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江苏下扬子区海相中、古生界石油天然气成藏机制、成藏过程研究
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摘要
江苏下扬子区位于淮阴—响水断裂、郯庐断裂东南,指具有扬子型海相沉积分布的江苏省中南部地区。大地构造位置位于扬子板块东部的下扬子区的东部。勘探面积约7.7万平方千米。该区经历多期构造活动改造,海相中、古生界构造变形极为复杂。本文应用多种地球化学方法,研究了海相中、古生界的生烃演化特征、油气显示的分带和来源、剖析了油气藏的特征和成藏期次、探讨了油气藏的控制因素等,取得了如下主要认识:
     海相中、古生界烃源岩经历了多期构造运动,形成了多期生烃过程。通过采用裂变径迹、镜质体发射率、包裹体温度、粘土矿物演化特征等多种分析手段,建立了多旋回演化区复杂的埋藏史模型,在此基础上,恢复了烃源岩多期生烃历史。全区累计生油146.23亿吨,生气6379.19千亿方,合计6525.42(亿吨,千亿方)。阶段生烃增长量最多的是志留纪,其次晚白垩世、石炭-二叠纪、寒武—奥陶纪、三叠纪、早第三纪,分别为总生烃量的39.3%、14.5%、14.3%、11%、10.5%、9%。其中晚期生烃占总生烃量的1/4。下古生界烃源岩晚期生烃强度大的地区分布在苏北一带,上古生界烃源岩晚期生烃强度大的地区分布在句容—海安一带。
     海相中、古生界油气显示宏观上可分为南带沥青显示,中带轻质油、烃类气、二氧化碳气显示和北带普通重质油、烃类气显示。利用碳同位素、生物标记化合物、成熟度特征对比认为南带沥青显示分别来自下志留-中上奥陶统、中上寒武统、下寒武统和震旦系三套同位素分布有异的源岩;中带油及油显示主要来自下三叠统青龙组和二叠系源岩;北带油和油显示主要来自第三系源岩,盐城气的源岩为下二叠统栖霞组。南、中、北带的不同类型的显示分别对应下古生界早期生烃中心、上古生界晚期生烃中心和第三系生烃凹陷区。
     应用包裹体分析技术,确定了本区典型油气藏的成藏期次。句容地区油藏为一次成藏,油藏成藏期为90Ma左右。这一时期正是上古生界烃源岩大量生烃时期,油气运移活跃,生、储、盖配套关系良好。盐城朱家墩气藏天然气充注有两期,第一期为三垛组沉积时期,该期天然气充注较弱,油气包裹体含量少;第二期为盐城组沉积时期,是气藏的主要成藏期,油气包裹体含量高。黄桥气藏有三期充注过程,第一期在90Ma左右,油气充注为主;第二期在60Ma左右,油气充注为主,并伴有二氧化碳期运移成藏现象;第三次充注在25Ma左右,二氧化碳气充注,并驱替了早期的烃类。成藏期次分析表明,本区现存的油气藏成藏期晚,均在晚白垩纪以后,说明晚期成烃、成藏对本区油气勘探具有现实意义。
     在分析了生烃演化过程、油气显示及油气藏特征的基础上,研究了油气藏类型、形成阶段,探讨了油气成藏控制因素,认为与海相中、古生界有关的油气藏类型多样,有古生古储(自生自储)型、古生新储(下生上储)型和新生古储型三大类。油气藏成藏分两个阶段,加里东期—印支期前的油气藏成藏阶段和晚燕山—喜山期的油气藏成藏阶段,其中后一阶段形成的油气藏具有现实意义。油气成藏的主要控制因素包括三个方面:一是印支—早燕山运动对早期形成的油气藏起破坏作用;二是生烃中心控制油气藏的分布,晚期生烃中心具有重要意义;三是陆相中新生界覆盖对现存油气藏保存具有重要作用。
     本文应用多种方法对江苏下扬子区海相中、古生界的油气成藏特征和控制因素进行系统研究、探讨,在油气来源、油气藏形成期次及油气分布规律和控制因素等方面取得了一系列新的认识,对该区的油气勘探具有重要的指导意义,同时对我国南方海相油气藏的成藏研究具有借鉴作用。
Jiangsu lower Yangtze area is in the southeast of Huaiyin-Xiangshui and Tanlu fracture, and the area have sea facies aggradation distributing in middle and south of Jiangsu Province. In tectonic framework, it is in the east of the lower Yangtze area of the east of the Yangtze plate. The exploration acreage is about 77,000 km2. The area had come through many times reformation of tectonic cycle, the tectonic distortion of marine facies Mesozoic group and Proterozoic erathem were very intricate. The article used multi-method of geochemistry to research character of making hydrocarbon and evolvement of marine facies Mesozoic group and Proterozoic erathem, and distributing and source of oil and gas show, and took apart pool character and a period of time, and discussed control factor of pool, and etc. We obtained as follows main cognition:
    Marine facies Mesozoic group and Proterozoic erathem oil source rock came through many times tectonic movement, and formed many times course of making hydrocarbon. We got across many analyse artifice , for example fission track , vitrinite reflectance ratio, inclusion temperature , the evolvement character of clay mineral etc, and created complex imbed history in many gyration evolvement area. According as these, we resume many times making hydrocarbon history of oil source rock. The whole area accumulative total maked 14,623 bill ton oil, and 637,919 thousand bill square gas , add up 652,542(bill ton, thousand bill square). Most of phase making hydrocarbon quantity is Silurian period, the second is Late Cretaceous, Carboiferous to Permian , Cambrian to Ordovician, Triassic, early Tertiary, every part is 39.3%,14.5%,14.3%,11%,10.5%,9% of total making hydrocarbon quantity. Thereinto, afternoon is quarter of all. The larger area of the lower Proterozoic erathem making hydrcarbon intension is in Subei . The lar
    ger area of the higher Proterozoic erathem making hydrcarbon intension is in Jurong-Haian.
