低温等离子体催化处理含酮类有机废气
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摘要
文章介绍了含酮类有机废气的特征与危害、等离子体催化处理含酮类有机废气现状。重点探讨了不同类型的等离子体催化净化含酮废气装置,各种影响参数如放电功率、放电方式、气体浓度、气体流速、催化剂种类、性质、吸附性、温度、活性物种等对等离子体催化处理含酮类物质的影响,结果表明:等离子体催化处理含酮类有机废气技术具有去除率高、能耗低、效率高、产物选择性好等特点。文章同时探讨了等离子体催化氧化酮类物质的机理,提出了等离子体催化氧化酮类有机废气未来的发展方向。
This paper introduced the characteristics and hazards of ketone-containing organic waste gas and the status of plasma-catalysis treatment of ketone-containing organic waste gas.Different types of plasma-catalysis purification devices for ketone-containing waste gas devices were discussesd.The effect of various influencing parameters such as discharge power,discharge mode,gas concentration,gas flow rate,catalyst type,properties,adsorption,temperature and active species on plasma-catalysis treatment of ketone-containing organic waste gas were disscussed.The results showed that plasma-catalysis treatment of ketone-containing organic waste gas technology had the characteristics of high removal rate,low energy consumption,high efficiency and good product selectivity.At the same time,the mechanism of plasma-catalysis oxidation of ketones was discussed,and the future development direction of plasma-catalysis oxidation of ketone organic waste gas was proposed.
This paper introduced the characteristics and hazards of ketone-containing organic waste gas and the status of plasma-catalysis treatment of ketone-containing organic waste gas.Different types of plasma-catalysis purification devices for ketone-containing waste gas devices were discussesd.The effect of various influencing parameters such as discharge power,discharge mode,gas concentration,gas flow rate,catalyst type,properties,adsorption,temperature and active species on plasma-catalysis treatment of ketone-containing organic waste gas were disscussed.The results showed that plasma-catalysis treatment of ketone-containing organic waste gas technology had the characteristics of high removal rate,low energy consumption,high efficiency and good product selectivity.At the same time,the mechanism of plasma-catalysis oxidation of ketones was discussed,and the future development direction of plasma-catalysis oxidation of ketone organic waste gas was proposed.
引文
[1]田红旗,陈小方,张伟霞.打好蓝天保卫战 VOCs治理是关键——对话挥发性有机物污染治理技术与装备国家工程实验室主任叶代启[J].中国经济周刊,2017(16):64-65.
[2]CHIPER A S,BLIN-SIMIAND N,HENINGER M,et al.Detailed characterization of 2-heptanone conversion by dielectric barrier discharge in N(2) and N(2)/O(2) mixtures[J].Journal of Physical Chemistry A,2010,114(1):397-407.
[3]陈颖,叶代启,刘秀珍,等.我国工业源VOCs排放的源头追踪和行业特征研究[J].中国环境科学,2012,32(1):48-55.
[4]叶代启,陈小方.我国挥发性有机物减排阶段特征及政策应对[J].环境保护,2017,45(13):18-21.
[5]ZHENG C H,SHEN J L,ZHANG Y X,et al.Quantitative assessment of industrial VOC emissions in China:Historical trend,spatial distribution,uncertainties,and projection[J].Atmospheric Environment,2017,150:116-125.
[6]YANG T,GAO D X,YU Y L,et al.Dielectric barrier discharge micro-plasma emission spectrometry for the detection of acetone in exhaled breath[J].Talanta,2016,146:603-608.
[7]MACHALA Z,MORVOVA M,MARODE E,et al.Removal of cyclohexanone in transition electric discharges at atmospheric pressure[J].Journal of Physics D Applied Physics,2000,33(24):3198-3213.
[8]孙美玲,王少锋,项曙光.工业废气中丙酮处理工艺研究进展[J].当代化工,2014,43(9):1860-1862.
[9]KIM H H,OGATA A,FUTAMURA S.Oxygen partial pressure-dependent behavior of various catalysts for the total oxidation of VOCs using cycled system of adsorption and oxygen plasma[J].Applied Catalysis B:Environmental,2008,79(4):356-367.
[10]XIAO G,XU W,LUO Z,et al.Characteristics of toluene decomposition and adsorbent regeneration based on electrically conductive charcoal particle-triggered discharge[J].Rsc Advances,2017,7(71):44696-44705.
