高纯稀土金属制备方法及最新发展趋势
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摘要
稀土金属广泛应用于现代科技不可或缺的功能材料当中,如高性能稀土永磁材料、磁致伸缩材料、磁制冷材料、稀土贮氢材料、稀土发光材料等,没有足够纯度的稀土原材料,就不可能制备出性能优良的功能材料。以高纯稀土金属及其化合物制备的稀土新材料在现代高新技术和军事技术所发挥的特殊作用已经引起各国政府和专家的高度关注。综述了高纯稀土金属的制备方法、用途、关键设备以及未来发展趋势,为高纯稀土金属的制备研究提供借鉴和参考。
Rare earth material is an important material for modern technology,and widely used as high performance magnet materials,magnetostriction materials,magnetic refrigerant materials,hydrogen storage materials and luminescent materials,but the purity of rare earth material impairs seriously the performance of material.The special performance of high purity rare earth material in new and military technology is highly focused by government and experts.In this study,the preparation method,application,equipments and growing trend of high purity rare earth were summarized and providing references for the preparation of high purity rare earth.
Rare earth material is an important material for modern technology,and widely used as high performance magnet materials,magnetostriction materials,magnetic refrigerant materials,hydrogen storage materials and luminescent materials,but the purity of rare earth material impairs seriously the performance of material.The special performance of high purity rare earth material in new and military technology is highly focused by government and experts.In this study,the preparation method,application,equipments and growing trend of high purity rare earth were summarized and providing references for the preparation of high purity rare earth.
引文
[1]李中华,张卫平.稀土新材料在现代军事技术上的应用及发展趋势[J].湖南冶金,2006,34(4):43.
[2]秦治忠.稀土在现代军事中的作用[J].世界有色金属,1998(11):27.
[3]贾银松.扎实推进“稀土功能+”行动,为经济发展增添新动能[J].金属功能材料,2017,24(2):1.
[4]钟俊辉.高纯稀有金属材料[J].上海金属:有色分册,1991,12(4):44.
[5]徐光宪.稀土(中)[M].北京:冶金工业出版社,1995.
[6]Kobisk E H,Grisham W B.Application of reduction-diatillation method for preparing high-purity rare-earth iso-tope metals[J].Materials Research Bulletin,1969,4(9):651.
[7]中国超高纯稀土金属及合金节能环保制备技术研究取得重大进展[J].稀土,2014,35(6):105.
[8]张卫平,杨庆山,陈建军.高纯稀土金属制备方法与发展趋势[J].金属材料与冶金工程,2007,35(3):64.
[9]郝占忠,姜银举,杨家勇,等.金属镝、钬、铒蒸馏提纯效果的研究[J].稀土,1999,20(6):14.
[10]郝占忠,姜银举,杨家勇,等.金属铕制备工艺的研究[J].稀土,1999,20(4):24.
[11]张小琴,姜银举,代清.真空蒸馏法制备高纯金属钆[J].包钢科技,2007,33(3):17.
[12]庞思明,王志强,周林,等.稀土超磁致伸缩材料用高纯金属铽、镝的制备工艺研究[J].稀土,2008,29(6):31.
[13]刘宝忠.高纯金属镝的制备[J].稀有金属快报,2008,27(2):9.
[14]李宗安,张炜,徐静,等.高纯金属铽制备工艺研究[J].稀土,2002,23(6):36.
[15]杨庆山,柳术平,欧阳宇平,等.高纯金属铽制备工艺研究[J].江西有色金属,2005,19(1):31.
[16]张小琴,姜银举,代清.真空蒸馏法制备高纯金属钆[J].包钢科技,2007,33(3):17.
[17]陈卫平,柳术平,杨庆山,等.高纯金属铕的研制[J].稀有金属与硬质合金,2005,33(4):17.
[18]李国栋,刘永林.高纯金属钪的制备工艺及提纯机理研究[J].内蒙古大学学报,1997,28(5):614.
[19]胡华业.高纯金属钪的制备[J].稀土,1999,20(4):70.
[20]叶大伦,胡建华.实用无机物热力学数据手册[M].2版.北京:冶金工业出版社,2002.
[21]刘光启,马连湘,刘杰.化学化工物性数据手册[M].无机卷.北京:化学工业出版社,2002.
[22]稀有金属手册编辑委员会.稀有金属手册[M].下册.北京:冶金工业出版社,1995.
[23]储爱民,姜银举,赵玉萍.镧热还原氧化钐过程动力学控速环节的探索[J].江西有色金属,2005,19(2):26.
[24]姜银举,储爱民.镧热还原氧化钐过程冶金动力学分析[J].稀土,2006,27(2):49.
[2]秦治忠.稀土在现代军事中的作用[J].世界有色金属,1998(11):27.
[3]贾银松.扎实推进“稀土功能+”行动,为经济发展增添新动能[J].金属功能材料,2017,24(2):1.
[4]钟俊辉.高纯稀有金属材料[J].上海金属:有色分册,1991,12(4):44.
[5]徐光宪.稀土(中)[M].北京:冶金工业出版社,1995.
[6]Kobisk E H,Grisham W B.Application of reduction-diatillation method for preparing high-purity rare-earth iso-tope metals[J].Materials Research Bulletin,1969,4(9):651.
[7]中国超高纯稀土金属及合金节能环保制备技术研究取得重大进展[J].稀土,2014,35(6):105.
[8]张卫平,杨庆山,陈建军.高纯稀土金属制备方法与发展趋势[J].金属材料与冶金工程,2007,35(3):64.
[9]郝占忠,姜银举,杨家勇,等.金属镝、钬、铒蒸馏提纯效果的研究[J].稀土,1999,20(6):14.
[10]郝占忠,姜银举,杨家勇,等.金属铕制备工艺的研究[J].稀土,1999,20(4):24.
[11]张小琴,姜银举,代清.真空蒸馏法制备高纯金属钆[J].包钢科技,2007,33(3):17.
[12]庞思明,王志强,周林,等.稀土超磁致伸缩材料用高纯金属铽、镝的制备工艺研究[J].稀土,2008,29(6):31.
[13]刘宝忠.高纯金属镝的制备[J].稀有金属快报,2008,27(2):9.
[14]李宗安,张炜,徐静,等.高纯金属铽制备工艺研究[J].稀土,2002,23(6):36.
[15]杨庆山,柳术平,欧阳宇平,等.高纯金属铽制备工艺研究[J].江西有色金属,2005,19(1):31.
[16]张小琴,姜银举,代清.真空蒸馏法制备高纯金属钆[J].包钢科技,2007,33(3):17.
[17]陈卫平,柳术平,杨庆山,等.高纯金属铕的研制[J].稀有金属与硬质合金,2005,33(4):17.
[18]李国栋,刘永林.高纯金属钪的制备工艺及提纯机理研究[J].内蒙古大学学报,1997,28(5):614.
[19]胡华业.高纯金属钪的制备[J].稀土,1999,20(4):70.
[20]叶大伦,胡建华.实用无机物热力学数据手册[M].2版.北京:冶金工业出版社,2002.
[21]刘光启,马连湘,刘杰.化学化工物性数据手册[M].无机卷.北京:化学工业出版社,2002.
[22]稀有金属手册编辑委员会.稀有金属手册[M].下册.北京:冶金工业出版社,1995.
[23]储爱民,姜银举,赵玉萍.镧热还原氧化钐过程动力学控速环节的探索[J].江西有色金属,2005,19(2):26.
[24]姜银举,储爱民.镧热还原氧化钐过程冶金动力学分析[J].稀土,2006,27(2):49.