磁性固体螯合剂(MSC-IDA)对土壤镉污染的移除净化
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- 英文论文题名：Removal of Cd from contaminated soilby Magnetic Solid Chelator Micronparticles(MSC-IDA)
- 论文作者：范力仁 ; 宋吉青 ; 周洋 ; 赵攻城 ; 白文波 ; 李枭铭 ; 栗海峰 ; 张引 ; 周小丹 ; 刘路
- 英文论文作者：Liren Fan ; Jiqing Song ; Yang Zhou ; Gongcheng Zhao ; Wenbo Bai ; Xiaoming Li ; Haifeng Li ; Yin Zhang ; Xiaodan Zhou ; Lu Liu ; Faculty of Materials Science and Chemistry ; China University of Geosciences(Wuhan) ; Wuhan CUG GOLDEN SHIELD Environmental Technology Co. ; Ltd ; Institute of heavy metal Pollution Prevention and Resource Reuse ; Institute of Environment and Sustainable Development in Agriculture ; Chinses Academy of Agricultural Sciences
- 年：2016
- 作者机构：中国地质大学(武汉)材料与化学学院;武汉中地金盾环境科技有限公司;中地金盾重金属污染防治与资源化研究院;中国农业科学院农业环境与可持续发展研究所;
- 论文关键词：磁性固体螯合剂 ; 螯合捕集 ; 土壤重金属污染 ; 镉 ; 移除净化
- 英文论文关键词：Magnetic Solid Chelator ; Chelating capture ; Soil heavy metal pollution ; Cd ; Removal
- 会议召开时间：2016-12-01
- 会议录名称：第六届重金属污染防治及风险评价研讨会暨重金属污染防治专业委员会2016年学术年会论文集
- 语种：中文
- 分类号：X53
- 学会代码：HJKP
- 会议名称：第六届重金属污染防治及风险评价研讨会暨重金属污染防治专业委员会2016年学术年会
- 会议地点：中国福建厦门
- 主办单位：中国环境科学学会
- 学会名称：中国环境科学学会
- 页数：10
- 文件大小：1353k
- 原文格式：D
- 会议级别：全国
摘要
一种基于磁选净化的土壤修复方法已经被报道了,为了弄清其螯合转化机理,通过无机-有机杂化反应对核壳结构Fe_3O_4@SiO_2进行表面修饰亚胺二乙酸官能团,制备了磁性固体螯合剂;并表征了其结构、形貌、组成和性质.结果表明,经SiO_2包覆修饰后MSC-IDA仍具有良好的磁分离性能;在pH=7.0的水溶液中对Cd~(2+)的最大吸附容量Q_(max)=22.8mg/g;MSC-IDA能螯合捕集农田土壤中水溶态、离子交换态、碳酸盐结合态、铁锰氧化物结合态的镉,转化成MSC-IDA-Cd磁性固体螯合物,对指定土壤中镉重金属污染去除率高达84.9%,能够实现土壤中非磁性重金属污染的磁选移除净化.
A soil remediation method based on magnetic beneficiation has been reported. In order to research on the adsorption mechanics of MSC-IDA, MSC-IDA was prepared via inorganic-organic and organic synthesis reactions with Core-shell microspheres Fe3O4@Si O2 by graft iminodiacetic acid(IDA).The structures,morphology, component and property of the composites were characterized by means of modern testing techniques. Results showed that MSC-IDA has a good magnetic separation performance. The max adsorption capacities of MSC-IDA for Cd(Ⅱ)was 22.8 mg/g with the p H=7.0; MSC-IDA has the ability to chelate heavy metal ions(M) such as water-soluble, interchangeable, carbonate-bound, iron-manganese oxide-bound, into soluble magnetic solid that was easy to separate magnetically, resulting in the removal rate of approximately 84.9% for Cd.
A soil remediation method based on magnetic beneficiation has been reported. In order to research on the adsorption mechanics of MSC-IDA, MSC-IDA was prepared via inorganic-organic and organic synthesis reactions with Core-shell microspheres Fe3O4@Si O2 by graft iminodiacetic acid(IDA).The structures,morphology, component and property of the composites were characterized by means of modern testing techniques. Results showed that MSC-IDA has a good magnetic separation performance. The max adsorption capacities of MSC-IDA for Cd(Ⅱ)was 22.8 mg/g with the p H=7.0; MSC-IDA has the ability to chelate heavy metal ions(M) such as water-soluble, interchangeable, carbonate-bound, iron-manganese oxide-bound, into soluble magnetic solid that was easy to separate magnetically, resulting in the removal rate of approximately 84.9% for Cd.
