珀酸淀粉酯,产品的透明度比较高,包埋率偏低为90.3%。最佳制备条件为:酯化淀粉乳的浓度为20%(w/w),反应时间为10min,反应温度为95℃,反应pH为6.0,α-淀粉酶添加量的范围为10mL/g,此时的粘度为120maps左右。
热解制备羟丙基改性辛烯基琥珀酸淀粉酯的过程包括:以辛烯基琥珀酸淀粉酯为原料,采用羟丙基改性的方法制备低粘度的辛烯基琥珀酸淀粉酯,与改性前相比,产品的包埋能力更强,最高可以达到99.2%,表面油最高可以下降33.6%。工艺条件为:羟丙基酯化淀粉:淀粉酯的浓度是35%,环氧丙烷加入量为淀粉酯的10%(干基),常温维持30min,反应温度为50℃,时间为10h。
非晶颗粒态淀粉是吸水性比较强,以非晶颗粒态玉米为原料,经过辛烯基琥珀酸淀粉酯改性质后,可以大大改善吸附油脂的性能,拓宽了非晶颗粒态淀粉的应用范围。蜡质玉米淀粉制备的辛烯基琥珀酸淀粉酯的适合制备微胶囊,可以用来包埋易氧化的油脂如DHA,AA油和一些对身体有危害的食品添加剂,可以延长食品的货架保质期和降低食品添加剂的危害。
Octenyl succinic anhydride modified starch (SSOS) was prepared from non-crystal granular corn starch and waxy corn starch in this paper, then respectively dealed them withα-amylase or hot temperatuter, moreover using the products to prepare for different kinds of microcapsule.finally the embedding mechanism and reaction mechanisms were preliminarily studied.Including following several sections.
The process of preparing Non-crystal corn SSOS was:Non-crystal granular starch was prepared in ethanol-water system, low viscosity non-crystal granular SSOS was produced through enzymolysis and the properties of adsorption was very well, the maximal oil adsoption exceeded 161%,which was treble the adsorption of native SSOS,the optimum processcondition was: reactive temperature 35℃,pH8.5, reactive time 2h, the concentration of starch 0.25g/ml, the DS 0.0166..
The process of preparing waxy corn SSOS was: SSOS was prepared from waxy corn starch, then dealing it with pyrolysis and microcapsule, the embedding property of the product was very well, the rate of embedding oil exceeding 98%. Compared with home products, the surface oil was reduced 71%.The optimize condition was: the last temperature 165℃, reactive time 5h. The optimum technology of microcapsule was: the rate of the modified starch and oil 2:1, homogeneous pressure 30-40Mpa, homogeneous times 2-3, entering air temp 210℃, leaving air temp 80℃,nozzle cleaner 10 times/min.
The process of preparing SSOS including: SSOS was dealed with thermostable alphaα-amylase, taking apparent viscosity as index to decide the degree. The embedding property of product was not very well, the rate of embedding oil was 90.3%. The optimum condition was : the concentration of starch 20% (w/w), reactive temperature 95℃, pH 6.0, amylase added 10ml.
Hydroxypropyl modified SSOS was prepared from waxy corn starch, then dealing it with pyrolysis and microcapsule, the embedding property of the product is very well, themaximun rate of embedding oil 99.2%, the rudction of the surface oil was 33.6%. The preparing technics: the concentration of starch 35%, epoxy chloropropane addition 10%( dry basis of esterification), at 18℃reactive time half an hour, at 50℃reactive time 10h.
Non-crystal granular SSOS was hydrophilic, after modification, the abilty of oil obsorption was improved largely. Waxy corn starch is suit to prepare microcapsule, which could reduce the harm of food additive and prolong the shelf life of functional components of health product, such as DHA and AA oil.
引文
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