组合类和固态电解质锂空气电池的研究进展
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摘要
简要介绍新型电解质提高循环性能的原因,综述了近年来两类电解质在锂空气电池中的的研究现状,同时着重分析循环过程机理,指出制约性能的关键因素并提出解决方案,展望发展方向。
This paper briefly introduces the reasons for improving the cyclic performance of new electrolytes,summarizes the research status of two kinds of electrolytes in lithium-air batteries in recent years,analyzes the mechanism of the cycle process,points out the key factors restricting the performance and puts forward the solutions.Look forward to the direction of development.
This paper briefly introduces the reasons for improving the cyclic performance of new electrolytes,summarizes the research status of two kinds of electrolytes in lithium-air batteries in recent years,analyzes the mechanism of the cycle process,points out the key factors restricting the performance and puts forward the solutions.Look forward to the direction of development.
引文
[1] 童圣富,何平,张雪苹,等.基于有机和组合电解质的锂空气电池研究进展[J].电化学,2015,21(3):234-252.
[2] 黄洋,罗仲宽,王芳,等.锂-空气电池电解质研究进展[J].材料导报,2015,29(5):8-15.
[3] 蒋颉,刘晓飞,赵世勇,等.基于有机电解质的锂空气电池研究进展[J].化学学报,2014,72(4):417-426.
[4] Zhang P,Zhao Y,Zhang X.Functional and stability orientation synthesis of materials and structures in aprotic Li-O2 batteries[J].Chemical Society Reviews,2018,Advance Article.
[5] Wittmaier D,Danner T,Wagner N.Screening and further investigations on promising bi-functional catalysts for metal-air batteries with an aqueous alkaline electrolyte[J].Journal of Applied Electrochemistry,2013,44(1):73-85.
[6] 张涛,张晓平,温兆银.固态锂空气电池研究进展[J].储能科学与技术,2016,5(5):702-712.
[7] 王均凤,张锁江,陈慧萍.离子液体的性质及其在催化反应中的应用[J].过程工程学报,2003(2):177-185.
[8] Garciaaraez N,Novak P.Critical aspects in the development of lithium-air batteries[J].J Solid State Electrochem,2013,17(7):1793-1807.
[9] Gunasekara I,Mukerjee S,Plichta E J,et al.Microelectrode diagnostics of lithium-air batteries[J].Journal of the Electrochemical Society,2014,161(3):A381-A392.
[10] Lim H D,Park K Y,Gwon H,et al.The potential for long-term operation of a lithium-oxygen battery using a non-carbonate based electrolyte[J].Chem Commun,2012,67(48):8374-8376.
[11] Chen Y,Freunberger S A,Peng Z,et al.Li-O2 battery with a dimethylformamide electrolyte[J].Journal of the American Chemical Society,2012,134(18):7952-7957.
[12] Walker W,Giordani V,Uddin J,et al.A rechargeable Li-O2 battery using a lithium nitrate/N,N-dimethylacetamide electrolyte[J].Journal of the American Chemical Society,2013,135(6):2076-2079.
[13] McCloskey B D,Scheffler R,Speidel A,et al.On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries[J].J Am Chem Soc,2011,133(45):18038-18041.
[14] Freunberger S A,Chen Y,Drewett N E,et al.The lithium-oxygen battery with ether-based electrolytes[J].Angew Chem Int Ed,2011,50(37):8609-8613.
[15] 卢云,王伟,宫岩坤,等.二甲基亚砜对有机电解质锂空气电池性能的影响[J].材料导报,2017,31(12):1-5.
[16] 杨凤玉,张蕾蕾,徐吉静,等.非水系锂空气电池的正极材料和电解质研究进展[J].无机化学学报,2013,29(8):1563-1573.
[17] Xu W,Xiao J,Zhang J,et al.Optimization of nonaqueous electrolytes for primary lithium-air batteries operated in ambient enviornment batteries and energy storage[J].J Electrochem Soc,2009,156(10):A773-A779.
[18] Lee H,Yanilmaz M,Toprakci O,et al.A review of recent developments in membrane separators for rechargeable lithium-ion batteries[J].Energy Environ,2014(7):3857-3886.
[19] Zheng H,Xie Y,Xiang H,et al.A bifunctional electrolyte additive for separator wetting and dendrite suppression in lithium metal batteries[J].Electrochimica Acta,2018,270:62-69.
[20] Cecchetto L,Salomon M,Scrosati B,et al.Study of a Li-air battery having an electrolyte solution formed by a mixture of an ether-based aprotic solvent and an ionic liquid[J].Journal of Power Sources,2012,213:233-238.
