光催化Fenton降解邻苯二甲酸二乙酯，对硝基苯胺和对硝基苯酚的研究
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摘要
光催化技术与其他高级氧化技术的联合在环境领域的应用研究是近些年来的热点。光催化技术由于存在反应时间长,光催化降解效率低等问题,目前该技术在实际工程中应用较少；Fenton技术在水处理污染时具有快速、设备简单、无二次污染的特点,但由于其氧化降解不够充分、氧化剂用量较大、成本高等缺点,该技术在实际工程中也较少单独使用。本文采用零价铁类Fenton试剂、普通Fenton试剂氧化体系与光催化技术耦联对难降解有机废水进行了处理,主要进行了以下研究：
(1)光催化零价铁类Fenton体系对邻苯二甲酸二乙酯的处理研究。考察了主要影响因素：pH、双氧水量、铁粉量、催化剂量、紫外灯功率、温度和邻苯二甲酸二乙酯初始浓度等因素对邻苯二甲酸二乙酯降解效果的影响；通过GC/MS技术对其降解机理进行了初步探讨。结果表明：在目标物溶液pH为中性时,光催化零价铁类Fenton技术联合处理1h后,邻苯二甲酸二乙酯的降解率可达到86%以上；铁粉和TiO2重复利用3次后,仍有80%以上的降解率；苯环结构被破坏。
(2)光催化零价铁类Fenton体系对对硝基苯胺的处理研究。考察了主要影响因素：pH、双氧水量、铁粉量、紫外灯功率、催化剂Ti02用量、温度、甲醇、对硝基苯胺初始浓度等因素对对硝基苯胺降解效果的影响；通过GC/MS技术对其在酸性条件下的降解机理进行了研究。结果表明：pH对降解效果影响较大,中性或者碱性条件下,对硝基苯胺几乎不能降解；调节反应液pH为4时,光催化零价铁类Fenton试剂对对硝基苯胺的氧化降解率14min可达80%以上；铁粉和Ti02重复利用3次后,仍有60%以上的降解率。
(3)光催化Fenton体系对对硝基苯酚的处理研究。考察了主要影响因素：pH、双氧水量、Fe2+量、催化剂量和对硝基苯酚初始浓度等对对硝基苯酚降解效果的影响；通过GC/MS技术对其降解机理进行了研究,降解过程中主要产物有对苯二酚、4-硝基儿茶酚、对苯醌等。
The application of photo catalysis coupling with many other advanced oxidation processes attract many environmentalist' interesting in wastewater treatment in recent years. Because of its long reaction time, low efficiency and some other problems, the studies are still focused on the lab's field and the real application is just start. With the advantages of high speed of reaction, easy process and without second pollution of Fenton techniques, it's applying a lot but not alone because of its insufficiency degradation, high dose of oxidant and high cost.
In this dissertation, Fenton system and like-Fenton system using zero valent metallic iron facilitated by photo catalysis had been developed for the degradation of bio-refractory organic contaminations in wastewater.
(1) The degradation of DEP in a synergetic system of photo catalysis coupled with like-Fenton reagent was studied. The influences of operation conditions on the degradation of DEP was investigated, such as pH value, the concentration of DEP, the additional amount of Fe0 and H2O2 catalytic agent,temperature and the UV radiation power. Structures of intermediate products and final products were detected by gas chromatography-mass spectrometry (GC/MS). The results showed that the degradation rate reached 86% after treated for 1 hour with photo catalysis/Fenton technique, Moreover,80% of DEP were still degraded after reused the iron and TiO2 for 3 times, and the phenyl was decomposed to the bio-degradable substances.
(2) The degradation of p-nitroaniline using zero iron metal of Fenton process facilitated by photo catalysis was studied. The influences of UV irradiation, pH value, the concentration of p-nitroaniline, the additional amount of Fe0 and TiO2, H2O2 and temperature, CH3OH were investigated. GC/MS was applied to study the degradation pathways. The results showed that pH play an important role in the degradation. P-nitroaniline can not be reacted under the basic condition. The results showed that the degradation rate reached 80% after treated for 14min with photo catalysis/Fenton technique. Moreover,80% of p-nitroaniline were still degraded after reused the iron and TiO2 for 3 times.
(3) The degradation of 4-nitrophenol using Fenton process assisted by photo catalysis was studied. The influences of different impact factors such as pH value, the concentration of 4-nitrophenol, the additional amount of TiO2 and H2O2 were studied in detail. Further more, hydroquinone,4-nitrocatechol, p-Benzoquinone and other intermediate products were found by GC/MS and a probable degradation mechanism was proposed.
(1)光催化零价铁类Fenton体系对邻苯二甲酸二乙酯的处理研究。考察了主要影响因素：pH、双氧水量、铁粉量、催化剂量、紫外灯功率、温度和邻苯二甲酸二乙酯初始浓度等因素对邻苯二甲酸二乙酯降解效果的影响；通过GC/MS技术对其降解机理进行了初步探讨。结果表明：在目标物溶液pH为中性时,光催化零价铁类Fenton技术联合处理1h后,邻苯二甲酸二乙酯的降解率可达到86%以上；铁粉和TiO2重复利用3次后,仍有80%以上的降解率；苯环结构被破坏。
(2)光催化零价铁类Fenton体系对对硝基苯胺的处理研究。考察了主要影响因素：pH、双氧水量、铁粉量、紫外灯功率、催化剂Ti02用量、温度、甲醇、对硝基苯胺初始浓度等因素对对硝基苯胺降解效果的影响；通过GC/MS技术对其在酸性条件下的降解机理进行了研究。结果表明：pH对降解效果影响较大,中性或者碱性条件下,对硝基苯胺几乎不能降解；调节反应液pH为4时,光催化零价铁类Fenton试剂对对硝基苯胺的氧化降解率14min可达80%以上；铁粉和Ti02重复利用3次后,仍有60%以上的降解率。
(3)光催化Fenton体系对对硝基苯酚的处理研究。考察了主要影响因素：pH、双氧水量、Fe2+量、催化剂量和对硝基苯酚初始浓度等对对硝基苯酚降解效果的影响；通过GC/MS技术对其降解机理进行了研究,降解过程中主要产物有对苯二酚、4-硝基儿茶酚、对苯醌等。
The application of photo catalysis coupling with many other advanced oxidation processes attract many environmentalist' interesting in wastewater treatment in recent years. Because of its long reaction time, low efficiency and some other problems, the studies are still focused on the lab's field and the real application is just start. With the advantages of high speed of reaction, easy process and without second pollution of Fenton techniques, it's applying a lot but not alone because of its insufficiency degradation, high dose of oxidant and high cost.
