Fe~0-生物铁法强化污水处理研究进展
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摘要
生物铁法是一种研究广泛的生物强化处理工艺。在总结传统生物铁法的基础上,详细介绍了Fe~0-生物铁法的作用机理、研究现状及发展前景。相比传统生物铁法,Fe~0-生物铁法能够持续产生铁碳微电解作用和发生类Fenton效应,这些作用对微生物降解污染物具有协同强化作用;再者,Fe~0能以载体的形式投加到反应器中,大大减小了工程应用的难度。针对Fe~0-生物铁法应用现状,指出今后的研究方向应集中在开发适宜于Fe~0-生物铁法的工艺、工艺参数及性能良好的Fe~0材料等方面。
Fe~0-bioferric process is a kind of far-ranging biologically enhanced treatment technology. Based on asummary of the traditional bioferric process,the mechanism,research status and development prospect of Fe~0-bioferric process are introduced in detail. Compared with traditional bioferric process,Fe~0-bioferric process cancontinuously produce Fe/C micro-electrolysis and Fenton-like effects. These functions have synergistic and enhancingeffects on the microbial-degradation of pollutants. In addition,Fe~0 can be added to the reactor in form of carriers,asa result,reducing the hardness of engineering application greatly. Aiming at the application status of Fe~0-bioferricprocess,it is pointed out that the future research directions should be focused on the development of technologiesthat are suitable for Fe~0-bioferric process,the determination of technological parameters,and the research on Fe~0 materials with excellent performances.
Fe~0-bioferric process is a kind of far-ranging biologically enhanced treatment technology. Based on asummary of the traditional bioferric process,the mechanism,research status and development prospect of Fe~0-bioferric process are introduced in detail. Compared with traditional bioferric process,Fe~0-bioferric process cancontinuously produce Fe/C micro-electrolysis and Fenton-like effects. These functions have synergistic and enhancingeffects on the microbial-degradation of pollutants. In addition,Fe~0 can be added to the reactor in form of carriers,asa result,reducing the hardness of engineering application greatly. Aiming at the application status of Fe~0-bioferricprocess,it is pointed out that the future research directions should be focused on the development of technologiesthat are suitable for Fe~0-bioferric process,the determination of technological parameters,and the research on Fe~0 materials with excellent performances.
引文
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[22]李双.海绵铁加量对SBR反应器性能的影响研究[D].兰州:兰州交通大学,2015.
[23]沈燕红.纳米铁添加协同生物脱氮除磷效果及其对微生物的影响[D].杭州:浙江大学,2014.
[24]古创,吴春英,支霞辉,等.铁刨花对A/O/A工艺脱氮除磷效果的影响[J].中国给水排水,2010,26(11):12-15.
[25]王霞.有机多孔——金属微孔复合填料的开发及在生活污水脱氮除磷中的应用研究[D].兰州:兰州交通大学,2012.
[26]李宁,金朝晖,李铁龙,等.生物膜对纳米铁-微生物去除地下水中NO3--N的影响[J].环境科学,2011,32(6):1620-1626.
[27]支霞辉.铁内电解法与生物法耦合脱氮工艺的研究[D].上海:同济大学,2006.
[28]王梦月,马鲁铭.催化铁强化低碳废水生物反硝化过程的探讨[J].环境科学,2014,35(7):2633-2638.
[29]吴春英,白鹭,谷风.金属铁对SBR短程硝化反硝化的影响[J].中国给水排水,2015,31(19):64-67.
[30]冯娟娟,王亚娥,李杰,等.新型富铁多孔复合填料强化生化处理效能研究[J].中国给水排水,2013,29(3):24-28.
[31]马斌,张耀斌,全燮,等.ZVI强化厌氧处理高浓度颜料废水[J].环境工程学报,2015,9(2):767-772.
[32]汤文琪.Fe0-厌氧微生物联合体系处理活性染料的试验研究[D].湘潭:湘潭大学,2009.
[33]林港.零价铁强化厌氧处理难降解废水的实验研究[D].大连:大连理工大学,2012.
[2]任雪锋,毕学军,程丽华,等.复合铁酶促活性污泥强化生物脱氮除磷研究[J].中国给水排水,2011,27(3):24-28.
[3]张文玮.提高焦化污水的生化处理效果[J].煤化工,1988(3):19-22.
[4]Zou Haiyan,Xi Danli.Studies on the performance of BioferricSMBR[J].Environmental Science,2005,26(6):65-70.
[5]Zou Haiyan,Xi Danli.Performance of bioferric-submerged membrane bioreactor for dyeing wastewater treatment[J].Frontiers of Environmental Science&Engineering,2007,1(3):374-380.