[21] 肖尧,郎笑石,吴昊,等.锂空气电池用离子液体基复合电解质的性能[J].电池,2017,47(2):90-92.
[22] Asadi M,Sayahpour B.A lithium-oxygen battery with a long cycle life in an air-like atmosphere[J].Nature,2018,555(7697):502-506.
[23] Wang Y G,Zhou H S.A lithium-air battery with a potential to continuously reduce O2 from air for delivering energy[J].Journal of Power Sources,2010,195(1):358-361.
[24] Gierszewski P J,Finn P A,Kirk D W.Properties of LiOH and LiNO3 aqueous solutions[J].Fusion Engineering and Design,1990,13(1):59-71.
[25] 张栋,张存中,穆道斌,等.锂空气电池研究述评[J].化学进展,2012,24(12):2472-2482.
[26] He P,Wang Y G,Zhou H S.A Li-Air fuel cell with recycle aqueous electrolyte for improved stability[J].Electrochem Commun,2010,12:1686-1689.
[27] He P,Wang Y,Zhou H.The effect of alkalinity and temperature on the performance of lithium-air fuel cell with hybrid electrolytes[J].Journal of Power Sources,2011,196(13):5611-5616.
[28] Wang Y R,Ohnishi R H,Yoo E,et al.Nano-and micro-sized TiN as the electrocatalysts for ORR in Li-air fuel cell with alkaline aqueous electrolyte[J].Journal of Materials Chemistry,2012,22(31):15549-15555.
[29] Zhang T,Imanishi N,Shimonishi Y,et al.A novel high energy density rechargeable lithium-air battery[J].Chem Commun,2010,46:1661-1663.
[30] Thokchom J S,Gupta N,Kumar B.Superionic conductivity in a lithium aluminum germanium phosphate glass-ceramic[J].Journal of the Electrochemical Society,2008,155 (12):A915-A920.
[31] Zhu X B,Zhao T S,Wei Z H,et al.A novel solid-state Li-O2 battery with an integrated electrolyte and cathode structure[J].Energy Environ,2015,9(8):2782-2790.
[32] 王章俊.基于Li6.6La3Zr1.6Ta0.4O12固体电解质的全固态锂空气电池[C]//第18届全国固态离子学学术会议暨国际电化学储能技术论坛论文集.桂林:广西师范大学,2016:1.
[33] Kitaura H,Zhou H.Electrochemical performance and reaction mechanism of all-solid-state lithium-air batteries composed of lithium,Li1+xAlyGe2-y(PO4)3 solid electrolyte and carbon nanotube air electrode[J].Energy & Environmental Science,2012,5(10):9077-9084.
[34] Hartmann P,Leichtweiss T,Busche M R,et al.Degradation of NASICON-type materials in contact with lithium metal:Formation of mixed conducting interphases (MCI) on solid electrolytes[J].The Journal of Physical Chemistry C,2013,41(117):21064-21074.
[35] Kumar J,Kumar B.Development of membranes and a study of their interfaces for rechargeable lithium-air battery[J].Journal of Power Sources,2009,194(2):1113-1119.
[36] Kumar B,Kumar J,Leese R,et al.A solid-state,rechargeable,long cycle life lithium-air battery[J].Journal of The Electrochemical Society,2010,157(1):A50-A54.
[37] Zhang T,Zhou H.A reversible long-life lithium-air battery in ambient air[J].Nature Communications,2013,4:1817-1824.
[38] Hassoun J,Croce F,Armand M,et al.Investigation of the O2 electrochemistry in a polymer electrolyte solid-state cell[J].Angew Chem Int Ed,2011,50(13):2999-3002.
[39] Balaish M,Peled E,Golodnitsky D.Liquid-free lithium-oxygen batteries[J].Angew Chem Int Ed,2015,54:436-440.
[40] Lu Q,Gao Y,Zhao Q,et al.Novel polymer electrolyte from poly(carbonate-ether) and lithium tetrafluoroborate for lithium-oxygen battery[J].Journal of Power Sources,2013,242:677-682.
[41] 陈婉琦,张旺,尹微,等.无机熔融盐电解质在锂空气电池的应用[J].储能科学与技术,2017,6(6):1273-1279.
[42] Jung K N,Lee J I,Jung J H,et al.A quasi-solid-state rechargeable lithium-oxygen battery based on a gel polymer electrolyte with an ionic liquid[J].Chem Commun,2014,50:5458-5461.
[43] Kim H,Kim T Y,Roe V V,et al.Enhanced electrochemical stability of quasi-solid-state electrolyte containing SiO2 nanoparticles for Li-O2 battery applications[J].ACS Appl Mater Interfaces,2016,8:1344-1350.
