Efficient Generation of Titanocene Lewis Acids from Inert Cp_2TiCl_2 and their Catalytic Applications

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• 英文论文题名：Efficient Generation of Titanocene Lewis Acids from Inert Cp_2TiCl_2 and their Catalytic Applications
• 论文作者：Ya Wu ; Xiu Wang ; Yanlong Luo ; Yunyun Wang ; Jing Wang ; Weiqiang Zhang ; Ziwei Gao
• 英文论文作者：Ya Wu ; Xiu Wang ; Yanlong Luo ; Yunyun Wang ; Jing Wang ; Weiqiang Zhang ; Ziwei Gao ; Key Laboratory of Applied Surface and Colloid Chemistry ; MOE ; School of Chemistry and Chemical Engineering ; Shaanxi Normal University
• 年：2016
• 作者机构：Key Laboratory of Applied Surface and Colloid Chemistry, MOE, School of Chemistry and Chemical Engineering, Shaanxi Normal University;
• 会议召开时间：2016-05-06
• 会议录名称：第七届全国物理无机化学学术会议论文集
• 语种：英文
• 分类号：O643.36
• 学会代码：ZGHY
• 会议名称：第七届全国物理无机化学学术会议
• 会议地点：中国北京
• 主办单位：中国化学会、国家自然科学基金委员会
• 学会名称：中国化学会
• 页数：1
• 文件大小：309k
• 原文格式：D
• 会议级别：全国

摘要

<正>Organometallic Lewis acids have been of fundamental interests in homogenous catalysis due to their ubiquitous reactivity and selectivity in classic organic transformations.1 Recently,we developed a binary catalyst via Br?nsted acid/base assisted activation of Cp_2TiCl_2 for it is abundant,stable sandwich structure for devising organometallic Lewis acids.[2-4]The increased reactivity of organometallic titanocene

引文

[1]Wu,Y.;Chen,C.;Jia,G.;Zhu,X.;Sun,H.;Zhang,G.;Zhang,W.;Gao,Z.Chem.Eur.J.2014,20,8530.
    [2]Xiu,W.Zhenhua,G.Zhang,W.Zhang,Y.Wu,Z.Gao,Eur.J.Org.Chem.2016,507-509,15298.
    [3]Zhu,X.;Chen,C.;Yu,B.;Wu,Y.;Zhang,G.;Zhang,W.;Gao,Z.Catal.Sci.Technol.2015,5,4346.
    [4]Zhu,X.;Chen,C.;Yu,B.;Wu,Y.;Zhang,G.;Zhang,W.;Gao,Z.Chem.Lett.2014,43,1832.
    [5]Wu,Y.;Wang,X.;Luo,Y.;Wang,J.;Jian,Y.;Sun,H.;Zhang,G.;Zhang,W.;Gao,Z.Adv.2016,6.