竹炭/胶乳海绵复合材料的制备及性能研究
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摘要
以胶乳海绵为基体,竹炭为填料,运用间歇加工法制备了一系列不同竹炭含量的竹炭/胶乳海绵复合材料。该复合材料既有吸附和调湿性能,又兼有胶乳海绵的优良特性,是一种具有广泛应用前景的新型功能材料。
本论文重点探讨了该复合材料的制备条件,测定了复合材料的力学性能。用热重分析研究了竹炭的加入对材料热性能的影响;用扫描电镜观察了竹炭粉末与胶乳海绵的结合形态。研究结果表明:复合材料的力学性能随着竹炭含量的增大而降低,但是各性能参数均能达到指标要求:竹炭的加入对胶乳海绵的热稳定性几乎没有影响:复合材料具有开孔网络结构,泡孔之间相互连通但是泡孔大小不均,竹炭颗粒分布在泡体的骨架上而不是被包覆在胶乳内。
初步考察了复合材料的调湿性能。研究结果表明:复合材料的调湿性能优于普通的胶乳海绵;采用静态吸附法分别考察了不同竹炭含量的样品对甲醛、氨的吸附,初步解释了该复合材料对甲醛、氨吸附的情况。
采用氨水浸渍法对竹炭进行试验性的改性研究。结果发现改性的竹炭对甲苯的吸附效果不理想但却提高了对苯酚的吸附量。
The latex foams containing bamboo charcoal stuff were synthesized via intermittent process. The composites exhibited possible applications for their humidity-controlling and adsorbent capability as well as excellent latex foam properties.
In this paper, the preparation conditions of composites were mainly discussed and the mechanical properties were determined. The influence of bamboo charcoal on material thermal property was studied by thermo gravimetric analysis; the morphous that the bamboo charcoal on latex foam was observed using scanning electron microscope. The results showed that the mechanical properties of composites degraded with the increasing content of bamboo charcoal but every property parameters could reach the target request.And the thermal property was hardly affected. Besides, the composites possessed network structure of open pore and the bamboo charcoal distributed on frameworks of foams.
The humidity-controlling capability of composites was initially investigated. It showed that the humidity-controlling capability was better than that of common latex foam. The adsorption of composites with different contents of bamboo charcoal for formaldehyde and amonia was studied using static adsorptive process .In addition; the state of adsorption was initially explained.
The bamboo charcoal was modified by ammonia dipping process. The result showed that the adsorption of modified bamboo charcoals for toluene was not good but the adsorption for phenol was improved.
本论文重点探讨了该复合材料的制备条件,测定了复合材料的力学性能。用热重分析研究了竹炭的加入对材料热性能的影响;用扫描电镜观察了竹炭粉末与胶乳海绵的结合形态。研究结果表明:复合材料的力学性能随着竹炭含量的增大而降低,但是各性能参数均能达到指标要求:竹炭的加入对胶乳海绵的热稳定性几乎没有影响:复合材料具有开孔网络结构,泡孔之间相互连通但是泡孔大小不均,竹炭颗粒分布在泡体的骨架上而不是被包覆在胶乳内。
初步考察了复合材料的调湿性能。研究结果表明:复合材料的调湿性能优于普通的胶乳海绵;采用静态吸附法分别考察了不同竹炭含量的样品对甲醛、氨的吸附,初步解释了该复合材料对甲醛、氨吸附的情况。
采用氨水浸渍法对竹炭进行试验性的改性研究。结果发现改性的竹炭对甲苯的吸附效果不理想但却提高了对苯酚的吸附量。
The latex foams containing bamboo charcoal stuff were synthesized via intermittent process. The composites exhibited possible applications for their humidity-controlling and adsorbent capability as well as excellent latex foam properties.
In this paper, the preparation conditions of composites were mainly discussed and the mechanical properties were determined. The influence of bamboo charcoal on material thermal property was studied by thermo gravimetric analysis; the morphous that the bamboo charcoal on latex foam was observed using scanning electron microscope. The results showed that the mechanical properties of composites degraded with the increasing content of bamboo charcoal but every property parameters could reach the target request.And the thermal property was hardly affected. Besides, the composites possessed network structure of open pore and the bamboo charcoal distributed on frameworks of foams.
The humidity-controlling capability of composites was initially investigated. It showed that the humidity-controlling capability was better than that of common latex foam. The adsorption of composites with different contents of bamboo charcoal for formaldehyde and amonia was studied using static adsorptive process .In addition; the state of adsorption was initially explained.
The bamboo charcoal was modified by ammonia dipping process. The result showed that the adsorption of modified bamboo charcoals for toluene was not good but the adsorption for phenol was improved.
引文
[1]杜春贵,金春德笛.中国竹材资源的深加工[J].延边大学农学学报.2004,26(1):50.
[2]Eldon.D.Enger,Bradley F.smith.Environment Seience-A study of interrelationships[M],seventh edition.McGraw Hill.2000:23-46.