    Oil & gas show of marine facies Mesozoic group and Proterozoic erathem in macroscopy can set off show cincture that asphaltum in south, light oil & hydrocarbon gas & CO2 in middle, general weighty & gas in north. Using carbon isotopes and organism sign compound and character of maturity to compare, we think that asphaltum show in south cincture is from three set source rock of different carbon isotopes-lower Silurian to middle and upper Ordovician, middle and upper Cambrian lower Cambrian & Sinian; oil & oil show in middle is from source rock of Qinglong formation of lower Triassic and Permian: oil & oil show in north is from source rock of tertiary, the source rock of Yanchcng ga.; is from Qixia formation of lower Permian. The different type in south, middle and north fit separate making
    
    
    hydrocarbon center from forepart in lower Proterozoic erathenu afternoon in upper Proterozoic erathem and indentation in tertiary.
    Using inclusion analysis technology, we made sure times of representative pool in this area. Jurong pool is once-form, the time is about 90Ma. The time just grow hydrocarbon fastigium in upper Proterozoic erathem, oil & gas move active, and have good collocate relationship. Zhujiadun natural gas store have two times to immit, firstly is Sanduo formation sediment time that natural gas immit less and have little inclusion; secondly is Yancheng formation sediment time that is gas store main form time and have much inclusion. Huangqiao gas store have three times to immit,firstly is in about 90Ma that mostly immit oil & gas; secondly is in about 60Ma that mostly immit oil & gas and have CC moving and form store; the third is in about 25Ma that CC2 immit and drive out early hydrocarbon. The result of analysis form store's times, the area's oil & gas store of preserving now were form later, after late Cretaceous at all, these ideas explain that hydrocarbon and store form later is important to prospect for this area
     and have real sense.
    The base on analysis course of making hydrocarbon and evolvement> oil & gas show and character of oil & gas store, after we researched the type of
引文
[1] 陈沪生.下扬子地区HQ-13线综合地球物理调查及其地质意义.石油与天然气地质,1988,9(3):211-221
    [2] 陈荣书.石油及天然气地质学.北京:中国地质大学出版社,1994
    [3] 陈文正.再论四川盆地威远震旦系气藏的气源.天然气工业,1992,12(16):28-32
    [4] 程克明等著.吐哈盆地油气生成.北京:石油工业出版社,1994
