云南都龙锡锌多金属矿床曼家寨矿段流体包裹体研究
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摘要
云南都龙锡锌多金属矿床属于滇东南区域锡多金属成矿带中重要组成部分。该矿床由铜街、曼家寨、辣子寨、五口硐、南当厂五个矿段组成,其中仅曼家寨为超大型规模。本文以都龙锡锌矿曼家寨矿段为研究对象,在野外及镜下工作基础上进行矿床地质特征研究和流体包裹体测温分析,进而获得以下认识:(1)包裹体寄主矿物主要为方解石和石英,其类型多为富液相包裹体,少数富气相包裹体,成矿流体主要为H_2O-NaCl体系与CO_2-H_2O体系两种。NaCl-H_2O型包裹体完全均一温度范围为145.1℃~247.6℃,盐度范围2.07wt%NaCleqv~12.96wt%NaCleqv,密度范围:0.84g·cm~(-3)~0.98g·cm~(-3);CO_2-H_2O型包裹体完全均一温度范围为145.4℃~341.9℃,盐度范围7.38wt%NaCleqv~17.48wt%NaCleqv。(2)成矿流体由高温高盐度演变为中低温低盐度流体,且可能具有不混溶或沸腾特征。(3)综合研究结果,推测内岩浆热液顺层交代形成层状矽卡岩,并在成岩过程中随着物理化学条件变化与沸腾作用下,大量沉淀析出金属矿物。
As one important component of the polymetallic mineralization belt in southeastern Yunnan Province,the Dulong Sn-Zn polymetallic deposit consists of five mining sections: Tongjie,Manjiazhai,Lazizhai,Wkoudong and Nandangchang,of which only Manjiazhai is a large one. Taking Manjiazhai as the object,based on field surveys and microscopic observations,This work studied geological features and measured temperature of fluid inclusions of the deposit. Some insights are obtained as follows:( 1) The main host minerals are calcite and quartz,dominated by liquid-rich inclusions,with a few vapour-rich inclusions. There are two primary types of ore-forming fluids: NaCl-H_2O and CO_2-H_2O. For type NaCl-H_2O,the ranges of homogeneous temperature,mineralizated fluid salinity and fluid density are 145. 1℃ ～ 247. 6℃,2. 07 wt% NaCleqv ～ 12. 96 wt% NaCleqv,and 0. 84 g·cm~(-3)～ 0. 98 g·cm~(-3),respectively. For type CO_2-H_2O,the ranges of homogeneous temperature and mineralization fluid salinity are 145. 4℃ ～341. 9℃ and 7. 38 wt% NaCleqv ～ 17. 48 wt% NaCleqv,respectively.( 2) Overall,the mode of ore-forming fluid has changed from high-temperature and high-salinity fluids into low-temperature and low-salinity fluids. At the same time,the ore-forming fluid may be have the characteristic of immiscibility and ebullition.( 3) Comprehensive study suggests that stratiform skarn is the product of magmatic hydrothermal fluids reaction with wall rock.With changes of physicochemical conditions and boiling action,massive amount of sediments of metalliferous mineral might be precipitated from the fluids.
As one important component of the polymetallic mineralization belt in southeastern Yunnan Province,the Dulong Sn-Zn polymetallic deposit consists of five mining sections: Tongjie,Manjiazhai,Lazizhai,Wkoudong and Nandangchang,of which only Manjiazhai is a large one. Taking Manjiazhai as the object,based on field surveys and microscopic observations,This work studied geological features and measured temperature of fluid inclusions of the deposit. Some insights are obtained as follows:( 1) The main host minerals are calcite and quartz,dominated by liquid-rich inclusions,with a few vapour-rich inclusions. There are two primary types of ore-forming fluids: NaCl-H_2O and CO_2-H_2O. For type NaCl-H_2O,the ranges of homogeneous temperature,mineralizated fluid salinity and fluid density are 145. 1℃ ～ 247. 6℃,2. 07 wt% NaCleqv ～ 12. 96 wt% NaCleqv,and 0. 84 g·cm~(-3)～ 0. 98 g·cm~(-3),respectively. For type CO_2-H_2O,the ranges of homogeneous temperature and mineralization fluid salinity are 145. 4℃ ～341. 9℃ and 7. 38 wt% NaCleqv ～ 17. 48 wt% NaCleqv,respectively.( 2) Overall,the mode of ore-forming fluid has changed from high-temperature and high-salinity fluids into low-temperature and low-salinity fluids. At the same time,the ore-forming fluid may be have the characteristic of immiscibility and ebullition.( 3) Comprehensive study suggests that stratiform skarn is the product of magmatic hydrothermal fluids reaction with wall rock.With changes of physicochemical conditions and boiling action,massive amount of sediments of metalliferous mineral might be precipitated from the fluids.
