稠油地面催化改质降黏技术的研究进展
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摘要
综述了稠油地面催化改质、催化水热裂解改质、离子液体改质和物理场辅助催化改质降黏技术的研究进展。从催化水热裂解的理论机理研究方面对水热裂解催化降黏方法进行了介绍,分析了稠油水热裂解涉及的催化裂解化学反应及其机理。
The progresses in the research of surface catalytic upgrading,catalytic aquathermolysis,ion liquid modifi cation and physical fi eld assisted catalytic degradation for the viscosity reduction of heavy oil were summarized. The mechanism of the viscosity reduction by the catalytic aquathermolysis was introduced and the involved reactions were discussed.
The progresses in the research of surface catalytic upgrading,catalytic aquathermolysis,ion liquid modifi cation and physical fi eld assisted catalytic degradation for the viscosity reduction of heavy oil were summarized. The mechanism of the viscosity reduction by the catalytic aquathermolysis was introduced and the involved reactions were discussed.
引文
[1]丁彬,刘玉章,罗健辉,等.委内瑞拉稠油水包油乳化降黏的研究[J].石油化工,2011,40(2):184-188.
[2]龚姚进.厚层块状稠油油藏平面火驱技术研究与实践[J].特种油气藏,2012,19(3):58-62.
[3]杨帆.稠油冷采技术现场应用及研究[J].当代化工,2012,41(5):522-523.
[4]邓勇,易绍金.稠油微生物开采技术现状及进展[J].油田化学,2006,23(3):289-292.
[5]张金秋.糖脂类生物表面活性剂及其在稠油降黏中的应用研究[D].青岛:中国海洋大学,2012.
[6]刘红飞,杨海霞.稠油水热催化裂解机理的研究进展[J].山东化工,2013,42(12):75-77.
[7]王新亮,李小瑞,王磊,等.稠油用聚合物/表面活性剂二元复合表面活性剂[J].石油化工,2014,43(5):551-554.
[8]Clark P D,Hyne J B,Tyrer J D,Chemistry of organosulfur compound type occurring in heavy oil sands:Ⅰ.High temperature hydrolysis and thermolysis of tetrahydrothiophenein relation to steam stimulation process[J].Fuel,1983,62(5):959-962.
[9]敬加强,游万模.稠油特性及其输送技术研究[J].特种油气藏,2001,8(2):53-55.
[10]秦文龙,苏碧云,蒲春生.稠油井下改质降黏开采中高效催化剂的应用[J].石油学报:石油加工,2009,25(6):772-776.
[11]张凯.特超稠油改质降黏技术研究[D].青岛:中国石油大学(华东),2011.
[12]彭旭.稠油催化改质降黏实验研究[J].重庆科技学院学报:自然科学版,2014,16(5):20-23.
[13]黄娟,任波,李本高,等.塔河稠油地面催化改质降黏中试研究[J].石油炼制与化工,2014,45(9):20-23.
[14]中国海洋石油总公司,中海油研究总院,西南石油大学.一种改质降粘催化剂及其制备方法:103386323 A[P].2013-11-13.
[15]Akstinat M H.Gas evolution and change of oil composition during steam flooding[J].Pet Geol,1983,5(4):363-388.
[16]Clark P D,Hyne J B.Studies on the chemical reactions of heavy oils under steam stimulation condition[J].AOSTRA J Res,1990,29(6):29-39.
[17]陈尔跃,刘永建,闻守斌.辽河稠油中胶质在催化水热裂解反应中的降解[J].石油与天然气化工,2006,35(1):49-50.
[18]Clark P D,Kirk M J.Studies on the upgrading of bituminous oils with water and transition metal catalysts[J].Energy Fuels,1994,8(2):380-387.
[19]范洪富,刘永建.金属盐对辽河稠油水热裂解反应影响研究[J].燃料化学学报,2001,29(5):430-433.
[20]陈勇,陈艳玲,朱明.过渡金属的有机酸盐对稠油水热裂解降黏反应的催化作用[J].地质科技情报,2005,24(3):75-79.
[21]李伟,朱建华,齐建华.纳米Ni催化剂在超稠油水热裂解降黏中的应用研究[J].燃料化学学报,2007,35(2):176-180.