In this dissertation, Fenton system and like-Fenton system using zero valent metallic iron facilitated by photo catalysis had been developed for the degradation of bio-refractory organic contaminations in wastewater.
(1) The degradation of DEP in a synergetic system of photo catalysis coupled with like-Fenton reagent was studied. The influences of operation conditions on the degradation of DEP was investigated, such as pH value, the concentration of DEP, the additional amount of Fe0 and H2O2 catalytic agent,temperature and the UV radiation power. Structures of intermediate products and final products were detected by gas chromatography-mass spectrometry (GC/MS). The results showed that the degradation rate reached 86% after treated for 1 hour with photo catalysis/Fenton technique, Moreover,80% of DEP were still degraded after reused the iron and TiO2 for 3 times, and the phenyl was decomposed to the bio-degradable substances.
(2) The degradation of p-nitroaniline using zero iron metal of Fenton process facilitated by photo catalysis was studied. The influences of UV irradiation, pH value, the concentration of p-nitroaniline, the additional amount of Fe0 and TiO2, H2O2 and temperature, CH3OH were investigated. GC/MS was applied to study the degradation pathways. The results showed that pH play an important role in the degradation. P-nitroaniline can not be reacted under the basic condition. The results showed that the degradation rate reached 80% after treated for 14min with photo catalysis/Fenton technique. Moreover,80% of p-nitroaniline were still degraded after reused the iron and TiO2 for 3 times.
(3) The degradation of 4-nitrophenol using Fenton process assisted by photo catalysis was studied. The influences of different impact factors such as pH value, the concentration of 4-nitrophenol, the additional amount of TiO2 and H2O2 were studied in detail. Further more, hydroquinone,4-nitrocatechol, p-Benzoquinone and other intermediate products were found by GC/MS and a probable degradation mechanism was proposed.
引文
[1]Balagure P,Francois F,Comunate F, et al. Sci. Total. En[J],1999,233 (3):47-56
[2]Chai Xiaoli, Ji Rong, Wu Jun, Tong Huanhuan and Zhao Youcai, Abiotic association of PAEs with humic substances and its influence on the fate of PAEs in landfill leachate[J]Chemosphere, Volume 78, Issue 11, March 2010, Pages:1362-1367
[3]汤付寿.食品塑料包装材料中邻苯二甲酸酯类环境激素分析方法研究.中国地质大学硕士学位论文[M]2009,5
[4]Rastogi RC, Maas RP, Patch SC, Pandolfo TJ,The safe of Chemicals promote sustainable develop ment, IFCS/FORUM-V/03-TS,2006,9,25-29
[5]石志博,姚宁,朱玉,张晓明.邻苯二甲酸酯类增塑剂的正确评价和使用[J].塑料助剂,,2009,5(77)：43-48
[6]Feng Zeng, Kunyan Cui, Zhiyong Xie,Phthalate esters(PAEs):Emerging organic contaminants in agricultural soils in peri-urban areas around Guangzhou, China[J]. Environmental Pollution, Volume 156, Issue 2, November 2008, Pages:425-434
[7]王琳,罗启芳.环境内分泌干扰物邻苯二甲酸二丁酯的生物降解特性[J].卫生研究.2003,32(3)：187-189
[8]NIAZU H, PRASAD DT, KARCGOUDAR TB. Initial degradation of diethyl phthalate by esterase from Bacillus species [J].FEMS Microbiology Letters,2001,196:201-205
[9]王建龙,吴立波,钱易等.驯化活性污泥降解邻苯二甲酸酯类化合物的研究[J].环境科学,1998,19(1)：18-20
[10]WANG J L. Biodegradation of phthalic acid esters PAEs in soil bioaugmented with acclimated activated sludge [J]Process Biochemistry,2004,39 12:1837-1841
[11]张国宇,王鹏,姜思朋.微波辐射处理酯化废水的工艺技术研究[J].给水排水.2004,30(8)： 61
[12]刘军,王珂.臭氧-活性炭工艺对饮用水中邻苯二甲酸酯的去除[J].环境科学,2003：24(7)：77-80
[13]YANG G P, ZHAO X K, SUN X J. Oxidative degradation of diethyl phthalate by photo chemically-enhanced Fenton reaction[J]. Journal of Hazardous Materials.2005,126(1-3):112- 118
[14]BAJTO, MAILHOT G, BOLTEM. Degradation of dibutyl phthalate by homogeneous photo catalysis with Fe Ⅲ in aqueous solution [J]. Appl. Catal. B:Environmental,2001,33:239-248
[15]G.Mailhot, M.Sarakha, B.Lavedrine, J.Caceres, S.Malato Fe(Ⅲ)-solar light induced degradation of diethyl phthalate (DEP) in aqueous solutions,[J] Chemosphere 49(2002):525-532
[16]Huan-Jung Fan, Shiuh-Tsuen Huang, Wen-Hsin Chung, Degradation pathways of crystal violet by Fenton and Fenton-likesystems:Condition optimization and intermediate separation and identification [J] Journal of Hazardous Materials,Volume 171, Issues 1-3,15 November 2009, Pages 1032-1044
[17]B.Muthukumari, K. Selvam, I. Muthuve and M. Swaminathan. Photoassisted hetero-Fenton mineralisation of azo dyes by Fe(Ⅱ)-Al2O3 catalyst [J].Chemical Engineering Journal Volume 153, Issues 1-3,1 November 2009, Pages 9-15
[18]Bin Xu,Nai-Yun Gao, Xiao-Feng Sun, Sheng-Ji Xia, Min Rui, Photochemical degradation of diethyl phthalate with UV/H2O2[J]. Journal of Hazardous Materials (B139) 2007,132-139
[19]边绍伟,王敏,杨睿媛,王文峰.苯胺类污染物的电子束辐照降解研究.辐射研究与辐射工艺学报.2005,23(2)：119
[20]田凯勋,戴友芝,张良长.超声波/零价铁降解对氯苯胺性能及机理研究.环境工程学报.2008,2(2)：166-169
[21]傅厚暾,赵俐敏,冯娟.Fenton试剂-超声波降解对硝基苯胺产物的分析.江汉大学学报(自然科学版),2004,32(2)：74-76
[22]王存,王鹏,徐柏庆ZnO-SnO2纳米复合氧化物光催化剂催化降解对硝基苯胺.催化学报.2004,25(12)：967-972
[23]胡文勇,郑正,郑寿荣,郭照冰.超声波/零价铁降解对硝基苯胺的试验研究.环境污染治理技术与设备[J].2005,6(3)：28-32
[24]王磊,芦小飞,牛学坤,王新德.Fe/C/H2O2混凝法对N-甲基对硝基苯胺生产废水的预处理.化学推进剂与高分子材料[J].2008.6(1)：59-62
[25]何国利,张运掏.光催化降解对硝基苯胺的模拟研究.计算机与应用化学[J].2009,26(4)： 435-439
[26]Ting, W.-P., M.-C. Lu, and Y.-H. Huang.Kinetics of 2,6-dimethylaniline degradation by electro-Fenton process. Journal of Hazardous Materials,2009.161(2-3):1484-1490.
