武汉城市圈岩溶热储水化学特征及水——岩作用研究
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摘要
根据武汉城市圈岩溶热储地热田的地下热水水化学数据,总结了岩溶热水的水化学类型,分析了岩溶热水中主要组分随温度的变化特征,重点研究了水—岩作用程度和作用时间的关系,系统分析了热水中主要离子的水化学作用过程。研究结果表明,热水中主要组分含量受温度和水岩作用过程控制,TDS含量随水岩作用时间的增加而增加,随着TDS含量的增加,水岩作用受碳酸盐溶解控制逐渐转变为受硫酸盐溶解控制,高TDS时,盐岩溶解作用加强;浪口、五洪山、蛇屋山地热田属同一个岩溶水流系统,汤池地热田、马口地热井属同一个水流系统,其他地热田属各自独立的水流系统。
Based on the geothermal water hydrochemical data of karst geothermal fields of Wuhan urban agglomeration,the authors summarized the hydrochemical type of karst hot mineral water,analyzed the variation characteristics of main components of karst hot mineral water with temperature,studied the relationship between the degree and time of water-rock action,and analyzed the hydrochemical processes of the main ions in hot water. The results show that the content of main components in hot water is controlled by temperature and water-rock interaction process,the total dissolved solids content increases with the increase of water-rock action time.As the total dissolved solids content increases,the water-rock interaction was gradually transformed from carbonate dissolution to sulfate dissolution,at high total dissolved solids,the dissolution of salt rocks is enhanced. the Langkou geothermal field,the Wuhongshan geothermal field and the Shewushan geothermal field belong to the same water flow system,the Tangchi geothermal field and the Makou geothermal well belong to the same water flow system,and other geothermal fields belong to separated water flow systems.
Based on the geothermal water hydrochemical data of karst geothermal fields of Wuhan urban agglomeration,the authors summarized the hydrochemical type of karst hot mineral water,analyzed the variation characteristics of main components of karst hot mineral water with temperature,studied the relationship between the degree and time of water-rock action,and analyzed the hydrochemical processes of the main ions in hot water. The results show that the content of main components in hot water is controlled by temperature and water-rock interaction process,the total dissolved solids content increases with the increase of water-rock action time.As the total dissolved solids content increases,the water-rock interaction was gradually transformed from carbonate dissolution to sulfate dissolution,at high total dissolved solids,the dissolution of salt rocks is enhanced. the Langkou geothermal field,the Wuhongshan geothermal field and the Shewushan geothermal field belong to the same water flow system,the Tangchi geothermal field and the Makou geothermal well belong to the same water flow system,and other geothermal fields belong to separated water flow systems.
引文
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[18]张人权,梁杏,靳孟贵,等.水文地质学基础[M].北京:地质出版社,2011.Zhang R Q,Liang X,Jin M G,et al.Fundamentals of hydrogeology[M].Beijing:Geological Publishing House,2011.
[19]肖琼.重庆三叠系碳酸盐岩热储成因与水-岩作用过程研究[D].重庆:西南大学,2012.Xiao Q.Water-rock interaction and genesis of thermal groundwater in carbonate reservoir in Chongqing[D].Chongqing:Southwest U-niversity,2012.
[20]王焰新,孙连发,罗朝晖,等.指示娘子关泉群水动力环境的水化学-同位素信息分析[J].水文地质工程地质,1997,24(3):1-5.Wang Y X,Sun L F,Luo Z H,et al.Analysis of hydrochemical-isotope information indicating hydrodynamic environment of Niangziguan Spring Group[J].Hydrogeology and Engineering Geology,1997,24(3):1-5.
[21]王增银,刘娟,崔银祥,等.延河泉岩溶水系统Sr/Mg、Sr/Ca分布特征及其应用[J].水文地质工程地质,2003(2):15-19.Wang Z Y,Liu J,Cui Y X,et al.Distribution characteristics of Sr/Mg、Sr/Ca and applications in Yanhe spring karst water system[J].Hydrogeology and Engineering Geology,2003(2):15-19.
[2]沈照理.应该重视水-岩相互作用的研究[J].水文地质工程地质,1991,18(2):1.Shen Z L.More attention should be paid to water-rock interaction studies[J].Hydrogeology and Engineering Geology,1991,18(2):1.
[3]王焰新,沈照理.水-岩相互作用研究历史回顾与创新领域展望[C]//第四届世界华人地质科学研讨会论文摘要集,2002.Wang Y X,Shen Z L.Historical review and outlook for innovation field of water-rock interaction studies[C]//Summary of Papers of the Fourth World Chinese Symposium on Geological Sciences,2002.
[4]Ellis A J,Mahon W A J.Geochemistry and Geothermal Systems[M].New York:Academic Press,1977.
[5]Giggenbach W F.Andesitic water:A phanton of isotonpic evolution of water-silicate system[J].Earth and Planetery Science Letters,1990(120):519-522.
