预处理对煤液化反应性的影响研究
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摘要
论文对不同变质程度煤液化反应性以及煤质(灰分、挥发分、H／C原子比)对液化反应性的影响进行了对比研究。通过控制原料煤水分,研究了煤的初始水分含量对其液化反应性的影响；选择了代表性的褐煤和长焰煤进行水热预处理,研究了水热预处理对煤的液化反应性的影响；以四氢呋喃及异丙醇为溶剂对煤进行溶胀预处理,研究了溶剂、溶胀时间、溶胀温度对煤液化反应性的影响；对液化过程的压力变化特征进行分析研究,明确不同预处理方法的效应。论文还对液化反应过程中初始水分作用机理、水热处理作用机理和有机溶剂溶胀处理作用机理进行了分析探讨。
In this paper, the laws of liquefaction reaction of different metamorphic rank coal were studied in comparison, and the effect of the coal rank, ash, volatile matter and H/C atomic ratio on liquefaction reaction were investigated. The effects of the initial water content of coal on liquefaction reactivity were studied by controlling the coal initial water content. The brown coal and long flame coal were selected, which have representability and operability, and hydrothermal pretreatment on liquefaction reactivity were studied. Also, the swelling pretreatments of coal in THF and IPA on liquefaction reactivity were studied, and the effects of solvent, swelling time and swelling temperature were investigated respectively. The changing laws of pressure in the process of coal liquefaction reaction were analyzed, and the characteristics of different pretreatment effects on coal liquefaction reaction were confirmed. The mechanism of initial water content, hydrothermal pretreatment and organic solvent swelling pretreatment in the liquefaction processes was also analyzed and discussed.
In this paper, the laws of liquefaction reaction of different metamorphic rank coal were studied in comparison, and the effect of the coal rank, ash, volatile matter and H/C atomic ratio on liquefaction reaction were investigated. The effects of the initial water content of coal on liquefaction reactivity were studied by controlling the coal initial water content. The brown coal and long flame coal were selected, which have representability and operability, and hydrothermal pretreatment on liquefaction reactivity were studied. Also, the swelling pretreatments of coal in THF and IPA on liquefaction reactivity were studied, and the effects of solvent, swelling time and swelling temperature were investigated respectively. The changing laws of pressure in the process of coal liquefaction reaction were analyzed, and the characteristics of different pretreatment effects on coal liquefaction reaction were confirmed. The mechanism of initial water content, hydrothermal pretreatment and organic solvent swelling pretreatment in the liquefaction processes was also analyzed and discussed.
引文
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18.凌大琦,王志忠.内蒙胜利煤液化反应速度研究.燃料化学学报,1983,4；25～28
19.刘飞.大柳塔煤液化反应性能的研究大连理工大学硕士学位论文,2001,6；9～10
20. Parkash S, Carson D, Ignasiak B, Petrographic composition and liquefaction behavior of North Dakota and Texas lignites. Fuel,1983,62(6):627～631
21.唐跃刚,王洁.论褐煤煤岩学与加氢液化的关系.中国矿业大学学报,1990,19(2)：80～86
22.戴和武,马治帮.适合直接液化的烟煤特性研究.煤炭学报,1988,(2)：80～86
23. Mochida I, Kishino M, Sakanishi K et al. Reactivity of inert macerals in the hydrogen transferring liquefaction.1987 International Conference on Coal Science, Amsterdam 1987, 303～306
24. Shibaoka M, Ueda S. Formation and stability of mesophase during coal hydrogenation. Fuel, 1978,57.(11):667～672
25. Heng S, Shibaoka M. Hydrogenation of the inerinite macerals of Bayswater coal. Fuel,1983, 62(5):610～612
26. Given P H, Cronauer D C, Spackman W et al. Dependence of coal liquefaction behavior on coal characteristics. Fuel,1975,54(1):40-49
27.韩德馨.中国煤岩学.徐州：中国矿业大学出版社,1996,419～421
28.李文华.东胜-神府煤的煤质特征与转化特征(兼论中国动力煤的岩相特征)[博士学位论文].煤炭科学研究总院,2001,6：69～70
29. Li Wenhua, Huo Weidong, Shu Geping et al. Hydroliquefaction characteristics of majiata coal and its macerals components.燃料化学学报,2001,29 (2):104～107
30. Keogh R A, Chawla B, Taulbee D et al. Liquefaction of macerals separated from single coal [C]. International Conference on Coal Science. Tokyo, Japan.1989,683～686
31. Steller M, The influence of maceral intergrowth on the hydrogenation of coal [C]. International Conference on Coal Science, July,1987, Columbia University, USA,115～118
32. Brodzki D, Akar A A, Mariadassou G D et al. Liquefaction of coal and maceral concentrates in a stirred micro-autoclave and flowing-solvent reactor. Fuel,1994,73 (8):1331～1337
33.薛永兵,凌开成,邹纲明.煤直接液化中溶剂的作用与种类.煤炭转化,1999,(10)：1～4
34. McMillen D F, Malhotra R, HumGetal. Hydrogen-transfer-promoted bond sission initiated by coal fragments. Energy & FuelS.1987,5 (2):193～198
35. McMillen D F, Malhotra R, Chang S J et al. Mechanism of hydrogen transfer and bond scission of bonded coal structures in donor solvent systems. Fuel,1987,66 (12):1611～1620
36. McMillen D F, Malhotra R, Tse D S. Interactive effects solvent components:possible chemical origin of synergy in liquefaction and coprocessing. Energy & Fuels,1991,5 (1):179-187
37. Malhotra R, McMillen D F. Relevance of cleavage of strong bonds in coal liquefaction. Energy & Fuels,1993,7(2):227～233
38. Smith C M, Savage P E. Reactions of polycyclic alkylaromatics. Energy & Fuels,1992,6 (2): 195～202
39. Savage P E. Hydrogen-transfer mechanism in 1-dodecylpyrene pyrolysis. Energy & Fuels,1995, 9 (4):590～598
40. Billmers R, Griffith L L, Stein S E. Hydrogen trasfer between anthracene structures. Phys Chem,1986,90(3):517～523
41. Autrey T, Albroun E A, Franz J A et al. Solvent-Induced Scission of Diarylmethanes in Dihydroarene Donor Solvents:An Experimental and Mechanistic Modeling Study of Hydrogen-Transfer Pathways. Energy & Fuels,1995,9(5):420～426
42. Ouchi K, Makabe M. Hydrogen Transfer in the Hydrogenation of Model Compounds. Fuel,1988, 67(11):1536～1541
43. Wei X Y, Zong Z M. Solvent effect on diphenylmethane hydrocracking. Energy & Fuels,1992,6(2):236～237
44. Masanumi G, Masaru S, Atsushi I. Elucidation ofcoal liquefaction mechanisms using a tritium tracer method:hydrogen exchangereaction of solvents with tritiated molecular hydrogen in the Presence and absence of H2S. Fuel,1998,77(9/10):947～952
45. Artok L, Erbatur 0, Schobert H H. Reaction of dinaphthyl and diphenyl ethers at liquefaction conditions. Fuel Process Technol,1996,47(2):153～176
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