[3]张齐生.重视竹木化学利用,开发竹炭应用技术[J].竹子研究汇刊.2000,20(3):34-35.
[4]陈文渊.竹炭吸附水中有机污染物的研究.农林大学硕士研究生学位论文.2004:4.
[5]张齐生.重视竹材化学利用,开发竹炭应用技术[J].竹于研究汇刊.2001,20(3):34-35.
[6]张齐生.中国竹材工业化利用[M].北京林业出版社.1995,1200.
[7]周芳纯.竹林培育和利用[M].北京:中国林业出版社,1999,1-20.
[8]刘志坤,邵千钧.竹材加工剩余物综合利用研究[J].竹子研究汇刊.2003,22(3):44.
[9]谭宏超,王定尚.竹炭的加工与利用[J].云南林业.2004,25(4):21-22.
[10]张文标.竹炭生产和应用[J].竹子研究汇刊.2001,20(2):49-54.
[11]#12
[12]中原惠.竹材の处理方法及びその装置.公开特许公报,平8-209149.
[13]板井止美.竹林等の处理方法.公开特许公报:平8-157832.
[14]大平辰郎.可搬性炭化炉.公开特许化报:平1-213392.
[15]王伟龙,陈文照.浙江省竹炭的加工利用现状和对策[J].竹子研究汇刊.2002,21(4):58-63.
[16]张文标,王伟龙等.竹炭生产工艺的现状与建议[J].竹子研究汇刊.2003,22(1):8-12.
[17]张文标.竹炭.竹醋液的研究.南京林业大学博士论文.2002:22-27.
[18]田岛次郎,德田进助.木竹炭等の新用途开发じ间する研究.日本科学技术文献速报:J99064440.
[19]#12
[20]Nomum Takaya.Effect of Smoke Drying as Pretreatment of Raw Bamboo Materials.Symposium of International Academic Discussion on Bamboo Charcoal & Bamboo Vinegar in 2001.Beijing:China Forestry Publishing House,2001:241-253.
[21]#12
[22]细川健次,山口克.竹类の活性炭の调制そ の前处理方法の检讨[J].Bamboo Journal.1988,6:67-72.
[23]野春隆哉.竹炭制造技术基础研究前处理的烟熏热处理效果[M].第48回,日本木材学大 会研究发表要旨集,静冈:日本木材学会.1998:497.
[24]张文标,华毓坤,叶良民.竹炭导电机理的研究[J].南京林业大学学报,2002,26(4):47-50.
[25]张齐生,姜树海,黄河浪,等.竹炭和竹醋液的机能与科学[M].北京:中国林业出版社.2001:6-9.
[26]姜树海编译,张齐生编审.竹炭.竹醋液.南京林业大学竹材工程研究中心内部参考资料,2001:9.
[27]刘洪波,李红波,等.竹节制备高比表面活性炭的研究[J].林产化学与化工.2001,21(4):11-15.
[28]#12
[29]张文标.竹炭.竹醋液的研究.南京林业大学博士论文.2002:32.
[30]岩田磨治,佐野募,等.竹炭の物性评价と用途开发(第2报),用途开发.日本科学技术义献速报:J99053855.
[31]津村忠,竹炭の物性评价と用途开发(第1报),用途开发.日本科学技术文献速报:J99053854.
[32]#12
[33]T.Takahagi and Ishitani.XPS study on the surface structure of carbon fibers using chemical modification and CIs line shape analysis[J].Carbon,1988,25(3):389-396.
[34]周建斌.竹炭环境效应及作用机理的研究.南京林业大学博士学位论文.2005:42-43.
[35]#12
[36]杉浦银治.竹の炭烧き.日本科学技术文献速报:J95113573.
[37]高知吾川村.森林组合利用丰富的竹资源开发除臭剂[刊.日],特产情报.1995,3:29-31.
f38]佐久间光好.竹を活力す(竹炭ぉ ふ わ)日本科学技术文献速报:J98033393.
[391佐久间光好.竹利用の床下调湿材,日本科学技术文献速报:J98104435.
[40]#12
[41]#12
[42]岩田磨治,佐野募等.竹炭の物性评价と用途开发(第2报),用途开发[J].日本科学技术文献速报:J99053855.
[43]DAVID N S.Hon Wood and Cellulosic Chemistry[M].New York:Marcec Dekker Inc,1991, 665-702.
[44]#12
[45]Hasegawa Kigohide.用竹子生产活性炭过程中的液体制备抗菌纤维织品和纸制品[P].日本公開特許公報:平9-176965.
[46]ZHANG Qi-sheng,JIANG Shu-hai,HUANG He-lang et al.Research on Absorption Properties and-Relative Factors of Bamboo Charcoal on 2,4-dichlom Hyclroxy benzene.Symposium of International Academic Discussion on Bamboo Charcoal&Bamboo Vinegar in 2001.Beijing:China Forestry Publishing House,10-15.