[6]王思建,王东东,谢新展.混合微电解-生物铁-气浮法处理印染废水[J].环境科技,2007,20(2):37-39.
[7]裴保安,张慧利,宋同鹤,等.生物铁法处理制革污水[J].河南科技,1997(9):19-19.
[8]胡伟.生物铁法及其在焦化污水处理上的应用[J].农经,2000(5):20.
[9]张瑞.絮凝及固定化微生物法处理炼油废水的研究[D].杨凌:西北农林科技大学,2009.
[10]王国栋,刘书琴,倪福功,等.生物增效法和生物铁法在炼油废水处理中的应用[J].中国给水排水,2011,27(11):98-100.
[11]秦许河,刘旭东,李慧.生物铁-MBR处理生活污水的试验研究[J].工业用水与废水,2010,41(5):52-55.
[12]Marchand E A,Silverstein J.The role of enhanced heterotrophic bacterial growth on iron oxidation by Acidithiobacillus ferrooxidans[J].Geomicrobiology Journal,2003,20(3):231-244.
[13]Kharchenko U V,Beleneva I A,Karpov V A,et al.Microbiological activity of fouling communities as indicator of biocorrosion aggressiveness of sea water[J].Protection of Metals and Physical Chemistry of Surfaces,2010,46(7):842-845.
[14]Feitz A J,Joo S H,Guan Jing,et al.Oxidative transformation of contaminants using colloidal zero-valent iron[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2005,265(1/2/3):88-94.
[15]Joo S H,Feitz A J,Sedlak D L,et al.Quantification of the oxidizing capacity of nanoparticulate zero-valent iron[J].Environmental Science&Technology,2005,39(5):1263-1268.
[16]Joo S H,Feitz A J,Waite T D.Oxidative degradation of the carbothioate herbicide,molinate,using nanoscale zero-valent iron[J].Environmental Science&Technology,2004,38(7):2242.
[17]Keenan C R,Sedlak D L.Factors affecting the yield of oxidants from the reaction of nanoparticulate zero-valent iron and oxygen[J].Environmental Science&Technology,2008,42(14):5377.
[18]王亚娥,李杰,翟思媛,等.Fe0对SBBR工艺处理腈纶废水性能影响[J].化工学报,2013,64(8):2996-3002.
[19]Wang Xiaomao,Waite T D.Iron speciation and iron species transformation in activated sludge membrane bioreactors[J].Water Research,2010,44(11):3511-3521.
[20]Voegelin A,Hug S J.Catalyzed oxidation of arsenic(Ⅲ)by hydrogen peroxide on the surface of ferrihydrite:an in situ ATR FTIR study[J].Environmental Science&Technology,2003,37(5):972-978.
[21]李正.生物海绵铁在好氧除磷过程中的理论研究[D].兰州:兰州交通大学,2014.
[22]李双.海绵铁加量对SBR反应器性能的影响研究[D].兰州:兰州交通大学,2015.
[23]沈燕红.纳米铁添加协同生物脱氮除磷效果及其对微生物的影响[D].杭州:浙江大学,2014.
[24]古创,吴春英,支霞辉,等.铁刨花对A/O/A工艺脱氮除磷效果的影响[J].中国给水排水,2010,26(11):12-15.
[25]王霞.有机多孔——金属微孔复合填料的开发及在生活污水脱氮除磷中的应用研究[D].兰州:兰州交通大学,2012.
[26]李宁,金朝晖,李铁龙,等.生物膜对纳米铁-微生物去除地下水中NO3--N的影响[J].环境科学,2011,32(6):1620-1626.
[27]支霞辉.铁内电解法与生物法耦合脱氮工艺的研究[D].上海:同济大学,2006.
[28]王梦月,马鲁铭.催化铁强化低碳废水生物反硝化过程的探讨[J].环境科学,2014,35(7):2633-2638.
[29]吴春英,白鹭,谷风.金属铁对SBR短程硝化反硝化的影响[J].中国给水排水,2015,31(19):64-67.
[30]冯娟娟,王亚娥,李杰,等.新型富铁多孔复合填料强化生化处理效能研究[J].中国给水排水,2013,29(3):24-28.
[31]马斌,张耀斌,全燮,等.ZVI强化厌氧处理高浓度颜料废水[J].环境工程学报,2015,9(2):767-772.
[32]汤文琪.Fe0-厌氧微生物联合体系处理活性染料的试验研究[D].湘潭:湘潭大学,2009.
[33]林港.零价铁强化厌氧处理难降解废水的实验研究[D].大连:大连理工大学,2012.