序批式生物反应器处理农村生活垃圾中试研究
摘要
本论文以浙江省富阳市新登镇施村农村生活垃圾为对象,构建了两套生物反应器系统R1(序批式生物反应器)和R2(渗滤液直接回灌型生物反应器),进行了70天左右的农村生活垃圾生物处理中试研究以及后续渗滤液土壤吸附、解吸和净化小试研究,结果表明:
(1)系统R1和R2新鲜垃圾在运行进程中的减容率趋势总体一致,试验结束时系统R1和R2新鲜垃圾减容率分别高达57%和53%。
(2)系统R1和R2新鲜垃圾生物反应器上、下层有机质含量以及BDM都经历逐渐减小,最后趋于稳定的类似变化过程。在整个运行期间,系统R1新鲜垃圾生物反应器中垃圾体有机质和BDM下降的速度明显比R2要快,试验结束时系统R1新鲜垃圾生物反应器中垃圾体上、下层有机质含量分别稳定在221.2g/kg和223.5g/kg,BDM分别稳定在19.1%和18.3%。而系统R2新鲜垃圾生物反应器中垃圾体上、下层有机质含量分别稳定在250.2g/kg和264.4g/kg,BDM分别稳定在20.2%和21.1%。
(3)系统R1和R2经过70天左右的运行,填埋垃圾基本不再产生新的渗滤液。试验结束时系统R1和R2新鲜垃圾渗滤液累积水量各自在440L左右,系统问渗滤液量相差很小。
(4)系统R1渗滤液pH值从第3天的4.78开始缓慢上升,基本恒定在6.00～8.00的中性范围内。系统R2渗滤液pH值从中试开始到结束为止一直呈酸性,基本上在5.20左右。
(5)系统R1和R2新鲜垃圾渗滤液COD、VFA浓度变化相差甚远。系统R1渗滤液COD、VFA浓度分别从最初的14800.2mg/L和5689.3mg/L上升到最高点的24770.5mg/L和17932.4mg/L,而后较之系统R2快速下降。试验结束时,COD、VFA浓度分别为10113.1mg/L和1502.3mg/L。而系统R2渗滤液COD、VFA浓度分别从最初的15098.0mg/L和6510.3mg/L快速上升到最高点的41328.4mg/L和34688.0mg/L。但随着时间的延长,渗滤液COD和VFA浓度下降缓慢,始终处于较高状态。试验结束时,系统R2渗滤液COD浓度高居35300.9mg/L,sr~(2+)VFA浓度为23723.4mg/L,分别是系统R1的3.49倍和15.79倍。
(6)系统R1和R2渗滤液TN和NH_4~+-N浓度的变化趋势基本相同,都经历了由低到高、逐渐累积稳定的过程,但两者上升速度和最终累计值不一样。系统R1渗滤液TN和NH_4~+-N浓度分别从开始的502.9mg/L和410.2mg/L不断累积,最终稳定在822.3mg/L和765.5mg/L。而系统R2渗滤液TN和NH_4~+-N浓度分别从开始的567.1mg/L和432.6mg/L不断累积,最终稳定在2790.6mg/L和2309.1mg/L,分别是系统R1的3.39倍和3.02倍。
(7)陈垃圾在运行进程中的减容率很小,排除试验开始因不压实引起的减容率外,试验结束时陈垃圾减容率只有2%,陈垃圾基本稳定化。
(8)陈垃圾生物反应器对渗滤液具有一定的缓冲能力和有机物降解性能,渗滤液出水基本呈中性,COD去除率由一开始的7.4%逐渐上升到最高值的39.2%,然后下降,基本稳定在10.O%左右。
(9)土壤对渗滤液COD和NH_4~+-N的吸附方程符合Langmuir等温吸附方程,吸附量都是随着平衡溶液中各自浓度的增加而增加。由于吸附是放热反应,所以土壤对渗滤液COD和NH_4~+-N的吸附量均随温度的升高而下降,饱和吸附量的大小依次是10℃、20℃和30℃。渗滤液COD和NH_4~+-N的解吸量都是随土壤中各自吸附量的增加而增加,但从土壤中解吸的比例较低。
(10)温度对渗滤液COD在土壤中的净化效果影响较大。20℃和30℃状况下,随着培养时间的延长,渗滤液COD在土壤中的溶出量呈大幅度下降趋势。经过3天的时间,渗滤液A中COD溶出量分别从第0天的1984.8mg/kg迅速下降到第3天的52.0mg/kg和54.2mg/kg。渗滤液B中COD溶出量分别从第O天的768.0mg/kg迅速下降到第3天的54.18mg/kg和50.98mg/kg。3天以后,两种渗滤液COD溶出量均变化很小,浓度很低。而在低温10℃状况下,渗滤液随着培养时间的延长,COD下降缓慢,经过一周的时间,渗滤液A在土壤中COD溶出量仍高达714.0mg/kg。渗滤液B由于本身所含污染物较低,故与20℃、30℃相比净化效果不是特别明显,且随着时间的延长慢慢缩小,一周后渗滤液B在土壤中COD溶出量为98.0mg/kg。