[47]叶桂足,陈清松,等.竹炭对水溶液中苯酚的吸附性能研究[J].林产化学与工业.2005,25(增刊):139-142.
[48]福建日报.2005-6-11.www.618.gov.cn.
[49]细川健次,中野达明,高野中男,等.竹炭の诸特性の测定[J].bamboo Journal.2001,18:70-73.
[50]Zhang Wenbiao,Hua Yukun.A Study on the Moisture Content of Bamboo Charcoal and Influencing Factors.Symposium of Utilization of A cultural and Forestry Residues in 2001 in Nanjing.2001,Nanjing:Science&Technique Literature Press.
[51]严建敏,王翔,等.竹炭吸湿性的初步研究[J].竹子研究汇刊.2005,24(3):41-47.
[52]卢克阳,张齐生,蒋身学.竹炭吸湿性能的初步研究[J].木材工业.2006,20(3):20-22.
[53]姜树海编译,张齐生编审.《竹炭·竹醋液》.南京林业大学竹材工程研究中心内部参考资料,2001,9.
[54]左宋林,高尚愚,等.炭化过程中竹材内部形态结构的变化[J].林产化学与工业.2004,24(4):56-60.
[55]高尚愚译.炭素材料科学会编.活性炭应用基础[M].第一版.中国林业出版社,1984:23-25.
[56]胡又牧,魏邦柱主编.胶乳应用技术[M].北京:化学工业出版社,1990:393-394.
[57]David Eaves主编.周南桥,彭响方,谢小莉等译.泡沫塑料[M].北京:化学工业出版社:2006:199
[58]F.H.Untiedt,inventor:no assignee:US1777,945,1930.
[59]E.A.Murphy,W.H.Chapman andD.W,Potmder,inventors;Dunlop Rubber Company Ltd,assignee:GB332,525,1930.
[60]J.A.Talalay,inventor;no assignee:GB455,138,1938.
[61]唐翠芳摘译.“Talalay''(胶乳)生产工艺法[J].世界橡胶工业.2004,31(5):22.
[62]David Eaves主编.周南桥,彭响方,谢小莉等译.泡沫塑料[M].北京:化学工业出版社:2006:226.
[63]http://www.buildbook.com.cn/ebook/2007/B10031149/4.html
[64]杨彬,丘坚华,等.天然橡胶胶乳与天然纤维共同发泡材料的研制[J].贵州化工.2004,29(5):24.
[65]http://baike.baidu.com/view/45827.htm
[66]闫冰、曹德容,等.天然纤维复合泡沫材料的制备[J].中国塑料.2003,17(10):60.
[67]胡玉娟,黄雪红.竹炭/泡沫塑料复合材料对甲醛吸附性能的研究[J].合成化学.2005,13(6):203.
[68]罗学涛,吴清良,等.电化学方法制备纤维增强金属基复合材料的初步研究[J].厦门大学学报.2003,42(6):746.
[69]张万强,杨鸿吕,等.纳米SiO2改性环氧复合泡沫塑料研究[J].宇航材料工艺.2006,3:26.
[70]曹勇,合田公一,陈鹤梅.绿色复合材料的研究进展[J].材料研究学报.2007,21(2):119-123.
[71]P.Lodha,A.N.Netravali.Characterization of interfacial and mechanical properties of "green"composites with soy protein isolate and ramie fiber[J].Mater.Sci.2002,37:3657.
[72]P.Lodha,A.N.Netravali.Recent Advances in Polymer and Composites[M].Allied Publishers,New Delhi,2000.
[73]A.S.Hermann,J.Nickel,U.Riedel.Construction materials based upon biologically renewable resources-from components to finished parts[J].Polymer.1998,59:251.
[74]U.Riedel,J.Nickel,Natural fiber-reinforced biopolymers as contruction materials-new discoveries[J].Die Angewandte Makromolekulare Chemic.1999,272.
[75]H.Takagi,R.Takara,Y.Ichihara,S.Ochi,H.Misawa,R.Niki,The mechanical properties of bamboo fibers prepared by steam-explosion method[J].J.Soc.Mat.Sci.2003,52(4):353.
[76]H.Takagi,R.Takara.The manufacture and mechanical properties of composite boards made from starch-based biodegradable plastic and bamboo powder[J].J.Soc,Mat.Sci.2003,52(4):357.
[77]周良峰,唐红涛.室内空气污染与防治][J].科学咨询(生态.环保).2007,9:58.
[78]张熙,明松,黄进.建筑装饰材料与室内空气污染[J].山西建筑.2007,33(19):237.
[79]娄树立,张海军.室内空气污染的危害及治理[J].中国辐射卫生.2007,16(3):330.
[80]Anthony V Arundel,Elia M Sterling,Judith H Biggin,etal.Indirect Health Effects of Relative Humidity in Indoor Environments Health Perspectives[J].Journal of Environmental Science and Health.1986,65:351-361.