[11]ROHANI V,NOBREGA P A,ZADEH M,et al.Combination of VOC degradation and electro-hydrodynamic pumping actions in a surface dielectric barrier discharge reactor[J].Chemical Engineering Journal,2017,309:471-479.
[12]HOU L,LI X,XIE D,et al.Effects of BTEX on the removal of acetone in a coaxial non-thermal plasma reactor:role analysis of the methyl group[J].Molecules,2018,23(4):890(1-15).
[13]DEVINS J C,BURTON M.Formation of hydrazine in electric discharge decomposition of ammonia1,2[J].Journal of the American Chemical Society,1954,76(10):2618-2626.
[14]朱爱民,宫为民,师华,等.低温等离子体催化[J].化学研究与应用,1997,9(5):449-454.
[15]郭玉芳,叶代启.废气治理的低温等离子体-催化协同净化技术[J].环境工程学报,2003,4(7):41-46.
[16]TRINH Q H,GANDHI M S,MOK Y S.Adsorption and plasma-catalytic oxidation of acetone over zeolite-supported silver catalyst[J].Japanese Journal of Applied Physics,2015,54(1S):01AG4.
[17]BESOV A S,VORONTSOV A V.Acceleration of acetone destruction process under synergistic action of photocatalytic oxidation and barrier discharge[J].Plasma Chemistry & Plasma Processing,2007,27(5):624-634.
[18]LYULYUKIN M N,BESOV A S,VORONTSOV A V.Acetone and ethanol vapor oxidation via negative atmospheric corona discharge over titania-based catalysts[J].Applied Catalysis B:Environmental,2016,183:18-27.
[19]TRINH H Q,MOK Y S.Plasma-catalytic oxidation of acetone in annular porous monolithic ceramic-supported catalysts[J].Chemical Engineering Journal,2014,251:199-206.
[20]AYRAULT C,BARRAULT J,BLIN S N,et al.Oxidation of 2-heptanone in air by a DBD-type plasma generated within a honeycomb monolith supported Pt-based catalyst[J].Catalysis Today,2004,89(1-2):75-81.
[21]CHANG C L,LIN T S.Decomposition of toluene and acetone in packed dielectric barrier discharge reactors[J].Plasma Chemistry & Plasma Processing,2005,25(3):227-243.
[22]ZHU X,GAO X,YU X,et al.Catalyst screening for acetone removal in a single-stage plasma-catalysis system[J].Catalysis Today,2015,256:108-114.
[23]ZHU X,TU X,MEI D,et al.Investigation of hybrid plasma-catalytic removal of acetone over CuO/γ-Al2O3 catalysts using response surface method[J].Chemosphere,2016,155:9-17.
[24]GMEZ R A,MONTORO A M,RODR G M A,et al.Improving the pollutant removal efficiency of packed-bed plasma reactors incorporating ferroelectric components[J].Chemical Engineering Journal,2017,314:311-319.
[25]MALIK M A,JIANG X Z.Destruction of VOCs by combination of corona discharge and catalysis techniques[J].Journal of Environmental Sciences,1998,10(3):21-26.
[26]TU X,GALLON H J,WHITEHEAD J C.Plasma-assisted reduction of a NiO/Al2O3 catalyst in atmospheric pressure H2/Ar dielectric barrier discharge[J].Catalysis Today,2013,211(8):120-125.
[27]ZHU X,GAO X,ZHENG C,et al.Plasma-catalytic removal of a low concentration of acetone in humid conditions[J].Rsc Advances,2014,4(71):37796-37805.
[28]LYULYUKIN M N,BESOV A S,VORONTSOV A V.The Influence of corona electrodes thickness on the efficiency of plasma chemical oxidation of acetone[J].Plasma Chemistry & Plasma Processing,2011,31(1):23-39.
[29]WANG X,WU X,HE L,et al.Corona dielectric barrier co-discharges for acetone degradation in a continuous flow[J].Chinese Journal of Enviromental Engineering,2018,12(3):848-854.
[30]ABEDI K,GHORBANI S F,JALEH B,et al.Decomposition of chlorinated volatile organic compounds (CVOCs) using NTP coupled with TiO2/GAC,ZnO/GAC,and TiO2-ZnO/GAC in a plasma-assisted catalysis system[J].Journal of Electrostatics,2015,73(4):80-88.
[31]SIVACHANDIRAN L,THEVENET F,ROUSSEAU A.Non-thermal plasma assisted regeneration of acetone adsorbed TiO2 surface[J].Plasma Chemistry & Plasma Processing,2013,33(5):855-871.
