耐阴极剥离有机涂层的研究进展
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摘要
简介了水环境中有机涂层保护、阴极保护及其联合用于金属防护的机理,综述了有机涂层阴极剥离机理,分析了影响有机涂层阴极剥离的因素,综述了耐阴极剥离有机涂层的设计原则,最后指出了耐阴极剥离有机涂层的研究方向。
This paper gave a brief introduction of metal protection mechanisms by organic coating,cathodic protection and their combination in water-containing environment,summarized the cathodic disbonded mechanism of organic coating,analyzed the factors influencing cathodic disbonded of organic coating,reviewed the design principle of anti-cathodic disbonded organic coating,and at last presented the research direction of anti-cathodic disbonded organic coating.
This paper gave a brief introduction of metal protection mechanisms by organic coating,cathodic protection and their combination in water-containing environment,summarized the cathodic disbonded mechanism of organic coating,analyzed the factors influencing cathodic disbonded of organic coating,reviewed the design principle of anti-cathodic disbonded organic coating,and at last presented the research direction of anti-cathodic disbonded organic coating.
引文
[1]洪啸吟,冯汉保.涂料化学[M].北京:科学出版社,2008.
[2]熊金平,左禹.船舶防腐蚀涂料的研究发展方向[J].现代涂料与涂装,2006(6):18-21.
[3]陈光章,王晶晶,王军.涂料防腐与电化学保护之间的协同效应[J].涂料技术与文摘,2008,29(9):9-11.
[4]Leidheiser H Jr.Corrosion of Painted Metals-A Review[J].NACE,1982,38(7):374-383.
[5]S?rensen P A,Kill S,Dam-Johansen K,et al.Anticorrosive Coatings:A Review[J].J.Coat.Technol.Res.,2009,6(2):135-176.
[6]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 2:First Stage of Delamination,Effect of Type and Concentration of Cations on Delamination,Chemical Analysis of the Interface[J].Corros.Sci.,1999(41):579-597.
[7]S?rensen P A,Dam-Johansen K,Weinell C E,et al.Cathodic Delamination of Sea Water Immersed Anticorrosive Coatings:Mapping of Parameters Affecting the Rate[J].Prog.Org.Coat.,2010,68(4):283-292.
[8]Reddy B,Doherty M J,Sykes J M.Breakdown of Organic Coatings in Corrosive Environments Examined by Scanning Kelvin Probe and Scanning Acoustic Microscopy[J].Electrochim.Acta.,2004,49(17-18):2 965-2 972.
[9]赵增元,王佳.有机涂层阴极剥离作用研究进展[J].中国腐蚀与防护学报,2008,28(2):116-119.
[10]胡吉明,张鉴清,谢德明,等.水在有机涂层中的传输Ⅰ.Fick扩散过程[J].中国腐蚀与防护学报,2002,22(5):311-315.
[11]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 1:Calibration of the Kelvinprobe and Basic Delamination Mechanism[J].Corros.Sci.,1999,41(3):547-578.
[12]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 3:Effect of the Oxygen Partial Pressure on the Delamination Reaction and Current Distribution at the Metal Polymer Interface[J].Corros.Sci.,1999,41(3):599-620.
[13]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 2:First Stage of Delamination,Effect of Type and Concentration of Cations on Delamination,Chemical Analysis of the Interface[J].Corros.Sci.,1999,41(3):579-598.
[14]Flavio Deflorian,Stefano Rossi.An EIS Study of Ion Diffusion through Organic Coatings[J].Electrochim.Acta.,2006(51):1 736-1 744.
[15]方健君,沈海鹰,王秀娟,等.海洋环境下抗阴极剥离重防腐涂层的研究[J].涂料工业,2010,40(10):1-4.
[16]Harun M K,Marsh J,Lyon S B.The Effect of Surface Modification on the Cathodic Disbondment Rate of Epoxy and Alkyd Coatings[J].Prog.Org.Coat.,2005,54(4):317-321.