(11)温度对渗滤液NH_4~+-N在土壤中的净化效果影响较大。20℃和30℃状况下,随着培养时间的延长,渗滤液NH_4~+-N在土壤中的溶出量呈大幅度下降趋势。经过5天的时间,渗滤液A中NH_4~+-N溶出量分别从第0天的105.32mg/kg迅速下降到第5天的4.36mg/kg和4.34mg/kg。渗滤液B中NH_4~+-N溶出量分别从第0天的106.38mg/kg迅速下降到第5天的4.38mg/kg和4.34mg/kg。5天以后,两种渗滤液NH_4~+-N溶出量均变化很小,浓度很低。而在低温10℃状况下,渗滤液随着培养时间的延长,NH_4~+-N下降缓慢,经过一周的时间,渗滤液A和B在土壤中NH_4~+-N溶出量分别为33.44mg/kg和33.58mg/kg。
(12)该村生活垃圾经过序批式生物反应器处理后,渗滤液年产生量为10000L,需要396.8m~2土壤经过5天处理后,渗滤液COD和NH_4~+-N溶出量均变化很小,浓度很低。又因为每套生物反应器装置70天左右才排放渗滤液1次,即396.8m~2土壤每年仅处理渗滤液1次,则被土壤吸附的COD和NH_4~+-N,经过1年的时间,势必能得到很好降解。
(13)序批式生物反应器经过70天左右运行后产生的渗滤液经过土壤1次净化后,土壤中Cu增量为0.2mg/kg,Zn增量为0.5mg/kg,再由于这块土壤每年仅净化处理渗滤液1次,则重金属对土壤污染较低。
In this paper,rural domestic refuse in Shi village of Fu Yang city was investigated,and two sets of bioreactor systems named R1(sequencing batch bioreactor)and R2(leachate recirculated directly bioreactor)were designed.A study of biological treatment of rural domestic refuse at pilot scale was conducted for about 70 days,and a follow-up experiment of leachate absorption,desorption and purification by soil was carried out in laboratory.The main results of this research were summarized as follows:
(1)On the whole,the trends of fresh refuse reduction in R1 and R2 were similar during operation.In the end,reduction rate of R1 and R2 were up to 57%and 53%, respectively.
(2)Fresh refuse organic matter content and BDM in upper and lower layers of R1 and R2 decreased throughout the pilot process,and finally became stable.During operation,refuse organic matter content and BDM in R1 declined significantly faster than R2.In the end,refuse organic matter content in upper and lower layers of R1 dropped to 221.2 g/kg and 223.5 g/kg,and R2 for the corresponding 250.2 g/kg and 264.4 g/kg,respectively.BDM in upper and lower layers of R1 dropped to 19.1%and 18.3%,and R2 for the corresponding 20.2%and 21.1%.
(3)After running for about 70 days,refuse almost didn't produce leachate any longer.In the end,leachate amount of R1 and R2 was almost the same,each of which accumulating to a total of 440L,respectively.
(4)Leachate pH value of R1 rised slowly from the third day of 4.78,and then was basically neutral,ranged from 6.00 to 8.00.During the whole pilot,the leachate pH value of R2 had been acid,basically around 5.20.