[44] Yi J,Liu X,Guo S,et al.Novel stable gel polymer electrolyte:Toward a high safety and long life Li-air battery[J].ACS Appl Mater Interfaces,2015,7:23798-23804.
[45] Kumar J,Kichambare P.A high performance ceramic-polymer separator for lithium batteries[J].J Power Sources,2016,301:194-198.
[46] 孙继杨,崔忠慧,郭向欣.无机陶瓷固体电解质基固态锂空气电池的研究进展及挑战[J].陶瓷学报,2016,37(5):451-459.
[2] 黄洋,罗仲宽,王芳,等.锂-空气电池电解质研究进展[J].材料导报,2015,29(5):8-15.
[3] 蒋颉,刘晓飞,赵世勇,等.基于有机电解质的锂空气电池研究进展[J].化学学报,2014,72(4):417-426.
[4] Zhang P,Zhao Y,Zhang X.Functional and stability orientation synthesis of materials and structures in aprotic Li-O2 batteries[J].Chemical Society Reviews,2018,Advance Article.
[5] Wittmaier D,Danner T,Wagner N.Screening and further investigations on promising bi-functional catalysts for metal-air batteries with an aqueous alkaline electrolyte[J].Journal of Applied Electrochemistry,2013,44(1):73-85.
[6] 张涛,张晓平,温兆银.固态锂空气电池研究进展[J].储能科学与技术,2016,5(5):702-712.
[7] 王均凤,张锁江,陈慧萍.离子液体的性质及其在催化反应中的应用[J].过程工程学报,2003(2):177-185.
[8] Garciaaraez N,Novak P.Critical aspects in the development of lithium-air batteries[J].J Solid State Electrochem,2013,17(7):1793-1807.
[9] Gunasekara I,Mukerjee S,Plichta E J,et al.Microelectrode diagnostics of lithium-air batteries[J].Journal of the Electrochemical Society,2014,161(3):A381-A392.
[10] Lim H D,Park K Y,Gwon H,et al.The potential for long-term operation of a lithium-oxygen battery using a non-carbonate based electrolyte[J].Chem Commun,2012,67(48):8374-8376.
[11] Chen Y,Freunberger S A,Peng Z,et al.Li-O2 battery with a dimethylformamide electrolyte[J].Journal of the American Chemical Society,2012,134(18):7952-7957.
[12] Walker W,Giordani V,Uddin J,et al.A rechargeable Li-O2 battery using a lithium nitrate/N,N-dimethylacetamide electrolyte[J].Journal of the American Chemical Society,2013,135(6):2076-2079.
[13] McCloskey B D,Scheffler R,Speidel A,et al.On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries[J].J Am Chem Soc,2011,133(45):18038-18041.
[14] Freunberger S A,Chen Y,Drewett N E,et al.The lithium-oxygen battery with ether-based electrolytes[J].Angew Chem Int Ed,2011,50(37):8609-8613.
[15] 卢云,王伟,宫岩坤,等.二甲基亚砜对有机电解质锂空气电池性能的影响[J].材料导报,2017,31(12):1-5.
[16] 杨凤玉,张蕾蕾,徐吉静,等.非水系锂空气电池的正极材料和电解质研究进展[J].无机化学学报,2013,29(8):1563-1573.
[17] Xu W,Xiao J,Zhang J,et al.Optimization of nonaqueous electrolytes for primary lithium-air batteries operated in ambient enviornment batteries and energy storage[J].J Electrochem Soc,2009,156(10):A773-A779.
[18] Lee H,Yanilmaz M,Toprakci O,et al.A review of recent developments in membrane separators for rechargeable lithium-ion batteries[J].Energy Environ,2014(7):3857-3886.
[19] Zheng H,Xie Y,Xiang H,et al.A bifunctional electrolyte additive for separator wetting and dendrite suppression in lithium metal batteries[J].Electrochimica Acta,2018,270:62-69.
[20] Cecchetto L,Salomon M,Scrosati B,et al.Study of a Li-air battery having an electrolyte solution formed by a mixture of an ether-based aprotic solvent and an ionic liquid[J].Journal of Power Sources,2012,213:233-238.
[21] 肖尧,郎笑石,吴昊,等.锂空气电池用离子液体基复合电解质的性能[J].电池,2017,47(2):90-92.
[22] Asadi M,Sayahpour B.A lithium-oxygen battery with a long cycle life in an air-like atmosphere[J].Nature,2018,555(7697):502-506.
[23] Wang Y G,Zhou H S.A lithium-air battery with a potential to continuously reduce O2 from air for delivering energy[J].Journal of Power Sources,2010,195(1):358-361.
