MoS_2及其金属复合表面增强拉曼散射基底的发展及应用
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摘要
表面增强拉曼散射(surface enhanced Raman spectroscopy, SERS)作为一种超灵敏的无标签分析技术,在分子检测领域得到了广泛的研究及发展,而增强机理的探究及灵敏度、均匀性、稳定性等性能的提升一直是研究人员面临的重要挑战.本文通过梳理SERS机理的国内外研究进展,综述了单一金属基底、二硫化钼(MoS_2)基底及金属/MoS2复合基底的机理及研究现状和存在的问题等;总结介绍了二硫化钼基底及金属/二硫化钼复合基底制备方法的优缺点;概述了二硫化钼及其金属复合基底在食品检测、生物医学、环境污染监测等方面的应用研究进展;最后提出了SERS技术目前存在的不足并对其发展前景进行了展望.
Surface-enhanced Raman scattering is an ultra-sensitive molecular detection technology, and the exploration of its mechanism and the improvement of sensitivity, uniformity and stability have always been significant challenge to researchers. In this paper, the development of surface-enhanced Raman scattering mechanism and its research progress, and thus review the mechanism, research status and existing problems of single metal substrate, molybdenum disulfide substrate and metal/molybdenum disulfide composite substrate are summarized; The preparation method of the molybdenum disulfide substrate including hydrothermal/solvothermal method, micromechanical peeling method, chemical meteorological deposition method, and preparation method of metal/molybdenum disulfide composite substrate are briefly introduced, in which the electrochemical method, thermal reduction method, seed-mediated growth method, and electron beam lithography method are covered, and the advantages and disadvantages of the above preparation methods are evaluated; The research progress of the applications of molybdenum disulfide and its metal composite substrates in food testing, biomedicine, environmental pollution monitoring, etc. are briefly overviewed The surfaceenhanced Raman scattering study is extended to other transition metal binary compounds and their metal composite structures. Therefore, the metal/molybdenum disulfide composite substrate expands the types of surface-enhanced Raman scattering substrates, thereby making up for the deficiency of low reproducibility, poor stability, and weak adsorption. Moreover, it has the advantages of fluorescence quenching effect, high sensitivity, wide detection range, and it can be combined with on-site rapid separation technology, and thus has widespread application prospects. Finally, the shortcomings of surface-enhanced Raman scattering technology and prospects for its development are also pointed out.
Surface-enhanced Raman scattering is an ultra-sensitive molecular detection technology, and the exploration of its mechanism and the improvement of sensitivity, uniformity and stability have always been significant challenge to researchers. In this paper, the development of surface-enhanced Raman scattering mechanism and its research progress, and thus review the mechanism, research status and existing problems of single metal substrate, molybdenum disulfide substrate and metal/molybdenum disulfide composite substrate are summarized; The preparation method of the molybdenum disulfide substrate including hydrothermal/solvothermal method, micromechanical peeling method, chemical meteorological deposition method, and preparation method of metal/molybdenum disulfide composite substrate are briefly introduced, in which the electrochemical method, thermal reduction method, seed-mediated growth method, and electron beam lithography method are covered, and the advantages and disadvantages of the above preparation methods are evaluated; The research progress of the applications of molybdenum disulfide and its metal composite substrates in food testing, biomedicine, environmental pollution monitoring, etc. are briefly overviewed The surfaceenhanced Raman scattering study is extended to other transition metal binary compounds and their metal composite structures. Therefore, the metal/molybdenum disulfide composite substrate expands the types of surface-enhanced Raman scattering substrates, thereby making up for the deficiency of low reproducibility, poor stability, and weak adsorption. Moreover, it has the advantages of fluorescence quenching effect, high sensitivity, wide detection range, and it can be combined with on-site rapid separation technology, and thus has widespread application prospects. Finally, the shortcomings of surface-enhanced Raman scattering technology and prospects for its development are also pointed out.