    [5] 程克明,熊英等.吐哈盆地煤成烃研究新进展.沉积学报,2002,2Q(3):456-461
    [6] 程克明,熊英等.吐哈盆地煤成烃研究.石油学报,2002,23(4):13-17
    [7] 戴卿林,郝石生等.吐哈盆地侏罗纪煤系源岩芳烃组成及生源、环境意义.沉积学报,1997,15(2):199-201
    [8] 戴金星.我国煤成气藏类型和有利的煤成气远景区.见:煤成气勘探.北京:石油工业出版社,1986
    [9] 戴金星.概论有机烷烃气碳同位素系列倒转的成因问题.天然气工业,1990,10(6):16-21
    [10] 戴金星,戚厚发,郝石生.天然气地质学概论.北京:石油工业出版社,1989
    [11] 戴金星,裴锡古,戚厚发主编.中国天然气地质学(卷一).北京:石油工业出版社,1992
    [12] 戴金星,王庭斌,宋岩等.中国大中型天然气田形成条件与分布规律.北京:地质出版社,1997
    [13] 戴金星,宋岩,孙永祥.吐鲁番—哈密盆地的煤成气.石油勘探与开发,1993,20(2):6-10
    [14] 戴金星,宋岩,张厚福等.中国天然气的聚集区带.北京:科学出版社,1997
    [15] 戴金星,钟宁宁,刘德汉等.中国煤成大中型气田的形成条件.北京:石油工业出版社,2000
    [16] 戴金星,夏新宇,洪峰等.中国煤成大中型气田形成的主要控制因素初探.科学通报,2000,44(11):2455—2464
    [17] 董树文.下扬子中三叠世—中侏罗世沉积相与印支运动.地质论评,1994,40(2):111-119
    [18] 丁道桂、朱婴等.中、下扬子区古生代盆地基底拆离式改造与油气领域,石油与天然气地质,1991,(4):376—384
    [19] 冯福凯,吴乃苓.中国含煤—含气(油)盆地分析.见:石油与天然气地质文集.北京:地质出版社,1988
    [20] 冯增谟.四川盆地西部的超压天然气地质。见石油与天然气地质文集(第4集)。北京:地质出版社,1994:27-42
    [21] 费富安.苏北黄桥地区二氧化碳气的地球化学特征及成因探讨.成都地质学院学报,1985,(4):20-27
    [22] 付广,王剑秦.地壳抬升对油气藏保存条件的影响。天然气地球化学,2000,11(2):28-24
    [23] 付广,薛永超,杨勉.异常孔隙流体压力的成因及其贡献探讨。海相油气地质,1999,4(4):46-50
    [24] 傅家谟、刘德汉主编.天然气运移、聚集及封盖条件.北京:科学出版社,1992
    [25] 高岗,黄志龙,刚文哲.塔里木盆地库车坳陷依南气藏成藏期次研究,古地理学报,2002,4(2):98-104
    [26] 顾忆.塔里木盆地北部塔河油田油气藏成藏机制.石油实验地质.2000,22(4):
    
    307-312
    [27] 郭念发等.下扬子改造型海相盆地的多次生烃及晚期生烃资源评价.勘探家,1999,4(3):15-20
    [28] 郭念发,尤孝忠.苏北盆地溪桥含氦天然气田地质特征及含氦天然气勘探前景.石油勘探与开发,1999,26(5):24-26
    [29] 郝石生,柳广弟,高耀斌等.天然气资源评价的运聚动平衡模型,石油勘探与开发,1993,20(3):16-21
    [30] 郝石生.封存箱;中国海上油气(地质),1993,7(1)61—69
    [31] 何登发,陈红英,柳少波.柯克亚凝析油气田成藏机理。石油勘探与开发,1997,24(4):28-32
    [32] 何鲤.川西坳陷南段香溪群的天然气成藏模式及勘探目标.天然气工业,1992,12(2):13-19
    [33] 胡光灿,谢姚祥主编.中国四川东部高徒构造石炭系气田。北京:石油工业出版社,1997
    [34] 胡文宣,符琦,陆现彩,段振豪,含油气流体体系压力及相变规律初步研究,高校地质,1997,2(4):458-466
    [35] 黄传波.塔里木盆地北部凝析气藏特征及成藏机制探讨.天然气工业,1999,3:28-32
    [36] 黄籍中,陈盛吉.四川盆地早、中三叠世有机相与天然气生成条件分析.石油学报,1991,12(2):10-19
    [37] 黄志龙,冷胜荣等.吐哈盆地吐玉克油田油气成藏条件.新疆石油地质,1998,19(5):366-368
    [38] 黄志龙,高岗,刚文哲.川西平落坝气田原生与次生气藏烃类组成特征.天然气地球科学,2003,14(2):116-119
    [39] 黄志龙,王延斌,高岗.八角场气田煤型气藏的成藏过程研究.煤田地质与勘探,2002,(4):9-13
    [40] 姜平.千米桥潜山构造凝析气藏的初步分析.石油与天然气地质,2001,22(1):72-74
    [41] 姜振学,刘和甫,黄志龙等.亚含油气系统划分与评价—以吐哈盆地为例.地学前缘,1999,6(1):114-117
    [42] 姜振学,庞雄奇.吐哈盆地鄯善油田油气运聚期次及成藏过程研究.石油大学学报(自然科学版),2000,24(4):105-107
    [43] 金强,荣启宏,万从礼.无机与有机混合成因的天然气藏,矿物岩石,1999,19(3):41-45
    [44] 李春光,试论东营盆地高压油气藏的特征、成因及找油意义.石油学报,1992,13(1):37-43
