用于电容去离子技术的电极材料研究进展及展望
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- 英文论文题名：Review on Electrode Materials for Capacitive Deionization Technology
- 论文作者：郭涛 ; 董堃 ; 蔡玉 ; 汪长征 ; 许萍 ; 张雅君
- 英文论文作者：GUO Tao ; DONG Kun ; CAI Yu ; WANG Changzheng ; XU Ping ; ZHANG Yajun ; Key Laboratory of Urban Storm Water System and Water Environment ; Beijing University of Civil Engineering and Architecture ; Beijing Water Science & Technology Institute
- 年：2016
- 作者机构：北京建筑大学城市雨水系统与水环境教育部重点实验室;北京市水科学技术研究院;
- 论文关键词：电容去离子 ; 电极材料 ; 双电层 ; 脱盐
- 英文论文关键词：capacitive deionization ; electrode material ; electrical double layer ; desalination
- 会议召开时间：2016-11-18
- 会议录名称：第一届先进材料前沿学术会议论文集（《材料导报》2016年第30卷第Z1期）
- 语种：中文
- 分类号：O646
- 学会代码：CLDB
- 会议名称：第一届先进材料前沿学术会议
- 会议地点：中国陕西西安
- 主办单位：《材料导报》杂志社
- 学会名称：材料导报编辑部
- 页数：7
- 文件大小：1269k
- 原文格式：O
- 会议级别：全国
摘要
电容去离子技术具有能耗低、无需化学试剂、环境友好等优点,已成为工业水处理、海水淡化等处理工艺的重要技术。当在电极两端施加适当的外加电压时,原水中的离子在静电力的作用下发生迁移,离子存储在电极表面的双电层中,从而实现原水中离子的去除。简要介绍了电容去离子技术的工作原理,着重介绍了用于电容去离子技术的电极材料的研究现状和制备方法,并对其发展前景进行了展望。
Capacitive deionization technology(CDI) has the advantages of low energy consumption,no chemical reagents,environmental friendliness and so on,which has become one of the main technologies used in the process of water treatment such as industrial waste water treatment and seawater desalination.The ions in the raw water are transferred under the action of electrostatic force by applying the appropriate voltage at both ends of the electrode,and stored in the double layer of the electrode surface to realize ion removal.In this paper,the principle of capacitive deionization is introduced.Research and development of desalination techniques in the treatment of wastewater is discussed,as well as some suggestions for the future research.
Capacitive deionization technology(CDI) has the advantages of low energy consumption,no chemical reagents,environmental friendliness and so on,which has become one of the main technologies used in the process of water treatment such as industrial waste water treatment and seawater desalination.The ions in the raw water are transferred under the action of electrostatic force by applying the appropriate voltage at both ends of the electrode,and stored in the double layer of the electrode surface to realize ion removal.In this paper,the principle of capacitive deionization is introduced.Research and development of desalination techniques in the treatment of wastewater is discussed,as well as some suggestions for the future research.
引文
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7 Zhao Tingyue,Zhang Lingxiao,Zhang Aimin,et al.Application of electro-sorption technology in water treatment[J].Shangdong Water Resour,2003(2):35(in Chinese).赵亭月,张凌晓,张爱民,等.电吸附技术在水处理中的应用[J].山东水利,2003(2):35.
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9 Dong Xiaoning,Wang Yali.Electro-absorption technology in the water treatment and research progress[J].Guangdong Chem Ind,2010,37(8):26(in Chinese).董晓宁,王亚丽.电吸附技术在水处理中的应用及其研究进展[J].广东化工,2010,37(8):26.
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11 Li Dandan,Sun Wenquan,Li Jinxin,et al.Study on electric adsorption desalination of volume-activated carbon fiber electrode[J].Environ Eng,2015(33):198(in Chinese).李丹丹,孙文全,李金鑫,等.卷式活性炭纤维电极电吸附除盐试验研究[J].环境工程,2015(33):198.
12 Man Yuenan,Wang Xiaojuan,Wang Yintao,et al.New research progress and development trend of seawater desalinization technology D].Ind Water Treat,2014(11):8(in Chinese).满曰南,王晓娟,王银涛,等.海水淡化技术研究新进展和发展趋势[J].工业水处理,2014(11):8.
13 Ma Junpeng.Development trend of industrial water treatment technology[J].Theor Res Urban Constr:Electron,2013(23)(in Chinese).马军朋.工业水处理技术的发展趋势[J].城市建设理论研究:电子版,2013(23).
