硅烷偶联剂在橡胶中的应用研究进展(续完)
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摘要
介绍硅烷偶联剂在橡胶工业中的应用研究进展,展望橡胶用硅烷偶联剂的发展趋势和应用前景。硅烷偶联剂的使用大大提高了橡胶制品的综合性能,促进了无机填料在橡胶工业中的应用。目前橡胶用硅烷偶联剂主要种类为含硫烃基类、乙烯基类、甲基丙烯酰氧烷基类、氨烃基类和环氧烃基类。随着新型轮胎和橡胶制品的快速发展,市场对橡胶用硅烷偶联剂的性能和使用技术也提出更高的要求,尤其是轮胎绿色化进程的加快,对硅烷偶联剂的需求快速增长,以NXT为代表的新型硅烷偶联剂是未来橡胶用硅烷偶联剂的发展方向之一。
In this paper,the research progress of silane coupling agent in rubber industry,and the development trend and application prospect were presented. The use of silane coupling agent greatly improved the comprehensive properties of rubber products and promoted the application of inorganic fillers in rubber industry. At present,the main types of silane coupling agents for rubber were sulfur alkyl,vinyl,methacryloxy alkyl,amino alkyl and epoxy alkyl silane. With the rapid development of new tires and rubber products,the requirements for the performance and application technology of silane coupling agent for rubber were raised. With the acceleration of the green process of tire,the demand for silane coupling agent increased rapidly. The new products represented by silane coupling agent NXT were one of the development directions of silane coupling agent for rubber in the future.
In this paper,the research progress of silane coupling agent in rubber industry,and the development trend and application prospect were presented. The use of silane coupling agent greatly improved the comprehensive properties of rubber products and promoted the application of inorganic fillers in rubber industry. At present,the main types of silane coupling agents for rubber were sulfur alkyl,vinyl,methacryloxy alkyl,amino alkyl and epoxy alkyl silane. With the rapid development of new tires and rubber products,the requirements for the performance and application technology of silane coupling agent for rubber were raised. With the acceleration of the green process of tire,the demand for silane coupling agent increased rapidly. The new products represented by silane coupling agent NXT were one of the development directions of silane coupling agent for rubber in the future.
引文
[42]杨英,潘宏丽.天然橡胶轮胎胶料中硅烷偶联剂种类对白炭黑增强效率的影响[J].世界橡胶工业,2017,44(8):9-20.
[43]罗权熄,王真智.硅烷偶联剂对硅橡胶性能的影响[J].特种橡胶制品,1998,19(5):7-11.
[44]陈玉刚,李晓,赵慧欣,等.硅烷偶联剂对纳米二氧化硅/硅橡胶复合材料界面作用及性能的影响[J].合成橡胶工业,2015,38(3):200-205.
[45]华欣倩,田佰刚,范玉曼,等.不同硅烷偶联剂改性白炭黑对溶聚丁苯橡胶性能的影响[J].合成橡胶工业,2016,39(4):334-337.
[46]Ye Xin,Tian Miao,Zhang Liqun.Some Interesting Phenomena in Silica-filled HNBR with the Addition of Silane Coupling Agent[J].Journal of Applied Polymer Science,2012,124(2):927-934.
[47]Manna Ajak K,DE P P,Tripathy D K.Bonding between Precipitated Silica and Epoxidized Natural Rubber in the Presence of Silane Coupling Agent[J].Journal of Applied Polymer Science,1999,74(2):389-398.
[48]宋成芝,张志广,车永兴,等.偶联剂γ-氨丙基三乙氧基硅烷对炭黑增强丁腈橡胶性能的影响[J].合成橡胶工业,2010,33(6):459-463.
[49]邱贤亮,岑兰,陈福林,等.偶联剂改性白炭黑对SBR胶料性能的影响[J].弹性体,2012,22(6):19-23.
[50]潘其维,王兵兵,周瑛,等.一种硅烷偶联剂的合成及其在白炭黑/天然橡胶复合材料中的应用[J].高分子学报,2014(2):202-209.
[51]赵金义,毕雪玲,周丽玲,等.硅烷偶联剂改性白炭黑在丁苯橡胶中的应用[J].青岛科技大学学报,2004,25(2):160-162.