引文
Deng Dan-li,Li Bao-hua,Gao Kun-li,Li Bao-peng.2016.Study of fluid inclusions from the Daping gold deposit of Yunnan and implications[J].Geology and Exploration,52(5):865-873(in Chinese with English abstract)
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Han Long,Jiang Ying-jiu.2017.Fluid inclusions and genetic type of the Yanweishan Cu-Ag deposit in the Northern Great Xing'an Rang[J].Geology and Exploration,53(3):445-455(in Chinese with English abstract)
He Fang,Zhang qian,Wang da-peng,Liu Yu-ping,Ye Lin,Bao Tan,Wang Xiao-juan,Miao Ying-li,Zhang Shi-kui,Su Hang,Wei Wen-biao.2014.Ore-forming materials sources of the Dulong SnZn polymetallic deposit,Yunnan,evidences from S-C-O stable isotopes[J].Bulletin of Mineralogy,Petrology and Geochemistry,33(6):900-907(in Chinese with English abstract)
He Fang,Zhang qian,Liu yu-ping,Ye Lin,Miao Ying-li,Wang dapeng,Su Hang,Bao Tan,Wang Xiao-juan.2015.Lead isotope compositions of Dulong Sn-Zn polymetallic deposit,Yunnan,China:Contraints on ore-forming metal sources[J].Acta Mineralogica Sinica,35(3):309-317(in Chinese with English abstract)
Huang Zheng.2016.Skarn mineral assemblage zoning and geochemical charactcristics of Manjiazhai ore block of Dulong tin-deposit,Yunnan Province[D].Kunming:Kunming University of Science and Technology:1-84(in Chinese with English abstract)
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Jia Fu-ju,Qin De-xian,Zhang Wen-yuan,Wu Wei,Yang Xiaokun.2010.Trend and regularity of mineralization in Dulong tin zinc polymentallic deposit in Yunnan Province[J].Nonferrous Metals,62(1):84-87(in Chinese with English abstract)
Li Chang-zhe,Zeng Kai,Liu Heng-da,Li Ting-jun.2014.Review of the genesis of Dulong Tin-Zinc-Copper polymentallic deposit in Maguan Province China[J].Journal of Changchun Institute of Technology(Natural Science Edition),15(4):99-105(in Chinese with English abstract)
Li Zhong-xuan,Liu Yu-ping,Ye Lin,Liao Zhen,Zhang Qian,Wang Biao.2016.Microanalysis of Oolitic Pyrite in Dulong Sn-Zn Polymetallic Deposit,Maguan,Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):510-518(in Chinese with English abstract)
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Ma Qian.2016.Characteristics of fluid inclusions and the mineralization process of the Anba gold deposit in the Yangshan gold-ore zone of the West Qinling[J].Geology and Exploration,52(4):601-613(in Chinese with English abstract)
Su Hang,Wei Wen-biao,Tao Zhi-hua,Dao Xue-qiao,Li Ting-jun.2016.Geological and geochemical Characteristics of Later Yanshanian concealed granite and its relation with Sn-Zn polymetallic mineralization[J].Acta Mineralogica Sinica,36(04):488-496(in Chinese with English abstract)
Tang Yi-ang,Lai Jian-qing,Yang Mu,Mei Jia-jing,Wu Jian,Chen Hou-cheng,Guo Lan-xuan.2017.Characteristics of fluid inclusions and metallogenesis of the Meizichong Pb-Zn-W polymetallic deposit in Guangdong Province[J].Geology and Exploration,53(2):217-226(in Chinese with English abstract)
Tao Zhi-hua,Su Hang,Wei Wen-biao,Dao Xue-qiang.2016.Evolution process of N-S direction faults in Dulong ore area,SE Yunnan Province,China and its mineralization significance[J].Acta Mineralogica Sinica,36(4):497-502(in Chinese with English abstract)
Wang Jin-liang,Wang Xiao-juan,Liu Yu-ping,Wei Wen-biao,Su Hang.2016.Geochemistry of garnet from ore-hosting skarn from Dulong Sn-Zn deposit,SE Yunnan Province,China and its mineralization and exploration significance[J].Acta Mineralogica Sinica,36(4):519-528(in Chinese with English abstract)
