摘要
由H_2salen与Nd(NO_3)_3·6H_2O,NdCl_3·6H_2O构筑了一种新颖的稀土配合物Nd(salen)_2(NO_3)_2Cl(H_2salen=乙二胺缩水杨醛),晶体解析表示H_2salen在结构中作为桥连配体,使配合物呈现三维结构并对其近红外性质进行研究。
Reaction of N,N′-bis(3-hydroxy)ethylene-1,2-diamine(H_2salen) with Nd(NO_3)_3·6H_2O and NdCl_3·6H_2O yields a novel lanthanide complex,namely,Nd(salen)_2(NO_3)_2Cl(1).X-ray crystallographical analysis revealed that H_2salen effectively functions as a bridging ligand forming a kind of novel 3D structure complex.The near-infrared(NIR)property of 1 in solid state was also studied.
引文
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[3]Fondo,M.;Doejo,J.;García-Deibe A.M.;Ocampo,N.;Sanmartín J.Polyhedron 2015,101,78.