复合固体推进剂基体/填料界面研究现状
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摘要
复合固体推进剂广泛应用于航天火箭及常规战备武器中,其基体与填料间的界面问题一直是科研工作者关注的焦点。因基体/填料界面属于推进剂的弱作用点,研究界面问题可在一定程度上反映推进剂的整体结构完整性。简要介绍了目前关于固体推进剂中基体/填料界面的主要研究方法,从物相表征和力学测试两方面进行分类,分别介绍了红外光谱、显微镜、X射线光电子能谱、接触角测量及拉伸测试法和动态力学性能测试法在基体/填料界面处的应用,并介绍了几种常见界面作用理论。通过总结和对比,展望了固体推进剂基体/填料界面研究的发展方向,指出界面研究将朝着对单一界面进行研究、从微观角度测试力学性能以及界面分子动力学研究的方向发展。
The composite solid propellant which matrix/filler interface problem was widely focused,was used in rockets and conventional weapons extensively.As a key,the matrix/filler interface had a close connection with the structural integrity of composite solid propellants.The research methods of interface in the aspects of characterization and test were reviewed.The application of infrared spectroscopy,microscope,X-ray photoelectron spectroscopy,contact angle,tensile test and dynamic mechanical measurement as well as several effect mechanisms were introduced and compared.In the future,the studies of sole interface,micromechanical test and molecular dynamics were the research focuses for the matrix/filler interface.
The composite solid propellant which matrix/filler interface problem was widely focused,was used in rockets and conventional weapons extensively.As a key,the matrix/filler interface had a close connection with the structural integrity of composite solid propellants.The research methods of interface in the aspects of characterization and test were reviewed.The application of infrared spectroscopy,microscope,X-ray photoelectron spectroscopy,contact angle,tensile test and dynamic mechanical measurement as well as several effect mechanisms were introduced and compared.In the future,the studies of sole interface,micromechanical test and molecular dynamics were the research focuses for the matrix/filler interface.
引文
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[25]王国强,史爱娟,丁黎,等.丁羟推进剂的热加速老化力学性能及寿命预估[J].火炸药学报,2015,38(1):47-50.
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[29] Herrmann M,F9rter-Barth U,Bohn M A,et al.Microstructure of the HMX-Based PBX KS32after mechanical loading[J].Propellants Explosives Pyrotechnics,2015,40(6):880-885.
[30] Aurilia M,Piscitelli F,Sorrentino L,et al.Detailed analysis of dynamic mechanical properties of TPU nanocomposite:the role of the interfaces[J].European Polymer Journal,2011,47(5):925-936.
[31]赵俊会.高分子化学与物理[M].北京:中国轻工业出版社,2010.
[32]杨彪.聚合物材料的表面与界面[M].北京:中国标准出版社,2013.
[33]邱丰,王猛,周化光,等.Pb液滴在Ni基底润湿铺展行为的分子动力学模拟[J].物理学报,2013,62(12):120203-120209.
[34]朱锦涛,邓剑如,盛亚俊,等.界面酸碱作用理论在聚合物基复合材料界面粘接性能研究中的应用[J].湖南大学学报:自然科学版,2002,29(3):20-24.
[35]喻鸿钢,邓剑如,申红光,等.丁羟推进剂组分间界面酸碱作用研究[J].固体火箭技术,2009,32(6):659-662.
[36]张习龙,刘苗娥,王祝愿,等.BEBA对丁羟推进剂界面粘接作用的研究[J].固体火箭技术,2016,39(5):667-671.
[37]崔瑞禧,张炜,邓剑如.硼酸酯键合剂在丁羟四组元推进剂中作用机理研究[J].推进技术,2010,31(4):448-451.
[2] Huggett C,Bartley C E,Mills M M.Solid propellant rockets[M].New Jersey:Princeton University Press,2015:1-176.
[3]张炜,鲍桐,周星.火箭推进剂[M].北京:国防工业出版社,2014:143-159.
[4]侯林法.复合固体推进剂[M].北京:中国宇航出版社,1994:36-52.
[5]杜永强,郑坚,彭威,等.HTPB推进剂贮存老化建模及寿命预估研究综述[J].化工进展,2016,35(S2):219-224.
[6]秦浩,杜仕国,闫军,等.固体推进剂老化性能研究进展[J].化工进展,2013,32(8):1862-1865.
[7]王玉峰,董可海,曲凯,等.复合固体推进剂振动疲劳损伤耗散特性研究[J].四川兵工学报,2015,36(11):23-25.
[8]陈广南.固体火箭发动机机械撞击载荷作用下安全性研究[D].长沙:国防科学技术大学,2015.
[9] Sojourner T S,Richardson D E,Allen B D,et al.Solid rocket booster reliability and historical failure modes review[C].51st AIAA/SAE/ASEE Joint Propulsion Conference,2015.
[10] Wu W E,Chen C,Fu X,et al.The correlation between chemical stability and binder network structure in NEPE propellant[J].Propellants Explosives Pyrotechnics,2017,42(5):1-7.