14 Cha Zhenlin,Yu Yixiong,Luo Yatian,et al.Electro-sorption technology and its application in water treatment[J].Sichuan Chem Ind,2005,8(4):52(in Chinese).查振林,余以雄,罗亚田,等.电吸附技术及其在水处理中的应用[J].四川化工,2005,8(4):52.
15 Han L,Karthikeyan K G,Anderson M A,et al.Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization[J].Electrochim Acta,2013,90(5):573.
16 Zhang M,Zhao X,Zhuang Q,Preparation and electrochemical properties of multiscale porous active carbon for supercapacitor electrodes made from ultra-pure lignite by microwave irradiation[J].Int J Electrochem Sci,2016,11(3):2153.
17 Villar I,Roldan S,Ruiz V,et al.Capacitive deionization of NaCl solutions with modified activated carbon electrodes[J].Energy Fuels,2010,24(6):3329.
18 Zou L,Morris G,Qi D.Using activated carbon electrode in electrosorptive deionisation of brackish water[J].Desalination,2008,225(1):329.
19 Pekala R W.Organic aerogels from the polycondensation of resorcinol with formaldehyde[J].J Mater Sri,1989,24(9):3221.
20 Rasines G,Lavela P,Marias C,et al.Electrochemical response of carbon aerogel electrodes in saline water[J].J Electroanal Chem,2012,671(5):92.
21 Pei X,Drewes J E,Heil D,et al.Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology[J].Water Res,2008,42(10):2605.
22 Li Yajie,Ni Xingyuan,Shen Jun,et al.Preparation and performance of polypyrrole/nitric acid activated carbon aerogel nanocomposite materials for supercapacitors[J].Acta Phys Chim Sin,2016,32(2):493(in Chinese).李亚捷,倪星元,沈军,等.聚吡咯/硝酸活化碳气凝胶纳米复合材料的制备表征及其在超级电容器中的应用[J].物理化学学报,2016,32(2):493.
23 Meng Y,Gu D,Fuqiang Zhang,et al.A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chem Mater,2006,18(18):4447.
24 Peng Z,Zhang D,Shi L,et al.Comparative electroadsorption study of mesoporous carbon electrodes with various pore structures[J].J Phys Chem C,2011,115(34):17068.
25 Zou L,Li L,Song H,et al.Using mesoporous carbon electrodes for brackish water desalinationD].Water Res,2008,42(8):2340.
26 Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56.
27 Zhang D,Shi L,Fang J,et al.Influence of diameter of carbon nanotubes mounted in flow-through capacitors on removal of NaCl from salt water[J].J Mater Sci,2007,42(7):2471.
28 Chen G,Sakurai S,Yumura M,et al.Highly pure,millimeter-tall,sub-2-nanometer diameter single-walled carbon nanotube forests[J].Carbon,2016,107:433.
29 Gui X,Wei J,Wang K,et al.Carbon nanotube sponges[J].Adv Mater,2010,22(5):617.
30 Wang L.Capacitive deionization of NaCl solutions using carbon nanotube sponge electrodes[J].J Mater Chem,2011,21(45):18295.
31 Wang M,Huang Z H,Wang L,et al.Electrospun ultrafine carbon fiber webs for electrochemical capacitive desalination[J].New J Chem,2010,34(9):1843.
32 Du Tao,Zhang Hongdi.Fan Tongxiang.Recent progress on grapheme/metal composites D].Mater Rev:Rev,2015,29(3):121(in Chinese).独涛,张洪迪,范同祥.石墨烯/金属复合材料的研究进展[J].材料导报:综述篇,2015,29(3):121.
33 Li H,Zou L,Pan L,et al.Novel graphene-like electrodes for capacitive deionization[J].Environ Sci Technol,2010,44(22):8692.
34 Li H,Lu T,Pan L,et al.Electrosorption behavior of graphene in NaCl solutions[J].J Mater Chem,2009,19(37):6773.
35 Jia B,Zou L.Graphene nanosheets reduced by a multi-step process as high-performance electrode material for capacitive deionization[J].Carbon,2012,50(6):2315.
36 Wang Z,Yue L,Liu Z T,et al.Functional graphene nanocomposite as an electrode for the capacitive removal of FeCl_3 from water[J].J Mater Chem,2012,22(28):14101.