[17]陈晶,郭英,侯宁,等.管道补口用环氧底漆阴极剥离性能研究[J].石油与化工设备,2010,13(10):52-54.
[18]Cmaitland C,Mayne J E O.Factors Affecting the Electrolytic Resistance of Polymer Films[J].Official Digest,1962,34(1):972.
[19]Huang M W,Allely C,Ogle K,et al.A Mathematical Model for Cathodic Delamination of Coated Metal Including a Kinetic p H-Porosity Relationship[J].J.Electrochem.Soc.,2008,155(5):279-292.
[20]Steinsmo U,Skar JI.Factors Influencing the Rate of Cathodic Disbonding of Coatings[J].Corrosion-Housto Tx-,1994,50(12):934-939.
[21]Leidheiser H R J,Wang W,et al.The Mechanism for the Cathodic Delamination of Organic Coatings from A Metal Surface[J].J.Prog.Org.Coat.,1983(11):19-40.
[22]刘征,龚敏,熊娟,等.极化电位对埋地钢质管道涂层剥离的影响[J].表面技术,2013,42(1):32-34.
[23]郑宇礼,李劲,潘明阳,等.交变应力对钢表面有机涂层阴极剥离行为的影响[J].腐蚀科学与防护技术,1999,11(4):209-212.
[24]王德中.抗阴极剥离型重防腐环氧粉末涂料的技术进展[J].上海涂料,2012,50(1):32-36.
[25]D.Roy,G.P.Simon,M.Forsyth,et al.Modification of Thermoplastic Coatings for Improved Cathodic Disbondment Performance on A Steel Substrate:A Study on Failure Mechanisms[J].Int.J.Adhesion.Adhes.,2002(2):395-403.
[26]Thu QL,Takenouti H,Touzain S.EIS Characterization of Thick Flawed Organic Coatings Aged Under Cathodic Protection in Seawater[J].Electrochim.Acta.,2006,51(12):2 491-2 502.
[27]魏强邦,周永峰.玻璃鳞片对环氧涂料抗阴极剥离性能的影响[J].腐蚀与防护,2008,29(8):490-491.
[28]李敏,王秀娟,刘宝成,等.海洋环境防腐蚀玻璃鳞片涂料的研制[J].涂料工业,2010,40(1):49-53.
[29]Naderi R,Attar M M.The Role of Zinc Aluminum Phosphate Anticorrosive Pigment in Protective Performance and Cathodic Disbondment of Epoxy Coating[J].Corrosion Sci.,2010(52):1 291-1 296.
[30]Lu X,Zuo Y,Zhao X,et al.The Influence of Aluminum Tri-Polyphosphate on the Protective Behavior of MgRich Epoxy Coating on AZ91D Magnesium Alloy[J].Electrochim.Acta.,2013,93(4):53-64.
[31]李荣光,刘明辉,等.聚脲涂层的耐阴极剥离性能研究[J].油气储运,2008,27(3):33-35.
[32]曹长娥.添加V2O5对聚乙烯涂层耐阴极剥离性能的影响[J].焊管,2002,25(5):29.
[33]Collazo A,Izquierdo M,Nóvoa XR,et al.Surface Treatment of Carbon Steel Substrates to Prevent Cathodic Delamination[J].Electrochim.Acta.,2007,52(27):7 513-7 518.
[34]Ferreira M G S,Duarte R G,Montemor M F.Silanes and Rare Earth Salts as Chromate Replacers for Pre-Treatments on Galvanised Steel[J].Electrochemical Methods in Corrosion Research,2004,49(17-18):2 927-2 935.
[35]Deflorian F,Rossi S,Fedrizzi L.Silane Pre-Treatments on Copper and Aluminum[J].Electrochim.Acta.,2006,51(27):6 097-6 103.
[36]Fedrizzi L,Rossi S,Rodriguez F J,et al.The Use of Electrochemical Techniques to Study the Corrosion Behavior of Organic Coatings on Steel Pretreated with SolGel Zirconia Films[J].Electrochim.Acta.,2001,46(24):3 715-3 724.