[27]Kavitha V, Palanivelu K.Degradation of nitrophenols by Fenton and photo-Fenton process [J].J.Photochem. Photobiol. A:Chem.,2005,170(1):83-95.
[28]刘琼玉,陈汉全,邹隐文等太阳光Fenton氧化-混凝联合处理含酚废水[J].太阳能学报,2007,28(7)：695-700
[29]许春建,王卉,吕东来等.US/Fenton试剂法在水体系中降解对硝基苯酚的研究.高校化学工程学报[J].2005,19(04)：567-570
[30]刘自力,孙建华.液电等离子体降解对硝基苯酚的研究.广州大学学报(自然科学版)[J].2008,7(5)：34-39
[31]杨芬,甘复兴,侯能邦,汪帆,吕泽良Sb-SnO2/Ti电极对对硝基苯酚电催化氧化影响因素和机理研究.水处理技术[J].2009,35(2)：58-61
[32]史惠祥,徐献文,汪大晕.US/O3降解对硝基苯酚的影响因素及机理.化工学报[J].2006,57(2)：390-396
[33]鲁秀国,刘玮,翟建,刘福强,焦玲,任焕弟,张全兴.磁强化次氯酸钠氧化法处理邻硝基苯酚废水的实验研究.环境污染与防治[J].2005,27(4)：268-270
[34]卜龙利,陈硕,全燮,刘希涛,赵慧敏.微波辅助湿式氧化处理对硝基酚溶液的研究.中国科学E辑[J].工程科学材料科学2005,35(3)：324-336
[35]黄艳娥,琚行松纳米二氧化钛光催化降解水中有机污染物的研究[J].现代化工,2001,21(4)：45-48
[36]张丹,张学俊.TiO2光催化剂掺杂改性的研究进展.化学中间体[J].2010,7：18-20
[37]何建波,张鑫,魏凤玉等.TiO2薄膜晶相组成对苯胺光催化降解的影响.应用化学[J].1999,165(5)：57～60
[38]Lindner M, Kato K, Solar Water Detoxification:Novel TiO2 Powders a Highly Active Photo catalysts[J].Journal of Solar Energy Engineering 1997,119(3):120-125
[39]史载锋.光催化陶瓷膜反应器的实验研究与数学模拟[D].南京：南京化工大学,1999
[40]高湘,贾西宁,赵雪松.Fenton氧化法对PVC生产废水的处理的研究.中小企业管理与科技.[J].2008,45(29)：147～148
[41]Huiling zhang; Yaping HuangTreatment of p-nitrophenol Solution by Ultrasound-Fenton Environmental Science and Management. [J] 2006,31(8),141-144,
[42]Ma, Y.S., Huang, S.T. and Lin, J.G.. Degradation of 4-nitrophenol using the Fenton process. Water Sci. Technol [J].2000,71 (42):155-160
[43]Hui Zhang, Chengzhi Fei, Daobin Zhang et al Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials.[J].2007,31 (145):227-232
[44]C. Pulgarin, P. Peringer, P. Albers, J. Kiwi, Effect of Fe-ZSM-5-Zeolite on the photo chemical and biochemical degradation of 4-nitrophenol, J. Mol. Catal. A:Chem.[J].1995,12(95): 61-74.
[45]C.L.Hsueh Y.H. Huang et al. Degradation of azo dyes using low iron concentration of Fenton and Fenton-like system Chemosphere.[J].2005,13(58) 1409-1414
[46]K. Barbusinski, J.Majewski, Degradation of azo dye acid red18 by Fenton reagent in the presence of iron powder, Polish J. Environ. Stud.[J].2003,14(12):151-155.
[47]Oliver sze nga sum, Jiyun Feng, Xijun Hu, Po Lock Yue, Photo assisted Fenton mineralization of an azo dye acid black 1 using a modified laponite clay based Fe nano composite as a heterogeneous catalysts, Top. Catal [J].2005,45(33):233-242
[48]L. Gomathi Devi, S. Girish Kumar, K. Mohan Reddy et al. Journal of Hazardous Materials 2009,65(164):459-467
[49]Jiasheng Cao, Liping Wei, Qinggguo Huang, Liansheng Wang, Shuokui Han,Reducing degradation of azo dye by Zero Valent Iron in aqueous solution,Chemosphere 1999,25(38): 565-571.