[22]Wei ssman J G.Review of processes for downhole catalytic upgrading of heavy crude oil[J].Fuel Process Technol,1997,50(2):199-213.
[23]Weissman J G,Kessler R V,Sawicki R A,et al.Down-hole catalytic upgrading of heavy crude oil[J].Energy Fuels,1996,10(4):883-889.
[24]Board N E.Canada’s oil sands opportunities and challenges to2015:An update[M].Canada:Alberta,2006.
[25]Gre aves M,Dong L L,Rigby S P.Simulation study of the toe-to-heel air injection three-dimensional combustion cell experiment and effects in the mobile oil zone[J].Energy Fuels,2012,26(3):1656-1669.
[26]Hart A,Shah A,Leeke G,et al.Optimization of the CAPRI process for heavy oil upgrading:Effect of hydrogen and guard bed[J].Ind Eng Chemres,2013,52(44):15394-15406.
[27]Xia T,Greaves M.3D physical model studies of downhole catalytic upgrading of Wolf Lake heavy oil using THAI[J].J Can Pet Technol,2002,41(8):58-64.
[28]Guan Wenlong,Xi Changfeng,Chen Yaping,et al.Fireflooding technologies in post-steam-injected heavy oil reservoirs[J].Petrol Explor Dev,2011,38(4):452-463.
[29]Hart A,Leeke G,Greaves M,et al.Down-hole heavy crude oil upgrading by CAPRI:Effect of hydrogen and methane gases upon upgrading and coke formation[J].Fuel,2014,119:226-235.
[30]赵法军.利用供氢体对稠油进行水热裂解催化改质的研究进展[J].油田化学,2006,23(4):379-384.
[31]孙道华,景萍,方维平,等.甲醇对稠油热裂解降黏过程的影响[J].石油化工,2009,38(5):504-507.
[32]刘永建.稠油的甲酸供氢催化水热裂解改质实验研究[J].油田化学,2008,25(2):133-136.
[33]吴川,苏建政,张汝生,等.特超稠油水热裂解降黏反应研究[J].科学技术与工程,2012,20(23):5728-5731.
[34]吴川,雷光伦,姚传进,等.双亲催化剂作用超稠油水热裂解降黏机理研究[J].燃料化学学报,2015,38(6):684-690.
[35]范洪富,刘永建,赵晓非,等.国内首例井下水热裂解催化降黏开采稠油现场试验[J].石油钻采工艺,2001,23(3):42-44
[36]张庆华,王瑞峰,李作鹏,等.离子液体在绿色催化和清洁合成中应用的进展[J].石油化工,2007,36(10):975-984.
[37]杨阳.吡啶类离子液体对稠油改质降黏研究[D].大庆:大庆石油学院,2009.
[38]Shaban S,Dessouky S,Badawi A E F,et al.Upgrading and viscosity reduction of heavy oil by catalytic ionic liquid[J].Energy Fuels,2014,28(10):6545-6553.
[39]范洪富,李忠宝,梁涛.离子液体催化改质稠油实验研究[J].燃料化学学报,2007,35(1):32-35.
[40]Subramanian D,Wu K,Firoozabadi A.Ionic liquids as viscosity modifiers for heavy and extra-heavy crude oils[J].Fuel,2015,143:519-526.
[41]李忠宝.咪唑类离子液体改质稠油实验研究[D].大庆:大庆石油学院,2008.
[42]Naderi K,Babadagli T.Clarifi cations on oil/heavy oil recovery under ultrasonic radiation through core and 2D visualization experiments[J].J Can Pet Technol,2008,47(11):56.
[43]Shedid S A,Attallah S R.Infl uences of ultrasonic radiation on asphaltene behavior with and without solvent effects[C]//SPE international symposium and exhibition on formation damage control.Canada:Society of petroleum engineers,2004,25(8):856-865.
[44]Xu Hong-xing,Pu Chun-sheng.Experimental study of heavy oil underground aquathermolysis using catalyst and ultrasonic[J].J Fuel Chem Technol,2011,39(8):606-610.
[45]张华,冯兵,董凤娟,等.微波对稠油作用机理的数学模型研究[J].特种油气藏,2006,13(5):100-102.