[81]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:415-416.
[82]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:191.
[83]David Eaves.Handbook of polymer foams.周南桥,彭响方,谢小莉等译[M].北京:化学工业出版社.2006:209.
[84]G.D Miles and Ross.Journal of Physical Chemistry.1994,48,280.
[85]A.D.T.Gorton.Rubber Chemistry and Technology.1970,43.
[86]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:403-404.
[87]魏邦柱.胶乳.乳液应用技术[M].北京:化学工业出版社.2003:371.
[88]胡义牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:431.
[89]David Eaves.Handbook of polymer foams.周南桥,彭响方,谢小莉等译[M].北京:化学工业出版社.2006:204.
[90]http://jpkc.scuta.edu.1n/kecheng/jrzpgy/syja.doc
[91]魏邦柱.胶乳.乳液应州技术[M].化学工业出版社.2003:408.
[92]杨彬,丘坚华,黄照伟,杨建林.天然橡胶胶乳与天然纤维共同发泡材料的研制[J].贵州化工.2004,29(5):26.
[93]吴叔青,鲁戈平,邓剑如.炭黑对聚氨酯泡沫塑料微相分离和力学性能的影响[J].高分子材料科学与工程.2004,20(5):151-154.
[94]胡秉双,张鸿波,刘会杰.无机矿物补强橡胶的研究现状与展望[J].煤炭加工与综合利用.2006,1:44.
[95]侯婷婷,钟杰平,等.天然橡胶和胶清橡胶的热氧降解特性研究[J].广州化工.2006,36(6):32.
[96]刘钦甫,张玉德,等.纳米高岭土/橡胶复合材料的性能研究[J].橡胶工业.2006,53(9):528.
[97]蒋止武.调湿材料的研究进展[J].材料导报.2006,20(10):8.
[98]孙学锋,李勇刚,周志华.调湿材料的研究与应用[J].煤气与热力.2006,26(1):66.
[99]冉茂宇.日本对调湿材料的研究及应用[J].材料导报.2002,16(11):42 44.
[100]C.Isetti,L.Laurenti,A.Ponticiello.Predicting Vapor of the Indoor Air and Latent Load for Air-conditioned[J].Energy and Building.1988,12:141-148.
[101]Akio Ishii,Shizuo Iwamoto etc al.The effect of humidity reduction on thermal Sensations[J].Proceedings of Indoor Air.1993:115-119.
[102]#12
[103]冉茂宁,杨若函.调湿材料及其研究应用现状.中国建筑学会建筑物理分会第八届年会,天津,2001.
[104]蒋正武.调湿材料的研究进展[J].材料导报.2006,20(10):8.
[105]李双林.高分子调湿材料调湿性能的实验及应用研究.北京工业大学硕士学位论文.2004.
[106]西藤宫野.屋内湿度变化壁体材料.日本建筑学会研究报告:第3集.福冈:秀巧社印刷株式会社,1949.21.
[107]彭吴.建筑围护结构调湿材料理论和实验的基础研究.同济大学硕士学位论文.2006:23.
[108]岩田磨治,佐野寡,等.竹炭の物性评价と用途开发(第2报),用途开发.日本科学技术文献速报:79905385.
[109]卢克阳.竹炭生产工艺及吸湿机理的研究.南京林业大学硕士学位论文.2004:52.
[110]Greenland D J,Hayes M H B.The Chemistry of Soil Constituents[M].New York:John Wiley & Sons Ltd,1978.
[111]章燕豪编著.吸附作用[M].第一版.上海:上海科学技术文献出版社:1989.
[112]陈文渊.竹炭吸附水中有机污染物的研究.福建农林大学硕士论文.2004:26-27.
[113]范延臻,王宝贞.活性炭表面化学[J].煤炭转化.2000,23(4):26-27.
[114]Pontius F W.Complying with Future Water Regulations[J].JAWWA.1999,91(3):46-58.
[115]Lahaye J.The chemistry of Carbon Surfaces[J].Fuel.1998,77(6):543-547.
[116]Radovic L R,Silva I F,Ume J I,eatl.An Experimental and Theoretical study of Adsorption of Aromatics Possessing Electrom With drawing and Electron Donating Functional Groups by chemical Modified Activated Carbon[J].Carbon.1997,35(9):1339-1348.
[117]高尚愚译.炭素材料科学会编.活性炭应用基础[M].北京:中国林业出版社,1984:23-25.
[118]王九思,陈学民,肖举强,等.水处理化学[M].北京:化学工业出版社.2002,5:237-238.
[119]Manahan S E.Environment Chemistry[M].New York:John Wiley & Sons,1980:286.
[120]Snoeyink V L,Jenkins D.Water Chemistry[M].New York:John Wiley &Sons,1980:185.
[121]冯孝庭,吸附分离技术[M].第一版.北京:化学工业出版社.2000:3-9.
[122]庾勃.室内空气污染研究进展[J].江苏预防医学.2006,17(4):80-81.