(5)The change of leachate COD and VFA concentration of R1 and R2 was greatly different.Leachate COD and VFA concentration of R1 rised slowly from 14800.2 mg/L and 5689.3 mg/L to the peak of 24770.5 mg/L and 17932.4 mg/L,then decreased rapidly compared with R2.In the end,leachate COD and VFA concentrations were 10113.1 mg/L and 1502.3 mg/L.On the contrary,leachate COD and VFA concentration of R2 rised rapidly from the third day of 15098.0 mg/L and 6510.3 mg/L to the peak of 41328.4.mg/L and 34688.0 mg/L.Then,leachate COD and VFA concentration of R2 decreased slowly,maintaining at a high level.In the end, leachate COD and VFA concentrations of R2 were 35300.9 mg/L and 23723.4 mg/L, which were 3.49 and 15.79 times R1,respectively.
(6)Leachate TN and NH_4~+-N concentration of R1 and R2 changed same,firstly increased and then gradually stabilized,but the increased speed and the final accumulated value were different.Leachate TN and NH_4~+-N concentration of R1 rised slowly from 502.9 mg/L and 410.2 mg/L to the end of 822.3 mg/L and 765.5 mg/L. On the contrary,leachate TN and NH_4~+-N concentration of R2 rised rapidly from 567.1 mg/L and 432.6 mg/L to the end of 2790.6 mg/L and 2309.1 mg/L,which was 3.39 and 3.02 times R1,respectively.
(7)During operation,there was little reduction of aged refuse.Ruling out the reduction caused by no compaction,reduction rate of aged refuse was only 2%in the end,indicated that aged refuse was basically stable.
(8)Aged-refuse-based bioreactor had a buffer capacity and degradation performance of organic matter for leachate.Leachate effluent was basically neutral, and COD removal efficiency increased from the start of 7.4%gradually to a maximum value of 39.2%,and then dropped,basically stable at around 10.0%.
(9)The adsorption equation of leachate COD and NH_4~+-N in the soil was consistent with Langmuir isothermal adsorption equation,and the adsorption of leachate COD and NH_4~+-N by the soil increased by their concentration.Because adsorption was a exothermic reaction,adsorption of COD and NH_4~+-N decreased by temperature,saturated adsorption of the order was in 10℃、20℃and 30℃.The desorption of leachate COD and NH_4~+-N increased by their adsorption amount,but desorbed little from the soil.
(10)Temperature had a great impact on the purifying effect of leachate COD by the soil.At 20℃and 30℃,with the extension of culture time,the exudation of leachate COD was on a significant downward trend.For three days,the COD exudation of leachate(A)decreased rapidly from the beginning of 1984.8 mg/kg to the third day of 52.0 mg/kg and 54.2 mg/kg.The COD exudation of leachate(B) decreased rapidly from the beginning of 768.0 mg/kg to the third day of 54.18 mg/kg and 50.98 mg/kg.And then,the COD exudation of both leachate changed very little. At low temperature of 10℃,the exudation of leachate COD declined slowly.After a week,the COD exudation of leachate(A)was still up to 714.0 mg/kg.As leachate(B) contained little pollutants,the purifying effect was not particularly evident compared with 20℃,30℃,and gradually narrow with the extension of time.The COD exudation of leachate(B)was 98.0 mg/kg after a week.
(11)Temperature had a great impact on the purifying effect of leachate NH_4~+-N by the soil..At 20℃and 30℃,With the extension of culture time,the exudation of leachate NH_4~+-N was on a significant downward trend.For 5 days,the NH_4~+-N exudation of leachate(A)decreased rapidly from the beginning of 105.32 mg/kg to the fifth day of 4.36 mg/kg and 4.34 mg/kg.The NH_4~+-N exudation of leachate(B) decreased rapidly from the beginning of 106.38 mg/kg to the fifth day of 4.38 mg/kg and 4.34 mg/kg.And then,the NH_4~+-N exudation of both leachate changed very little, and the NH_4~+-N concentration was very low.At low temperature of 10℃,the exudation of leachate NH_4~+-N declined slowly.After a week,the NH_4~+-N exudation of leachate(A)and leachate(B)were 33.44 mg/kg and 33.58 mg/kg,respectively.
(12)When the rural domestic refuse in Shi village was disposed by sequencing batch bioreactor,total leachate amount was 10000L one year.Therefore,it need a soil of 396.8m~2 and five days treatment to reach a low COD and NH_4~+-N exudation.As each set of bioreactor apparatus discharged leachate once in 70 days,that is,the 396.8m~2 soil treated leachate only once in a year,leachate COD and NH_4~+-N adsorbed by the soil could be degradated well.
