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Saturn-Like Charge-Transfer Complexes Li_4&B_(36), Li_5&B_(36)~+, and Li_6&B_(36)~(2+):Exohedral Metalloborospherenes with A Perfect Cage-Like B_(36)~(4-) Core
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摘要
<正>Cage-like borospherenes B_n~q(q=n-40)and their metalloborospherenes have received considerable attention since the discovery of B_(40)~(-/0).Based on extensive first-principles theory calculations,we present herein the possibility of the Saturn-like exohedral charge-transfer complexes Li_4&B_(36)(2),Li_5&B_(36)~+(3),
引文
[1]Zhai,H.-J.;Zhao,Y.-F.;Li,W.-L.;Chen,Q.;Bai,H.;Hu,H.-S.;Piazza,Z.A.;Tian,W.-J.;Lu,H.-G.;Wu,Y.-B.;Mu,Y.-W.;Wei,G.-F.;Liu,Z.-P.;Li,J.;Li,S.-D.;Wang L.-S.Nat.Chem.2014,6,727.
    [2]Bai,H.;Chen,Q.;Zhai,H.-J.;Li.S.-D.Angew.Chem.Int.Ed.2015,54,941.

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