可充锌锰电池的研究进展
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摘要
锌锰电池问世以来,由于其结构简单、安全、无毒、成本低廉且环保等特点得以广泛应用。在传统的碱性电解液中的循环稳定性差,难以实现连续多次充放循环,限制了锌锰电池的应用。而在中性电解液中,锌锰电池可以有上千次的循环寿命。在介绍不同电解液中电池工作机理的基础上,阐述了电解液对锌锰电池可充性的影响,并对可充锌锰电池技术未来的发展进行了展望。
Since the advent of the Zn/MnO_2 battery, it has been widely used because of its simple structure, safety, nontoxic, low cost and environmental friendly. In the traditional alkaline batteries, the stability is poor, and it is difficult to realize the continuous charging of long circulation to limit more applications of the batteries. While in mild electrolyte, the battery shows thousands of cycle life. On the basis of introducing the mechanism in different electrolyte, the effects of electrolyte on the rechargeability for the Zn/MnO_2 battery were discussed and its future development was proposed.
Since the advent of the Zn/MnO_2 battery, it has been widely used because of its simple structure, safety, nontoxic, low cost and environmental friendly. In the traditional alkaline batteries, the stability is poor, and it is difficult to realize the continuous charging of long circulation to limit more applications of the batteries. While in mild electrolyte, the battery shows thousands of cycle life. On the basis of introducing the mechanism in different electrolyte, the effects of electrolyte on the rechargeability for the Zn/MnO_2 battery were discussed and its future development was proposed.
引文
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[29] SUN W, WANG F, HOU S, et al. Zn/MnO2battery chemistry with H+and Zn2+coinsertion[J]. J Am Chem Soc, 2017, 139(29):9775-9778.
[2] LARCHER D, TARASCON J M.Towards greener and more sustainable batteries for electrical energy storage[J]. Nature Chemistry,2015, 7(1):19-29.
[3] TARASCON J M, ARMAND M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001, 414(6861):359-367.
[4] LIU J, ZHANG J G, YANG Z, et al. Materials science and materials chemistry for large scale electrochemical energy storage:From transportation to electrical grid[J]. Advanced Functional Materials, 2013,23(8):929-946.
[5] JIANG J, LI Y, LIU J, et al. Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage[J].Adv Mater, 2012, 24(38):5166-5180.
[6] QU D Y. Studies of the activated carbons used in double-layer supercapacitors[J]. Journal of Power Sources, 2002, 109(2):403-411.
[7] SIMON P, GOGOTSI Y. Materials for electrochemical capacitors[J]. Nat Mater, 2008, 7(11):845-854.
[8] ZHAI Y P, DOU Y Q, ZHAO D Y, et al. Carbon materials for chemical capacitive energy storage[J]. Advanced Materials, 2011, 23(42):4828-4850.
[9] KOUSKSOU T, BRUEL P, JAMIL A, et al. Energy storage:Applications and challenges[J]. Solar Energy Materials and Solar Cells,2014, 120:59-80.
[10] DANG Z M, YUAN J K, YAO S H, et al. Flexible nanodielectric materials with high permittivity for power energy storage[J]. Adv Mater, 2013, 25(44):6334-6365.
[11] ZHAI D, LI B, DU H, et al. The preparation of graphene decorated with manganese dioxide nanoparticles by electrostatic adsorption for use in supercapacitors[J]. Carbon, 2012, 50(14):5034-5043.
[12] XU C,LI B,DU H, et al. Energetic zinc ion chemistry:The rechargeable zinc ion battery[J]. Angewandte Chemie International Edition, 2012, 51(4):933-935.
[13] JUSTIN R C, VARMA K B R. Synthesis and electrical properties of the(PVA)0.7(KI)0.3·x H2SO4(0≤x≤5)polymer electrolytes and their performance in a primary Zn/MnO2battery[J].Electrochimica Acta, 2010, 56(2):649-656.
[14] ZHANG Y, LIU H, ZHU Z H, et al. Control synthesis and lithium ion battery performance of manganese dioxide nanowires with tunable structures but similar morphology[J]. Journal of Applied Electrochemistry, 2013, 43(7):705-710.
[15] CHEN H, ZENG S, CHEN M, et al. Oxygen evolution assisted fabrication of highly loaded carbon nanotube/MnO2hybrid films for high-performance flexible pseudosupercapacitors[J]. Small, 2016,12(15):2035-2045.
[16] WINTER M, BRODD R J. What are batteries, fuel cells, and supercapacitors?[J]. Chemical Reviews, 2004, 104(10):4245-4270.
[17] SU D S, THOMAS A. Nanochemical concepts for a sustainable energy supply[J]. Chem Sus Chem, 2010, 3(2):120.
[18] AURBACH D, LU Z, SCHECHTER A, et al. Prototype systems for rechargeable magnesium batteries[J]. Nature, 2000, 407(6805):724-727.
[19] HERTZBERG B J, HUANG A, HSIEH A, et al. Effect of multiple cation electrolyte mixtures on rechargeable Zn·Mn O2alkaline battery[J]. Chemistry of Materials, 2016, 28(13):4536-4545.
[20] MASKELL W C, SHAW J E A, TYE F L. Manganese dioxide electrode-IV.Chemical and electrochemical reduction of an electrolytic g-MnO2[J]. Electrochimica Acta, 1981, 26(10):1403-1410.
[21] MCBREEN J.The electrochemistry ofβ-MnO2and g-MnO2in alkaline electrolyte[J]. Electrochimica Acta, 1975, 20(3):221-225.
[22] KOZAWA A, POWERS R A. The manganese dioxide electrode in alkaline electrolyte; the electron-proton mechanism for the discharge process from Mn O2to Mn O1.5[J]. Journal of the Electrochemical Society, 1966, 113(9):870-878.
[23] ERA A, TAKEHARA Z, YOSHIZAWA S. Discharge mechanism of the manganese dioxide electrode[J].Electrochimica Acta, 1967,12(9):1199-1212.
[24] DEVARAJ S, MUNICHANDRAIAH N. Effect of crystallographic structure of Mn O2on its electrochemical capacitance properties[J].The Journal of Physical Chemistry C, 2008, 112(11):4406-4417.
[25] IM D, MANTHIRAM A. Role of bismuth and factors influencing the formation of Mn3O4in rechargeable alkaline batteries based on bismuth-containing manganese oxides[J]. Journal of the Electrochemical Society, 2003, 150(1):A 68-A 73.
[26] LEE B, SEO H R, LEE H R, et al. Critical role of pH evolution of electrolyte in the reaction mechanism for rechargeable zinc batteries[J]. Chem Sus Chem, 2016, 9(20):2948-2956.
[27] ALFARUQI M H, GIM J, KIM S, et al. Enhanced reversible divalent zinc storage in a structurally stableα-Mn O2nanorod electrode[J]. Journal of Power Sources, 2015, 288:320-327.
[28] PAN H, SHAO Y, YAN P,et al.Reversible aqueous zinc/manganese oxide energy storage from conversion reactions[J]. Nature Energy,2016, 1(5):16039.
[29] SUN W, WANG F, HOU S, et al. Zn/MnO2battery chemistry with H+and Zn2+coinsertion[J]. J Am Chem Soc, 2017, 139(29):9775-9778.