[24] Gierszewski P J,Finn P A,Kirk D W.Properties of LiOH and LiNO3 aqueous solutions[J].Fusion Engineering and Design,1990,13(1):59-71.
[25] 张栋,张存中,穆道斌,等.锂空气电池研究述评[J].化学进展,2012,24(12):2472-2482.
[26] He P,Wang Y G,Zhou H S.A Li-Air fuel cell with recycle aqueous electrolyte for improved stability[J].Electrochem Commun,2010,12:1686-1689.
[27] He P,Wang Y,Zhou H.The effect of alkalinity and temperature on the performance of lithium-air fuel cell with hybrid electrolytes[J].Journal of Power Sources,2011,196(13):5611-5616.
[28] Wang Y R,Ohnishi R H,Yoo E,et al.Nano-and micro-sized TiN as the electrocatalysts for ORR in Li-air fuel cell with alkaline aqueous electrolyte[J].Journal of Materials Chemistry,2012,22(31):15549-15555.
[29] Zhang T,Imanishi N,Shimonishi Y,et al.A novel high energy density rechargeable lithium-air battery[J].Chem Commun,2010,46:1661-1663.
[30] Thokchom J S,Gupta N,Kumar B.Superionic conductivity in a lithium aluminum germanium phosphate glass-ceramic[J].Journal of the Electrochemical Society,2008,155 (12):A915-A920.
[31] Zhu X B,Zhao T S,Wei Z H,et al.A novel solid-state Li-O2 battery with an integrated electrolyte and cathode structure[J].Energy Environ,2015,9(8):2782-2790.
[32] 王章俊.基于Li6.6La3Zr1.6Ta0.4O12固体电解质的全固态锂空气电池[C]//第18届全国固态离子学学术会议暨国际电化学储能技术论坛论文集.桂林:广西师范大学,2016:1.
[33] Kitaura H,Zhou H.Electrochemical performance and reaction mechanism of all-solid-state lithium-air batteries composed of lithium,Li1+xAlyGe2-y(PO4)3 solid electrolyte and carbon nanotube air electrode[J].Energy & Environmental Science,2012,5(10):9077-9084.
[34] Hartmann P,Leichtweiss T,Busche M R,et al.Degradation of NASICON-type materials in contact with lithium metal:Formation of mixed conducting interphases (MCI) on solid electrolytes[J].The Journal of Physical Chemistry C,2013,41(117):21064-21074.
[35] Kumar J,Kumar B.Development of membranes and a study of their interfaces for rechargeable lithium-air battery[J].Journal of Power Sources,2009,194(2):1113-1119.
[36] Kumar B,Kumar J,Leese R,et al.A solid-state,rechargeable,long cycle life lithium-air battery[J].Journal of The Electrochemical Society,2010,157(1):A50-A54.
[37] Zhang T,Zhou H.A reversible long-life lithium-air battery in ambient air[J].Nature Communications,2013,4:1817-1824.
[38] Hassoun J,Croce F,Armand M,et al.Investigation of the O2 electrochemistry in a polymer electrolyte solid-state cell[J].Angew Chem Int Ed,2011,50(13):2999-3002.
[39] Balaish M,Peled E,Golodnitsky D.Liquid-free lithium-oxygen batteries[J].Angew Chem Int Ed,2015,54:436-440.
[40] Lu Q,Gao Y,Zhao Q,et al.Novel polymer electrolyte from poly(carbonate-ether) and lithium tetrafluoroborate for lithium-oxygen battery[J].Journal of Power Sources,2013,242:677-682.
[41] 陈婉琦,张旺,尹微,等.无机熔融盐电解质在锂空气电池的应用[J].储能科学与技术,2017,6(6):1273-1279.
[42] Jung K N,Lee J I,Jung J H,et al.A quasi-solid-state rechargeable lithium-oxygen battery based on a gel polymer electrolyte with an ionic liquid[J].Chem Commun,2014,50:5458-5461.
[43] Kim H,Kim T Y,Roe V V,et al.Enhanced electrochemical stability of quasi-solid-state electrolyte containing SiO2 nanoparticles for Li-O2 battery applications[J].ACS Appl Mater Interfaces,2016,8:1344-1350.
[44] Yi J,Liu X,Guo S,et al.Novel stable gel polymer electrolyte:Toward a high safety and long life Li-air battery[J].ACS Appl Mater Interfaces,2015,7:23798-23804.
[45] Kumar J,Kichambare P.A high performance ceramic-polymer separator for lithium batteries[J].J Power Sources,2016,301:194-198.
[46] 孙继杨,崔忠慧,郭向欣.无机陶瓷固体电解质基固态锂空气电池的研究进展及挑战[J].陶瓷学报,2016,37(5):451-459.
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