[32]DURME J V,DEWULF J,LEYS C,et al.Combining non-thermal plasma with heterogeneous catalysis in waste gas treatment:A review[J].Applied Catalysis B:Environmental,2008,78(3):324-333.
[33]TU X,GALLON H J,WHITEHEAD J C.Electrical and spectroscopic diagnostics of a single-stage plasma-catalysis system:effect of packing with TiO2[J].Journal of Physics D Applied Physics,2011,44(48):482003.
[34]TRINH Q H,MOK Y S.Environmental plasma-catalysis for the energy-efficient treatment of volatile organic compounds[J].Korean Journal of Chemical Engineering,2016,33(3):735-748.
[35]LU M,WANG H,HUANG R,et al.Research of effect of catalyst on the VOCs degradation using plasma-assisted catalysis technology[J].Environmental Pollution & Control 2018,40(1):88-94.
[36]SUBRAHMANYAM C.Catalytic non-thermal plasma reactor for total oxidation of volatile organic compounds[J].Indian Journal of Chemistry,2009,48(8):1062-1068.
[37]JIANG N,LU N,SHANG K,et al.Innovative approach for benzene degradation using hybrid surface/packed-bed discharge plasmas[J].Environmental Science & Technology,2013,47(17):9898-9903.
[2]CHIPER A S,BLIN-SIMIAND N,HENINGER M,et al.Detailed characterization of 2-heptanone conversion by dielectric barrier discharge in N(2) and N(2)/O(2) mixtures[J].Journal of Physical Chemistry A,2010,114(1):397-407.
[3]陈颖,叶代启,刘秀珍,等.我国工业源VOCs排放的源头追踪和行业特征研究[J].中国环境科学,2012,32(1):48-55.
[4]叶代启,陈小方.我国挥发性有机物减排阶段特征及政策应对[J].环境保护,2017,45(13):18-21.
[5]ZHENG C H,SHEN J L,ZHANG Y X,et al.Quantitative assessment of industrial VOC emissions in China:Historical trend,spatial distribution,uncertainties,and projection[J].Atmospheric Environment,2017,150:116-125.
[6]YANG T,GAO D X,YU Y L,et al.Dielectric barrier discharge micro-plasma emission spectrometry for the detection of acetone in exhaled breath[J].Talanta,2016,146:603-608.
[7]MACHALA Z,MORVOVA M,MARODE E,et al.Removal of cyclohexanone in transition electric discharges at atmospheric pressure[J].Journal of Physics D Applied Physics,2000,33(24):3198-3213.
[8]孙美玲,王少锋,项曙光.工业废气中丙酮处理工艺研究进展[J].当代化工,2014,43(9):1860-1862.
[9]KIM H H,OGATA A,FUTAMURA S.Oxygen partial pressure-dependent behavior of various catalysts for the total oxidation of VOCs using cycled system of adsorption and oxygen plasma[J].Applied Catalysis B:Environmental,2008,79(4):356-367.
[10]XIAO G,XU W,LUO Z,et al.Characteristics of toluene decomposition and adsorbent regeneration based on electrically conductive charcoal particle-triggered discharge[J].Rsc Advances,2017,7(71):44696-44705.
[11]ROHANI V,NOBREGA P A,ZADEH M,et al.Combination of VOC degradation and electro-hydrodynamic pumping actions in a surface dielectric barrier discharge reactor[J].Chemical Engineering Journal,2017,309:471-479.
[12]HOU L,LI X,XIE D,et al.Effects of BTEX on the removal of acetone in a coaxial non-thermal plasma reactor:role analysis of the methyl group[J].Molecules,2018,23(4):890(1-15).
[13]DEVINS J C,BURTON M.Formation of hydrazine in electric discharge decomposition of ammonia1,2[J].Journal of the American Chemical Society,1954,76(10):2618-2626.
[14]朱爱民,宫为民,师华,等.低温等离子体催化[J].化学研究与应用,1997,9(5):449-454.
[15]郭玉芳,叶代启.废气治理的低温等离子体-催化协同净化技术[J].环境工程学报,2003,4(7):41-46.
[16]TRINH Q H,GANDHI M S,MOK Y S.Adsorption and plasma-catalytic oxidation of acetone over zeolite-supported silver catalyst[J].Japanese Journal of Applied Physics,2015,54(1S):01AG4.
[17]BESOV A S,VORONTSOV A V.Acceleration of acetone destruction process under synergistic action of photocatalytic oxidation and barrier discharge[J].Plasma Chemistry & Plasma Processing,2007,27(5):624-634.
