多次化学镀作用下钯型离子聚合物金属复合材料的力电响应特性研究
详细信息 查看官网全文
- 英文论文题名：Study on Electromechanical Responses of Pd-typed Ionic Polymer Metal Composites Affected by Multiple Electroless Plating
- 论文作者：王延杰 ; 罗斌 ; 常龙飞 ; 朱子才 ; 朱灯林 ; 姬翠翠
- 英文论文作者：WANG Yanjie ; LUO Bin ; CHANG Longfei ; ZHU Zicai ; ZHU Denglin ; JI Cuicui ; School of Mechanical and Electrical Engineering ; Hohai University ; School of Mechanical Engineering ; Xi'an Jiaotong University ; Institute of Industry &Equipment Technology ; Hefei University of Technology
- 年：2016
- 作者机构：河海大学机电工程学院;西安交通大学机械工程学院;合肥工业大学工业与装备技术研究院;
- 论文关键词：电活性材料 ; 钯电极 ; 浸泡-还原镀 ; 化学沉积镀 ; 力电响应
- 英文论文关键词：electroactive materials ; palladium electrode ; immersion-reduction plating ; electroless deposition ; electromechanical response
- 会议召开时间：2016-11-18
- 会议录名称：第一届先进材料前沿学术会议论文集（《材料导报》2016年第30卷第Z1期）
- 语种：中文
- 分类号：TB333;TB306
- 学会代码：CLDB
- 会议名称：第一届先进材料前沿学术会议
- 会议地点：中国陕西西安
- 主办单位：《材料导报》杂志社
- 学会名称：材料导报编辑部
- 页数：7
- 文件大小：2318k
- 原文格式：O
- 会议级别：全国
摘要
以具有典型工艺特征的钯型离子聚合物金属复合材料(Pd-typed ionic polymer metal composites,Pd-IPMC)为研究对象,旨在阐明不同电极生长机理(浸泡-还原镀和化学沉积镀)和施镀次数对Pd-IPMC材料的微观形貌、力电参数及变形特性的影响规律。首先,依据施镀机理和次数差异制备了具有特定形貌的Pd-IPMC材料,接着观察并探讨了微观电极形貌(表层电极厚度和电极渗入深度)与施镀次数之间的关系,然后分析了施镀次数对材料表面电阻率和弯曲刚度的影响规律,最后测试了Pd-IPMC材料的变形特性。实验表明,不能通过持续增加施镀次数使IPMC材料达到更优的变形特性,而应综合考虑表面电阻和弯曲刚度的作用,合理确定浸泡-还原镀和化学沉积镀的施镀次数,以获得最优的变形特性。
In this paper,to clarify the effects of electroless plating mechanisms and times on the micro-morphology,electromechanical parameters and deformation properties of IPMC,Pd-typed IPMC with typical fabrication technology features were investigated.First,Pd-typed IPMC with specific morphology were prepared according to the principle and times of electroless plating.Then,the relationship between micro-electrode morphology(surface electrode thickness and electrode penetration depth) and times of electroless plating was observed and discussed.And the effects of electroless plating times on the surface resistivity and bending rigidity of IPMC were analyzed.Finally,the deformation characteristics of the IPMC were tested.The results show that the better performance cannot be achieved by continuous electroless plating and the optimum deformation can be obtained by comprehensively considering the effect of surface resistance and bending rigidity determined by the electroless plating times.
In this paper,to clarify the effects of electroless plating mechanisms and times on the micro-morphology,electromechanical parameters and deformation properties of IPMC,Pd-typed IPMC with typical fabrication technology features were investigated.First,Pd-typed IPMC with specific morphology were prepared according to the principle and times of electroless plating.Then,the relationship between micro-electrode morphology(surface electrode thickness and electrode penetration depth) and times of electroless plating was observed and discussed.And the effects of electroless plating times on the surface resistivity and bending rigidity of IPMC were analyzed.Finally,the deformation characteristics of the IPMC were tested.The results show that the better performance cannot be achieved by continuous electroless plating and the optimum deformation can be obtained by comprehensively considering the effect of surface resistance and bending rigidity determined by the electroless plating times.
引文
1 Shen Q,Wang T,Liang J,et al.Hydrodynamic performance of a biomimetic robotic swimmer actuated by ionic polymer-metal composite[J].Smart Mater Struct,2013,22(7):075035.
2 Punning A,Kim K J,Palmre V,et al.Ionic electroactive polymer artificial muscles in space applications[J].Sci Rep,2014,4:6913.
3 Zhou Y,Chiu C W,Sanchez C J,et al.Sound modulation in singing katydids using ionic polymer-metal composites(IPMCs)[J].J Bionic Eng,2013,10(4):464.
4 Ganet F,Le M Q,Capsal J F,et al.Development of a smart guide wire using an electrostrictive polymer:Option for steerable orientation and force feedback[J].Sci Rep,2015,5(5):18593.