(13)After leachate running in sequencing batch bioreactor for 70 days was purified by the soil once,Cu incremental content in soil was 0.2 mg/kg,Zn incremental content was 0.5 mg/kg.As the soil treated leachate only once in a year,so heavy metal had little pollution to the soil.
(1)系统R1和R2新鲜垃圾在运行进程中的减容率趋势总体一致,试验结束时系统R1和R2新鲜垃圾减容率分别高达57%和53%。
(2)系统R1和R2新鲜垃圾生物反应器上、下层有机质含量以及BDM都经历逐渐减小,最后趋于稳定的类似变化过程。在整个运行期间,系统R1新鲜垃圾生物反应器中垃圾体有机质和BDM下降的速度明显比R2要快,试验结束时系统R1新鲜垃圾生物反应器中垃圾体上、下层有机质含量分别稳定在221.2g/kg和223.5g/kg,BDM分别稳定在19.1%和18.3%。而系统R2新鲜垃圾生物反应器中垃圾体上、下层有机质含量分别稳定在250.2g/kg和264.4g/kg,BDM分别稳定在20.2%和21.1%。
(3)系统R1和R2经过70天左右的运行,填埋垃圾基本不再产生新的渗滤液。试验结束时系统R1和R2新鲜垃圾渗滤液累积水量各自在440L左右,系统问渗滤液量相差很小。
(4)系统R1渗滤液pH值从第3天的4.78开始缓慢上升,基本恒定在6.00～8.00的中性范围内。系统R2渗滤液pH值从中试开始到结束为止一直呈酸性,基本上在5.20左右。
(5)系统R1和R2新鲜垃圾渗滤液COD、VFA浓度变化相差甚远。系统R1渗滤液COD、VFA浓度分别从最初的14800.2mg/L和5689.3mg/L上升到最高点的24770.5mg/L和17932.4mg/L,而后较之系统R2快速下降。试验结束时,COD、VFA浓度分别为10113.1mg/L和1502.3mg/L。而系统R2渗滤液COD、VFA浓度分别从最初的15098.0mg/L和6510.3mg/L快速上升到最高点的41328.4mg/L和34688.0mg/L。但随着时间的延长,渗滤液COD和VFA浓度下降缓慢,始终处于较高状态。试验结束时,系统R2渗滤液COD浓度高居35300.9mg/L,sr~(2+)VFA浓度为23723.4mg/L,分别是系统R1的3.49倍和15.79倍。
(6)系统R1和R2渗滤液TN和NH_4~+-N浓度的变化趋势基本相同,都经历了由低到高、逐渐累积稳定的过程,但两者上升速度和最终累计值不一样。系统R1渗滤液TN和NH_4~+-N浓度分别从开始的502.9mg/L和410.2mg/L不断累积,最终稳定在822.3mg/L和765.5mg/L。而系统R2渗滤液TN和NH_4~+-N浓度分别从开始的567.1mg/L和432.6mg/L不断累积,最终稳定在2790.6mg/L和2309.1mg/L,分别是系统R1的3.39倍和3.02倍。
(7)陈垃圾在运行进程中的减容率很小,排除试验开始因不压实引起的减容率外,试验结束时陈垃圾减容率只有2%,陈垃圾基本稳定化。
(8)陈垃圾生物反应器对渗滤液具有一定的缓冲能力和有机物降解性能,渗滤液出水基本呈中性,COD去除率由一开始的7.4%逐渐上升到最高值的39.2%,然后下降,基本稳定在10.O%左右。
(9)土壤对渗滤液COD和NH_4~+-N的吸附方程符合Langmuir等温吸附方程,吸附量都是随着平衡溶液中各自浓度的增加而增加。由于吸附是放热反应,所以土壤对渗滤液COD和NH_4~+-N的吸附量均随温度的升高而下降,饱和吸附量的大小依次是10℃、20℃和30℃。渗滤液COD和NH_4~+-N的解吸量都是随土壤中各自吸附量的增加而增加,但从土壤中解吸的比例较低。
(10)温度对渗滤液COD在土壤中的净化效果影响较大。20℃和30℃状况下,随着培养时间的延长,渗滤液COD在土壤中的溶出量呈大幅度下降趋势。经过3天的时间,渗滤液A中COD溶出量分别从第0天的1984.8mg/kg迅速下降到第3天的52.0mg/kg和54.2mg/kg。渗滤液B中COD溶出量分别从第O天的768.0mg/kg迅速下降到第3天的54.18mg/kg和50.98mg/kg。3天以后,两种渗滤液COD溶出量均变化很小,浓度很低。而在低温10℃状况下,渗滤液随着培养时间的延长,COD下降缓慢,经过一周的时间,渗滤液A在土壤中COD溶出量仍高达714.0mg/kg。渗滤液B由于本身所含污染物较低,故与20℃、30℃相比净化效果不是特别明显,且随着时间的延长慢慢缩小,一周后渗滤液B在土壤中COD溶出量为98.0mg/kg。
(11)温度对渗滤液NH_4~+-N在土壤中的净化效果影响较大。20℃和30℃状况下,随着培养时间的延长,渗滤液NH_4~+-N在土壤中的溶出量呈大幅度下降趋势。经过5天的时间,渗滤液A中NH_4~+-N溶出量分别从第0天的105.32mg/kg迅速下降到第5天的4.36mg/kg和4.34mg/kg。渗滤液B中NH_4~+-N溶出量分别从第0天的106.38mg/kg迅速下降到第5天的4.38mg/kg和4.34mg/kg。5天以后,两种渗滤液NH_4~+-N溶出量均变化很小,浓度很低。而在低温10℃状况下,渗滤液随着培养时间的延长,NH_4~+-N下降缓慢,经过一周的时间,渗滤液A和B在土壤中NH_4~+-N溶出量分别为33.44mg/kg和33.58mg/kg。
(12)该村生活垃圾经过序批式生物反应器处理后,渗滤液年产生量为10000L,需要396.8m~2土壤经过5天处理后,渗滤液COD和NH_4~+-N溶出量均变化很小,浓度很低。又因为每套生物反应器装置70天左右才排放渗滤液1次,即396.8m~2土壤每年仅处理渗滤液1次,则被土壤吸附的COD和NH_4~+-N,经过1年的时间,势必能得到很好降解。