引文
[1]Howard M W, Cooney R P, Mcquillan A J 2010 J. Raman Spectrosc. 9 273
[2]Hubbell J A, Chilkoti A 2012 Science 337 303
[3]Jin I L, Lee W K 2015 Materials Lett. 160 139
[4]Mulvihill M J, Ling X Y, Henzie J, Yang P 2010 J. Am.Chem. Soc. 132 268
[5]Otto A 2005 J. Raman Spectrosc. 36 497
[6]Sun Y, Wiederrecht G P 2007 Small 3 1825
[7]Willets K A, Van Duyne R P 2007 Annu. Rev. Phys. Chem.58 267
[8]Popp J, Mayerh?fer T 2009 Annu. Rev. Anal. Chem. 3941717
[9]Conley H, Wang B, Ziegler J I, Haglund R F, Pantelides S T,Bolotin K I 2013 Nano Lett. 13 3626
[10]Li X, Li J, Wang X, Hu J, Fang X, Chu X, Wei Z, Shan J,Ding X 2014 Integ. Ferroelectr. 158 26
[11]Li J, Li X, Wang X, Hu J, Chu X, Fang X, Wei Z 2016 Surf.Eng. 32 245
[12]Zhai Y, Li J, Chu X, Xu M, Jin F, Li X, Fang X, Wei Z,Wang X 2016 J. Alloy. Compd. 672 600
[13]Zhai Y, Li J, Chu X, Xu M, Jin F, Fang X 2016 IEEE International Conference on Manipulation, Manufacturing and Measurement on the Nanoscale(3M-NANO)Chongqing,China, July 18-22, p287s
[14]Shan J, Li J, Chu X, Xu M, Jin F, Fang X, Wei Z, Wang X2018 Appl. Surf. Sci. 443 31
[15]Shan J, Li J, Chu X, Xu M, Jin F, Wang X, Ma L, Fang X,Wei Z, Wang X 2018 RSC Adv. 8 7942
[16]Jiang S, Guo J, Zhang C, Li C, Wang M, Li Z, Gao S, Chen P, Si H, Xu S 2017 RSC Adv. 7 5764
[17]Hubbell J A, Chilkoti A 2013 Nature Materials 12 963
[18]Fears R, Gehr P 2012 Nature 488 281
[19]Singh R 2002 Phys. Perspect. 4 399
[20]Jeanmaire D L, Van Duyne R 1977 J. Electroanal. Chem.Interfacial Electrochem. 84 1
[21]Albrecht M G, Creighton J A 1977 J. Am. Chem. Soc. 995215
[22]Banholzer M J, Millstone J E, Qin L, Mirkin C K A 2008Chem. Soc. Rev. 37 885
[23]Khlebtsov B N, Khlebtsov N G 2007 J. Phys. Chem. C 11111516
[24]Li Y L, Kan C X, Wang C S, Liu J S, Xu H Y, Ni Y, Xu W,Ke J H, Shi D N 2014 Acta Phys.-Chim. Sin. 30 1827(in Chinese)[李玉玲,阚彩侠,王长顺,刘津升,徐海英,倪缘,徐伟,柯军华,施大宁2014物理化学学报30 1827]
[25]Brawley Z, Bauman S, Darweesh A, Debu D, Tork Ladani F,Herzog J 2018 Materials 11 942
[26]Kneipp K, Wang Y, Dasari R R, Feld M S 1995 Appl.Spectrosc. 49 780
[27]Zhang P, Yang S, Wang L, Zhao J, Zhu Z, Liu B, Zhong J,Sun X 2014 Nanotechnology 25 245301
[28]Chirumamilla M, Das G, Toma A, Gopalakrishnan A,Zaccaria R P, Liberale C, Angelis D F, Di Fabrizio E 2012Microelectron. Eng. 97 189
[29]Wu T, Lin Y W 2018 Appl. Surf. Sci. 435 1143