[18]LYULYUKIN M N,BESOV A S,VORONTSOV A V.Acetone and ethanol vapor oxidation via negative atmospheric corona discharge over titania-based catalysts[J].Applied Catalysis B:Environmental,2016,183:18-27.
[19]TRINH H Q,MOK Y S.Plasma-catalytic oxidation of acetone in annular porous monolithic ceramic-supported catalysts[J].Chemical Engineering Journal,2014,251:199-206.
[20]AYRAULT C,BARRAULT J,BLIN S N,et al.Oxidation of 2-heptanone in air by a DBD-type plasma generated within a honeycomb monolith supported Pt-based catalyst[J].Catalysis Today,2004,89(1-2):75-81.
[21]CHANG C L,LIN T S.Decomposition of toluene and acetone in packed dielectric barrier discharge reactors[J].Plasma Chemistry & Plasma Processing,2005,25(3):227-243.
[22]ZHU X,GAO X,YU X,et al.Catalyst screening for acetone removal in a single-stage plasma-catalysis system[J].Catalysis Today,2015,256:108-114.
[23]ZHU X,TU X,MEI D,et al.Investigation of hybrid plasma-catalytic removal of acetone over CuO/γ-Al2O3 catalysts using response surface method[J].Chemosphere,2016,155:9-17.
[24]GMEZ R A,MONTORO A M,RODR G M A,et al.Improving the pollutant removal efficiency of packed-bed plasma reactors incorporating ferroelectric components[J].Chemical Engineering Journal,2017,314:311-319.
[25]MALIK M A,JIANG X Z.Destruction of VOCs by combination of corona discharge and catalysis techniques[J].Journal of Environmental Sciences,1998,10(3):21-26.
[26]TU X,GALLON H J,WHITEHEAD J C.Plasma-assisted reduction of a NiO/Al2O3 catalyst in atmospheric pressure H2/Ar dielectric barrier discharge[J].Catalysis Today,2013,211(8):120-125.
[27]ZHU X,GAO X,ZHENG C,et al.Plasma-catalytic removal of a low concentration of acetone in humid conditions[J].Rsc Advances,2014,4(71):37796-37805.
[28]LYULYUKIN M N,BESOV A S,VORONTSOV A V.The Influence of corona electrodes thickness on the efficiency of plasma chemical oxidation of acetone[J].Plasma Chemistry & Plasma Processing,2011,31(1):23-39.
[29]WANG X,WU X,HE L,et al.Corona dielectric barrier co-discharges for acetone degradation in a continuous flow[J].Chinese Journal of Enviromental Engineering,2018,12(3):848-854.
[30]ABEDI K,GHORBANI S F,JALEH B,et al.Decomposition of chlorinated volatile organic compounds (CVOCs) using NTP coupled with TiO2/GAC,ZnO/GAC,and TiO2-ZnO/GAC in a plasma-assisted catalysis system[J].Journal of Electrostatics,2015,73(4):80-88.
[31]SIVACHANDIRAN L,THEVENET F,ROUSSEAU A.Non-thermal plasma assisted regeneration of acetone adsorbed TiO2 surface[J].Plasma Chemistry & Plasma Processing,2013,33(5):855-871.
[32]DURME J V,DEWULF J,LEYS C,et al.Combining non-thermal plasma with heterogeneous catalysis in waste gas treatment:A review[J].Applied Catalysis B:Environmental,2008,78(3):324-333.
[33]TU X,GALLON H J,WHITEHEAD J C.Electrical and spectroscopic diagnostics of a single-stage plasma-catalysis system:effect of packing with TiO2[J].Journal of Physics D Applied Physics,2011,44(48):482003.
[34]TRINH Q H,MOK Y S.Environmental plasma-catalysis for the energy-efficient treatment of volatile organic compounds[J].Korean Journal of Chemical Engineering,2016,33(3):735-748.
[35]LU M,WANG H,HUANG R,et al.Research of effect of catalyst on the VOCs degradation using plasma-assisted catalysis technology[J].Environmental Pollution & Control 2018,40(1):88-94.
[36]SUBRAHMANYAM C.Catalytic non-thermal plasma reactor for total oxidation of volatile organic compounds[J].Indian Journal of Chemistry,2009,48(8):1062-1068.
[37]JIANG N,LU N,SHANG K,et al.Innovative approach for benzene degradation using hybrid surface/packed-bed discharge plasmas[J].Environmental Science & Technology,2013,47(17):9898-9903.
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