引文
[1]Ali I.New Generation Adsorbents for Water Treatment[J].Chemical Reviews,2012,112(10):5073-5091.
[2]张敏,王美娥,陈卫平,等.湖南攸县典型煤矿和工厂区水稻田土壤镉污染特征及污染途径分析[J].环境科学,2015,36(4):1425-1430.
[3]国土资源部,环境保护部.全国土壤污染状况调查公报[D].
[4]顾继光,林秋奇,胡韧,等.土壤-植物系统中重金属污染的治理途径及其研究展望[J].土壤通报,2005,36(1):128-133.
[5]Ma LQ,Komar KM,Tu C,et al.A fern that hyperaccumulates arsenic[J].Nature,2001,409(6820):579-579.
[6]Gupta VK,Carrott PJM,Ribeiro Carrott MML,et al.Low-cost adsorbents:growing approach to wastewater treatment-a review[J].Critical Reivews in Environmental Science and Technology,2009,39(10):783-842.
[7]Bailey SE,Olin TJ,Bricka RM,et al.A review of potentially low-cost sorbents for heavy metals[J].Water Research,1999,33(11):2469-2479.
[8]Bhattacharyya KG,Gupta SS.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review[J].Advances in colloid and interface science,2008,140(2):114-131.
[9]Sud D,Mahajan G,Kaur MP.Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions–A review[J].Bioresource technology,2008,99(14):6017-6027.
[10]Pankhurst QA,Connodly J,Jones SK,et al.Applications of magnetic nanoparticles in biomedicine[J].Journal of physics D:Applied physics,2003,36(13):R167.
[11]Lu AH,Salabas EL,Schuth F.Magnetic nanoparticles:synthesis,protection,functionalization,and application[J].Angewandte Chemite International Edition,2007,46(8):1222-1244.
[12]Deng Y,Qi D,Deng C,et al.Superparamagnetic high-magnetization microspheres with an Fe3O4@Si O2core and perpendicularly aligned mesoporous Si O2 shell for removal of microcystins[J].Journal of the American Chemical Society,2008,130(1):28-29.
[13]Fan L,Song J,Bai W,et al.Chelating capture and magnetic removal of non-magnetic heavy metal substances from soil[J].Scientific reports,2016,6.
[14]Wang J,Zheng S,Shao Y,et al.Amino-functionalized Fe3O4@Si O2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal[J].Journal of Colloid and Interface Science,2010,349(1):293-299.
[15]Sun Z,Sun B,Qiao M,et al.A general chelate-assisted co-assembly to metallic nanoparticles-incorporated ordered mesoporous carbon catalysts for Fischer-Tropsch synthesis[J].Journal of the American Chemical Society,2012,134(42):17653-17660.
[16]Hochuli E,Dobeli H,Schacher A.New metal chelate adsorbent selective for proteins and peptides containing neighbouring histidine residues[J].Journal of Chromatography A,1987,411:177-184.
[17]Sun S,Zeng H.Size-Controlled Synthesis of Magnetic Nanoparticles[J].Journal of the American Chemical Society,2002,124(28):8204-8205.
[18]Dong Y,Wen B,Chen Y,et al.RSC advances,2016,6(69):64434-64440.
[19]Laurent S,Forge D,Port M,et al.Magnetic Iron Oxide Nanoparticles:Synthesis,Stabilization,Vectorization,Physicochemical Characterizations,and Biological Applications[J].Chemical Reviews,2008,108(6):2064-2110.
[20]Luo Q,Zou H,Xiao X,et al.Chromatographic separation of proteins on metal immobilized iminodiacetic acid-bound molded monolithic rods of macroporous ploy(glycidyl methacrylate-co-ethylene dimethacrylate)[J].Journal of Chromatography A,2001,926(2):255-264.
[21]Tessier A,Campbell P G C,Bisson M.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical chemistry,1979,51(7):844-851.