[30]Tian Z Q, Ren B, Wu D Y 2002 J. Phys. Chem. B 106 9463
[31]Moskovits M 1985 Rev. Mod. Phys. 57 783
[32]Natan M J 2006 Faraday Discuss. 132 321
[33]Schlücker S 2014 Angew. Chem. Int. Edit. 53 4756
[34]Zang X, Yao K, Yan A 2017 International Conference on Solid-State Sensors, Actuators and Microsystems(Transducers)Taiwan, China, June 18-22, 2017 p894
[35]Muehlethaler C, Considine C R, Menon V, Lin W C, Lee Y H, Lombardi J R 2016 Acs Photonics 3 1164
[36]Xia M 2016 Ph. D. Dissertation(California:University of California)
[37]Liang X, Wang Y S, You T T, Zhang X J, Yang N, Wang G S, Yin P G 2017 Nanoscale 9 8879
[38]Shakya J, Patel A S, Singh F, Mohanty T 2016 Appl. Phys.Lett. 108 013103
[39]Bhanu U, Islam M R, Tetard L, Khondaker S I 2014 Sci.Rep. 4 5575
[40]Lu J, Lu J H, Liu H, Liu B, Gong L, Tok E S, Loh K P, Sow C H 2015 Small 11 1792
[41]Hwang D Y, Suh D H 2017 Nanotechnology 28 025603
[42]Zeng Z Q, Tang D, Liu L W 2016 Nanotechnology 27 455301
[43]Li Z, Jiang S, Xu S, Zhang C, Qiu H, Li C, Sheng Y, Huo Y,Yang C, Man B 2016 Sensor. Actuat. B-Chem. 230 645
[44]Singha S S, Mondal S, Bhattacharya T S, Das L, Sen K,Satpati B, Das K, Singha A 2018 Biosens. Bioelectron. 119 10
[45]Fei X, Liu Z, Hou Y, Li Y, Yang G, Su C, Wang Z, Zhong H,Zhuang Z, Guo Z 2017 Materials 10 650
[46]Yan D, Qiu W, Chen X, Liu L, Lai Y, Meng Z, Song J, Liu X Y, Zhan D 2018 Phys. Chem. C 122 14467
[47]Qiu H, Li Z, Gao S, Chen P, Zhang C, Jiang S, Xu S, Yang C, Li H 2015 Rsc Adv. 5 83899
[48]Xia H K, Zou L F, Ma N, Ji T H 2016 J. Synthetic Cryst. 45291(in Chinese)[夏洪坤,邹利锋,马楠,嵇天浩2016人工晶体学报45 291]
[49]Najmaei S, Mlayah A, Arbouet A, Girard C, Léotin J, Lou J2014 Acs Nano 8 12682
[50]Butun S, Tongay S, Aydin K 2015 Nano Lett. 15 2700
[51]Lee B, Park J, Han G H, Ee H S, Naylor C H, Liu W,Johnson A T, Agarwal R 2015 Nano Lett. 15 3646
[52]Xu J, Li C, Si H, Zhao X, Wang L, Jiang S, Wei D, Yu J,Xiu X, Zhang C 2018 Opt. Express 26 21546
[53]Liang X, Zhang X J, You T T, Yang N, Wang G S, Yin P G2017 J. Raman Spectrosc. 49 245
[54]Jin K, Xie L, Tian Y, Liu D 2016 J. Phys. Chem. C 12011204
[55]Zhao Y, Pan X, Zhang L, Xu Y, Li C, Wang J, Ou J, Xiu X,Man B, Yang C 2017 Rsc Adv. 7 36516
[56]Kim J Y, Kim J, Joo J 2016 Opt. Express 24 27546
[57]Lu Z, Si H, Li Z, Yu J, Liu Y, Feng D, Zhang C, Yang W,Man B, Jiang S 2018 Opt. Express 26 21626
[58]Nair R, Gummaluri V S, Gayathri P K, Vijayan C 2017Mater. Res. Express 4 015025