5 Wang Yanjie,Wang Yongquan,Chen Hualing,et al.Design and performance investigation for miniature optical lens IPMC actuators[J].J Xi'an Jiaotong University,2012,46(5):79(in Chinese).王延杰,王永泉,陈花玲,等.新型智能材料微小型光学镜头致动器的设计与性能研究[J].西安交通大学学报,2012,46(5):79.
6 Jung S Y,Park J O,Park S.Replacement of surface roughening using polyvinyl alcohol coating in the fabrication of nafion-based ionic polymer metal composite(IPMC)actuators[J].J Polym Res,2016,23(9):178.
7 Park J,Palmre V,Hwang T,et al.Electromechanical performance and other characteristics of IPMCs fabricated with various commercially available ion exchange membranes[J].Smart Mater Struct,2014,23(7):074001.
8 Gu Na,Xiong Ke,An Yi.Preparation and electrochemical impedance analysis of pt-ionic polymer metal composites[J].Mater Rev:Res,2016,30(8):10(in Chinese).顾娜,熊克,安逸.铂型离子聚合物金属复合材料的制备与电化学阻抗分析[J].材料导报:研究篇,2016,30(8):10.
9 Fujiwara N,Asaka K,Nishimura Y,et al.Preparation of gold-solid polymer electrolyte composites as electric stimuli-responsive materials[J].Chem Mater,2000,12(6):1750.
10 Aoyagi W,Omiya M Mechanical and electrochemical properties of an IPMC actuator with palladium electrodes in acid and alkaline solutions[J].Smart Mater Struct,2013,22(5):055028.
11 Wang Y,Zhu Z,Liu J,et al.Effects of surface roughening of Nation 117 on the mechanical and physicochemical properties of ionic polymer-metal composite(IPMC)actuators[J].Smart Mater Struct,2016,25(8):085012.
12 Biswal D K,Bandopadhya D,Dwivedy S K.Preparation and experimental investigation of thermo-electro-mechanical behavior of AgIPMC actuator[J].Int J Precision Eng Manuf,2012,13(5):777.
13 Cellini F,Grillo A,Porfiri M Ionic polymer metal composites with polypyrrole-silver electrodes[J].Appl Phys Lett,2015,106(13):131902.
14 Brunetto P,Fortuna L,Giannone P,et al.Static and dynamic characterization of the temperature and humidity influence on IPMC actuators[J].IEEE Trans Instrumentation Measurement,2010,59(4):893.
15 Chang Longfei,Chen Hualing,Zhu Zicai,et al.Optimization for the manufacturing process of ionic polymer-metal composite with Pd electrodes[J].J Fund Mater,2014(7):7130(in Chinese).常龙飞,陈花玲,朱子才,等.钯型离子聚合物-金属复合材料的制备工艺参数优化研究[J].功能材料,2014(7):7130.
16 Lee S J,Han M J,Kim S J,et al.A new fabrication method for IPMC actuators and application to artificial fingers[J].Smart Mater Struct,2006,15(5):1217.
17 Park I S,Kim S M,Kim K J.Mechanical and thermal behavior of ionic polymer-metal composites:Effects of electroded metals[J].Smart Mater Struct,2007,16(4):1090.
18 Zhu Zicai.Large deformation mechanisms and multi-physical model of ionic polymer-metal composites[D].Xi'an:Xi'an Jiaotong University,2013(in Chinese).朱子才.离子聚合物-金属复合材料的大变形机理与多物理场模型研究[D].西安:西安交通大学,2013.
19 Bonomo C,Fortuna L,Graziani S,et al.A circuit to model an ionic polymer-metal composite as actuator[C]//Circuits and Systems,2004.ISCAS'04.Proceedings of the 2004 International Symposium on.IEEE,2004,4(4):IV864.
20 Chang L,Chen H,Zhu Z,et al.Manufacturing process and electrode properties of palladium-electroded ionic polymer-metal composited].Smart Mater Struct,2012,21(6):065018.
21 Zhu Z,Chen H,Chang L,et al.Influence of fabrication process steps on Pd-IPMC electrode morphologies and mechano-electrical properties[C]//SPIE Smart Structures and Materials+Nondestructive Evaluation and Health Monitoring.International Society for Optics and Photonics,2011:79762T.
22 Annabestani M,Maymandi-Nejad M,Naghavi N.Restraining IPMC back relaxation in large bending displacements:Applying non-feedback local gaussian disturbance by patterned electrodes[J].IEEE Trans Electron Devices,2016,63(4):1689.
23 Zhu Z,Horiuchi T,Kruusamaae K,et al.Influence of ambient humidity on the voltage response of ionic polymer-metal composite sensor[J].J Phys Chem B,2016,120(12):3215.
2 Punning A,Kim K J,Palmre V,et al.Ionic electroactive polymer artificial muscles in space applications[J].Sci Rep,2014,4:6913.
3 Zhou Y,Chiu C W,Sanchez C J,et al.Sound modulation in singing katydids using ionic polymer-metal composites(IPMCs)[J].J Bionic Eng,2013,10(4):464.