(13)序批式生物反应器经过70天左右运行后产生的渗滤液经过土壤1次净化后,土壤中Cu增量为0.2mg/kg,Zn增量为0.5mg/kg,再由于这块土壤每年仅净化处理渗滤液1次,则重金属对土壤污染较低。
In this paper,rural domestic refuse in Shi village of Fu Yang city was investigated,and two sets of bioreactor systems named R1(sequencing batch bioreactor)and R2(leachate recirculated directly bioreactor)were designed.A study of biological treatment of rural domestic refuse at pilot scale was conducted for about 70 days,and a follow-up experiment of leachate absorption,desorption and purification by soil was carried out in laboratory.The main results of this research were summarized as follows:
(1)On the whole,the trends of fresh refuse reduction in R1 and R2 were similar during operation.In the end,reduction rate of R1 and R2 were up to 57%and 53%, respectively.
(2)Fresh refuse organic matter content and BDM in upper and lower layers of R1 and R2 decreased throughout the pilot process,and finally became stable.During operation,refuse organic matter content and BDM in R1 declined significantly faster than R2.In the end,refuse organic matter content in upper and lower layers of R1 dropped to 221.2 g/kg and 223.5 g/kg,and R2 for the corresponding 250.2 g/kg and 264.4 g/kg,respectively.BDM in upper and lower layers of R1 dropped to 19.1%and 18.3%,and R2 for the corresponding 20.2%and 21.1%.
(3)After running for about 70 days,refuse almost didn't produce leachate any longer.In the end,leachate amount of R1 and R2 was almost the same,each of which accumulating to a total of 440L,respectively.
(4)Leachate pH value of R1 rised slowly from the third day of 4.78,and then was basically neutral,ranged from 6.00 to 8.00.During the whole pilot,the leachate pH value of R2 had been acid,basically around 5.20.
(5)The change of leachate COD and VFA concentration of R1 and R2 was greatly different.Leachate COD and VFA concentration of R1 rised slowly from 14800.2 mg/L and 5689.3 mg/L to the peak of 24770.5 mg/L and 17932.4 mg/L,then decreased rapidly compared with R2.In the end,leachate COD and VFA concentrations were 10113.1 mg/L and 1502.3 mg/L.On the contrary,leachate COD and VFA concentration of R2 rised rapidly from the third day of 15098.0 mg/L and 6510.3 mg/L to the peak of 41328.4.mg/L and 34688.0 mg/L.Then,leachate COD and VFA concentration of R2 decreased slowly,maintaining at a high level.In the end, leachate COD and VFA concentrations of R2 were 35300.9 mg/L and 23723.4 mg/L, which were 3.49 and 15.79 times R1,respectively.