[37]Dong C F,Fu A Q,Li X G,et al.Localized EIS Characterization of Corrosion of Steel at Coating Defect Under Cathodic Protection[J].Electrochim.Acta.,2008,54(2):628-633.
[38]Thu QL,Bonnet G,Compere C,et al.Modified Wire Beam Electrode:A Useful Tool to Evaluate Compatibility between Organic Coatings and Cathodic Protection[J].Progress in Organic Coatings,2005,52(2):118-125.
[2]熊金平,左禹.船舶防腐蚀涂料的研究发展方向[J].现代涂料与涂装,2006(6):18-21.
[3]陈光章,王晶晶,王军.涂料防腐与电化学保护之间的协同效应[J].涂料技术与文摘,2008,29(9):9-11.
[4]Leidheiser H Jr.Corrosion of Painted Metals-A Review[J].NACE,1982,38(7):374-383.
[5]S?rensen P A,Kill S,Dam-Johansen K,et al.Anticorrosive Coatings:A Review[J].J.Coat.Technol.Res.,2009,6(2):135-176.
[6]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 2:First Stage of Delamination,Effect of Type and Concentration of Cations on Delamination,Chemical Analysis of the Interface[J].Corros.Sci.,1999(41):579-597.
[7]S?rensen P A,Dam-Johansen K,Weinell C E,et al.Cathodic Delamination of Sea Water Immersed Anticorrosive Coatings:Mapping of Parameters Affecting the Rate[J].Prog.Org.Coat.,2010,68(4):283-292.
[8]Reddy B,Doherty M J,Sykes J M.Breakdown of Organic Coatings in Corrosive Environments Examined by Scanning Kelvin Probe and Scanning Acoustic Microscopy[J].Electrochim.Acta.,2004,49(17-18):2 965-2 972.
[9]赵增元,王佳.有机涂层阴极剥离作用研究进展[J].中国腐蚀与防护学报,2008,28(2):116-119.
[10]胡吉明,张鉴清,谢德明,等.水在有机涂层中的传输Ⅰ.Fick扩散过程[J].中国腐蚀与防护学报,2002,22(5):311-315.
[11]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 1:Calibration of the Kelvinprobe and Basic Delamination Mechanism[J].Corros.Sci.,1999,41(3):547-578.
[12]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 3:Effect of the Oxygen Partial Pressure on the Delamination Reaction and Current Distribution at the Metal Polymer Interface[J].Corros.Sci.,1999,41(3):599-620.
[13]Leng A,Streckel H,Stratmann M.The Delamination of Polymeric Coatings from Steel.Part 2:First Stage of Delamination,Effect of Type and Concentration of Cations on Delamination,Chemical Analysis of the Interface[J].Corros.Sci.,1999,41(3):579-598.
[14]Flavio Deflorian,Stefano Rossi.An EIS Study of Ion Diffusion through Organic Coatings[J].Electrochim.Acta.,2006(51):1 736-1 744.
[15]方健君,沈海鹰,王秀娟,等.海洋环境下抗阴极剥离重防腐涂层的研究[J].涂料工业,2010,40(10):1-4.
[16]Harun M K,Marsh J,Lyon S B.The Effect of Surface Modification on the Cathodic Disbondment Rate of Epoxy and Alkyd Coatings[J].Prog.Org.Coat.,2005,54(4):317-321.
[17]陈晶,郭英,侯宁,等.管道补口用环氧底漆阴极剥离性能研究[J].石油与化工设备,2010,13(10):52-54.
[18]Cmaitland C,Mayne J E O.Factors Affecting the Electrolytic Resistance of Polymer Films[J].Official Digest,1962,34(1):972.
[19]Huang M W,Allely C,Ogle K,et al.A Mathematical Model for Cathodic Delamination of Coated Metal Including a Kinetic p H-Porosity Relationship[J].J.Electrochem.Soc.,2008,155(5):279-292.