    [45] 李巧梅,王瑞英等.吐哈盆地煤成气勘探前景.新疆石油地质,2003,24(2),172-175
    [46] 李伟,赵文智.吐哈盆地煤系地层中烃类的独特运聚风格初探.石油学报,1997,18(2):8-12
    [47] 李伟,赵文智,刘宗诚等.中国西北挤压型盆地超压泥岩与油气运聚关系研究.石油勘探与开发,1997,24(5):15-19
    [48] 李小地.油气藏成因模式探讨.石油勘探与开发.1996,23(4):1-5
    [49] 林壬子主编.油气勘探与油藏地球化学.北京:石油工业出版社,1998
    [50] 刘得光.准噶尔盆地马桥凸起异常高压成因及油气成藏模式.石油勘探与开发,
    
    1998,25(1):21-25
    [51] 刘大听,张淑娟.冀中坳陷赵县背斜成藏模式。石油实验地质,2000,22(2):161-166
    [52] 刘洛夫,康永尚.运用原油吡咯类含氮化合物研究塔里木盆地塔中地区石油的二次运移.地球化学,1998,27(5):475-481
    [53] 刘洛夫,毛东风.石油运移研究的新方法.地球科学进展,1996,11(6):607-610
    [54] 刘洛夫,徐新德,毛东风等.咔唑类化合物在油气运移中的应用初探.科学通报,1997,42(4):420-422
    [55] 刘鑫、杨传忠.碳酸盐岩矿物流体包裹体的主要研究方法及其应用.石油实验地质.1991,13(4):399-407
    [56] 柳广弟,郑玉凌.油气成藏动力场模型.石油勘探与开发,2000,27(2):11-14
    [57] 柳益群,冯乔等.吐哈盆地侏罗系油藏煤成油问题的讨论.石油与天然气地质,2002,23(4):326-331
    [58] 柳益群,周鼎武等.吐哈盆地西部油气勘探前景分析.石油学报,2001,22(3):17-21
    [59] 卢焕章,李秉伦,沈昆.包裹体地球化学,北京:地质出版社,1990
    [60] 吕恩茂、孙竟雄.江苏东北部的前震旦系变质地层,江苏地质,1987(3):23-27
    [61] 梅廉夫,徐思煌,倪昌祥.江汉盆地王场地区裂缝作用与烃类运移,科学通报,1994,vol39(14):1312-1315
    [62] 庞雄奇,金之钧,左胜杰.油气藏动力学成因模式与分类.地学前缘,2000,7(4):507-514
    [63] 潘长春,肖中尧.沥青质脱附烃地球化学特征及其意义.中国科学(D辑),1997,27(5):453-456
    [64] 施继锡等,有机包裹体及其与油气的关系。中国科学(B辑),1987,(3):318-325
    [65] 史训知,戴金星等.煤成气地质研究.北京:石油工业出版社,1987
    [66] 苏传国,李定方等.吐哈盆地台北凹陷上二叠统源岩生烃潜力分析.新疆地质,2002,20(1):77-79
    [67] 沈平,徐永昌.中国陆相成因天然气同位素组成特征.地球化学,1991,(2):144-151
    [68] 寿建峰,朱国华.塔里木盆地古生界砂岩热成熟度与有效储层的预测.海相油气地质,1997,2(3):22-25
    [69] 孙甫南,曾庆庸.川西地区南部侏罗系次生气藏形成机制探讨.天然气地质.1994,14(1):23-28
    [70] 孙旭光,陈建平等.吐哈盆地侏罗纪煤中主要组分结构特征与生烃性分析.沉积学报,2002,20(4):721-725
    [71] 孙肇才,邱蕴玉.板内形变和晚期次生成藏:扬子区海相油气总体形成规律.石油实验地质,1991,13(2):107-142
    [72] 唐秉琦.冀中坳陷天然气类型及石炭系煤成气藏远景评价.古潜山,1984,(2):13-22
    [73] 覃建雄.矿物包裹体祚沉积学中的应用.矿物岩石,1992,12(2):132-142
    [74] 覃建雄,矿物包裹体研究在油气评价和预测中的应用.天然气地球科学,1993,(1):24-34
    [75] 童崇光.新疆构造演化与吐哈盆地油气地质特征.成都理工学院学报,1999,26(1):8-13
    [76] 涂小仙,梁浩,黄卫东.吐哈盆地鲁克沁弧形带油气成藏条件.新疆石油地质,1998,19(6):458-461
    [77] 王春江,夏燕青等.吐哈盆地侏罗系煤系有机质中支链烷烃的化学结构及地球化学
    
    意义.地球化学,1997,26(1):72-84
    [78] 王飞宇 郝石生 雷加锦.砂岩储层中自生伊利石定年分析油气藏形成期.石油学报,1998,19(2):40-43
    [79] 王金琪.油气活动的烟囱作用,石油实验地质,1997,19(3):193-200
    [80] 王敏,秦伟军,赵追等.南襄盆地泌阳凹陷油气藏形成条件及聚集规律.石油与天然气地质.22(2):169-172
    [81] 王铁冠、张枝焕.油藏地球化学的理论与实践.科学通报,1997,42(19):2017-2025
    [82] 王劲松,冯利平.吐哈盆地台北凹陷隐蔽油气藏勘探.新疆石油地质,2002,23(1),18-20
    [83] 王武和,张世焕.吐哈盆地中下侏罗统煤成烃的形成与富集规律.新疆地质,1999,17(1),27-32
    [84] 王新民,赵应成.吐哈盆地台北凹陷侏罗系油气富集地质条件及油气分布规律.地球科学进展,1998,13(4):343-350