37 Hummers Jr W S,Offeman R E.Preparation of graphitic oxide[J].J Am Chem Soc,1958,80(6):1339.
38 Li H,Pan L,Lu T,et al.A comparative study on electrosorptive behavior of carbon nanotubes and graphene for capacitive deionization[J].J Electroanal Chem,2011,653(l):40.
39 Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti_3AlC_2[J].Adv Mater.2011,23(37):4248.
40 Naguib M,Mashtalir O,Carle J,et al.Two-dimensional transition metal carbides[J].ACS Nano,2012,6(2):1322.
41 Naguib M,Mochalin V N,Barsoum M W,et al.25th anniversary article:MXenes:A new family of two-dimensional materials[J].Adv Mater,2014,26(7):992.
42 Li Zhengyang,Zhou Aiguo,Wang Libo,et al.Research progress on preparation and properties of two-dimensional crystal MXene[J].Bull Chin Ceram Soc,2013,32(8):1562(in Chinese).李正阳,周爱国,王李波,等.二维晶体MXene的制备与性能研究进展[J].硅酸盐通报,2013,32(8):1562.
43 Liu fanfan,Zhou Aiguo,Chen Jinfeng,et al.Safe synthesis and adsorption/catalysis application of two-dimensional structure MXene[J].Ordnance Mater Sci Eng,2016,39(1):120(in Chinese).刘凡凡,周爱国,陈进峰,等.二维结构MXene温和制备及吸附催化领域的应用[J].兵器材料科学与工程,2016,39(1):120.
44 Ghidiu M,Lukatskaya M R,Zhao M Q,et al.Conductive two-dimensional titanium carbide/clay/'with high volumetric capacitance[J].Nature,2014,516(7529):78.
45 Kajiyama S,Szabova L,Sodeyama K,et al.Sodium-ion intercalation mechanism in MXene nanosheets[J].ACS Nano,2016,10(3):3334.
46 Zhao M Q,Ren C E,Ling Z,et al.Flexible MXene/carbon nanotube composite paper with high volumetric capacitance[J].Adv Mater,2015,27(2):339.
47 Yan P,Zhang R,Jia J,et al.Enhanced supercapacitive performance of delaminated two-dimensional titanium carbide/carbon nanotube composites in alkaline electrolyte[J].J Power Sources,2015,284:38.
48李荻.电化学原理[M].北京:航空航天大学出版社,1999.
49 Atlas R.Purification of brackish or sea water using electronic water purification[J].Int Desalin Water Reuse Q.2001,10(4):10.
50 Mo Jianxiong,Gao Congjie.Inquiry into theory of dual electric layer model in capacitive adsorption-deionized technology[J].Technol Water Treat,2007,33(12)s26(in Chinese).莫剑雄,高从堦.电容吸附去离子技术的理论探讨[J].水处理技术,2007,33(12):26.
51 Yin Guangjun,Chen Fuming.Progress in capacitive deionization[J].Technol Water Treat,2003,29(2):63(in Chinese).尹广军,陈福明.电容去离子研究进展[J].水处理技术,2003,29(2):63.
2 Arnold B B,Murphy G W.Studies on the electrochemistry of carbon and chemically-modified carbon surfaces[J].J Phys Chem,1961,65(1):l35.
3 Oren Y.Capacitive deionization(CDI)for desalination and water treatment—Past,present and future(a review)[J].Desalination,2008,228(1):10.
4 Walha K,Amar R B,Firdaous L,et al.Brackish groundwater treatment by nanofiltration,reverse osmosis and electrodialysis in Tunisia:Performance and cost comparison[J].Desalination,2007,207(1):95.
5 Helal A M,El-Nashar A M,Al-Katheeri E,et al.Optimal design of hybrid RO/MSF desalination plants Part I:Modeling and algorithms[J].Desalination,2003,154(1):43.
6 Chen Zhaolin,Song Cunyi,Sun Xiaowei,et al.Progress in the research on the electrosorption desalination technology and its application[J].Ind Water Treat,2011,31(4):ll(in Chinese).陈兆林,宋存义,孙晓慰,等.电吸附除盐技术的研究与应用进展[J].工业水处理,2011,31(4):11.
7 Zhao Tingyue,Zhang Lingxiao,Zhang Aimin,et al.Application of electro-sorption technology in water treatment[J].Shangdong Water Resour,2003(2):35(in Chinese).赵亭月,张凌晓,张爱民,等.电吸附技术在水处理中的应用[J].山东水利,2003(2):35.
8查全性.电极过程动力学导论(第三版)[M].北京:科学出版社,2002.
