亲水聚醚在聚氨酯灌浆材料中的应用研究
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- 英文论文题名：Study on Hydrophilic Polyurethane Grouting Material Using Polyether Polyol
- 论文作者：宣理静 ; 金顺颖 ; 蒋晓群
- 英文论文作者：XUAN Lying ; JING Shunying ; JIANG Xiaoqun ; Sinopec Shanghai Gaoqiao Petrochemical Co.Ltd
- 年：2016
- 作者机构：中国石化上海高桥分公司;
- 论文关键词：亲水性聚醚多元醇 ; 灌浆料 ; 预聚体 ; 聚氨酯
- 英文论文关键词：hydrophilic polyether polyol ; grouting slurry ; prepolymer ; polyurethane
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TU578
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：6
- 文件大小：1393k
- 原文格式：D
- 会议级别：全国
摘要
以的几种不同分子量的亲水聚醚为原料合成聚氨酯灌浆预聚体并配置成单组分灌浆料,考察了预聚体反应温度、亲水聚醚分子量、异氰酸酯种类等对灌浆材料水溶性、黏度以及发泡活性的影响。筛选出了合适的异氰酸酯种类和有机硅表面活性剂。结果表明:采用MMC催化体系可以制备出质量稳定、相对分子质量分布宽度小于1.1的亲水聚醚;亲水聚醚与异氰酸酯在60℃反应制备的灌浆预聚体黏度最低;使用4000、5000分子量的亲水聚醚制得的亲水灌浆预聚体遇水自分散;在选用合适有机硅表面活性剂时,其用量对亲水灌浆预聚体发泡活性无影响,但对泡孔规整性有较大影响。使用自制的亲水聚醚制备的灌浆料经过红外谱图分析和发泡评价,其泡沫性能与目标产品非常接近,但发泡速度快于目标产品,浆液黏度稍高。
Hydrophilic polyurethane grouting prepolymers were prepared using a series of different molecule weight polyether polyols.The reaction temperature,the molecular weight of hydrophilic polyether polyol,and different kind of diisocyanate were studied to know the effect toward to the prepolymers' viscosity,solubility in water and their foaming activity.The results show that:the quality of polyether polyols using MMC catalyst is controllable and the polydispersity index is within 1.1.The grouting slurry automatic scattered in water using 4000 and 5000 molecular weight of hydrophilic polyether polyols.When choosing suitable silicone surfactant,the amount of the silicone had no effect to the foam activity,but has a great influence on the regularity of the bubble hole.Using selfmade preparation of hydrophilic polyether grouting material through infrared spectra analysis and evaluation of foam,the foam properties and the target product is very close,but foam faster than the target product,and the grouting slurry viscosity is a bit high.
Hydrophilic polyurethane grouting prepolymers were prepared using a series of different molecule weight polyether polyols.The reaction temperature,the molecular weight of hydrophilic polyether polyol,and different kind of diisocyanate were studied to know the effect toward to the prepolymers' viscosity,solubility in water and their foaming activity.The results show that:the quality of polyether polyols using MMC catalyst is controllable and the polydispersity index is within 1.1.The grouting slurry automatic scattered in water using 4000 and 5000 molecular weight of hydrophilic polyether polyols.When choosing suitable silicone surfactant,the amount of the silicone had no effect to the foam activity,but has a great influence on the regularity of the bubble hole.Using selfmade preparation of hydrophilic polyether grouting material through infrared spectra analysis and evaluation of foam,the foam properties and the target product is very close,but foam faster than the target product,and the grouting slurry viscosity is a bit high.
引文
[1]王正平,赵钢.NCO基在聚氨酯预聚体合成过程中的影响[J].应用科技,2002,29(2):37-38.
[2]赵晖,何凤,刘益军,等.水溶性聚氨酯化学灌浆材料的研制[J].化工新型材料,2005,33(8):61-63.
[3]宋虹霞,郑银才,邓爱华.高相对分子质量聚醚多元醇环氧乙烷的封端.高桥石化,2006,21(3):1-5.
[4]汤普森A M,施米德特W,罗尔D F,等.从双金属氰化物配合物催化的聚氧亚烷基多元醇制得的模塑和块料聚氨酯泡沫和适合制备它的多元醇:中国,1303402A[P],2001-07-11.
[2]赵晖,何凤,刘益军,等.水溶性聚氨酯化学灌浆材料的研制[J].化工新型材料,2005,33(8):61-63.
[3]宋虹霞,郑银才,邓爱华.高相对分子质量聚醚多元醇环氧乙烷的封端.高桥石化,2006,21(3):1-5.
[4]汤普森A M,施米德特W,罗尔D F,等.从双金属氰化物配合物催化的聚氧亚烷基多元醇制得的模塑和块料聚氨酯泡沫和适合制备它的多元醇:中国,1303402A[P],2001-07-11.