    [85] 王新洲,周迪贤,王学军.流体间歇压力运移—石油初次运移的重要方式之一.石油勘探与开发,1994,21(1):20-26
    [86] 卫延召,戴金星等.吐哈盆地台北凹陷西部油源浅析.石油实验地质,2001,23(2):191-194
    [87] 夏新能,下扬子区加里东运动初探,华东石油地质,1988(3):11-17
    [88] 夏新能,下扬子区下古生界油气地质条件及找油(气)前景,华东石油地质,1988(3):34-46
    [89] 向廷生,朱扬明,梅博文等塔里木盆地原油中氮化合物的分离及鉴定江汉石油学院学报.1996,18(4):31-35
    [90] 谢泽华.天然气成藏模式与勘探方法—以川西天然气藏为例.石油与天然气地质,2000,21(2):144-147
    [91] 徐克定,金梅春,周光拥.浙西古油藏成藏条件与演化特征.见:石宝珩等.扬子海相地质与油气.北京:石油出版社,1993:277-285
    [92] 阎吉柱,下扬子地区主要构造样式—对冲构造,华东石油地质,1988(3):27-31
    [93] 杨传忠.赤水凹陷天然气同位素特征及其成因类型和气源探讨.石油勘探与开发,1990,17(1):32-38
    [94] 杨惠民.包裹体类型和成分特征在油气运移研究和油气储层评价中的应用-以赤水气田为例.海相油气地质,1997,2(3):16-21
    [95] 杨家静,胡伯良.吐哈盆地原油和烃源岩单烃碳同位素组成特征及油源对比探讨.沉积学报,1997,15(2):208-211
    [96] 杨建业,任德贻等.吐哈与准噶尔盆地J煤系有机相及生气性研究.中国矿业大学学报,2001,30(1),67-72
    [97] 袁明生.吐哈盆地油气分布特征及勘探方向.新疆石油地质,1998,19(2):106-111
    [98] 袁明生,李华明等.吐哈盆地油源研究新进展.新疆石油地质,2001,22(2):17-20
    [99] 袁明生,李华明等.吐哈盆地台北西部原油族群及成藏期划分.新疆石油地质,2002,23(2):186-189
    [100] 曾溅辉,左胜杰.喜马拉雅运动对吐哈盆地油气藏的影响.石油与天然气地质,2001,22(4):382-384
    [101] 曾溅辉,左胜杰.吐哈盆地鲁克沁构造带流体地球化学、动力与油气运移和聚集.石油勘探与外发,2002,29(1):72-75
    [102] 曾学思.川东北海相碳酸盐岩气藏模式及勘探前景.天然气工业,
    
    1993,13(1):16-24
    [103] 张代生,焦立新.吐哈盆地台北凹陷深层含油气前景.新疆石油地质,1998,19(3):196-201
    [104] 张国成,王廷栋,徐志明等,塔里木盆地和田河气田碳酸盐岩储层的多期次多来源油气聚集特征,地学前缘,2000,17(增刊):239-248
    [105] 张金亮,常象春,民和盆地致密砂岩油藏油气充注史及含油气系统研究,特种油气藏,2000,7(4):5-8
    [106] 张明山,张进学.吐哈盆地地质结构和油气聚集规律的新认识.新疆石油地质,2002,26(3):189-192
    [107] 张晓宝,王琪等.吐哈盆地煤成油的同位素地球化学证据.新疆地质,1998,16(4):359-366
    [108] 张晓宝,徐永昌等.吐哈盆地水溶气组分与同位素特征形成机理及意义探讨.沉积学报,2002,20(4):706-709
    [109] 张新安.裹体研究的新进展.国外地质科技,1990,(2):132-135
    [110] 张义纲.油气运移与油气成藏系统分类;见:油气成藏机理及油气资源评价国际研讨会论文集.北京:石油工业出版社,1997:113-116
    [111] 张义纲等.然气的生成聚集和保存,南京:海大学出版社,1991
    [112] 张永鸿.扬子区构造演化中的黄桥转换事件与中、古生界油气勘探方向.1991,(4):339—447
    [113] 张永鸿.扬子盆地推覆构造在下古生界油气勘探中的现实意义.华东石油地质,1988,(3):1-19
    [114] 张志坚、张文淮,有机包裹体的研究现状,地质科技情报,1995,14(3):39-43
    [115] 赵长毅.成油生成、运移与油气藏形成.国矿业大学学报,1999,28(1):65-68
    [116] 赵长毅,程克明等.吐哈盆地煤成烃主要贡献组分剖析.沉积学报,1997,15(2):95-99
    [117] 赵长毅,赵文智等.吐哈盆地煤油源岩形成条件与生油评价.石油学报,1998,19(3):21-25
    [118] 赵文智,李伟,张研.吐哈盆地鲁克沁稠油藏成藏过程初探与勘探意义.石油勘探与开发,1998,25(2):1-7
    [119] 郑荣才.顺磁共振测年和包裹体在大安寨段成藏模式研究中的应用.矿物学报,1997,17(4):47-54
    [120] 郑玉凌,郝石生,柳广弟.流体封存箱研究若干问题思考.石油勘探与开发,1998,25(5):90-92
    [121] 周小进,范明,邱蕴玉.塔里木盆地塔中地区油气特征及成藏模式探讨.石油实验地质,1997,19(2):148-152
    [122] 周兴熙,黄传波,张国良等.塔里木油气田.北京:石油工业出版社,1995.