[123]杨锦耀.分光光度法测定纺织品中微量甲醛[J].扬州职业大学学报,2003,7(1):39-41.
[124]杨磊,陈清松,赖寿莲,等.竹炭对甲醛的吸附性能研究[J].林产化学与工业.2005,25(1):77-80.
[125]陈桂贻.公共场所空气中氨卫生检验标准方法(国家标准报批稿).
[126]王桂芳.室内空气中挥发性有机物概况及其污染现状[J].中国环境卫生.2007,10(2):32-35.
[127]王琨,姜安玺,等.活性炭吸附室内空气中挥发有机物[J].环境污染与防治.1999,21(2):14.
[128]胡玉娟.竹炭/泡沫塑料复合材料的制备及性能研究.福建师范大学硕士学位论文.2006,4.
[129]翁荔丹.竹炭/聚氨酯泡沫塑料复合材料的制备及性能研究.福建师范大学硕士学位论文.2007,5.
[130]韩严和,全燮,等.活性炭改性研究进展[J].环境污染治理技术与设备.2003,4(1):33-37.
[131]聂锦旭,肖贤明.改性膨润土吸附剂的制备及对苯酚的吸附性能[J].金属矿山.2006,2:75-77.
[132]立本英机,安部郁夫.活性炭的应用技术[M].高尚愚译.南京:东南大学出版社,2002:17.
[133]Boehm H.P.Some aspects of the surface chemistry of carbon black and other carbons [J].Carbon.1994,32:759-769.
[134]叶桂足,陈清松,等.竹炭对水溶液中苯酚的吸附性能研究[J].林产化学与工业.2005,25(增刊):140.
[135]张会平,钟辉,叶李艺.不同化学方法再生活性炭的对比研究[J].化工进展.1999,5:32.
[136]王秀芳,张会平,等.苯酚在竹炭上的吸附平衡和动力学研究[J].功能材料.2005,36(5):747-748.
[137]Charlesh,Tessmer,Radisavd,Vidic and Loisj.Impact of Oxygen-Containing Surface Functional Groups on Activated Carbon Adsorption of Phenols[J].Environ.Sei,1997,31:1872-1878.
[138]厉悦,李湘洲,刘敏.改性活性炭的表面特性及其对苯酚的吸附性能[J].林产化工通
讯.2004,35(5):14.
[2]Eldon.D.Enger,Bradley F.smith.Environment Seience-A study of interrelationships[M],seventh edition.McGraw Hill.2000:23-46.
[3]张齐生.重视竹木化学利用,开发竹炭应用技术[J].竹子研究汇刊.2000,20(3):34-35.
[4]陈文渊.竹炭吸附水中有机污染物的研究.农林大学硕士研究生学位论文.2004:4.
[5]张齐生.重视竹材化学利用,开发竹炭应用技术[J].竹于研究汇刊.2001,20(3):34-35.
[6]张齐生.中国竹材工业化利用[M].北京林业出版社.1995,1200.
[7]周芳纯.竹林培育和利用[M].北京:中国林业出版社,1999,1-20.
[8]刘志坤,邵千钧.竹材加工剩余物综合利用研究[J].竹子研究汇刊.2003,22(3):44.
[9]谭宏超,王定尚.竹炭的加工与利用[J].云南林业.2004,25(4):21-22.
[10]张文标.竹炭生产和应用[J].竹子研究汇刊.2001,20(2):49-54.
[11]#12
[12]中原惠.竹材の处理方法及びその装置.公开特许公报,平8-209149.
[13]板井止美.竹林等の处理方法.公开特许公报:平8-157832.
[14]大平辰郎.可搬性炭化炉.公开特许化报:平1-213392.
[15]王伟龙,陈文照.浙江省竹炭的加工利用现状和对策[J].竹子研究汇刊.2002,21(4):58-63.
[16]张文标,王伟龙等.竹炭生产工艺的现状与建议[J].竹子研究汇刊.2003,22(1):8-12.
[17]张文标.竹炭.竹醋液的研究.南京林业大学博士论文.2002:22-27.
[18]田岛次郎,德田进助.木竹炭等の新用途开发じ间する研究.日本科学技术文献速报:J99064440.
[19]#12
[20]Nomum Takaya.Effect of Smoke Drying as Pretreatment of Raw Bamboo Materials.Symposium of International Academic Discussion on Bamboo Charcoal & Bamboo Vinegar in 2001.Beijing:China Forestry Publishing House,2001:241-253.
[21]#12
[22]细川健次,山口克.竹类の活性炭の调制そ の前处理方法の检讨[J].Bamboo Journal.1988,6:67-72.
[23]野春隆哉.竹炭制造技术基础研究前处理的烟熏热处理效果[M].第48回,日本木材学大 会研究发表要旨集,静冈:日本木材学会.1998:497.
[24]张文标,华毓坤,叶良民.竹炭导电机理的研究[J].南京林业大学学报,2002,26(4):47-50.