[46]Mutya la S,Fairbridge C,Pare J R,et al.Microwave applications to oil sands and petroleum:A review[J].Fuel Process Technol,2010,91(2):127-135.
[47]Gref f J,Babadagli T.Use of nano-metal particles as catalyst under electromagnetic heating for in-situ heavy oil recovery[J].J Petrol Sci Eng,2013,112:258-265.
[48]Li Kewen,Hou Binchi,Lei Wang,et al.Application of carbon nanocatalysts in upgrading heavy crude oil assisted with microwave heating[J].Nano lett,2014,14(6):3002-3008.
[2]龚姚进.厚层块状稠油油藏平面火驱技术研究与实践[J].特种油气藏,2012,19(3):58-62.
[3]杨帆.稠油冷采技术现场应用及研究[J].当代化工,2012,41(5):522-523.
[4]邓勇,易绍金.稠油微生物开采技术现状及进展[J].油田化学,2006,23(3):289-292.
[5]张金秋.糖脂类生物表面活性剂及其在稠油降黏中的应用研究[D].青岛:中国海洋大学,2012.
[6]刘红飞,杨海霞.稠油水热催化裂解机理的研究进展[J].山东化工,2013,42(12):75-77.
[7]王新亮,李小瑞,王磊,等.稠油用聚合物/表面活性剂二元复合表面活性剂[J].石油化工,2014,43(5):551-554.
[8]Clark P D,Hyne J B,Tyrer J D,Chemistry of organosulfur compound type occurring in heavy oil sands:Ⅰ.High temperature hydrolysis and thermolysis of tetrahydrothiophenein relation to steam stimulation process[J].Fuel,1983,62(5):959-962.
[9]敬加强,游万模.稠油特性及其输送技术研究[J].特种油气藏,2001,8(2):53-55.
[10]秦文龙,苏碧云,蒲春生.稠油井下改质降黏开采中高效催化剂的应用[J].石油学报:石油加工,2009,25(6):772-776.
[11]张凯.特超稠油改质降黏技术研究[D].青岛:中国石油大学(华东),2011.
[12]彭旭.稠油催化改质降黏实验研究[J].重庆科技学院学报:自然科学版,2014,16(5):20-23.
[13]黄娟,任波,李本高,等.塔河稠油地面催化改质降黏中试研究[J].石油炼制与化工,2014,45(9):20-23.
[14]中国海洋石油总公司,中海油研究总院,西南石油大学.一种改质降粘催化剂及其制备方法:103386323 A[P].2013-11-13.
[15]Akstinat M H.Gas evolution and change of oil composition during steam flooding[J].Pet Geol,1983,5(4):363-388.
[16]Clark P D,Hyne J B.Studies on the chemical reactions of heavy oils under steam stimulation condition[J].AOSTRA J Res,1990,29(6):29-39.
[17]陈尔跃,刘永建,闻守斌.辽河稠油中胶质在催化水热裂解反应中的降解[J].石油与天然气化工,2006,35(1):49-50.
[18]Clark P D,Kirk M J.Studies on the upgrading of bituminous oils with water and transition metal catalysts[J].Energy Fuels,1994,8(2):380-387.
[19]范洪富,刘永建.金属盐对辽河稠油水热裂解反应影响研究[J].燃料化学学报,2001,29(5):430-433.
[20]陈勇,陈艳玲,朱明.过渡金属的有机酸盐对稠油水热裂解降黏反应的催化作用[J].地质科技情报,2005,24(3):75-79.
[21]李伟,朱建华,齐建华.纳米Ni催化剂在超稠油水热裂解降黏中的应用研究[J].燃料化学学报,2007,35(2):176-180.
[22]Wei ssman J G.Review of processes for downhole catalytic upgrading of heavy crude oil[J].Fuel Process Technol,1997,50(2):199-213.
[23]Weissman J G,Kessler R V,Sawicki R A,et al.Down-hole catalytic upgrading of heavy crude oil[J].Energy Fuels,1996,10(4):883-889.
[24]Board N E.Canada’s oil sands opportunities and challenges to2015:An update[M].Canada:Alberta,2006.