    [123] 周文.川西孝泉构造中侏罗统“次生气藏”特征及成藏机理探讨.石油实验地质,1992,14(4):399-409
    [124] 周雯雯.有机包裹体在珠三坳陷油气运移研究中的应用.地质科技情报,1998,17(增刊):93-99
    [125] 朱扬明.流体包裹体在油气勘探中的应用.勘探家,1999,4(4):29-32
    [126] 左胜杰,庞雄奇等.吐哈盆地台北凹陷侏罗系煤源岩排烃模拟研究.西南石油学院学报.2000,22(3):13-17
    [127] Aplin A C,Macleod G,Larter S R, et al. Combined use of confocal scaning microscopy
    
    and PVT simulation for estimating the composting and physcal properties of petroleum in fluid inclusion.Marine and Petroleum Geology. 1999,16:97-110
    [128] Aplin A C, Larter S R, Bigge M A,et al.PVTX history of the north sea's Judy oilfield,Journal of Geochemical Exploration.2000,69-70:641-644
    [129] Ball J S.Nitrogencompoundsinpetroleum.AcsDiv.Sci.Technol. 1962, (42) : 27-30
    [130] Bake I,A.J.&Philp,R.P. The distribution and quantitation of organonitrogen compounds in crude oil sandrock pyrolysates.OrganicGeochemisty. 1990, 16:353-367
    [131] Barker, C. Aquathermal pressuring: role of temperature in development of abnormal-pressure zones. AAPG. Bulletin 1972, 56(6): 2068-2071
    [132] Barth,T.and Bjorlykke,K. Organic acids from source rock maturation. Generation potentials, transport mechanisms and relevance for mineral diagenesis. Appli-ed Geochemistry, 1992, (8) : 325-337
    [133] Barth,T.and Riis,M. Interactions between organic acid anions in formation waters and reservoir mineral phases.Organic Geochemistry, 1992, (8) : 455-482
    [134] Ben E, Law and Spenser C. W. , Abnormal pressures in hydrocarbon environments.AAPG Memoir, 1998, 70: 1—11
    [135] Bradley, J. Abnormal formation pressure. AAPG. Bulletin, 1975, 59:957-973
    [136] Bredehoeft J.D., R.D.Djevanshir and K.R.Belitz. Lateral fluid flow in a compacting sand-shale sequence, South Caspian Sea. AAPG Bulletin, 1988, 72:416-424
    [137] Brothers,L.,Engel,M.H. and Kroos,B.M. The effects of fluid flow through porous media on the distribution of organic compounds in synthetic crude oils.Organic Geochemistry. 1991,17,11-24
    [138] Burchill,P., Herud,A.A.& Pritchard,E. Investigation of nitrogen compounds in coal tar products.Basic fractions.Fuel.1983, 62: 20-29
    [139] Cantalan L, Fu X W, Chatzis F, et al.Anexperimental study of secondary oil migration.AAPG bulletin, 1992, 76: 638-650
    [140] Cant D J.Spiritriver formation:Astratigraphie-diagenetie gastrapinthe deepbasin of Alberta.AA P G Bulletin,1983,67:577-587
    [141] Dalnes S.R. Aquathermal pressuring and geopressure evaluation. AAPG Bulletin, 1982, 66:931-939
    [142] Dahl ,B.and Speers,G.C. Geochemiseal characterization of a tar mat in the Oseberg field Norwegian sector ,North Sea Org.Geoehem. 1986,10: 547-558.
    [143] D H Liu,X M Xiao,J K Mi,X Q Li,J G Shen,Z G Song,P A Peng.Determination of trapping pressure and temperature of petroleum inclusion using PVT simulation inclusion of lower ordevician carbonates from the lunnan low oplift.Tarim Basin. Marine and Petroleum Geology.2003,20:29-43
    [144] Dickinson G. Geological aspects of abnormal reservoir pressures in Gulf Coast, Louisiana. AAPG Bulletin, 1953, 37:410-432
    [145] Dorbon M.,Ignatiadisl., & Schmitter J.M., et al. Identification of carbazoles and benzocarbazoles in acokergas oil and influence of catalytic hydrotreatment on their distribution.Fuel, 1984b, 63:565-570
    [146] Dorbon,M., Schmitters,J.M., Garrigues,P., Ignatladis,I., Ewald,M., Arpln,P.& GuiOchnO, G..Distribution of carbazole derivatives in petroleum. Organic Geochemistry, 1984b, 7: 111-120
    [147] Du Rouchet J,Stress fields:a key to oil magrtion.bull AAPG, 1981,65(1):74-85
    [148] Eadington P.J.et al. , 1991,Fluid history analysis—A new concept or prospect evaluation, The APEA Journal, (31):202~294
    [149] Eadington,P.J.,Hamilton,P.J.and Bai,G.P. Fluid history analysis-a new concept for
    
    prospect evaluation. Australian Petroleum Exploration Association,1991,31: 282-294
    [150] England ,W.A.,Mackenzic A.S.,Mann D.M. and Quigley T.M. The movement and entrapment of petroleum fluids in the subsurface.J.Geol.Soc , 1987,144: 327-347
    [151] England W.A.and Mackenzie A.S. Geochemistry of petroleum reservoirs.Geol Rundsch., 1989,78: 214-237
    [152] England ,W.A.,Mann D.M.and Mann A.L. Migration from source to trap and trap filling and mixing.Handbook of Petroleum Geology.AAPG, 1990
    [153] Fang,H,S.Yongchuan,L.Sitian, et al.Overpressure retardation of organic matter and petroleum generation: a case study from the Yinggehai and Qwiongdongnan basins, South China Sea. AAPG Bulletin, 1995, 79:551-562
    [154] Frolov, Y.B.& Vanyukova, N.A. Alkylcrbazoles of Samotlor crude Oil. Petroleum Chemistry, U.S.S.R. 1988, 28(3): 177-183
    [155] Frolov Y B. Liquid chromatography of petroleum carbazoles. Org.Geochem, 1997, 26(1-2): 43-47
    [156] Gies R M. Case history for a major Alberda Deep Basin gas trap: the Cadomin formation.AAPG memoir 38, 1984
    [157] Hillebrand,T.and Leythaeuser, D. Reservoir geochemistry of Stockstadt oilfield: com-positional heterogeneities reflecting accumulation history and multiple source input.Org.Geochem, 1992,19:119—131
