聚氨酯表面活性剂的结构对WPUA乳液及膜性能影响

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• 英文论文题名：Effect of Polyurethane Surfactant Structure on the Properties of Waterbome PolyurethaneAcrylate Emulsions and Its Coating Films
• 论文作者：王海利 ; 方华高 ; 孙静 ; 刘阳 ; 魏海兵 ; 杨善中 ; 丁运生
• 英文论文作者：WANG Haili ; FANG Huagao ; SUN Jing ; LIU Yang ; WEI Haibing ; YANG Shanzhong ; DING Yunsheng ; School of Chemistry and Chemical Engineering ; Hefei University of Technology ; Key Laboratory of Advanced Functional Materials and Devices
• 年：2016
• 作者机构：合肥工业大学化学与化工学院;先进功能材料与器件安徽省重点实验室;
• 论文关键词：聚氨酯表面活性剂 ; 结构 ; 水性聚氨酯-丙烯酸酯 ; 性能
• 英文论文关键词：polyurethane surfactant ; structure ; waterborne polyurethane-acrylate ; property
• 会议召开时间：2016-07-30
• 会议录名称：中国聚氨酯工业协会第十八次年会论文集
• 语种：中文
• 分类号：TQ423;TB383.2
• 学会代码：JAZG
• 会议名称：中国聚氨酯工业协会第十八次年会
• 会议地点：中国上海
• 主办单位：中国聚氨酯工业协会
• 学会名称：中国聚氨酯工业协会
• 页数：4
• 文件大小：1292k
• 原文格式：D
• 会议级别：全国

摘要

设计合成了3种聚氨酯表面活性剂(PUS),将此大分子表面活性剂用于甲基丙烯酸甲酯(MMA)的聚合,制备出3种不同乳胶粒结构的水性聚氨酯-丙烯酸酯乳液(WPUA)。对WPUA乳胶粒的粒径、粒子形貌和乳液黏度进行测试与表征,同时研究了WPUA膜的力学性能和物理老化行为。结果表明,PUS结构对水性聚氨酯-丙烯酸酯乳液与膜性能的影响显著,以聚碳酸酯二元醇(PCDL)合成的水性聚氨酯-聚丙烯酸酯,其乳液和膜的综合性能优良。
A series of waterborne polyurethane-acrylate(WPUA) were prepared with three different structure polyurethane surfactants.The emulsion was dried to give different structure films.The particle size,latex morphology were characterized,and Shear viscosity.Mechanical properties and physical aging behaviors of WPUA films were also investigated.The results show that variation of PUS structure has a significant influence on properties of WPUA latex and its film.Clear core-shell structure is achieved in PCDL-based WPUA,which exhibits the best comprehensive properties.

引文

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