Ye Lin,Biao Tan,Liu Yu-ping,Zhang Qian,Wang Xiao-juan,He Fang,Wang Da-peng,Lan Jiang-bo.2016.Mineralization stages and ore-forming fluid of Dulong Sn-Zn polymetal ore deposit,Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):503-509(in Chinese with English abstract)
Ye Lin,Liu Yu-ping,Zhang Qian,Biao Tan,He Fang,Wang Xiaojuan,Wang Da-peng,Lan Jiang-bo.2017.Trace and rare earth elements characteristics of sphalerite in Dulong[J].Journal of Jilin Unviersity:Earth Science Edition,47(3):734-750(in Chinese with English abstract)
Zhang Shi-kui.2013.A further discussion on ore-controlling factors and genesis of the Dulong Sn-Zn polymetallic deposit in Southeast Yunnan[J].Acta Geoscientia Sinica,34(s1):115-121(in Chinese with English abstract)
Zhang Suo-qing,Luo Ai-guo,Su Jian,Yang Zong.2016.Ore prospecting model and blind orebody prediction for Tongjie-Manjiazhai ore domain in Dulong mine,SE Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):549-554(in Chinese with English abstract)
Zhou Zu-gui.2002.Total value of resource in Dulong mine area[J].Yunnan Metallurgy,(5):62-64(in Chinese with English abstract)
邓丹莉,李葆华,高昆丽,李表鹏.2016.云南大坪金矿床流体包裹体研究及其意义[J].地质与勘探,52(5):865-873
高轲,唐菊兴,宋扬,刘治博,方向,杨欢欢,王勤,林彬,宋俊龙.2016.西藏拿若铜(金)矿床隐爆角砾岩流体包裹体研究[J].地质与勘探,52(5):815-825
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Han Long,Jiang Ying-jiu.2017.Fluid inclusions and genetic type of the Yanweishan Cu-Ag deposit in the Northern Great Xing'an Rang[J].Geology and Exploration,53(3):445-455(in Chinese with English abstract)
He Fang,Zhang qian,Wang da-peng,Liu Yu-ping,Ye Lin,Bao Tan,Wang Xiao-juan,Miao Ying-li,Zhang Shi-kui,Su Hang,Wei Wen-biao.2014.Ore-forming materials sources of the Dulong SnZn polymetallic deposit,Yunnan,evidences from S-C-O stable isotopes[J].Bulletin of Mineralogy,Petrology and Geochemistry,33(6):900-907(in Chinese with English abstract)
He Fang,Zhang qian,Liu yu-ping,Ye Lin,Miao Ying-li,Wang dapeng,Su Hang,Bao Tan,Wang Xiao-juan.2015.Lead isotope compositions of Dulong Sn-Zn polymetallic deposit,Yunnan,China:Contraints on ore-forming metal sources[J].Acta Mineralogica Sinica,35(3):309-317(in Chinese with English abstract)
Huang Zheng.2016.Skarn mineral assemblage zoning and geochemical charactcristics of Manjiazhai ore block of Dulong tin-deposit,Yunnan Province[D].Kunming:Kunming University of Science and Technology:1-84(in Chinese with English abstract)
Jia Fu-ju.2007.The deposit modeling and metallogenic prognosis in Manjiazhai tin zinc polymetallic deposit,Dulong in Yunnan[D].Kunming:Kunming University of Science and Technology:1-99(in Chinese with English abstract)
Jia Fu-ju,Qin De-xian,Zhang Wen-yuan,Wu Wei,Yang Xiaokun.2010.Trend and regularity of mineralization in Dulong tin zinc polymentallic deposit in Yunnan Province[J].Nonferrous Metals,62(1):84-87(in Chinese with English abstract)
Li Chang-zhe,Zeng Kai,Liu Heng-da,Li Ting-jun.2014.Review of the genesis of Dulong Tin-Zinc-Copper polymentallic deposit in Maguan Province China[J].Journal of Changchun Institute of Technology(Natural Science Edition),15(4):99-105(in Chinese with English abstract)
Li Zhong-xuan,Liu Yu-ping,Ye Lin,Liao Zhen,Zhang Qian,Wang Biao.2016.Microanalysis of Oolitic Pyrite in Dulong Sn-Zn Polymetallic Deposit,Maguan,Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):510-518(in Chinese with English abstract)
Liu Bin,Shen Kun.1999.Thermodynamic of fluid inclusions[M].Beijing:Geological Publishing House:44-118(in Chinese with English abstract)