[25]张齐生,姜树海,黄河浪,等.竹炭和竹醋液的机能与科学[M].北京:中国林业出版社.2001:6-9.
[26]姜树海编译,张齐生编审.竹炭.竹醋液.南京林业大学竹材工程研究中心内部参考资料,2001:9.
[27]刘洪波,李红波,等.竹节制备高比表面活性炭的研究[J].林产化学与化工.2001,21(4):11-15.
[28]#12
[29]张文标.竹炭.竹醋液的研究.南京林业大学博士论文.2002:32.
[30]岩田磨治,佐野募,等.竹炭の物性评价と用途开发(第2报),用途开发.日本科学技术义献速报:J99053855.
[31]津村忠,竹炭の物性评价と用途开发(第1报),用途开发.日本科学技术文献速报:J99053854.
[32]#12
[33]T.Takahagi and Ishitani.XPS study on the surface structure of carbon fibers using chemical modification and CIs line shape analysis[J].Carbon,1988,25(3):389-396.
[34]周建斌.竹炭环境效应及作用机理的研究.南京林业大学博士学位论文.2005:42-43.
[35]#12
[36]杉浦银治.竹の炭烧き.日本科学技术文献速报:J95113573.
[37]高知吾川村.森林组合利用丰富的竹资源开发除臭剂[刊.日],特产情报.1995,3:29-31.
f38]佐久间光好.竹を活力す(竹炭ぉ ふ わ)日本科学技术文献速报:J98033393.
[391佐久间光好.竹利用の床下调湿材,日本科学技术文献速报:J98104435.
[40]#12
[41]#12
[42]岩田磨治,佐野募等.竹炭の物性评价と用途开发(第2报),用途开发[J].日本科学技术文献速报:J99053855.
[43]DAVID N S.Hon Wood and Cellulosic Chemistry[M].New York:Marcec Dekker Inc,1991, 665-702.
[44]#12
[45]Hasegawa Kigohide.用竹子生产活性炭过程中的液体制备抗菌纤维织品和纸制品[P].日本公開特許公報:平9-176965.
[46]ZHANG Qi-sheng,JIANG Shu-hai,HUANG He-lang et al.Research on Absorption Properties and-Relative Factors of Bamboo Charcoal on 2,4-dichlom Hyclroxy benzene.Symposium of International Academic Discussion on Bamboo Charcoal&Bamboo Vinegar in 2001.Beijing:China Forestry Publishing House,10-15.
[47]叶桂足,陈清松,等.竹炭对水溶液中苯酚的吸附性能研究[J].林产化学与工业.2005,25(增刊):139-142.
[48]福建日报.2005-6-11.www.618.gov.cn.
[49]细川健次,中野达明,高野中男,等.竹炭の诸特性の测定[J].bamboo Journal.2001,18:70-73.
[50]Zhang Wenbiao,Hua Yukun.A Study on the Moisture Content of Bamboo Charcoal and Influencing Factors.Symposium of Utilization of A cultural and Forestry Residues in 2001 in Nanjing.2001,Nanjing:Science&Technique Literature Press.
[51]严建敏,王翔,等.竹炭吸湿性的初步研究[J].竹子研究汇刊.2005,24(3):41-47.
[52]卢克阳,张齐生,蒋身学.竹炭吸湿性能的初步研究[J].木材工业.2006,20(3):20-22.
[53]姜树海编译,张齐生编审.《竹炭·竹醋液》.南京林业大学竹材工程研究中心内部参考资料,2001,9.
[54]左宋林,高尚愚,等.炭化过程中竹材内部形态结构的变化[J].林产化学与工业.2004,24(4):56-60.
[55]高尚愚译.炭素材料科学会编.活性炭应用基础[M].第一版.中国林业出版社,1984:23-25.
[56]胡又牧,魏邦柱主编.胶乳应用技术[M].北京:化学工业出版社,1990:393-394.
[57]David Eaves主编.周南桥,彭响方,谢小莉等译.泡沫塑料[M].北京:化学工业出版社:2006:199
[58]F.H.Untiedt,inventor:no assignee:US1777,945,1930.
[59]E.A.Murphy,W.H.Chapman andD.W,Potmder,inventors;Dunlop Rubber Company Ltd,assignee:GB332,525,1930.
[60]J.A.Talalay,inventor;no assignee:GB455,138,1938.
[61]唐翠芳摘译.“Talalay''(胶乳)生产工艺法[J].世界橡胶工业.2004,31(5):22.
[62]David Eaves主编.周南桥,彭响方,谢小莉等译.泡沫塑料[M].北京:化学工业出版社:2006:226.
[63]http://www.buildbook.com.cn/ebook/2007/B10031149/4.html
[64]杨彬,丘坚华,等.天然橡胶胶乳与天然纤维共同发泡材料的研制[J].贵州化工.2004,29(5):24.