[50]C.L.Hsueh Y.H. Huang et al. Degradation of azo dyes using low iron concentration of Fenton and Fenton-like system Chemosphere.[J].2005,13(58):1409-1414
[51]李绍峰,黄君礼,陈志强Oxidative Treatment of Some Reactive Dyes by Fenton Reagent. Journal of Donghua University.[J].2003,54(01):70-73
[52]许景文.过氧化氢-铁盐化学氧化法用于有机废水深度处理[J].环境污染与防治,1985,7(5)： 1-3
[53]冀小元,云桂春.H2O2/Fe2+/TiO2 H2SO4体系处理废有机溶剂的研究[J].上海环境科学,1996,15(8)： 33-36
[54]Marina TrapidoAve DelloAnna GoiRein MunterDegradation of nitroaromatics with the Fenton reagent[J].ProcEstonian AcadSciChem2003,52(1):38-47
[55]Byung-Dae LeeMasaaki HosomiEthanol washing of PAH-contaminated soil and Fenton oxidation of washing solution[J]J Mater Cycles Waste Manag2000,224-30
[56]V Kavitha K Palanivelu Degradation of 2-Chlorophenot by Fenton and Photo-Fenton Processes-A Comparative Study[J].Journal of Environmental Science and Health2003,38(7):1215-1231
[57]Ghizlaine KaichouhNihal OturanMehmet AOturanKacem El Kacemi Abderrahim El HourchDegradation of the herbicide imazapy by Fenton reactions[J]Environ ChemLett2004,23:133
[58]BarbushiskiKFilipekK Use of Fenton's reagent for removal of pesticides from industrial wastewater[J]Polish Journal of Environmental Studies2001,10(4):207-212
[59]Arturo A BurbanoDionysios DDionysiouTeri LRichardsonMakram T Suidan Degradation of MTEB intermediates using Fenton's Reagent [J]. Journal of Environmental Engimeering2002,128(9):799-805
[60]Katherine RWeeksClifford JBruellNihar RMohantyUse of Fenton's reagent for the degradation of TCE in aqueous systems and soil slurries[J].Soil and Sediment Contamination2009,(4):331-345
[61]Carla WscheerenJosh Neri GPanizAyrton FMartinsComparison of advanced processes on the oxidation of acid orange 7 dye [J].Journal of Environmental Science and Health2002,37(7):1253-1261
[62]Marina TrapidoAve DelloAnna GoiRein Munter Degradation of nitroaromatics with the Fenton reagentProc[J].Estonian AcadSciChem2003,52(1):38-47
[63]Ivan WCLauPeng WangHerbert HPFangOrganic removal of anaerobically treated leachate by Fenton coagulation[J]. Journal of Environmental Engineering2001,127(7):666-669
[64]Hee-Chan YooSoon-haing ChoSeok-Oh KoModification of coagulation and Fenton oxidation processes for cost-effective leachate treatment[J]Journal of Environmental Science and Health2001,36(1):39-48
[65]黄晓东,徐寿昌.用芬顿试剂预氧化提高硝基苯废水的可生化性.江汉石油学院学报[J].1994,28(03)：74～78
[66]肖羽堂,许建华.利用芬顿试剂预处理难降解的二硝基氯化苯废水.重庆环境科学.[J].1997,32(06)：32～36
[67]李生彬,王拯,饶姗姗等.Fenton试剂氧化处理拆弹炸药废水.西北民族大学学报(自然科学版)[J].2005,42(01)：32～35
[68]F. Lucking, H. Koser, M. Jank, A. Ritter, Iron powder and graphite and activated carbon as a catalyst for the oxidation of 4-chlorophenol with hydrogen peroxide in aqueous solution,Water Res.[J].1998,65{32}:2607-2614.
[69]P. Papapolymerou, K. Ntampegliotis, Riga.A. Karayannis, V. Bontozoglou, V Decolorization kinetics of Procion H-exl dyes from textile dyeing using Fentonlike reactions, J. Hazard. Mater [J].2006,45 (136):75-84.
[70]Roger Matta, Khalil Hanna, Serge Chiron, Fenton like oxidation of 2,4,6 Trinitro toluene using different minerals, Sci. Total Environ.[J].2007,28(385):242-251.
[71]N. Daneshvar, A.R. Khataee, Removal of azo dye C.I. Acid Red 14 from contaminated water using Fenton,UV/H2O2,UV/H2O2/Fe(Ⅱ),UV/H2O2/Fe(Ⅲ) and UV/H2O2/Fe(Ⅲ)/oxalate processes: a comparative study. Environ. Sci. Health Part A [J].2006,34(41):315-328.
[72]B.H. Guan, Y.F. Meng, Dechlorination of chloroform in organic fluorine chemical plant waste water with Zero Valent Iron, Am. Chem. Soc.[J].2005,72 (229):U844.
[73]M.Neamtu,A.Yediler, I. Siminiceamu,A.Kettrup, Oxidation ofcommercial reactive azo dye aqueous solutions by the photo Fenton and Fenton-like processes, Photochem. Photobiol. A: Chem [J].2003,12(161):87-93
[74]夏良树,李来丙,王孟等.纳米TiO2协同Fenton试剂光催化降解甲基橙[J].太阳能学报.2007,28(1)：51-54
[75]Oliver sze nga sum, Jiyun Feng, Xijun Hu, Po Lock Yue, Photo assisted Fenton mineralization of an azo dye acid black 1 using a modified laponite clay based Fe nano composite as a heterogeneous catalysts, Top. Catal.[J].2005,45(33):233-242
[76]张乃东,黄君礼,郑威.强化UV/Fenton法降解水中苯酚的研究.环境污染治理技术与设备[J].2002,3(2)：19～24
[77]杨运平,唐金晶.UV/TiO2/enton光催化氧化垃圾渗滤液的研究.中国给水排水[J].2006,22(7)：34-38
[78]彭延治,徐明芳,曾常军等.UV-TiO2-Fenton光催化降解敌百虫农药废水的研究.工业水处理[J].2006,26(6)：33-36.
[79]Ruppert G, Bauer R. UV-O3、UV-H2O2、UV-TiO2 and the photo-Fenton reaction-comparison of AOPs for wasterwater treatment [J]. Chemosphere,1994,28(5):1447-1454
[80]Rein Munter.Advanced oxidation process-current status and prospects[J]. Estonian Acad Sci Chem,2001,50(2):59-80.
[81]Oller Malato S, Sanchez-Pe│rez J A, et al. A combined solar photocatalytic-biological field system for the mineralization of an industrial pollutant at pilot scale[J]. Catalysis Today,2007, 122 (1-2):150-159
[82]Kajitvichyanukul P, Suntronvipart N. Evaluation of biodegradability and oxidation degree of hospital wastewater using photo-Fenton process as the pretreatment method [J]. Journal of Hazardous Materials,2006,138 (2):384-391.
