海水及模拟海水中铜缓蚀剂的研究进展
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- 英文论文题名：Research and Development on Inhibitors for Copper in Seawater
- 论文作者：高玉华 ; 陈红 ; 刘振法 ; 张利辉 ; 王昕
- 英文论文作者：GAO Yu-hua ; Chen Hong ; LIU Zhen-fa ; ZHANG Li-hui ; Wang Xin ; Institute of Energy Resources ; Hebei Academy of Sciences ; Hebei Jiheng(Group) Pharmaceutiacl Co. ; Ltd. ; School of Chemical Engineering and Technology ; Hebei University of Technology
- 年：2012
- 作者机构：河北省科学院能源研究所;河北冀衡(集团)药业有限公司;河北工业大学化工学院;
- 论文关键词：铜 ; 海水腐蚀 ; 有机缓蚀剂 ; 海水缓蚀剂
- 英文论文关键词：copper ; seawater corrosion ; organic corrosion inhibitor ; seawater corrosion inhibitor
- 会议召开时间：2012-07-25
- 会议录名称：第十七届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十七届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国重庆
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：5
- 文件大小：2004k
- 原文格式：O
- 会议级别：全国
摘要
综述了海水及模拟海水中铜的单一有机缓蚀剂、绿色环保型海水缓蚀剂以及复配型缓蚀剂的国内外研究进展,国外研究侧重于单组分新品种的开发,在缓蚀剂结构的研究上更注重有效官能团的引入,而国内注重现有缓蚀剂品种的复配增效研究。展望了海水中铜缓蚀剂的研究方向,提出今后的研究工作要加强绿色环保型缓蚀剂的研究和应用,加强对新品种的整合利用。
Research progresses of single organic corrosion inhibitors,eco-friendly corrosion inhibitors and of compound corrosion inhibitor for copper in sea water are introduced.The studies have focused on the development of new varieties of the single component and the introduction of active functional groups in the agent structure in foreign.While the studies have focused on the synergies of corrosion inhibitors are compounded in home.The new research and development directions are predicted.The future research works are to strengthen the research and application of green corrosion inhibitors and strengthen the integration and the use of new varieties.
Research progresses of single organic corrosion inhibitors,eco-friendly corrosion inhibitors and of compound corrosion inhibitor for copper in sea water are introduced.The studies have focused on the development of new varieties of the single component and the introduction of active functional groups in the agent structure in foreign.While the studies have focused on the synergies of corrosion inhibitors are compounded in home.The new research and development directions are predicted.The future research works are to strengthen the research and application of green corrosion inhibitors and strengthen the integration and the use of new varieties.
引文
[1]Statake M.Structure of benzotriazole films on metals[J].Copper-Base Mater Technol,2003,42:253-257.
[2]郝彦忠,朱良,熊培文.模拟海水中铜腐蚀及缓蚀的光电化学研究[J].河北科技大学学报,1999,1(48):25-28.
[3]洪全,王艳波,侯保荣.高浓度氯离子环境中铜合金缓蚀的电化学研究[J].应用化工,2005,34(10):618-621.
[4]Zucchi F,Trabanelli G,Mnnticelli C.The inhibition ofcopper corrosion in 0.1 mol·L~(-1)NaCl under heat exchangeconditions[J].Corrosion Science,1996,38(1):147-154.
[5]Ravichandran R,Nanjundan S,Rajendran N.Effect of benzotriazole derivatives on the corosion and dezincificationof brass in neutral chloride solution[J].Journal of Applied Electrochemistry,2004,34:1171-1176.
[6]Ravichandran R,Nanjundan S,Raj endran N.Effect of benzotriazole derivatives on the corosion of brass in NaCl solutions[J].Applied Surface Science,2004,236:241-250.
[7]Ravichandran R,Rajendran N.Electrochemical behaviour of brass in artificial sea water:effect of organic inhibitors[J].Applied Surface Science,2005,241:449-458.
[8]Ravichandran R,Rajendran N.Influence of benzotriazolderivatives on the dezincification of 65 35 brass in sodiumchloride[J].Applied Surface Science,2005,239:182-192.