[65]http://baike.baidu.com/view/45827.htm
[66]闫冰、曹德容,等.天然纤维复合泡沫材料的制备[J].中国塑料.2003,17(10):60.
[67]胡玉娟,黄雪红.竹炭/泡沫塑料复合材料对甲醛吸附性能的研究[J].合成化学.2005,13(6):203.
[68]罗学涛,吴清良,等.电化学方法制备纤维增强金属基复合材料的初步研究[J].厦门大学学报.2003,42(6):746.
[69]张万强,杨鸿吕,等.纳米SiO2改性环氧复合泡沫塑料研究[J].宇航材料工艺.2006,3:26.
[70]曹勇,合田公一,陈鹤梅.绿色复合材料的研究进展[J].材料研究学报.2007,21(2):119-123.
[71]P.Lodha,A.N.Netravali.Characterization of interfacial and mechanical properties of "green"composites with soy protein isolate and ramie fiber[J].Mater.Sci.2002,37:3657.
[72]P.Lodha,A.N.Netravali.Recent Advances in Polymer and Composites[M].Allied Publishers,New Delhi,2000.
[73]A.S.Hermann,J.Nickel,U.Riedel.Construction materials based upon biologically renewable resources-from components to finished parts[J].Polymer.1998,59:251.
[74]U.Riedel,J.Nickel,Natural fiber-reinforced biopolymers as contruction materials-new discoveries[J].Die Angewandte Makromolekulare Chemic.1999,272.
[75]H.Takagi,R.Takara,Y.Ichihara,S.Ochi,H.Misawa,R.Niki,The mechanical properties of bamboo fibers prepared by steam-explosion method[J].J.Soc.Mat.Sci.2003,52(4):353.
[76]H.Takagi,R.Takara.The manufacture and mechanical properties of composite boards made from starch-based biodegradable plastic and bamboo powder[J].J.Soc,Mat.Sci.2003,52(4):357.
[77]周良峰,唐红涛.室内空气污染与防治][J].科学咨询(生态.环保).2007,9:58.
[78]张熙,明松,黄进.建筑装饰材料与室内空气污染[J].山西建筑.2007,33(19):237.
[79]娄树立,张海军.室内空气污染的危害及治理[J].中国辐射卫生.2007,16(3):330.
[80]Anthony V Arundel,Elia M Sterling,Judith H Biggin,etal.Indirect Health Effects of Relative Humidity in Indoor Environments Health Perspectives[J].Journal of Environmental Science and Health.1986,65:351-361.
[81]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:415-416.
[82]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:191.
[83]David Eaves.Handbook of polymer foams.周南桥,彭响方,谢小莉等译[M].北京:化学工业出版社.2006:209.
[84]G.D Miles and Ross.Journal of Physical Chemistry.1994,48,280.
[85]A.D.T.Gorton.Rubber Chemistry and Technology.1970,43.
[86]胡又牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:403-404.
[87]魏邦柱.胶乳.乳液应用技术[M].北京:化学工业出版社.2003:371.
[88]胡义牧,魏邦柱.胶乳应用技术[M].北京:化学工业出版社.1990:431.
[89]David Eaves.Handbook of polymer foams.周南桥,彭响方,谢小莉等译[M].北京:化学工业出版社.2006:204.
[90]http://jpkc.scuta.edu.1n/kecheng/jrzpgy/syja.doc
[91]魏邦柱.胶乳.乳液应州技术[M].化学工业出版社.2003:408.
[92]杨彬,丘坚华,黄照伟,杨建林.天然橡胶胶乳与天然纤维共同发泡材料的研制[J].贵州化工.2004,29(5):26.
[93]吴叔青,鲁戈平,邓剑如.炭黑对聚氨酯泡沫塑料微相分离和力学性能的影响[J].高分子材料科学与工程.2004,20(5):151-154.
[94]胡秉双,张鸿波,刘会杰.无机矿物补强橡胶的研究现状与展望[J].煤炭加工与综合利用.2006,1:44.
[95]侯婷婷,钟杰平,等.天然橡胶和胶清橡胶的热氧降解特性研究[J].广州化工.2006,36(6):32.
[96]刘钦甫,张玉德,等.纳米高岭土/橡胶复合材料的性能研究[J].橡胶工业.2006,53(9):528.
[97]蒋止武.调湿材料的研究进展[J].材料导报.2006,20(10):8.
[98]孙学锋,李勇刚,周志华.调湿材料的研究与应用[J].煤气与热力.2006,26(1):66.
[99]冉茂宇.日本对调湿材料的研究及应用[J].材料导报.2002,16(11):42 44.
[100]C.Isetti,L.Laurenti,A.Ponticiello.Predicting Vapor of the Indoor Air and Latent Load for Air-conditioned[J].Energy and Building.1988,12:141-148.
[101]Akio Ishii,Shizuo Iwamoto etc al.The effect of humidity reduction on thermal Sensations[J].Proceedings of Indoor Air.1993:115-119.