[25]Gre aves M,Dong L L,Rigby S P.Simulation study of the toe-to-heel air injection three-dimensional combustion cell experiment and effects in the mobile oil zone[J].Energy Fuels,2012,26(3):1656-1669.
[26]Hart A,Shah A,Leeke G,et al.Optimization of the CAPRI process for heavy oil upgrading:Effect of hydrogen and guard bed[J].Ind Eng Chemres,2013,52(44):15394-15406.
[27]Xia T,Greaves M.3D physical model studies of downhole catalytic upgrading of Wolf Lake heavy oil using THAI[J].J Can Pet Technol,2002,41(8):58-64.
[28]Guan Wenlong,Xi Changfeng,Chen Yaping,et al.Fireflooding technologies in post-steam-injected heavy oil reservoirs[J].Petrol Explor Dev,2011,38(4):452-463.
[29]Hart A,Leeke G,Greaves M,et al.Down-hole heavy crude oil upgrading by CAPRI:Effect of hydrogen and methane gases upon upgrading and coke formation[J].Fuel,2014,119:226-235.
[30]赵法军.利用供氢体对稠油进行水热裂解催化改质的研究进展[J].油田化学,2006,23(4):379-384.
[31]孙道华,景萍,方维平,等.甲醇对稠油热裂解降黏过程的影响[J].石油化工,2009,38(5):504-507.
[32]刘永建.稠油的甲酸供氢催化水热裂解改质实验研究[J].油田化学,2008,25(2):133-136.
[33]吴川,苏建政,张汝生,等.特超稠油水热裂解降黏反应研究[J].科学技术与工程,2012,20(23):5728-5731.
[34]吴川,雷光伦,姚传进,等.双亲催化剂作用超稠油水热裂解降黏机理研究[J].燃料化学学报,2015,38(6):684-690.
[35]范洪富,刘永建,赵晓非,等.国内首例井下水热裂解催化降黏开采稠油现场试验[J].石油钻采工艺,2001,23(3):42-44
[36]张庆华,王瑞峰,李作鹏,等.离子液体在绿色催化和清洁合成中应用的进展[J].石油化工,2007,36(10):975-984.
[37]杨阳.吡啶类离子液体对稠油改质降黏研究[D].大庆:大庆石油学院,2009.
[38]Shaban S,Dessouky S,Badawi A E F,et al.Upgrading and viscosity reduction of heavy oil by catalytic ionic liquid[J].Energy Fuels,2014,28(10):6545-6553.
[39]范洪富,李忠宝,梁涛.离子液体催化改质稠油实验研究[J].燃料化学学报,2007,35(1):32-35.
[40]Subramanian D,Wu K,Firoozabadi A.Ionic liquids as viscosity modifiers for heavy and extra-heavy crude oils[J].Fuel,2015,143:519-526.
[41]李忠宝.咪唑类离子液体改质稠油实验研究[D].大庆:大庆石油学院,2008.
[42]Naderi K,Babadagli T.Clarifi cations on oil/heavy oil recovery under ultrasonic radiation through core and 2D visualization experiments[J].J Can Pet Technol,2008,47(11):56.
[43]Shedid S A,Attallah S R.Infl uences of ultrasonic radiation on asphaltene behavior with and without solvent effects[C]//SPE international symposium and exhibition on formation damage control.Canada:Society of petroleum engineers,2004,25(8):856-865.
[44]Xu Hong-xing,Pu Chun-sheng.Experimental study of heavy oil underground aquathermolysis using catalyst and ultrasonic[J].J Fuel Chem Technol,2011,39(8):606-610.
[45]张华,冯兵,董凤娟,等.微波对稠油作用机理的数学模型研究[J].特种油气藏,2006,13(5):100-102.
[46]Mutya la S,Fairbridge C,Pare J R,et al.Microwave applications to oil sands and petroleum:A review[J].Fuel Process Technol,2010,91(2):127-135.
[47]Gref f J,Babadagli T.Use of nano-metal particles as catalyst under electromagnetic heating for in-situ heavy oil recovery[J].J Petrol Sci Eng,2013,112:258-265.
[48]Li Kewen,Hou Binchi,Lei Wang,et al.Application of carbon nanocatalysts in upgrading heavy crude oil assisted with microwave heating[J].Nano lett,2014,14(6):3002-3008.
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