Liu Xiang,Peng Zhen-an,Pang Wen-cong,Cao Jiang-shuai,Zhang Wen-bing,Li Qiang,Xue Yan-ping,Wei Gan-hua.2016.Study on fluid inclusions and H-O isotope of the Limu Tungsten-TinNiobium-Tantalum orefield in Guangxi[J].Geology and Exploration,52(6):1016-1028(in Chinese with English abstract)
Liu Xiao-wei.2008.The mineralization forecast of Dulong Tin-Zinc ore periphery deposit[D].Kunming:Kunming University of Science and Technology:1-91(in Chinese with English abstract)
Ma Qian.2016.Characteristics of fluid inclusions and the mineralization process of the Anba gold deposit in the Yangshan gold-ore zone of the West Qinling[J].Geology and Exploration,52(4):601-613(in Chinese with English abstract)
Su Hang,Wei Wen-biao,Tao Zhi-hua,Dao Xue-qiao,Li Ting-jun.2016.Geological and geochemical Characteristics of Later Yanshanian concealed granite and its relation with Sn-Zn polymetallic mineralization[J].Acta Mineralogica Sinica,36(04):488-496(in Chinese with English abstract)
Tang Yi-ang,Lai Jian-qing,Yang Mu,Mei Jia-jing,Wu Jian,Chen Hou-cheng,Guo Lan-xuan.2017.Characteristics of fluid inclusions and metallogenesis of the Meizichong Pb-Zn-W polymetallic deposit in Guangdong Province[J].Geology and Exploration,53(2):217-226(in Chinese with English abstract)
Tao Zhi-hua,Su Hang,Wei Wen-biao,Dao Xue-qiang.2016.Evolution process of N-S direction faults in Dulong ore area,SE Yunnan Province,China and its mineralization significance[J].Acta Mineralogica Sinica,36(4):497-502(in Chinese with English abstract)
Wang Jin-liang,Wang Xiao-juan,Liu Yu-ping,Wei Wen-biao,Su Hang.2016.Geochemistry of garnet from ore-hosting skarn from Dulong Sn-Zn deposit,SE Yunnan Province,China and its mineralization and exploration significance[J].Acta Mineralogica Sinica,36(4):519-528(in Chinese with English abstract)
Ye Lin,Biao Tan,Liu Yu-ping,Zhang Qian,Wang Xiao-juan,He Fang,Wang Da-peng,Lan Jiang-bo.2016.Mineralization stages and ore-forming fluid of Dulong Sn-Zn polymetal ore deposit,Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):503-509(in Chinese with English abstract)
Ye Lin,Liu Yu-ping,Zhang Qian,Biao Tan,He Fang,Wang Xiaojuan,Wang Da-peng,Lan Jiang-bo.2017.Trace and rare earth elements characteristics of sphalerite in Dulong[J].Journal of Jilin Unviersity:Earth Science Edition,47(3):734-750(in Chinese with English abstract)
Zhang Shi-kui.2013.A further discussion on ore-controlling factors and genesis of the Dulong Sn-Zn polymetallic deposit in Southeast Yunnan[J].Acta Geoscientia Sinica,34(s1):115-121(in Chinese with English abstract)
Zhang Suo-qing,Luo Ai-guo,Su Jian,Yang Zong.2016.Ore prospecting model and blind orebody prediction for Tongjie-Manjiazhai ore domain in Dulong mine,SE Yunnan Province,China[J].Acta Mineralogica Sinica,36(4):549-554(in Chinese with English abstract)
Zhou Zu-gui.2002.Total value of resource in Dulong mine area[J].Yunnan Metallurgy,(5):62-64(in Chinese with English abstract)
邓丹莉,李葆华,高昆丽,李表鹏.2016.云南大坪金矿床流体包裹体研究及其意义[J].地质与勘探,52(5):865-873
高轲,唐菊兴,宋扬,刘治博,方向,杨欢欢,王勤,林彬,宋俊龙.2016.西藏拿若铜(金)矿床隐爆角砾岩流体包裹体研究[J].地质与勘探,52(5):815-825
韩龙,姜迎久.2017.大兴安岭北段偃尾山铜银矿床流体包裹体与矿床成因类型研究[J].地质与勘探,53(3):445-455
何芳,张乾,王大鹏,刘玉平,叶霖,鲍谈,王小娟,缪应理,张世奎,苏航,韦文彪.2014.云南都龙Sn-Zn多金属矿床成矿物质来源-硫、碳、氧稳定同位素证据[J].矿物岩石地球化学通报,33(06):900-907
何芳,张乾,刘玉平,叶霖,缪应理,王大鹏,苏航,鲍谈,王小娟.2015.云南都龙锡锌多金属矿床铅同位素组成:成矿金属来源制约[J].矿物学报,35(3):309-317
黄拯.2016.云南都龙多金属矿床曼家寨矿段矽卡岩的矿物组合分带规律及其地球化学特征研究[D].昆明:昆明理工大学:1-84
贾福聚.2007.云南都龙曼家寨锡锌多金属矿床建模与成矿预测[D].昆明:昆明理工大学:1-99
贾福聚,秦德先,张文源,伍伟,杨晓坤.2010.云南都龙锡锌多金属矿床矿化趋势分析及成矿规律[J].有色金属,62(1):84-87
李长哲,曾凯,刘恒达,李廷俊.2014.云南马关都龙超大型锡锌铜多金属矿床成因评述[J].长春工程学院学报(自然科学版),15(4):99-105
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