9 Dong Xiaoning,Wang Yali.Electro-absorption technology in the water treatment and research progress[J].Guangdong Chem Ind,2010,37(8):26(in Chinese).董晓宁,王亚丽.电吸附技术在水处理中的应用及其研究进展[J].广东化工,2010,37(8):26.
10 Xu Chunling,Zhang Xiaoyong.Research progress of capacitance adsorption desalination technology[J].Guangzhou Chem Ind,2011,39(12):17(in Chinese).许春玲,张小勇.电容吸附法脱盐技术研究进展[J].广州化工,2011,39(12):17.
11 Li Dandan,Sun Wenquan,Li Jinxin,et al.Study on electric adsorption desalination of volume-activated carbon fiber electrode[J].Environ Eng,2015(33):198(in Chinese).李丹丹,孙文全,李金鑫,等.卷式活性炭纤维电极电吸附除盐试验研究[J].环境工程,2015(33):198.
12 Man Yuenan,Wang Xiaojuan,Wang Yintao,et al.New research progress and development trend of seawater desalinization technology D].Ind Water Treat,2014(11):8(in Chinese).满曰南,王晓娟,王银涛,等.海水淡化技术研究新进展和发展趋势[J].工业水处理,2014(11):8.
13 Ma Junpeng.Development trend of industrial water treatment technology[J].Theor Res Urban Constr:Electron,2013(23)(in Chinese).马军朋.工业水处理技术的发展趋势[J].城市建设理论研究:电子版,2013(23).
14 Cha Zhenlin,Yu Yixiong,Luo Yatian,et al.Electro-sorption technology and its application in water treatment[J].Sichuan Chem Ind,2005,8(4):52(in Chinese).查振林,余以雄,罗亚田,等.电吸附技术及其在水处理中的应用[J].四川化工,2005,8(4):52.
15 Han L,Karthikeyan K G,Anderson M A,et al.Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization[J].Electrochim Acta,2013,90(5):573.
16 Zhang M,Zhao X,Zhuang Q,Preparation and electrochemical properties of multiscale porous active carbon for supercapacitor electrodes made from ultra-pure lignite by microwave irradiation[J].Int J Electrochem Sci,2016,11(3):2153.
17 Villar I,Roldan S,Ruiz V,et al.Capacitive deionization of NaCl solutions with modified activated carbon electrodes[J].Energy Fuels,2010,24(6):3329.
18 Zou L,Morris G,Qi D.Using activated carbon electrode in electrosorptive deionisation of brackish water[J].Desalination,2008,225(1):329.
19 Pekala R W.Organic aerogels from the polycondensation of resorcinol with formaldehyde[J].J Mater Sri,1989,24(9):3221.
20 Rasines G,Lavela P,Marias C,et al.Electrochemical response of carbon aerogel electrodes in saline water[J].J Electroanal Chem,2012,671(5):92.
21 Pei X,Drewes J E,Heil D,et al.Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology[J].Water Res,2008,42(10):2605.
22 Li Yajie,Ni Xingyuan,Shen Jun,et al.Preparation and performance of polypyrrole/nitric acid activated carbon aerogel nanocomposite materials for supercapacitors[J].Acta Phys Chim Sin,2016,32(2):493(in Chinese).李亚捷,倪星元,沈军,等.聚吡咯/硝酸活化碳气凝胶纳米复合材料的制备表征及其在超级电容器中的应用[J].物理化学学报,2016,32(2):493.
23 Meng Y,Gu D,Fuqiang Zhang,et al.A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chem Mater,2006,18(18):4447.
24 Peng Z,Zhang D,Shi L,et al.Comparative electroadsorption study of mesoporous carbon electrodes with various pore structures[J].J Phys Chem C,2011,115(34):17068.
25 Zou L,Li L,Song H,et al.Using mesoporous carbon electrodes for brackish water desalinationD].Water Res,2008,42(8):2340.
26 Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56.
27 Zhang D,Shi L,Fang J,et al.Influence of diameter of carbon nanotubes mounted in flow-through capacitors on removal of NaCl from salt water[J].J Mater Sci,2007,42(7):2471.
28 Chen G,Sakurai S,Yumura M,et al.Highly pure,millimeter-tall,sub-2-nanometer diameter single-walled carbon nanotube forests[J].Carbon,2016,107:433.