[2]Hubbell J A, Chilkoti A 2012 Science 337 303
[3]Jin I L, Lee W K 2015 Materials Lett. 160 139
[4]Mulvihill M J, Ling X Y, Henzie J, Yang P 2010 J. Am.Chem. Soc. 132 268
[5]Otto A 2005 J. Raman Spectrosc. 36 497
[6]Sun Y, Wiederrecht G P 2007 Small 3 1825
[7]Willets K A, Van Duyne R P 2007 Annu. Rev. Phys. Chem.58 267
[8]Popp J, Mayerh?fer T 2009 Annu. Rev. Anal. Chem. 3941717
[9]Conley H, Wang B, Ziegler J I, Haglund R F, Pantelides S T,Bolotin K I 2013 Nano Lett. 13 3626
[10]Li X, Li J, Wang X, Hu J, Fang X, Chu X, Wei Z, Shan J,Ding X 2014 Integ. Ferroelectr. 158 26
[11]Li J, Li X, Wang X, Hu J, Chu X, Fang X, Wei Z 2016 Surf.Eng. 32 245
[12]Zhai Y, Li J, Chu X, Xu M, Jin F, Li X, Fang X, Wei Z,Wang X 2016 J. Alloy. Compd. 672 600
[13]Zhai Y, Li J, Chu X, Xu M, Jin F, Fang X 2016 IEEE International Conference on Manipulation, Manufacturing and Measurement on the Nanoscale(3M-NANO)Chongqing,China, July 18-22, p287s
[14]Shan J, Li J, Chu X, Xu M, Jin F, Fang X, Wei Z, Wang X2018 Appl. Surf. Sci. 443 31
[15]Shan J, Li J, Chu X, Xu M, Jin F, Wang X, Ma L, Fang X,Wei Z, Wang X 2018 RSC Adv. 8 7942
[16]Jiang S, Guo J, Zhang C, Li C, Wang M, Li Z, Gao S, Chen P, Si H, Xu S 2017 RSC Adv. 7 5764
[17]Hubbell J A, Chilkoti A 2013 Nature Materials 12 963
[18]Fears R, Gehr P 2012 Nature 488 281
[19]Singh R 2002 Phys. Perspect. 4 399
[20]Jeanmaire D L, Van Duyne R 1977 J. Electroanal. Chem.Interfacial Electrochem. 84 1
[21]Albrecht M G, Creighton J A 1977 J. Am. Chem. Soc. 995215
[22]Banholzer M J, Millstone J E, Qin L, Mirkin C K A 2008Chem. Soc. Rev. 37 885
[23]Khlebtsov B N, Khlebtsov N G 2007 J. Phys. Chem. C 11111516
[24]Li Y L, Kan C X, Wang C S, Liu J S, Xu H Y, Ni Y, Xu W,Ke J H, Shi D N 2014 Acta Phys.-Chim. Sin. 30 1827(in Chinese)[李玉玲,阚彩侠,王长顺,刘津升,徐海英,倪缘,徐伟,柯军华,施大宁2014物理化学学报30 1827]
[25]Brawley Z, Bauman S, Darweesh A, Debu D, Tork Ladani F,Herzog J 2018 Materials 11 942
[26]Kneipp K, Wang Y, Dasari R R, Feld M S 1995 Appl.Spectrosc. 49 780
[27]Zhang P, Yang S, Wang L, Zhao J, Zhu Z, Liu B, Zhong J,Sun X 2014 Nanotechnology 25 245301
[28]Chirumamilla M, Das G, Toma A, Gopalakrishnan A,Zaccaria R P, Liberale C, Angelis D F, Di Fabrizio E 2012Microelectron. Eng. 97 189
[29]Wu T, Lin Y W 2018 Appl. Surf. Sci. 435 1143
[30]Tian Z Q, Ren B, Wu D Y 2002 J. Phys. Chem. B 106 9463