[83]赵超,黄应平.可见光异相photo-Fenton体系降解有机染料橙Ⅱ.环境工程学报.[J].2007,1(06)：19～24
[84]Zapata, A. Evaluation of operational parameters involved in solar photo-Fenton degradation of a commercial pesticide mixture. Catalysis Today,2009.144(1-2):94-99.
[85]何丹凤,周付江,刘金泉.Fenton试剂对水体中多环芳烃(PAHs)污染物的去除效果研究.化学工程师.[J].2008,22(03)：42～45
[86]苏荣军.芬顿试剂氧化污水及无机离子影响的研究.哈尔滨商业大学学报(自然科学版).[J].2008,24(2)：210～217.
[87]Sara Goldstein, Dan Meyerstein, Gdion Czapski. The Fenton reagents[J].Free Radical Biology and Medicine,1993,15(4):435-445
[88]苏荣军.芬顿试剂氧化污水及无机离子影响的研究.哈尔滨商业大学学报(自然科学版).[J].2008,24(2)：210-217.
[89]陈序红,徐蕾.纳米二氧化钛与Fenton试剂光催化降解直接耐酸大红的研究[J].吉林工程技术师范学院学报(自然科学版).2007,23(3)：18-20
[90]陶长元,刘作华,孙大贵等.温度对Fenton法催化脱色甲基橙溶液影响的研究.[J].西南大学学报(自然科学版),2007,34(1)：157-160.
[91]M.Neamtu,A.Yediler, I. Siminiceamu,A.Kettrup, Oxidation ofcommercial reactive azo dye aqueous solutions by the photo Fenton and Fenton-like processes, Photochem. Photobiol. A: Chem.[J].2003,12(161):87-93
[92]C.S. Chiou, J.L. Shie, C.Y. Chang, C.C. Liu, C.T. Chang, Degradation of di-n-dutyl phthalate using photoreactor packed with TiO2 immobilized on glass beads[J]. J.Hazard.Mater., 2006,137:1123-1129
[93]班福忱,李亚峰,贾新军等.光助电-Fenton法催化降解硝基苯及影响因素.沈阳建筑大学学报(自然科学版)[J].2006,22(5)：809-811
[94]ARANA J,ROGRIGUEZL VM,DONA R JM, etal. The effect of aliphatic carboxylic acids on the photocatalytic degradation of p-nitrophenol[J]. Catalysis Today,2007,129(1-2):185-193.
[95]Yunfu Sun, Joseph J. Pignatello. Photochemical Reaction Involved in the TotalM ineralization of 2,4-D by Fe/H2O2/UV [J]. Environ. Sci. Technol,1993,272:304-310.
[96]许春建,王卉,吕东来等.US/Fenton试剂法在水体中降解对硝基苯酚的研究,高校化学工程学报[J].2005,19(4)：567-570.
[97]张惠灵,黄雅萍.超声波/Fenton联用对对硝基苯酚的处理.环境科学与管理[J].2006,31(8)：141-144.
[98]N.Daneshvar,M.A.Behnajady,Y.ZorriyehAsghar. Photooxidative degradation of 4-nitrophenol(4-NP) in UV/H2O2 process:Inf ence of operational parameters and reaction mechanism Journal of Hazardous Materials [J]B139(2007):275-279.
[99]HuiZhang, ChengzhiFei, DaobinZhang, FengTang.Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials [J] 145(2007):227-232.
[100]V.Kavitha,K.Palanivelu Degradation of nitrophenols by Fenton and photo-Fenton processes Journal of Photo chemistry and Photobiology A:Chemistry170(2005):83-95.
[101]冯小刚,戎非,袁春伟.TiO2光催化降解有机污染物的协同效应研究.环境污染治理技术与设备[J].2004,5(9)：12-15.
[102]田维,张洪林,蒋林时.光-Fenton试剂协同TiO2对苯酚废水降解加速作用的研究长春理工大学学报[J].2006,29(2)：100-103.
[103]钱易,米样支.现代废水处理新技术[M].北京：中国科学技术出版社,1993：162-163.
[104]何峰.UV-Fenton处理难降解有机废水的研究.浙江大学硕士论文[M].2002：58-60.
[105]Hui Zhang, Chengzhi Fei, Daobin Zhang et al Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials[J].2007,31 (145):227-230.
[2]Chai Xiaoli, Ji Rong, Wu Jun, Tong Huanhuan and Zhao Youcai, Abiotic association of PAEs with humic substances and its influence on the fate of PAEs in landfill leachate[J]Chemosphere, Volume 78, Issue 11, March 2010, Pages:1362-1367
[3]汤付寿.食品塑料包装材料中邻苯二甲酸酯类环境激素分析方法研究.中国地质大学硕士学位论文[M]2009,5
[4]Rastogi RC, Maas RP, Patch SC, Pandolfo TJ,The safe of Chemicals promote sustainable develop ment, IFCS/FORUM-V/03-TS,2006,9,25-29
[5]石志博,姚宁,朱玉,张晓明.邻苯二甲酸酯类增塑剂的正确评价和使用[J].塑料助剂,,2009,5(77)：43-48
[6]Feng Zeng, Kunyan Cui, Zhiyong Xie,Phthalate esters(PAEs):Emerging organic contaminants in agricultural soils in peri-urban areas around Guangzhou, China[J]. Environmental Pollution, Volume 156, Issue 2, November 2008, Pages:425-434
[7]王琳,罗启芳.环境内分泌干扰物邻苯二甲酸二丁酯的生物降解特性[J].卫生研究.2003,32(3)：187-189
[8]NIAZU H, PRASAD DT, KARCGOUDAR TB. Initial degradation of diethyl phthalate by esterase from Bacillus species [J].FEMS Microbiology Letters,2001,196:201-205
[9]王建龙,吴立波,钱易等.驯化活性污泥降解邻苯二甲酸酯类化合物的研究[J].环境科学,1998,19(1)：18-20
[10]WANG J L. Biodegradation of phthalic acid esters PAEs in soil bioaugmented with acclimated activated sludge [J]Process Biochemistry,2004,39 12:1837-1841