29 Gui X,Wei J,Wang K,et al.Carbon nanotube sponges[J].Adv Mater,2010,22(5):617.
30 Wang L.Capacitive deionization of NaCl solutions using carbon nanotube sponge electrodes[J].J Mater Chem,2011,21(45):18295.
31 Wang M,Huang Z H,Wang L,et al.Electrospun ultrafine carbon fiber webs for electrochemical capacitive desalination[J].New J Chem,2010,34(9):1843.
32 Du Tao,Zhang Hongdi.Fan Tongxiang.Recent progress on grapheme/metal composites D].Mater Rev:Rev,2015,29(3):121(in Chinese).独涛,张洪迪,范同祥.石墨烯/金属复合材料的研究进展[J].材料导报:综述篇,2015,29(3):121.
33 Li H,Zou L,Pan L,et al.Novel graphene-like electrodes for capacitive deionization[J].Environ Sci Technol,2010,44(22):8692.
34 Li H,Lu T,Pan L,et al.Electrosorption behavior of graphene in NaCl solutions[J].J Mater Chem,2009,19(37):6773.
35 Jia B,Zou L.Graphene nanosheets reduced by a multi-step process as high-performance electrode material for capacitive deionization[J].Carbon,2012,50(6):2315.
36 Wang Z,Yue L,Liu Z T,et al.Functional graphene nanocomposite as an electrode for the capacitive removal of FeCl_3 from water[J].J Mater Chem,2012,22(28):14101.
37 Hummers Jr W S,Offeman R E.Preparation of graphitic oxide[J].J Am Chem Soc,1958,80(6):1339.
38 Li H,Pan L,Lu T,et al.A comparative study on electrosorptive behavior of carbon nanotubes and graphene for capacitive deionization[J].J Electroanal Chem,2011,653(l):40.
39 Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti_3AlC_2[J].Adv Mater.2011,23(37):4248.
40 Naguib M,Mashtalir O,Carle J,et al.Two-dimensional transition metal carbides[J].ACS Nano,2012,6(2):1322.
41 Naguib M,Mochalin V N,Barsoum M W,et al.25th anniversary article:MXenes:A new family of two-dimensional materials[J].Adv Mater,2014,26(7):992.
42 Li Zhengyang,Zhou Aiguo,Wang Libo,et al.Research progress on preparation and properties of two-dimensional crystal MXene[J].Bull Chin Ceram Soc,2013,32(8):1562(in Chinese).李正阳,周爱国,王李波,等.二维晶体MXene的制备与性能研究进展[J].硅酸盐通报,2013,32(8):1562.
43 Liu fanfan,Zhou Aiguo,Chen Jinfeng,et al.Safe synthesis and adsorption/catalysis application of two-dimensional structure MXene[J].Ordnance Mater Sci Eng,2016,39(1):120(in Chinese).刘凡凡,周爱国,陈进峰,等.二维结构MXene温和制备及吸附催化领域的应用[J].兵器材料科学与工程,2016,39(1):120.
44 Ghidiu M,Lukatskaya M R,Zhao M Q,et al.Conductive two-dimensional titanium carbide/clay/'with high volumetric capacitance[J].Nature,2014,516(7529):78.
45 Kajiyama S,Szabova L,Sodeyama K,et al.Sodium-ion intercalation mechanism in MXene nanosheets[J].ACS Nano,2016,10(3):3334.
46 Zhao M Q,Ren C E,Ling Z,et al.Flexible MXene/carbon nanotube composite paper with high volumetric capacitance[J].Adv Mater,2015,27(2):339.
47 Yan P,Zhang R,Jia J,et al.Enhanced supercapacitive performance of delaminated two-dimensional titanium carbide/carbon nanotube composites in alkaline electrolyte[J].J Power Sources,2015,284:38.
48李荻.电化学原理[M].北京:航空航天大学出版社,1999.
49 Atlas R.Purification of brackish or sea water using electronic water purification[J].Int Desalin Water Reuse Q.2001,10(4):10.
50 Mo Jianxiong,Gao Congjie.Inquiry into theory of dual electric layer model in capacitive adsorption-deionized technology[J].Technol Water Treat,2007,33(12)s26(in Chinese).莫剑雄,高从堦.电容吸附去离子技术的理论探讨[J].水处理技术,2007,33(12):26.
51 Yin Guangjun,Chen Fuming.Progress in capacitive deionization[J].Technol Water Treat,2003,29(2):63(in Chinese).尹广军,陈福明.电容去离子研究进展[J].水处理技术,2003,29(2):63.
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