[31]Moskovits M 1985 Rev. Mod. Phys. 57 783
[32]Natan M J 2006 Faraday Discuss. 132 321
[33]Schlücker S 2014 Angew. Chem. Int. Edit. 53 4756
[34]Zang X, Yao K, Yan A 2017 International Conference on Solid-State Sensors, Actuators and Microsystems(Transducers)Taiwan, China, June 18-22, 2017 p894
[35]Muehlethaler C, Considine C R, Menon V, Lin W C, Lee Y H, Lombardi J R 2016 Acs Photonics 3 1164
[36]Xia M 2016 Ph. D. Dissertation(California:University of California)
[37]Liang X, Wang Y S, You T T, Zhang X J, Yang N, Wang G S, Yin P G 2017 Nanoscale 9 8879
[38]Shakya J, Patel A S, Singh F, Mohanty T 2016 Appl. Phys.Lett. 108 013103
[39]Bhanu U, Islam M R, Tetard L, Khondaker S I 2014 Sci.Rep. 4 5575
[40]Lu J, Lu J H, Liu H, Liu B, Gong L, Tok E S, Loh K P, Sow C H 2015 Small 11 1792
[41]Hwang D Y, Suh D H 2017 Nanotechnology 28 025603
[42]Zeng Z Q, Tang D, Liu L W 2016 Nanotechnology 27 455301
[43]Li Z, Jiang S, Xu S, Zhang C, Qiu H, Li C, Sheng Y, Huo Y,Yang C, Man B 2016 Sensor. Actuat. B-Chem. 230 645
[44]Singha S S, Mondal S, Bhattacharya T S, Das L, Sen K,Satpati B, Das K, Singha A 2018 Biosens. Bioelectron. 119 10
[45]Fei X, Liu Z, Hou Y, Li Y, Yang G, Su C, Wang Z, Zhong H,Zhuang Z, Guo Z 2017 Materials 10 650
[46]Yan D, Qiu W, Chen X, Liu L, Lai Y, Meng Z, Song J, Liu X Y, Zhan D 2018 Phys. Chem. C 122 14467
[47]Qiu H, Li Z, Gao S, Chen P, Zhang C, Jiang S, Xu S, Yang C, Li H 2015 Rsc Adv. 5 83899
[48]Xia H K, Zou L F, Ma N, Ji T H 2016 J. Synthetic Cryst. 45291(in Chinese)[夏洪坤,邹利锋,马楠,嵇天浩2016人工晶体学报45 291]
[49]Najmaei S, Mlayah A, Arbouet A, Girard C, Léotin J, Lou J2014 Acs Nano 8 12682
[50]Butun S, Tongay S, Aydin K 2015 Nano Lett. 15 2700
[51]Lee B, Park J, Han G H, Ee H S, Naylor C H, Liu W,Johnson A T, Agarwal R 2015 Nano Lett. 15 3646
[52]Xu J, Li C, Si H, Zhao X, Wang L, Jiang S, Wei D, Yu J,Xiu X, Zhang C 2018 Opt. Express 26 21546
[53]Liang X, Zhang X J, You T T, Yang N, Wang G S, Yin P G2017 J. Raman Spectrosc. 49 245
[54]Jin K, Xie L, Tian Y, Liu D 2016 J. Phys. Chem. C 12011204
[55]Zhao Y, Pan X, Zhang L, Xu Y, Li C, Wang J, Ou J, Xiu X,Man B, Yang C 2017 Rsc Adv. 7 36516
[56]Kim J Y, Kim J, Joo J 2016 Opt. Express 24 27546
[57]Lu Z, Si H, Li Z, Yu J, Liu Y, Feng D, Zhang C, Yang W,Man B, Jiang S 2018 Opt. Express 26 21626
[58]Nair R, Gummaluri V S, Gayathri P K, Vijayan C 2017Mater. Res. Express 4 015025