[11]张国宇,王鹏,姜思朋.微波辐射处理酯化废水的工艺技术研究[J].给水排水.2004,30(8)： 61
[12]刘军,王珂.臭氧-活性炭工艺对饮用水中邻苯二甲酸酯的去除[J].环境科学,2003：24(7)：77-80
[13]YANG G P, ZHAO X K, SUN X J. Oxidative degradation of diethyl phthalate by photo chemically-enhanced Fenton reaction[J]. Journal of Hazardous Materials.2005,126(1-3):112- 118
[14]BAJTO, MAILHOT G, BOLTEM. Degradation of dibutyl phthalate by homogeneous photo catalysis with Fe Ⅲ in aqueous solution [J]. Appl. Catal. B:Environmental,2001,33:239-248
[15]G.Mailhot, M.Sarakha, B.Lavedrine, J.Caceres, S.Malato Fe(Ⅲ)-solar light induced degradation of diethyl phthalate (DEP) in aqueous solutions,[J] Chemosphere 49(2002):525-532
[16]Huan-Jung Fan, Shiuh-Tsuen Huang, Wen-Hsin Chung, Degradation pathways of crystal violet by Fenton and Fenton-likesystems:Condition optimization and intermediate separation and identification [J] Journal of Hazardous Materials,Volume 171, Issues 1-3,15 November 2009, Pages 1032-1044
[17]B.Muthukumari, K. Selvam, I. Muthuve and M. Swaminathan. Photoassisted hetero-Fenton mineralisation of azo dyes by Fe(Ⅱ)-Al2O3 catalyst [J].Chemical Engineering Journal Volume 153, Issues 1-3,1 November 2009, Pages 9-15
[18]Bin Xu,Nai-Yun Gao, Xiao-Feng Sun, Sheng-Ji Xia, Min Rui, Photochemical degradation of diethyl phthalate with UV/H2O2[J]. Journal of Hazardous Materials (B139) 2007,132-139
[19]边绍伟,王敏,杨睿媛,王文峰.苯胺类污染物的电子束辐照降解研究.辐射研究与辐射工艺学报.2005,23(2)：119
[20]田凯勋,戴友芝,张良长.超声波/零价铁降解对氯苯胺性能及机理研究.环境工程学报.2008,2(2)：166-169
[21]傅厚暾,赵俐敏,冯娟.Fenton试剂-超声波降解对硝基苯胺产物的分析.江汉大学学报(自然科学版),2004,32(2)：74-76
[22]王存,王鹏,徐柏庆ZnO-SnO2纳米复合氧化物光催化剂催化降解对硝基苯胺.催化学报.2004,25(12)：967-972
[23]胡文勇,郑正,郑寿荣,郭照冰.超声波/零价铁降解对硝基苯胺的试验研究.环境污染治理技术与设备[J].2005,6(3)：28-32
[24]王磊,芦小飞,牛学坤,王新德.Fe/C/H2O2混凝法对N-甲基对硝基苯胺生产废水的预处理.化学推进剂与高分子材料[J].2008.6(1)：59-62
[25]何国利,张运掏.光催化降解对硝基苯胺的模拟研究.计算机与应用化学[J].2009,26(4)： 435-439
[26]Ting, W.-P., M.-C. Lu, and Y.-H. Huang.Kinetics of 2,6-dimethylaniline degradation by electro-Fenton process. Journal of Hazardous Materials,2009.161(2-3):1484-1490.
[27]Kavitha V, Palanivelu K.Degradation of nitrophenols by Fenton and photo-Fenton process [J].J.Photochem. Photobiol. A:Chem.,2005,170(1):83-95.
[28]刘琼玉,陈汉全,邹隐文等太阳光Fenton氧化-混凝联合处理含酚废水[J].太阳能学报,2007,28(7)：695-700
[29]许春建,王卉,吕东来等.US/Fenton试剂法在水体系中降解对硝基苯酚的研究.高校化学工程学报[J].2005,19(04)：567-570
[30]刘自力,孙建华.液电等离子体降解对硝基苯酚的研究.广州大学学报(自然科学版)[J].2008,7(5)：34-39
[31]杨芬,甘复兴,侯能邦,汪帆,吕泽良Sb-SnO2/Ti电极对对硝基苯酚电催化氧化影响因素和机理研究.水处理技术[J].2009,35(2)：58-61
[32]史惠祥,徐献文,汪大晕.US/O3降解对硝基苯酚的影响因素及机理.化工学报[J].2006,57(2)：390-396
[33]鲁秀国,刘玮,翟建,刘福强,焦玲,任焕弟,张全兴.磁强化次氯酸钠氧化法处理邻硝基苯酚废水的实验研究.环境污染与防治[J].2005,27(4)：268-270
[34]卜龙利,陈硕,全燮,刘希涛,赵慧敏.微波辅助湿式氧化处理对硝基酚溶液的研究.中国科学E辑[J].工程科学材料科学2005,35(3)：324-336
[35]黄艳娥,琚行松纳米二氧化钛光催化降解水中有机污染物的研究[J].现代化工,2001,21(4)：45-48
[36]张丹,张学俊.TiO2光催化剂掺杂改性的研究进展.化学中间体[J].2010,7：18-20
[37]何建波,张鑫,魏凤玉等.TiO2薄膜晶相组成对苯胺光催化降解的影响.应用化学[J].1999,165(5)：57～60
[38]Lindner M, Kato K, Solar Water Detoxification:Novel TiO2 Powders a Highly Active Photo catalysts[J].Journal of Solar Energy Engineering 1997,119(3):120-125
[39]史载锋.光催化陶瓷膜反应器的实验研究与数学模拟[D].南京：南京化工大学,1999
[40]高湘,贾西宁,赵雪松.Fenton氧化法对PVC生产废水的处理的研究.中小企业管理与科技.[J].2008,45(29)：147～148
[41]Huiling zhang; Yaping HuangTreatment of p-nitrophenol Solution by Ultrasound-Fenton Environmental Science and Management. [J] 2006,31(8),141-144,
[42]Ma, Y.S., Huang, S.T. and Lin, J.G.. Degradation of 4-nitrophenol using the Fenton process. Water Sci. Technol [J].2000,71 (42):155-160
[43]Hui Zhang, Chengzhi Fei, Daobin Zhang et al Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials.[J].2007,31 (145):227-232
[44]C. Pulgarin, P. Peringer, P. Albers, J. Kiwi, Effect of Fe-ZSM-5-Zeolite on the photo chemical and biochemical degradation of 4-nitrophenol, J. Mol. Catal. A:Chem.[J].1995,12(95): 61-74.