4 Ganet F,Le M Q,Capsal J F,et al.Development of a smart guide wire using an electrostrictive polymer:Option for steerable orientation and force feedback[J].Sci Rep,2015,5(5):18593.
5 Wang Yanjie,Wang Yongquan,Chen Hualing,et al.Design and performance investigation for miniature optical lens IPMC actuators[J].J Xi'an Jiaotong University,2012,46(5):79(in Chinese).王延杰,王永泉,陈花玲,等.新型智能材料微小型光学镜头致动器的设计与性能研究[J].西安交通大学学报,2012,46(5):79.
6 Jung S Y,Park J O,Park S.Replacement of surface roughening using polyvinyl alcohol coating in the fabrication of nafion-based ionic polymer metal composite(IPMC)actuators[J].J Polym Res,2016,23(9):178.
7 Park J,Palmre V,Hwang T,et al.Electromechanical performance and other characteristics of IPMCs fabricated with various commercially available ion exchange membranes[J].Smart Mater Struct,2014,23(7):074001.
8 Gu Na,Xiong Ke,An Yi.Preparation and electrochemical impedance analysis of pt-ionic polymer metal composites[J].Mater Rev:Res,2016,30(8):10(in Chinese).顾娜,熊克,安逸.铂型离子聚合物金属复合材料的制备与电化学阻抗分析[J].材料导报:研究篇,2016,30(8):10.
9 Fujiwara N,Asaka K,Nishimura Y,et al.Preparation of gold-solid polymer electrolyte composites as electric stimuli-responsive materials[J].Chem Mater,2000,12(6):1750.
10 Aoyagi W,Omiya M Mechanical and electrochemical properties of an IPMC actuator with palladium electrodes in acid and alkaline solutions[J].Smart Mater Struct,2013,22(5):055028.
11 Wang Y,Zhu Z,Liu J,et al.Effects of surface roughening of Nation 117 on the mechanical and physicochemical properties of ionic polymer-metal composite(IPMC)actuators[J].Smart Mater Struct,2016,25(8):085012.
12 Biswal D K,Bandopadhya D,Dwivedy S K.Preparation and experimental investigation of thermo-electro-mechanical behavior of AgIPMC actuator[J].Int J Precision Eng Manuf,2012,13(5):777.
13 Cellini F,Grillo A,Porfiri M Ionic polymer metal composites with polypyrrole-silver electrodes[J].Appl Phys Lett,2015,106(13):131902.
14 Brunetto P,Fortuna L,Giannone P,et al.Static and dynamic characterization of the temperature and humidity influence on IPMC actuators[J].IEEE Trans Instrumentation Measurement,2010,59(4):893.
15 Chang Longfei,Chen Hualing,Zhu Zicai,et al.Optimization for the manufacturing process of ionic polymer-metal composite with Pd electrodes[J].J Fund Mater,2014(7):7130(in Chinese).常龙飞,陈花玲,朱子才,等.钯型离子聚合物-金属复合材料的制备工艺参数优化研究[J].功能材料,2014(7):7130.
16 Lee S J,Han M J,Kim S J,et al.A new fabrication method for IPMC actuators and application to artificial fingers[J].Smart Mater Struct,2006,15(5):1217.
17 Park I S,Kim S M,Kim K J.Mechanical and thermal behavior of ionic polymer-metal composites:Effects of electroded metals[J].Smart Mater Struct,2007,16(4):1090.
18 Zhu Zicai.Large deformation mechanisms and multi-physical model of ionic polymer-metal composites[D].Xi'an:Xi'an Jiaotong University,2013(in Chinese).朱子才.离子聚合物-金属复合材料的大变形机理与多物理场模型研究[D].西安:西安交通大学,2013.
19 Bonomo C,Fortuna L,Graziani S,et al.A circuit to model an ionic polymer-metal composite as actuator[C]//Circuits and Systems,2004.ISCAS'04.Proceedings of the 2004 International Symposium on.IEEE,2004,4(4):IV864.
20 Chang L,Chen H,Zhu Z,et al.Manufacturing process and electrode properties of palladium-electroded ionic polymer-metal composited].Smart Mater Struct,2012,21(6):065018.
21 Zhu Z,Chen H,Chang L,et al.Influence of fabrication process steps on Pd-IPMC electrode morphologies and mechano-electrical properties[C]//SPIE Smart Structures and Materials+Nondestructive Evaluation and Health Monitoring.International Society for Optics and Photonics,2011:79762T.
22 Annabestani M,Maymandi-Nejad M,Naghavi N.Restraining IPMC back relaxation in large bending displacements:Applying non-feedback local gaussian disturbance by patterned electrodes[J].IEEE Trans Electron Devices,2016,63(4):1689.
23 Zhu Z,Horiuchi T,Kruusamaae K,et al.Influence of ambient humidity on the voltage response of ionic polymer-metal composite sensor[J].J Phys Chem B,2016,120(12):3215.