[11] Zhou Q C,Xu J S,Chen X,et al.Review of the adhesively bonded interface in a solid rocket motor[J].The Journal of Adhesion,2016,92(5):402-428.
[12] Naya T,Kohga M.Influences of particle size and content of RDX on burning characteristics of RDX-based propellant[J].Aerospace Science and Technology,2014,32(1):26-34.
[13] Hori K,Iwama A,Fukuda T.On the adhesion between hydroxyl-terminated polybutadiene fuel-binder and ammonium perchlorate.Performance of bonding agents[J].Propellants Explosives Pyrotechnics,1985,10(6):176-180.
[14] Hori K,Iwama A,Fukuda T.FT-IR spectroscopic study on the interaction between ammonium perchlorate and bonding agents[J].Propellants Explosives Pyrotechnics,1990,15(3):99-102.
[15] Gui D,Zong Y,Ding S,et al.In-situ characterization and cure kinetics in NEPE propellant/HTPB liner interface by microscopic FT-IR[J].Propellants Explosives Pyrotechnics,2017,42(4):410-416.
[16] McDonald B A,Rice J R,Kirkham M W.Humidity induced burning rate degradation of an iron oxide catalyzed ammonium perchlorate/HTPB composite propellant[J].Combustion and Flame,2014,161(1):363-369.
[17] Zhang X L,Liu M E,Tan X L,et al.Synthesis and application of borate ester bonding agents for a four-component hydroxylterminated polybutadiene propellant[J].Propellants Explosives Pyrotechnics,2015,40(6):831-837.
[18] Zhang X L,Liu M E,Liu W Z,et al.Synthesis and interfacial adhesion interaction of borate ester bonding agents used for HTPB propellant[J].Propellants Explosives Pyrotechnics,2016,41(5):814-821.
[19]魏小琴,杨万均,罗天元,等.X射线光电子能谱在HTPB推进剂老化机理研究中的应用[J].装备环境工程,2013,10(5):52-57.
[20] Chen Y,Liu Y F,Shi L,et al.Study on the synthesis and interfacial interaction performance of novel dodecylamine-based bonding agents used for composite solid propellants[J].Propellants Explosives Pyrotechnics,2015,40(1):50-59.
[21]张兴高,张炜,芦伟,等.HTPB推进剂填料/基体界面粘结性能老化特性研究[J].含能材料,2009,17(3):269-273.
[22]喻鸿钢.复合固体推进剂界面粘结的预估、表征及优化[D].长沙:湖南大学,2008.
[23]庞爱民.固体火箭推进剂理论与工程[M].北京:中国宇航出版社,2014:56-92.
[24]王建祥,陈建康,白树林.基于损伤演化的共混/填充高聚物体系本构关系研究进展[J].复合材料学报,2002,19(6):1-7.
[25]王国强,史爱娟,丁黎,等.丁羟推进剂的热加速老化力学性能及寿命预估[J].火炸药学报,2015,38(1):47-50.
[26] Wang Z J,Qiang H F,Wang G,et al.Tensile mechanical properties and constitutive model for HTPB propellant at low temperature and high strain rate[J].Journal of Applied Polymer Science,2015,132(24):42104-42112.
[27] Wang Z J,Qiang H F,Wang G.Experimental investigation on high strain rate tensile behaviors of HTPB propellant at low temperatures[J].Propellants Explosives Pyrotechnics,2015,40(6):814-820.
[28] Wang Z J,Qiang H F,Wang G,et al.A new test method to obtain biaxial tensile behaviors of solid propellant at high strain rates[J].Iranian Polymer Journal,2016,25(6):515-524.
[29] Herrmann M,F9rter-Barth U,Bohn M A,et al.Microstructure of the HMX-Based PBX KS32after mechanical loading[J].Propellants Explosives Pyrotechnics,2015,40(6):880-885.
[30] Aurilia M,Piscitelli F,Sorrentino L,et al.Detailed analysis of dynamic mechanical properties of TPU nanocomposite:the role of the interfaces[J].European Polymer Journal,2011,47(5):925-936.
[31]赵俊会.高分子化学与物理[M].北京:中国轻工业出版社,2010.
[32]杨彪.聚合物材料的表面与界面[M].北京:中国标准出版社,2013.
[33]邱丰,王猛,周化光,等.Pb液滴在Ni基底润湿铺展行为的分子动力学模拟[J].物理学报,2013,62(12):120203-120209.
[34]朱锦涛,邓剑如,盛亚俊,等.界面酸碱作用理论在聚合物基复合材料界面粘接性能研究中的应用[J].湖南大学学报:自然科学版,2002,29(3):20-24.
[35]喻鸿钢,邓剑如,申红光,等.丁羟推进剂组分间界面酸碱作用研究[J].固体火箭技术,2009,32(6):659-662.
[36]张习龙,刘苗娥,王祝愿,等.BEBA对丁羟推进剂界面粘接作用的研究[J].固体火箭技术,2016,39(5):667-671.
[37]崔瑞禧,张炜,邓剑如.硼酸酯键合剂在丁羟四组元推进剂中作用机理研究[J].推进技术,2010,31(4):448-451.