[45]C.L.Hsueh Y.H. Huang et al. Degradation of azo dyes using low iron concentration of Fenton and Fenton-like system Chemosphere.[J].2005,13(58) 1409-1414
[46]K. Barbusinski, J.Majewski, Degradation of azo dye acid red18 by Fenton reagent in the presence of iron powder, Polish J. Environ. Stud.[J].2003,14(12):151-155.
[47]Oliver sze nga sum, Jiyun Feng, Xijun Hu, Po Lock Yue, Photo assisted Fenton mineralization of an azo dye acid black 1 using a modified laponite clay based Fe nano composite as a heterogeneous catalysts, Top. Catal [J].2005,45(33):233-242
[48]L. Gomathi Devi, S. Girish Kumar, K. Mohan Reddy et al. Journal of Hazardous Materials 2009,65(164):459-467
[49]Jiasheng Cao, Liping Wei, Qinggguo Huang, Liansheng Wang, Shuokui Han,Reducing degradation of azo dye by Zero Valent Iron in aqueous solution,Chemosphere 1999,25(38): 565-571.
[50]C.L.Hsueh Y.H. Huang et al. Degradation of azo dyes using low iron concentration of Fenton and Fenton-like system Chemosphere.[J].2005,13(58):1409-1414
[51]李绍峰,黄君礼,陈志强Oxidative Treatment of Some Reactive Dyes by Fenton Reagent. Journal of Donghua University.[J].2003,54(01):70-73
[52]许景文.过氧化氢-铁盐化学氧化法用于有机废水深度处理[J].环境污染与防治,1985,7(5)： 1-3
[53]冀小元,云桂春.H2O2/Fe2+/TiO2 H2SO4体系处理废有机溶剂的研究[J].上海环境科学,1996,15(8)： 33-36
[54]Marina TrapidoAve DelloAnna GoiRein MunterDegradation of nitroaromatics with the Fenton reagent[J].ProcEstonian AcadSciChem2003,52(1):38-47
[55]Byung-Dae LeeMasaaki HosomiEthanol washing of PAH-contaminated soil and Fenton oxidation of washing solution[J]J Mater Cycles Waste Manag2000,224-30
[56]V Kavitha K Palanivelu Degradation of 2-Chlorophenot by Fenton and Photo-Fenton Processes-A Comparative Study[J].Journal of Environmental Science and Health2003,38(7):1215-1231
[57]Ghizlaine KaichouhNihal OturanMehmet AOturanKacem El Kacemi Abderrahim El HourchDegradation of the herbicide imazapy by Fenton reactions[J]Environ ChemLett2004,23:133
[58]BarbushiskiKFilipekK Use of Fenton's reagent for removal of pesticides from industrial wastewater[J]Polish Journal of Environmental Studies2001,10(4):207-212
[59]Arturo A BurbanoDionysios DDionysiouTeri LRichardsonMakram T Suidan Degradation of MTEB intermediates using Fenton's Reagent [J]. Journal of Environmental Engimeering2002,128(9):799-805
[60]Katherine RWeeksClifford JBruellNihar RMohantyUse of Fenton's reagent for the degradation of TCE in aqueous systems and soil slurries[J].Soil and Sediment Contamination2009,(4):331-345
[61]Carla WscheerenJosh Neri GPanizAyrton FMartinsComparison of advanced processes on the oxidation of acid orange 7 dye [J].Journal of Environmental Science and Health2002,37(7):1253-1261
[62]Marina TrapidoAve DelloAnna GoiRein Munter Degradation of nitroaromatics with the Fenton reagentProc[J].Estonian AcadSciChem2003,52(1):38-47
[63]Ivan WCLauPeng WangHerbert HPFangOrganic removal of anaerobically treated leachate by Fenton coagulation[J]. Journal of Environmental Engineering2001,127(7):666-669
[64]Hee-Chan YooSoon-haing ChoSeok-Oh KoModification of coagulation and Fenton oxidation processes for cost-effective leachate treatment[J]Journal of Environmental Science and Health2001,36(1):39-48
[65]黄晓东,徐寿昌.用芬顿试剂预氧化提高硝基苯废水的可生化性.江汉石油学院学报[J].1994,28(03)：74～78
[66]肖羽堂,许建华.利用芬顿试剂预处理难降解的二硝基氯化苯废水.重庆环境科学.[J].1997,32(06)：32～36
[67]李生彬,王拯,饶姗姗等.Fenton试剂氧化处理拆弹炸药废水.西北民族大学学报(自然科学版)[J].2005,42(01)：32～35
[68]F. Lucking, H. Koser, M. Jank, A. Ritter, Iron powder and graphite and activated carbon as a catalyst for the oxidation of 4-chlorophenol with hydrogen peroxide in aqueous solution,Water Res.[J].1998,65{32}:2607-2614.
[69]P. Papapolymerou, K. Ntampegliotis, Riga.A. Karayannis, V. Bontozoglou, V Decolorization kinetics of Procion H-exl dyes from textile dyeing using Fentonlike reactions, J. Hazard. Mater [J].2006,45 (136):75-84.
[70]Roger Matta, Khalil Hanna, Serge Chiron, Fenton like oxidation of 2,4,6 Trinitro toluene using different minerals, Sci. Total Environ.[J].2007,28(385):242-251.
[71]N. Daneshvar, A.R. Khataee, Removal of azo dye C.I. Acid Red 14 from contaminated water using Fenton,UV/H2O2,UV/H2O2/Fe(Ⅱ),UV/H2O2/Fe(Ⅲ) and UV/H2O2/Fe(Ⅲ)/oxalate processes: a comparative study. Environ. Sci. Health Part A [J].2006,34(41):315-328.
[72]B.H. Guan, Y.F. Meng, Dechlorination of chloroform in organic fluorine chemical plant waste water with Zero Valent Iron, Am. Chem. Soc.[J].2005,72 (229):U844.