[9]Otmai H,Telegdi J,Papp K,et al.Pro-tective properties of an Inhibitor layer formed on copper inneutral chloride solutionJomal[J].Applied Electrochemistry,2004:545-550.
[10]Otmacic H,Stupnisek Lisac E.Copper corosion inhibitors in near neutral media[J].Electrochemical Acta,2003,48(8):985-991.
[11]Gaparac R,Martin C R,Stupni Ek-Lisac E.Insitu studies of imidazole and its derivatives as copper corrosion inhibitors.Activation energies and thermodynamics of adsorption[J].J Electrochem Soc,2000,147(3):548-552.
[12]张大全,高立新,汪知恩.NaCl溶液中烷基咪唑对铜的缓蚀作用研究[J].中国腐蚀与防护学报,2002,22(4):237-240.
[13]于萍,罗运柏.改性噻二唑有机铜缓蚀剂性能的研究[J].材料保护,1997,30(10):6-7.
[14]高立新,张大全,陆柱,等.含苯并三唑和噻二唑单元的铜缓蚀剂制备和缓蚀作用[J].华东理工大学学报,2001,27(1):84-88.
[15]El Sayed M.Sherif.Effects of 2-amino-5-(ethyl-thio)-l,3,4-thiadiazole on copper corosion as a corrosion inhibitor in 3%NaCl solutions[J].Applied Surface Science,2006,252:8615.
[16]Sherif E M,Su-Moon Park.2-Amino-5-ethyl-l,3,4-thiadiazole as corosion inhibitor for copper in 3.0%NaCl solutions[J].Corosion Science,2006,48:4065.
[17]董泉玉,陈号位,杨从贵,等.羧酸类铜缓蚀剂的制备及性能测试[J].材料保护,2001,3(3):49-50.
[18]Waheed A Badawy,Khaled M.Ismail,Ahlam M Fathi.Corrosion control of Cu-Ni alloys in neutral chloride solutions by amino acids[J].Electrochimica Acta,2006,51:4182-4189.
[19]韶晖,冷一欣.聚天冬氨酸阻垢性能的研究[J].油田化学,2001,18(2):181-183.
[20]徐群杰,曹敏,周国定.聚天冬氨酸及其复配对3%NaCl溶液中黄铜的缓蚀作用[J].华北电力技术,2005,(9):1-3.
[21]徐群杰,池国镇,时士峰,等.聚环氧琥珀酸对白铜在3%NaCl溶液中的缓蚀作用[J].材料保护,2011,44(7):71-73.
[22]张大全,高立新.苯并三氮唑和8-羟基喹啉对铜缓蚀作用的研究[J].材料保护,2002,35(4):10-11.
[23]董泉玉,张强,李白托,等.羧酸类铜缓蚀剂与苯并三氮唑在海水中协同效应的研究[J].腐蚀与防护,2004,25(10):426-428.
[24]李白托,贾丰春,董泉玉,等.新型复合型铜缓蚀剂的实验研究[J].腐蚀科学与防护技术,2006,18(1):58-60.
[25]张大全,高立新.3%NaCl溶液中咪唑和苯并三唑对Cu缓蚀协同作用的研究[J].腐蚀科学与防护技术,2005,13(3):136-138.
[26]扈显琦,彭乔,张明嘉.海水中铜的缓蚀剂研究[J].四川I化工与腐蚀控制,1999,2(3):4-8.
[2]郝彦忠,朱良,熊培文.模拟海水中铜腐蚀及缓蚀的光电化学研究[J].河北科技大学学报,1999,1(48):25-28.
[3]洪全,王艳波,侯保荣.高浓度氯离子环境中铜合金缓蚀的电化学研究[J].应用化工,2005,34(10):618-621.
[4]Zucchi F,Trabanelli G,Mnnticelli C.The inhibition ofcopper corrosion in 0.1 mol·L~(-1)NaCl under heat exchangeconditions[J].Corrosion Science,1996,38(1):147-154.