[6]曹云.重庆市北温泉景区温泉和钙华的地球化学研究[D].重庆:西南大学,2007.Cao Y.Study on geochenical characteristicd of warm spring water and travertine in north springs of Chongqing[D].Chongqing:Southwest University,2007.
[7]曹云.重庆市北温泉与四川康定温泉水之地球化学特征对比[J].中国岩溶,2006,25(2):112-120.Cao Y.Comparison of geochemical features of warm springs between Chongqing and Kangding[J].Carsologica Sinica,2006,25(2):112-120.
[8]黄爽兵,李晓,刘昌蓉.云南省龙陵县地下热水特征及控制因素研究[J].水土保持研究,2007,14(3):147-149.Huang S B,Li X,Liu C R.Study on characteristics and control factors of underground hot water in area of Nongling,Yunnan[J].Research of Soil and Water Conservation,2007,14(3):147-149.
[9]牛俊强,苏呈,廖媛.湖北省地下热水成因类型及成矿模式分析[J].资源环境与工程,2018,32(4):595-598.Niu J Q,Su C,Liao Y.Genetic type and metallogenic model of geothemal water in Hubei Province[J].Resources Environment&Engineering,2018,32(4):595-598.
[10]程伯禹.湖北省地热资源与可持续开发利用[J].资源环境与工程,2007,21(S1):107-110.Cheng B Y.Geothermal resources and its sustainable development in Hubei Province[J].Resources Environment&Engineering,2007,21(S1):107-110.
[11]陆天平,陈忠奎.湖北省地热的基本类型、特征及生成规律[J].资源环境与工程,2007,21(6):691-694.Lu T P,Chen Z K.Basic types,characteristics and forming rules of terrestrial heatin Hubei[J].Resources Environment&Engineering,2007,21(6):691-694.
[12]宁国民,陆柏树,李刚,等.江汉盆地洪湖乌林浅埋型地热田综合评价[J].资源环境与工程,2007,21(S1):111-115.NIing G M,Lu B S,Li G,et al.Comprehensive evaluation of the Wulin geothermal field in Honghu City of Jianghan basin[J].Resources Environment&Engineering,2007,21(S1):111-115.
[13]汪集旸.中低温对流型地热系统[M].北京:科学出版社,1993.Wang J Y.Low-medium temperature geothermal system of convective type[M].Beijing:Science Publishing House,1993.
[14]郭海清,马瑞,王焰新,等.盆-山地下水系统演化及其水资源-环境效应[M].北京:科学出版社,2010.Guo H Q,Ma R,Wang Y X,et al.Evolution of basin-mountainscale groundwater system and its water resource-environment effects:A case study at Taiyuan basin,Shanxi Province,China[M].Beijing:Science Publishing House,2010.
[15]马腾,王焰新,马瑞,等.太原盆地区碳酸盐岩中-低温地热系统演化[J].地球科学:中国地质大学学报,2012,37(2):229-238.Ma T,Wang Y X,Ma R,et al.Evolution of medium-low temperature carbonate geothermal system in Taiyuan,northern China[J].Earth Science-Journal of China University of Geosciences,2012,37(2):229-238.
[16]梁杏,张人权,靳孟贵.地下水流系统[M].北京:地质出版社,2015.Liang X,Zhang R Q,Jin M G.Systems of groundwater flow[M].Beijing:Geological Publishing House,2015.
[17]Jozsef Toth.重力驱动地下水流系统理论及其应用[M].北京:地质出版社,2015.Jozsef Toth.Gravitational systems of groundwater flow:Theory,evaluation,utilization[M].Beijing:Geological Publishing House,2015.
[18]张人权,梁杏,靳孟贵,等.水文地质学基础[M].北京:地质出版社,2011.Zhang R Q,Liang X,Jin M G,et al.Fundamentals of hydrogeology[M].Beijing:Geological Publishing House,2011.
[19]肖琼.重庆三叠系碳酸盐岩热储成因与水-岩作用过程研究[D].重庆:西南大学,2012.Xiao Q.Water-rock interaction and genesis of thermal groundwater in carbonate reservoir in Chongqing[D].Chongqing:Southwest U-niversity,2012.
[20]王焰新,孙连发,罗朝晖,等.指示娘子关泉群水动力环境的水化学-同位素信息分析[J].水文地质工程地质,1997,24(3):1-5.Wang Y X,Sun L F,Luo Z H,et al.Analysis of hydrochemical-isotope information indicating hydrodynamic environment of Niangziguan Spring Group[J].Hydrogeology and Engineering Geology,1997,24(3):1-5.
[21]王增银,刘娟,崔银祥,等.延河泉岩溶水系统Sr/Mg、Sr/Ca分布特征及其应用[J].水文地质工程地质,2003(2):15-19.Wang Z Y,Liu J,Cui Y X,et al.Distribution characteristics of Sr/Mg、Sr/Ca and applications in Yanhe spring karst water system[J].Hydrogeology and Engineering Geology,2003(2):15-19.
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