炭基电极电容去离子法脱盐性能研究进展
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摘要
电容脱盐是一种新开发的水处理技术,它相对于传统的脱盐技术具有绿色环保、安全高效的优点,逐渐成为国内外科研工作者的研究热点。分析了电容脱盐的基本原理、电极材料的选择以及如何提高脱盐效率,并对CDI未来发展前景进行了展望。
引文
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[4]莫剑雄,高从增.电容吸附去离子技术的理论探讨[J].水处理技术,2008,33(12):26-29.
[5]Zou L,Morris G,Qi D.Using activated carbon electrode in electrosorptive deionisation of brackish water[J].Desalination,2008,225(1):329-340.
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[8]Yang C M,Choi W H,Na B K,et al.Capacitive deionization of NaCl solution with carbon aerogel-silicagel composite electrodes[J].Desalination,2005,174(2):125-133.
[9]Bordjiba T,Mohamedi M,Dao L H.Synthesis and electrochemical capacitance of binderless nanocomposite electrodes formed by dispersion of carbon nanotubes and carbon aerogels[J].Journal of Power Sources,2007,172(2):991-998.
[10]史永胜,李雪红,宁青菊,等.石墨烯的制备及表征研究进展[J].电子元件与材料,2010(12):59-63.
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[13]Lee J H,Bae W S,Choi J H.Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process[J].Desalination,2010,258(1):159-163.
[14]Barbieri O,Hahn M,Herzog A,et al.Capacitance limits of high surface area activated carbons for double layer capacitors[J].Carbon,2005,43(6):1303-1310.
[15]Yang K L,Ying T Y,Yiacoumi S,et al.Electrosorption of ions from aqueous solutions by carbon aerogel:an electrical double-layer model[J].Langmuir,2001,17(6):1961-1969.
[16]Li L,Zou L,Song H,et al.Ordered mesoporous carbons synthesized by a modified sol-gel process for electrosorptive removal of sodium chloride[J].Carbon,2009,47(3):775-781.
[17]Pan L,Wang X,Gao Y,et al.Electrosorption of anions with carbon nanotube and nanofibre composite film electrodes[J].Desalination,2009,244(1):139-143.
[18]Oren Y,Soffer A.The electrical double layer of carbon and graphite electrodes:PartⅢ.Charge and dimensional changes at wide potential range[J].Journal of electroanalytical chemistry and interfacial electrochemistry,1986,206(1):101-114.
[19]L Zou,G Morris,D D Qi.Using activated carbon electrode in electrosorptive deionization of brackish water,Desalination,2008,225:329-340.
[20]孟庆函,刘玲,宋怀河,等.金属Mn/活性炭电极材料电化学性能的研究[J].功能材料,2004,35(2):209-211.
[21]徐晓,田艳红,张学军.石墨烯/二氧化锰复合材料的电化学性能[J].硅酸盐学报,2013,41(1):38-43.
[22]Ryoo M W,Kim J H,Seo G.Role of titania incorporated on activated carbon cloth for capacitive deionization of NaCl solution[J].Journal of colloid and interface science,2003,264(2):414-419.
[23]Chang L M,Duan X Y,Liu W.Preparation and electrosorption desalination performance of activated carbon electrode with titania[J].Desalination,2011,270(1):285-290.
[24]Leonard K C,Genthe J R,Sanfilippo J L,et al.Synthesis and characterization of asymmetric electrochemical capacitive deionization materials using nanoporous silicon dioxide and magnesium doped aluminum oxide[J].Electrochimica Acta,2009,54(22):5286-5291.
[25]白锋,王树林,苏丹,等.超级电容器MnO_2/活性炭复合电极的研究[J].中国粉体技术,2007,13(4):5-6.
[26]卢淼,刘建允,王世平,等.磺化石墨烯/活性炭复合电极的制备及其不对称电容器脱盐[J].高等学校化学学报,2014,35(7):15.
[2]Johnson A M,VENOLIA W.The electrosorb process for desalting water[J].1970.
[3]杨红生,周啸.电化学电容器最新研究进展:Ⅰ.双电层电容器[J].电子元件与材料,2003,22(2):13-16.