[22]EI-Bahy SM,EI-Bahy ZM.Synthesis and characterization of a new iminodiacetate chelating resin for removal of toxic heavy metal ions from aqueous solution[J].Korean J.Chem.Eng,2015:1-10.
[2]张敏,王美娥,陈卫平,等.湖南攸县典型煤矿和工厂区水稻田土壤镉污染特征及污染途径分析[J].环境科学,2015,36(4):1425-1430.
[3]国土资源部,环境保护部.全国土壤污染状况调查公报[D].
[4]顾继光,林秋奇,胡韧,等.土壤-植物系统中重金属污染的治理途径及其研究展望[J].土壤通报,2005,36(1):128-133.
[5]Ma LQ,Komar KM,Tu C,et al.A fern that hyperaccumulates arsenic[J].Nature,2001,409(6820):579-579.
[6]Gupta VK,Carrott PJM,Ribeiro Carrott MML,et al.Low-cost adsorbents:growing approach to wastewater treatment-a review[J].Critical Reivews in Environmental Science and Technology,2009,39(10):783-842.
[7]Bailey SE,Olin TJ,Bricka RM,et al.A review of potentially low-cost sorbents for heavy metals[J].Water Research,1999,33(11):2469-2479.
[8]Bhattacharyya KG,Gupta SS.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review[J].Advances in colloid and interface science,2008,140(2):114-131.
[9]Sud D,Mahajan G,Kaur MP.Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions–A review[J].Bioresource technology,2008,99(14):6017-6027.
[10]Pankhurst QA,Connodly J,Jones SK,et al.Applications of magnetic nanoparticles in biomedicine[J].Journal of physics D:Applied physics,2003,36(13):R167.
[11]Lu AH,Salabas EL,Schuth F.Magnetic nanoparticles:synthesis,protection,functionalization,and application[J].Angewandte Chemite International Edition,2007,46(8):1222-1244.
[12]Deng Y,Qi D,Deng C,et al.Superparamagnetic high-magnetization microspheres with an Fe3O4@Si O2core and perpendicularly aligned mesoporous Si O2 shell for removal of microcystins[J].Journal of the American Chemical Society,2008,130(1):28-29.
[13]Fan L,Song J,Bai W,et al.Chelating capture and magnetic removal of non-magnetic heavy metal substances from soil[J].Scientific reports,2016,6.
[14]Wang J,Zheng S,Shao Y,et al.Amino-functionalized Fe3O4@Si O2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal[J].Journal of Colloid and Interface Science,2010,349(1):293-299.
[15]Sun Z,Sun B,Qiao M,et al.A general chelate-assisted co-assembly to metallic nanoparticles-incorporated ordered mesoporous carbon catalysts for Fischer-Tropsch synthesis[J].Journal of the American Chemical Society,2012,134(42):17653-17660.
[16]Hochuli E,Dobeli H,Schacher A.New metal chelate adsorbent selective for proteins and peptides containing neighbouring histidine residues[J].Journal of Chromatography A,1987,411:177-184.
[17]Sun S,Zeng H.Size-Controlled Synthesis of Magnetic Nanoparticles[J].Journal of the American Chemical Society,2002,124(28):8204-8205.
[18]Dong Y,Wen B,Chen Y,et al.RSC advances,2016,6(69):64434-64440.
[19]Laurent S,Forge D,Port M,et al.Magnetic Iron Oxide Nanoparticles:Synthesis,Stabilization,Vectorization,Physicochemical Characterizations,and Biological Applications[J].Chemical Reviews,2008,108(6):2064-2110.
[20]Luo Q,Zou H,Xiao X,et al.Chromatographic separation of proteins on metal immobilized iminodiacetic acid-bound molded monolithic rods of macroporous ploy(glycidyl methacrylate-co-ethylene dimethacrylate)[J].Journal of Chromatography A,2001,926(2):255-264.
[21]Tessier A,Campbell P G C,Bisson M.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical chemistry,1979,51(7):844-851.
[22]EI-Bahy SM,EI-Bahy ZM.Synthesis and characterization of a new iminodiacetate chelating resin for removal of toxic heavy metal ions from aqueous solution[J].Korean J.Chem.Eng,2015:1-10.