[5]Ravichandran R,Nanjundan S,Rajendran N.Effect of benzotriazole derivatives on the corosion and dezincificationof brass in neutral chloride solution[J].Journal of Applied Electrochemistry,2004,34:1171-1176.
[6]Ravichandran R,Nanjundan S,Raj endran N.Effect of benzotriazole derivatives on the corosion of brass in NaCl solutions[J].Applied Surface Science,2004,236:241-250.
[7]Ravichandran R,Rajendran N.Electrochemical behaviour of brass in artificial sea water:effect of organic inhibitors[J].Applied Surface Science,2005,241:449-458.
[8]Ravichandran R,Rajendran N.Influence of benzotriazolderivatives on the dezincification of 65 35 brass in sodiumchloride[J].Applied Surface Science,2005,239:182-192.
[9]Otmai H,Telegdi J,Papp K,et al.Pro-tective properties of an Inhibitor layer formed on copper inneutral chloride solutionJomal[J].Applied Electrochemistry,2004:545-550.
[10]Otmacic H,Stupnisek Lisac E.Copper corosion inhibitors in near neutral media[J].Electrochemical Acta,2003,48(8):985-991.
[11]Gaparac R,Martin C R,Stupni Ek-Lisac E.Insitu studies of imidazole and its derivatives as copper corrosion inhibitors.Activation energies and thermodynamics of adsorption[J].J Electrochem Soc,2000,147(3):548-552.
[12]张大全,高立新,汪知恩.NaCl溶液中烷基咪唑对铜的缓蚀作用研究[J].中国腐蚀与防护学报,2002,22(4):237-240.
[13]于萍,罗运柏.改性噻二唑有机铜缓蚀剂性能的研究[J].材料保护,1997,30(10):6-7.
[14]高立新,张大全,陆柱,等.含苯并三唑和噻二唑单元的铜缓蚀剂制备和缓蚀作用[J].华东理工大学学报,2001,27(1):84-88.
[15]El Sayed M.Sherif.Effects of 2-amino-5-(ethyl-thio)-l,3,4-thiadiazole on copper corosion as a corrosion inhibitor in 3%NaCl solutions[J].Applied Surface Science,2006,252:8615.
[16]Sherif E M,Su-Moon Park.2-Amino-5-ethyl-l,3,4-thiadiazole as corosion inhibitor for copper in 3.0%NaCl solutions[J].Corosion Science,2006,48:4065.
[17]董泉玉,陈号位,杨从贵,等.羧酸类铜缓蚀剂的制备及性能测试[J].材料保护,2001,3(3):49-50.
[18]Waheed A Badawy,Khaled M.Ismail,Ahlam M Fathi.Corrosion control of Cu-Ni alloys in neutral chloride solutions by amino acids[J].Electrochimica Acta,2006,51:4182-4189.
[19]韶晖,冷一欣.聚天冬氨酸阻垢性能的研究[J].油田化学,2001,18(2):181-183.
[20]徐群杰,曹敏,周国定.聚天冬氨酸及其复配对3%NaCl溶液中黄铜的缓蚀作用[J].华北电力技术,2005,(9):1-3.
[21]徐群杰,池国镇,时士峰,等.聚环氧琥珀酸对白铜在3%NaCl溶液中的缓蚀作用[J].材料保护,2011,44(7):71-73.
[22]张大全,高立新.苯并三氮唑和8-羟基喹啉对铜缓蚀作用的研究[J].材料保护,2002,35(4):10-11.
[23]董泉玉,张强,李白托,等.羧酸类铜缓蚀剂与苯并三氮唑在海水中协同效应的研究[J].腐蚀与防护,2004,25(10):426-428.
[24]李白托,贾丰春,董泉玉,等.新型复合型铜缓蚀剂的实验研究[J].腐蚀科学与防护技术,2006,18(1):58-60.
[25]张大全,高立新.3%NaCl溶液中咪唑和苯并三唑对Cu缓蚀协同作用的研究[J].腐蚀科学与防护技术,2005,13(3):136-138.
[26]扈显琦,彭乔,张明嘉.海水中铜的缓蚀剂研究[J].四川I化工与腐蚀控制,1999,2(3):4-8.
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