[102]#12
[103]冉茂宁,杨若函.调湿材料及其研究应用现状.中国建筑学会建筑物理分会第八届年会,天津,2001.
[104]蒋正武.调湿材料的研究进展[J].材料导报.2006,20(10):8.
[105]李双林.高分子调湿材料调湿性能的实验及应用研究.北京工业大学硕士学位论文.2004.
[106]西藤宫野.屋内湿度变化壁体材料.日本建筑学会研究报告:第3集.福冈:秀巧社印刷株式会社,1949.21.
[107]彭吴.建筑围护结构调湿材料理论和实验的基础研究.同济大学硕士学位论文.2006:23.
[108]岩田磨治,佐野寡,等.竹炭の物性评价と用途开发(第2报),用途开发.日本科学技术文献速报:79905385.
[109]卢克阳.竹炭生产工艺及吸湿机理的研究.南京林业大学硕士学位论文.2004:52.
[110]Greenland D J,Hayes M H B.The Chemistry of Soil Constituents[M].New York:John Wiley & Sons Ltd,1978.
[111]章燕豪编著.吸附作用[M].第一版.上海:上海科学技术文献出版社:1989.
[112]陈文渊.竹炭吸附水中有机污染物的研究.福建农林大学硕士论文.2004:26-27.
[113]范延臻,王宝贞.活性炭表面化学[J].煤炭转化.2000,23(4):26-27.
[114]Pontius F W.Complying with Future Water Regulations[J].JAWWA.1999,91(3):46-58.
[115]Lahaye J.The chemistry of Carbon Surfaces[J].Fuel.1998,77(6):543-547.
[116]Radovic L R,Silva I F,Ume J I,eatl.An Experimental and Theoretical study of Adsorption of Aromatics Possessing Electrom With drawing and Electron Donating Functional Groups by chemical Modified Activated Carbon[J].Carbon.1997,35(9):1339-1348.
[117]高尚愚译.炭素材料科学会编.活性炭应用基础[M].北京:中国林业出版社,1984:23-25.
[118]王九思,陈学民,肖举强,等.水处理化学[M].北京:化学工业出版社.2002,5:237-238.
[119]Manahan S E.Environment Chemistry[M].New York:John Wiley & Sons,1980:286.
[120]Snoeyink V L,Jenkins D.Water Chemistry[M].New York:John Wiley &Sons,1980:185.
[121]冯孝庭,吸附分离技术[M].第一版.北京:化学工业出版社.2000:3-9.
[122]庾勃.室内空气污染研究进展[J].江苏预防医学.2006,17(4):80-81.
[123]杨锦耀.分光光度法测定纺织品中微量甲醛[J].扬州职业大学学报,2003,7(1):39-41.
[124]杨磊,陈清松,赖寿莲,等.竹炭对甲醛的吸附性能研究[J].林产化学与工业.2005,25(1):77-80.
[125]陈桂贻.公共场所空气中氨卫生检验标准方法(国家标准报批稿).
[126]王桂芳.室内空气中挥发性有机物概况及其污染现状[J].中国环境卫生.2007,10(2):32-35.
[127]王琨,姜安玺,等.活性炭吸附室内空气中挥发有机物[J].环境污染与防治.1999,21(2):14.
[128]胡玉娟.竹炭/泡沫塑料复合材料的制备及性能研究.福建师范大学硕士学位论文.2006,4.
[129]翁荔丹.竹炭/聚氨酯泡沫塑料复合材料的制备及性能研究.福建师范大学硕士学位论文.2007,5.
[130]韩严和,全燮,等.活性炭改性研究进展[J].环境污染治理技术与设备.2003,4(1):33-37.
[131]聂锦旭,肖贤明.改性膨润土吸附剂的制备及对苯酚的吸附性能[J].金属矿山.2006,2:75-77.
[132]立本英机,安部郁夫.活性炭的应用技术[M].高尚愚译.南京:东南大学出版社,2002:17.
[133]Boehm H.P.Some aspects of the surface chemistry of carbon black and other carbons [J].Carbon.1994,32:759-769.
[134]叶桂足,陈清松,等.竹炭对水溶液中苯酚的吸附性能研究[J].林产化学与工业.2005,25(增刊):140.
[135]张会平,钟辉,叶李艺.不同化学方法再生活性炭的对比研究[J].化工进展.1999,5:32.
[136]王秀芳,张会平,等.苯酚在竹炭上的吸附平衡和动力学研究[J].功能材料.2005,36(5):747-748.
[137]Charlesh,Tessmer,Radisavd,Vidic and Loisj.Impact of Oxygen-Containing Surface Functional Groups on Activated Carbon Adsorption of Phenols[J].Environ.Sei,1997,31:1872-1878.
[138]厉悦,李湘洲,刘敏.改性活性炭的表面特性及其对苯酚的吸附性能[J].林产化工通
讯.2004,35(5):14.