    [158] Horstad, I.,Larter, S.R.,Dypvik,H.,Aargaard, P.,Bjornvik,A.M.,Johansen,P.E.and Eriksen, S. Degrada-tion and maturity controls on oil field petroleum column heterogeneity in the Gullfaks field,Norwegian North Sea Org.Geochem, 1990,16: 497-510
    [159] Horstad,B., Larter, S.R. and Mills,N. Migration of hydrocarbon in the Tampen Spur eare,Norwegian North Sea:A reservoir geochemical evaluation ,1995,
    [160] Hunt, J. M.Generation and migrattion of petroleum for abnormally pressure fluid compartments.AAPG Bulletin, 1990, 74(1): 1-12
    [161] Karlsen D.A.and Larter S. Analysis of petroleum fractions by TLC-FID :applications to petroleum reservoir description .Org. Geochem,1991,17: 603-617
    [162] Karlsen D A,Nedkvitne T, Larter S R,et al.Hytrocarbon composition of authigenic inclusions application to elucidation of petroleum reservoir filling history.Geochimica et Comochimica Acta,1993,57:3641-3659
    [163] Lafargue,E.and Barker, C. Effect of watar washing on crude oil composi-tions.AAPG Bull,1988,27: 263-276
    [164] Later, D.W.,Lee,M.L.Bartle,K.D.,Kong,R.C.& Vassilaros,D.L. Chemical class separation and characterization of organic compounds in syntheticfuels. Analytical chemistry, 1981, 53: 1612—1620
    [165] Larter, S.R.and Mills,N. Phase-controlled molecular fractionation in migrating petroleum charges. In: England,W.A. and Fleet,A.J.(eds)Petroleum Migration. Geo-logical Society ,London,Special Publication, 1992,59: 137-147
    [166] Larter, S.R. Reservoir geochemistry ,the definition of migration conduits and subtle trap.Geological Society Special Publications,1992,67: 27-28.
    [167] Larter, S.R.,and Aplin, A.C. Reservoir geochemistry: methods, applications and opportunities. In:Cubitt,J.M. & England, W.A.& (eds) The Geochemistry of Reservoirs. Geological Society Special Publication, 1995, 86: 5-32.
    [168] Law B E and Dickinson W W.Conceptual model for origin of abnormally pressured gas accumulation in low-permeability reservoirs.AAPG bulltin, 1985,69:1295-1304
    [169] Lcythaesuer D.,Schaefer R.G.and Yukler A. Diffusion of light hydro-carbons through near-surface rocks:Nature,1980,66: 522-525.
    
    
    [170] Leythaeuser, etal.Geochemical effects of petroleum migrationin Kimmeridge source rocks in the Hils Syncline area,NWG ermany[A].In:MattavelliL,Novelli LEd.Advance sinor ganic geochemistry and migration 1987[C].Pergamon Oxford:Org.Geochem, 1988,13:489~502
    [171] Leythaeuser D.and Ruckheim J. Heterogeneity of oil composition within a reservoir as a reflection of accumulation history .Geochim.Cosmochim.Acta, 1989,53: 2119-2123
    [172] Li,M. and Larter, S.R. Interactions of organic nitrogen species with mineral/water and organic networks:Implication to petroleum geochemistry .25th American Chemical Society Meeting, Abstracts, American Chemical Society.,1993: 144
    [173] Li M.,Larter S.R.,and Frolov Y.B. Adsorptive interactions between nitrogen compounds and organic/mineral phases in subsurface rocks as models for compositional fractionation of pyrrolic nitrogen compounds in petroleum during petroleum igration. Journal of High Resolution Chromatography, 1994
    [174] Li M., Larter S.R.,Stoddart D, et al.Fractionation of pyrrolic nitrogen compounds in prtroluem during migration derivation of migration related geochemical paramenters[A].In: Cubitt J.M, England W。 A, eds.The geochemistry of reservoirs[c].geological Society Sprcial Publication, 1995, 86: 103-123
    [175] Lubomir F. Jansa.Victor hugo noguera lerrea, geology and diagenetic history of overpressued sandstone reservoirs, Venture Gas Field onffshore Nova Scotia, Canada. AAPG, 1990, 74(10): 1640—1658
    [176] Luo M., Baker M.R., LeMone D.V.Distribution and generation of the overpressure system, Eastern Delaware Basin, Western Texas and Southern New Mexico. AAPG Bulletin,1994, 78(9): 1386-1405
    [177] Luo X. and G.Vasseur. Contributions of compaction and aquathermal pressuring to geopressure and the influence of environmental conditions. AAPG Bulletin, 1992, 76:1550-1559
    [178] Mark J.O.著,杨玉峰译,重新评价沉积盆地中超压的形成机制.国外油气勘探,1998,10(4):427~444
    [179] Masters J A.Deep basin gas trap, western Cananda.AAPG bulltin, 1979, 63 (2): 152-181
    [180] Me Auliffe.C.D.oil and gas migration-chemical and physical constraints,AAPG,1979,63(5):761~781
    [181] MckayJ.F., WeberJ.H.and LathamD.R. Characterization of nitrogen basesin high-boiling petroleum distillates.Anal.Chem. 1976, 48: 891—898
    [182] Mello U.T.and Karner G.D. Development of sediment overpressure and its effect on thermal maturation: application to the Gulf of Mexico Basin. AAPG. Bulletin,1996,80(9): 1367-1396
    [183] Miles,J.A. Secondary migration routes in the Brent sandstones of the Viking Granben and East Shetland basin:Evidence from oil residues and subsurface pressure data.AAPG Bulletin,1990, 74: 1718-1735.