[73]M.Neamtu,A.Yediler, I. Siminiceamu,A.Kettrup, Oxidation ofcommercial reactive azo dye aqueous solutions by the photo Fenton and Fenton-like processes, Photochem. Photobiol. A: Chem [J].2003,12(161):87-93
[74]夏良树,李来丙,王孟等.纳米TiO2协同Fenton试剂光催化降解甲基橙[J].太阳能学报.2007,28(1)：51-54
[75]Oliver sze nga sum, Jiyun Feng, Xijun Hu, Po Lock Yue, Photo assisted Fenton mineralization of an azo dye acid black 1 using a modified laponite clay based Fe nano composite as a heterogeneous catalysts, Top. Catal.[J].2005,45(33):233-242
[76]张乃东,黄君礼,郑威.强化UV/Fenton法降解水中苯酚的研究.环境污染治理技术与设备[J].2002,3(2)：19～24
[77]杨运平,唐金晶.UV/TiO2/enton光催化氧化垃圾渗滤液的研究.中国给水排水[J].2006,22(7)：34-38
[78]彭延治,徐明芳,曾常军等.UV-TiO2-Fenton光催化降解敌百虫农药废水的研究.工业水处理[J].2006,26(6)：33-36.
[79]Ruppert G, Bauer R. UV-O3、UV-H2O2、UV-TiO2 and the photo-Fenton reaction-comparison of AOPs for wasterwater treatment [J]. Chemosphere,1994,28(5):1447-1454
[80]Rein Munter.Advanced oxidation process-current status and prospects[J]. Estonian Acad Sci Chem,2001,50(2):59-80.
[81]Oller Malato S, Sanchez-Pe│rez J A, et al. A combined solar photocatalytic-biological field system for the mineralization of an industrial pollutant at pilot scale[J]. Catalysis Today,2007, 122 (1-2):150-159
[82]Kajitvichyanukul P, Suntronvipart N. Evaluation of biodegradability and oxidation degree of hospital wastewater using photo-Fenton process as the pretreatment method [J]. Journal of Hazardous Materials,2006,138 (2):384-391.
[83]赵超,黄应平.可见光异相photo-Fenton体系降解有机染料橙Ⅱ.环境工程学报.[J].2007,1(06)：19～24
[84]Zapata, A. Evaluation of operational parameters involved in solar photo-Fenton degradation of a commercial pesticide mixture. Catalysis Today,2009.144(1-2):94-99.
[85]何丹凤,周付江,刘金泉.Fenton试剂对水体中多环芳烃(PAHs)污染物的去除效果研究.化学工程师.[J].2008,22(03)：42～45
[86]苏荣军.芬顿试剂氧化污水及无机离子影响的研究.哈尔滨商业大学学报(自然科学版).[J].2008,24(2)：210～217.
[87]Sara Goldstein, Dan Meyerstein, Gdion Czapski. The Fenton reagents[J].Free Radical Biology and Medicine,1993,15(4):435-445
[88]苏荣军.芬顿试剂氧化污水及无机离子影响的研究.哈尔滨商业大学学报(自然科学版).[J].2008,24(2)：210-217.
[89]陈序红,徐蕾.纳米二氧化钛与Fenton试剂光催化降解直接耐酸大红的研究[J].吉林工程技术师范学院学报(自然科学版).2007,23(3)：18-20
[90]陶长元,刘作华,孙大贵等.温度对Fenton法催化脱色甲基橙溶液影响的研究.[J].西南大学学报(自然科学版),2007,34(1)：157-160.
[91]M.Neamtu,A.Yediler, I. Siminiceamu,A.Kettrup, Oxidation ofcommercial reactive azo dye aqueous solutions by the photo Fenton and Fenton-like processes, Photochem. Photobiol. A: Chem.[J].2003,12(161):87-93
[92]C.S. Chiou, J.L. Shie, C.Y. Chang, C.C. Liu, C.T. Chang, Degradation of di-n-dutyl phthalate using photoreactor packed with TiO2 immobilized on glass beads[J]. J.Hazard.Mater., 2006,137:1123-1129
[93]班福忱,李亚峰,贾新军等.光助电-Fenton法催化降解硝基苯及影响因素.沈阳建筑大学学报(自然科学版)[J].2006,22(5)：809-811
[94]ARANA J,ROGRIGUEZL VM,DONA R JM, etal. The effect of aliphatic carboxylic acids on the photocatalytic degradation of p-nitrophenol[J]. Catalysis Today,2007,129(1-2):185-193.
[95]Yunfu Sun, Joseph J. Pignatello. Photochemical Reaction Involved in the TotalM ineralization of 2,4-D by Fe/H2O2/UV [J]. Environ. Sci. Technol,1993,272:304-310.
[96]许春建,王卉,吕东来等.US/Fenton试剂法在水体中降解对硝基苯酚的研究,高校化学工程学报[J].2005,19(4)：567-570.
[97]张惠灵,黄雅萍.超声波/Fenton联用对对硝基苯酚的处理.环境科学与管理[J].2006,31(8)：141-144.
[98]N.Daneshvar,M.A.Behnajady,Y.ZorriyehAsghar. Photooxidative degradation of 4-nitrophenol(4-NP) in UV/H2O2 process:Inf ence of operational parameters and reaction mechanism Journal of Hazardous Materials [J]B139(2007):275-279.
[99]HuiZhang, ChengzhiFei, DaobinZhang, FengTang.Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials [J] 145(2007):227-232.
[100]V.Kavitha,K.Palanivelu Degradation of nitrophenols by Fenton and photo-Fenton processes Journal of Photo chemistry and Photobiology A:Chemistry170(2005):83-95.
[101]冯小刚,戎非,袁春伟.TiO2光催化降解有机污染物的协同效应研究.环境污染治理技术与设备[J].2004,5(9)：12-15.
[102]田维,张洪林,蒋林时.光-Fenton试剂协同TiO2对苯酚废水降解加速作用的研究长春理工大学学报[J].2006,29(2)：100-103.
[103]钱易,米样支.现代废水处理新技术[M].北京：中国科学技术出版社,1993：162-163.
[104]何峰.UV-Fenton处理难降解有机废水的研究.浙江大学硕士论文[M].2002：58-60.
[105]Hui Zhang, Chengzhi Fei, Daobin Zhang et al Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method Journal of Hazardous Materials[J].2007,31 (145):227-230.
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