[4]莫剑雄,高从增.电容吸附去离子技术的理论探讨[J].水处理技术,2008,33(12):26-29.
[5]Zou L,Morris G,Qi D.Using activated carbon electrode in electrosorptive deionisation of brackish water[J].Desalination,2008,225(1):329-340.
[6]Tanaka F,Okabe T,Okuda H,et al.Factors controlling the strength of carbon fibres in tension[J].Composites Part A:Applied Science and Manufacturing,2014,57:88-94.
[7]Soneda Y,Toyoda M,Hashiya K,et al.Huge electrochemical capacitance of exfoliated carbon fibers[J].Carbon,2003,41(13):2680-2682.
[8]Yang C M,Choi W H,Na B K,et al.Capacitive deionization of NaCl solution with carbon aerogel-silicagel composite electrodes[J].Desalination,2005,174(2):125-133.
[9]Bordjiba T,Mohamedi M,Dao L H.Synthesis and electrochemical capacitance of binderless nanocomposite electrodes formed by dispersion of carbon nanotubes and carbon aerogels[J].Journal of Power Sources,2007,172(2):991-998.
[10]史永胜,李雪红,宁青菊,等.石墨烯的制备及表征研究进展[J].电子元件与材料,2010(12):59-63.
[11]Stoller M D,Park S,Zhu Y,et al.Graphene-based ultracapacitors[J].Nano letters,2008,8(10):3498-3502.
[12]程杰,张文峰,方敏,等.活性炭电极电容法脱盐性能的研究[J].精细化工,2008,25(6):521-524.
[13]Lee J H,Bae W S,Choi J H.Electrode reactions and adsorption/desorption performance related to the applied potential in a capacitive deionization process[J].Desalination,2010,258(1):159-163.
[14]Barbieri O,Hahn M,Herzog A,et al.Capacitance limits of high surface area activated carbons for double layer capacitors[J].Carbon,2005,43(6):1303-1310.
[15]Yang K L,Ying T Y,Yiacoumi S,et al.Electrosorption of ions from aqueous solutions by carbon aerogel:an electrical double-layer model[J].Langmuir,2001,17(6):1961-1969.
[16]Li L,Zou L,Song H,et al.Ordered mesoporous carbons synthesized by a modified sol-gel process for electrosorptive removal of sodium chloride[J].Carbon,2009,47(3):775-781.
[17]Pan L,Wang X,Gao Y,et al.Electrosorption of anions with carbon nanotube and nanofibre composite film electrodes[J].Desalination,2009,244(1):139-143.
[18]Oren Y,Soffer A.The electrical double layer of carbon and graphite electrodes:PartⅢ.Charge and dimensional changes at wide potential range[J].Journal of electroanalytical chemistry and interfacial electrochemistry,1986,206(1):101-114.
[19]L Zou,G Morris,D D Qi.Using activated carbon electrode in electrosorptive deionization of brackish water,Desalination,2008,225:329-340.
[20]孟庆函,刘玲,宋怀河,等.金属Mn/活性炭电极材料电化学性能的研究[J].功能材料,2004,35(2):209-211.
[21]徐晓,田艳红,张学军.石墨烯/二氧化锰复合材料的电化学性能[J].硅酸盐学报,2013,41(1):38-43.
[22]Ryoo M W,Kim J H,Seo G.Role of titania incorporated on activated carbon cloth for capacitive deionization of NaCl solution[J].Journal of colloid and interface science,2003,264(2):414-419.
[23]Chang L M,Duan X Y,Liu W.Preparation and electrosorption desalination performance of activated carbon electrode with titania[J].Desalination,2011,270(1):285-290.
[24]Leonard K C,Genthe J R,Sanfilippo J L,et al.Synthesis and characterization of asymmetric electrochemical capacitive deionization materials using nanoporous silicon dioxide and magnesium doped aluminum oxide[J].Electrochimica Acta,2009,54(22):5286-5291.
[25]白锋,王树林,苏丹,等.超级电容器MnO_2/活性炭复合电极的研究[J].中国粉体技术,2007,13(4):5-6.
[26]卢淼,刘建允,王世平,等.磺化石墨烯/活性炭复合电极的制备及其不对称电容器脱盐[J].高等学校化学学报,2014,35(7):15.