[52]李彬,刘述梅,袁俊轩,等.分散剂和偶联剂对白炭黑填充硅橡胶性能的影响[J].橡胶工业,2011,58(7):415-418.
[53]Balan Aparna K,Sreejith Mottakkunnu Parambil,Shaniba Vakyath,et al.Coconut Shell Powder Reinforced Thermoplastic Polyurethane/Natural Rubber Blend-Composites:Effect of Silane Coupling Agents on the Mechanical and Thermal Properties of the Composites[J].Journal of Materials Science,2017,52(11):6712-6725.
[54]Yan Xuesong,Hamed Gary R,Jia Li.Urushiol-derived Non-silane Coupling Agent[J].Polymer,2017,125(7):172-181.
[55]沈梅,张波,辛振祥.腰果酚改性白炭黑/纳米甲壳素对丁苯橡胶/顺丁橡胶复合材料性能的影响[J].合成橡胶工业,2017,40(5):391-395.
[56]沈梅,马晨,侯占峰,等.一种单宁酸改性白炭黑补强丁苯橡胶的制备方法[P].中国:CN 107641229,2017-10-11.
[43]罗权熄,王真智.硅烷偶联剂对硅橡胶性能的影响[J].特种橡胶制品,1998,19(5):7-11.
[44]陈玉刚,李晓,赵慧欣,等.硅烷偶联剂对纳米二氧化硅/硅橡胶复合材料界面作用及性能的影响[J].合成橡胶工业,2015,38(3):200-205.
[45]华欣倩,田佰刚,范玉曼,等.不同硅烷偶联剂改性白炭黑对溶聚丁苯橡胶性能的影响[J].合成橡胶工业,2016,39(4):334-337.
[46]Ye Xin,Tian Miao,Zhang Liqun.Some Interesting Phenomena in Silica-filled HNBR with the Addition of Silane Coupling Agent[J].Journal of Applied Polymer Science,2012,124(2):927-934.
[47]Manna Ajak K,DE P P,Tripathy D K.Bonding between Precipitated Silica and Epoxidized Natural Rubber in the Presence of Silane Coupling Agent[J].Journal of Applied Polymer Science,1999,74(2):389-398.
[48]宋成芝,张志广,车永兴,等.偶联剂γ-氨丙基三乙氧基硅烷对炭黑增强丁腈橡胶性能的影响[J].合成橡胶工业,2010,33(6):459-463.
[49]邱贤亮,岑兰,陈福林,等.偶联剂改性白炭黑对SBR胶料性能的影响[J].弹性体,2012,22(6):19-23.
[50]潘其维,王兵兵,周瑛,等.一种硅烷偶联剂的合成及其在白炭黑/天然橡胶复合材料中的应用[J].高分子学报,2014(2):202-209.
[51]赵金义,毕雪玲,周丽玲,等.硅烷偶联剂改性白炭黑在丁苯橡胶中的应用[J].青岛科技大学学报,2004,25(2):160-162.
[52]李彬,刘述梅,袁俊轩,等.分散剂和偶联剂对白炭黑填充硅橡胶性能的影响[J].橡胶工业,2011,58(7):415-418.
[53]Balan Aparna K,Sreejith Mottakkunnu Parambil,Shaniba Vakyath,et al.Coconut Shell Powder Reinforced Thermoplastic Polyurethane/Natural Rubber Blend-Composites:Effect of Silane Coupling Agents on the Mechanical and Thermal Properties of the Composites[J].Journal of Materials Science,2017,52(11):6712-6725.
[54]Yan Xuesong,Hamed Gary R,Jia Li.Urushiol-derived Non-silane Coupling Agent[J].Polymer,2017,125(7):172-181.
[55]沈梅,张波,辛振祥.腰果酚改性白炭黑/纳米甲壳素对丁苯橡胶/顺丁橡胶复合材料性能的影响[J].合成橡胶工业,2017,40(5):391-395.
[56]沈梅,马晨,侯占峰,等.一种单宁酸改性白炭黑补强丁苯橡胶的制备方法[P].中国:CN 107641229,2017-10-11.