(6)Leachate TN and NH_4~+-N concentration of R1 and R2 changed same,firstly increased and then gradually stabilized,but the increased speed and the final accumulated value were different.Leachate TN and NH_4~+-N concentration of R1 rised slowly from 502.9 mg/L and 410.2 mg/L to the end of 822.3 mg/L and 765.5 mg/L. On the contrary,leachate TN and NH_4~+-N concentration of R2 rised rapidly from 567.1 mg/L and 432.6 mg/L to the end of 2790.6 mg/L and 2309.1 mg/L,which was 3.39 and 3.02 times R1,respectively.
(7)During operation,there was little reduction of aged refuse.Ruling out the reduction caused by no compaction,reduction rate of aged refuse was only 2%in the end,indicated that aged refuse was basically stable.
(8)Aged-refuse-based bioreactor had a buffer capacity and degradation performance of organic matter for leachate.Leachate effluent was basically neutral, and COD removal efficiency increased from the start of 7.4%gradually to a maximum value of 39.2%,and then dropped,basically stable at around 10.0%.
(9)The adsorption equation of leachate COD and NH_4~+-N in the soil was consistent with Langmuir isothermal adsorption equation,and the adsorption of leachate COD and NH_4~+-N by the soil increased by their concentration.Because adsorption was a exothermic reaction,adsorption of COD and NH_4~+-N decreased by temperature,saturated adsorption of the order was in 10℃、20℃and 30℃.The desorption of leachate COD and NH_4~+-N increased by their adsorption amount,but desorbed little from the soil.
(10)Temperature had a great impact on the purifying effect of leachate COD by the soil.At 20℃and 30℃,with the extension of culture time,the exudation of leachate COD was on a significant downward trend.For three days,the COD exudation of leachate(A)decreased rapidly from the beginning of 1984.8 mg/kg to the third day of 52.0 mg/kg and 54.2 mg/kg.The COD exudation of leachate(B) decreased rapidly from the beginning of 768.0 mg/kg to the third day of 54.18 mg/kg and 50.98 mg/kg.And then,the COD exudation of both leachate changed very little. At low temperature of 10℃,the exudation of leachate COD declined slowly.After a week,the COD exudation of leachate(A)was still up to 714.0 mg/kg.As leachate(B) contained little pollutants,the purifying effect was not particularly evident compared with 20℃,30℃,and gradually narrow with the extension of time.The COD exudation of leachate(B)was 98.0 mg/kg after a week.
(11)Temperature had a great impact on the purifying effect of leachate NH_4~+-N by the soil..At 20℃and 30℃,With the extension of culture time,the exudation of leachate NH_4~+-N was on a significant downward trend.For 5 days,the NH_4~+-N exudation of leachate(A)decreased rapidly from the beginning of 105.32 mg/kg to the fifth day of 4.36 mg/kg and 4.34 mg/kg.The NH_4~+-N exudation of leachate(B) decreased rapidly from the beginning of 106.38 mg/kg to the fifth day of 4.38 mg/kg and 4.34 mg/kg.And then,the NH_4~+-N exudation of both leachate changed very little, and the NH_4~+-N concentration was very low.At low temperature of 10℃,the exudation of leachate NH_4~+-N declined slowly.After a week,the NH_4~+-N exudation of leachate(A)and leachate(B)were 33.44 mg/kg and 33.58 mg/kg,respectively.
(12)When the rural domestic refuse in Shi village was disposed by sequencing batch bioreactor,total leachate amount was 10000L one year.Therefore,it need a soil of 396.8m~2 and five days treatment to reach a low COD and NH_4~+-N exudation.As each set of bioreactor apparatus discharged leachate once in 70 days,that is,the 396.8m~2 soil treated leachate only once in a year,leachate COD and NH_4~+-N adsorbed by the soil could be degradated well.
(13)After leachate running in sequencing batch bioreactor for 70 days was purified by the soil once,Cu incremental content in soil was 0.2 mg/kg,Zn incremental content was 0.5 mg/kg.As the soil treated leachate only once in a year,so heavy metal had little pollution to the soil.
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