[20]Steinsmo U,Skar JI.Factors Influencing the Rate of Cathodic Disbonding of Coatings[J].Corrosion-Housto Tx-,1994,50(12):934-939.
[21]Leidheiser H R J,Wang W,et al.The Mechanism for the Cathodic Delamination of Organic Coatings from A Metal Surface[J].J.Prog.Org.Coat.,1983(11):19-40.
[22]刘征,龚敏,熊娟,等.极化电位对埋地钢质管道涂层剥离的影响[J].表面技术,2013,42(1):32-34.
[23]郑宇礼,李劲,潘明阳,等.交变应力对钢表面有机涂层阴极剥离行为的影响[J].腐蚀科学与防护技术,1999,11(4):209-212.
[24]王德中.抗阴极剥离型重防腐环氧粉末涂料的技术进展[J].上海涂料,2012,50(1):32-36.
[25]D.Roy,G.P.Simon,M.Forsyth,et al.Modification of Thermoplastic Coatings for Improved Cathodic Disbondment Performance on A Steel Substrate:A Study on Failure Mechanisms[J].Int.J.Adhesion.Adhes.,2002(2):395-403.
[26]Thu QL,Takenouti H,Touzain S.EIS Characterization of Thick Flawed Organic Coatings Aged Under Cathodic Protection in Seawater[J].Electrochim.Acta.,2006,51(12):2 491-2 502.
[27]魏强邦,周永峰.玻璃鳞片对环氧涂料抗阴极剥离性能的影响[J].腐蚀与防护,2008,29(8):490-491.
[28]李敏,王秀娟,刘宝成,等.海洋环境防腐蚀玻璃鳞片涂料的研制[J].涂料工业,2010,40(1):49-53.
[29]Naderi R,Attar M M.The Role of Zinc Aluminum Phosphate Anticorrosive Pigment in Protective Performance and Cathodic Disbondment of Epoxy Coating[J].Corrosion Sci.,2010(52):1 291-1 296.
[30]Lu X,Zuo Y,Zhao X,et al.The Influence of Aluminum Tri-Polyphosphate on the Protective Behavior of MgRich Epoxy Coating on AZ91D Magnesium Alloy[J].Electrochim.Acta.,2013,93(4):53-64.
[31]李荣光,刘明辉,等.聚脲涂层的耐阴极剥离性能研究[J].油气储运,2008,27(3):33-35.
[32]曹长娥.添加V2O5对聚乙烯涂层耐阴极剥离性能的影响[J].焊管,2002,25(5):29.
[33]Collazo A,Izquierdo M,Nóvoa XR,et al.Surface Treatment of Carbon Steel Substrates to Prevent Cathodic Delamination[J].Electrochim.Acta.,2007,52(27):7 513-7 518.
[34]Ferreira M G S,Duarte R G,Montemor M F.Silanes and Rare Earth Salts as Chromate Replacers for Pre-Treatments on Galvanised Steel[J].Electrochemical Methods in Corrosion Research,2004,49(17-18):2 927-2 935.
[35]Deflorian F,Rossi S,Fedrizzi L.Silane Pre-Treatments on Copper and Aluminum[J].Electrochim.Acta.,2006,51(27):6 097-6 103.
[36]Fedrizzi L,Rossi S,Rodriguez F J,et al.The Use of Electrochemical Techniques to Study the Corrosion Behavior of Organic Coatings on Steel Pretreated with SolGel Zirconia Films[J].Electrochim.Acta.,2001,46(24):3 715-3 724.
[37]Dong C F,Fu A Q,Li X G,et al.Localized EIS Characterization of Corrosion of Steel at Coating Defect Under Cathodic Protection[J].Electrochim.Acta.,2008,54(2):628-633.
[38]Thu QL,Bonnet G,Compere C,et al.Modified Wire Beam Electrode:A Useful Tool to Evaluate Compatibility between Organic Coatings and Cathodic Protection[J].Progress in Organic Coatings,2005,52(2):118-125.
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