    [184] Milner, C.W.D.,Rogers,M.A.and Evans,C.R. Petroleum transforma-tions in:reser-voirs.J.Geochem.Explor, 1977,7: 101-153
    [185] Nedkvinte T. Karlsen D.A. et al. Relationship between reservoir diagenetic evolution and petroleum emplacement in the Ula Field, North Sea. Marine and Petroleum Geology, 1993. (10):255-277
    [186] Neuzil, C. E., Abnormal pressure as hydrodynamic phenomena. American Journal of Science, 1995,295:742-786
    [187] Osborne, M. J.and Swarbrick, R. E., Mechanisms for generating overpressure in
    
    sedimentary basins: A reevaluation. AAPG Bulletin, 1997, 61(6): 1023-1041
    [188] Perrin T S and Bailey J R. The nitrogen compounds in petroleum distillates,Ⅳ Cumulative extraction of kero bases,Theisolation of 2,4,8-trimethylquinoline among the kero bases, Journal of American Chemical Society, 1933, 55: 4136-4140
    [189] Peters ,K.E.and Moldowan,J.M. The Biomarker Guide:Interpreting Moleculer Fossils in Petroleum and Ancient Sediments.Prentice Hall,Inc,1993
    [190] Price L.C.and L.M.Wenger. The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis. Organic Geochemistry, 1992, 19:141-159
    [191] Powley, D. E. : Pressures and hydrogeology in petroleum basins; Earth ScienceReviews, 1990, 29, 215—226
    [192] Randi S H等著,吴文旷译,己出版文献中有关异常压力的综述:对研究压力封存箱的意义。国外油气勘探,1998,10(2):148~158
    [193] Richter F P, Caesar P D, Meisel S L and Offenhauer R D. Distribution of nitrogen in petroleum according to basicity. Industrial and Engineering Chemistry, 1952, 44: 2601—2605
    [194] Rose P R.Gas Generation and Migrationinthe Deep Basinof Western Canada[C].AAPG Memoir38,1984.190-197
    [195] Schowalter T T.Mechanics of secondary hydrocarbon migration and entrapment.AAPG bulltin, 1979,63(5):723-760
    [196] Schmitter J M,Collin H,ExcoffierJLetal. Identification of triaromatic nitrogen bases in crude oils.Analytical Chemistry, 1982,54:769-772
    [197] Schmitter J M,and Arpino P J. Possible Origin and fate of a-methylquinolines and a-methyl-benzo[h]quinolines from crude oils. In :Bjoroy, M.(ed.), Advances in Organic Geochemistry 1982
    [198] Schmitter J M,Ignatladis I.and Arpino P J. Distribution of diaromatic nitrogen bases in crude oils.Geochimicaet CosmochimicaActa, 1983,47:1975-1984
    [199] Smalley P C and Oxtoby N H. Spatial and temporal variation in the formation water composition during diagenesis and petroleum charging of a chalk oilfield. In:Kharaka, Y.K.and Maest,A.S.(eds) Water-rock Interaction. Balkema, Rotter-dam, 1992:1201-1204
    [200] Smirnov M B and Frolov E B. Use of H NMR spectroscopy to study petroleum alkylcarbazoles, polymethylcarbazoles in acCl_4+CDCI_3 mixture, petrol. Chem. USSR, 1989,29:220-229
    [201] Smirnov M B , Frolov E B. A study of petroleum alkylcarbazoles using 1H NMR spectroscopy.Org.Geochem, 1997,26:33-42
    [202] Snyder L R. Petroleum nitrogen compounds and oxgin compounds .Acc. Chem. Res, 1970,3:290-299
    [203] Stoddart D P, Hall P B, Larter S R, et al.The reservoir geochemistry of the Eldfist Field, Norwegion North Sea.In: Cubitt J M, England W A, eds.The Geochemistry of Reservior.Geological Socienty Special Publication, 1995, 86:257-279
    [204] Thomas M M.Diagenetic sequences and K-Ar dating in Jurassic sand-stones, central Viking Graben; effects on reservoirs properies.Clay Minerals, 1986,21(4):695-710
    [205] Thomas M M. Comments on calculation of diffusion coefficients from hydrocarbon concentration profiles in rocks:AAPG Bulletin, 1989,73:787-791
    [206] Thomas M M and Clause J A.Scaled physical model of secondary oil migration.AAPG bulltin, 1995,79:19-29
    [207] Thompson K M F. Classification and thermal history of petroleum based on lignite hydrocarbon: Geochimica et Cosmochimica Acta, 1983,47:303-316
    [208] Trindade L A F.and Brassell S C.Geochemical assessment of petroleum migration phenomena on a regional scale:case studies from brazilian marginal basins.Org.Geochem., 1992,19:13-27
    
    
    [209] Vogler H A. and Robison B A. Exploration for deep geopressured gas: Corsair Trend, offshore Texas. AAPG bulltin,1987, 71(7):777—787
    [210] Yamamoto M. Fractionation of azarenes during oil migration. Organic Geochemistry, 1992,19:389-402
    [211] Yamamoto M, Taguchi T, Sasaki K.Basic nitrogen compounds in bitumen and crude oils.Chemical Geology, 1991,93:193-206

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