纳滤膜分离技术处理饮用水研究进展
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摘要
综述了纳滤膜分离技术及其在饮用水处理中的应用。研究发现,纳滤膜分离技术在含有多种复杂有毒有害污染物的饮用水处理中可发挥重要作用,可以高效去除饮用水中的有机物、无机物、重金属离子、微量污染物等有害物质。膜分离技术的去除污染物机理一般为筛分作用及电荷效应。纳滤膜在去除饮用水中有毒有害物质有良好的作用效果,突破纳滤膜制备成本、使用寿命瓶颈的膜分离技术对相应物质浓缩富集效能的提升具有重要意义。
The nanofiltration membrane technology and its application in drinking water treatment were reviewed. Nanofiltration membrane separation technology played an important role in drinking water treatment,especially in water containing a variety of complex toxic and harmful pollutants. Nanofiltration membranes removaled pollutants via the screening effect and charge effect. This technology could effectively removal many inorganic and organic matters,e. g.,heavy metals,trace pollutants and other harmful substances. The cut-down of nanofiltration membrane preparation cost and the prolonging of service life have important significance of membrane technology in the use of material enrichment.
The nanofiltration membrane technology and its application in drinking water treatment were reviewed. Nanofiltration membrane separation technology played an important role in drinking water treatment,especially in water containing a variety of complex toxic and harmful pollutants. Nanofiltration membranes removaled pollutants via the screening effect and charge effect. This technology could effectively removal many inorganic and organic matters,e. g.,heavy metals,trace pollutants and other harmful substances. The cut-down of nanofiltration membrane preparation cost and the prolonging of service life have important significance of membrane technology in the use of material enrichment.
引文
[1]敬双怡,刘杨,张列宇,等.纳滤膜在直饮水终端系统中的应用[J].水处理技术,2016,11(10):117-120.
[2]王晓琳,涂丛慧,方彦彦,等.纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J].膜科学与技术,2011,31(3):127-134.
[3]高麟.新型多孔膜及膜分离技术工业前沿应用[C]//第四届全国膜分离技术在冶金工业中应用研讨会论文集.成都:中国工业协会,2014.
[4]李祥,张忠国,任晓晶,等.纳滤膜材料研究进展[J].化工进展,2014,5(12):1210-1218.
[5]韩永萍,林强,李亚秋.纳滤膜传质过程的研究[J].化学世界,2011,52(30):760-764.
[6]尚洪涛.纳滤过程原理综述[J].科技信息,2013,20(1):67-70.
[7]Agboola O,Maree J,Kolesnikov A,et al.Theoretical performance of nanofiltration membranes for wastewater treatment[J].Environmental Chemistry Letters,2015,13(1):37-47.
[8]王晓琳,涂丛慧,方彦彦,等.纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J].膜科学与技术,2011,31(8):127-134.
[9]Rahimpour A.Preparation and modification of nano-porous polyimide(PI)membranes by UV photo-grafting process:Ultrafiltration and nanofiltration performance[J].Korean Journal of Chemical Engineering,2011,28(1):261-266.
[10]Mohammad A W,Teow Y H,Ang W L,et al.Nanofiltration membranes review:Recent advances and future prospects[J].Desalination,2015,3(56):226-254.
[11]Ladewig B,Al-Shaeli M N Z.Introduction to Membrane Bioreactors[M]//Fundamentals of Membrane Bioreactors.Singapore:Springer,2017,12(1):1-12.
[12]郑甜甜,黄丹,班允赫,等.膜法生产饮用水过程中纳滤膜生物污染的研究[J].水处理技术,2013,39(10):50-52.
[13]陶润先,陈立,朱开东,等.生物活性炭作为纳滤预处理工艺的试验研究[C]//中国土木工程学会水工业分会全国给水深度处理研究会.上海:2010年年会,2010.
[14]杨忠盛,芦敏,袁东星,等.活性炭结合超滤及纳滤工艺深度处理饮用水的中试研究[J].给水排水,2011,37(5):29-34.
[15]何忠,王志良,杨绍贵,等.纳滤、反渗透工艺深度处理饮用水研究[J].长江科学院院报,2016,33(4):11-15.
[16]徐兵,杨程.纳滤膜处理微污染原水的中试研究[J].给水排水,2016,42(11):11-15.
[17]陈欢林,吴礼光,陈小洁,等.钱塘江潮汐水源的饮用水膜法集成系统示范运行经验[C]//2013给水深度处理及饮用水安全保障技术交流会.武汉:中国膜法协会,2013.
[18]王磊,李靖平,张岩,等.臭氧-生物活性炭-纳滤膜深度处理饮用水试验研究[J].给水排水,2009,35(8):17-20.
[19]侯立安,左莉.纳滤去除饮用水中有机物及类炭疽杆菌的研究[J].中国给水排水,2006,22(7):62-64.
[20]孔繁鑫,王小,杨宏伟,等.纳滤控制饮用水中消毒副产物的研究进展[J].中国给水排水,2013,29(18):28-32.
[21]吴礼光,项雯.纳滤膜去除饮用水中微量三唑磷的研究[J].环境科学与技术,2011,34(6):53-58.
[22]李清雪,肖伟,吴伟,等.纳滤组合工艺深度处理微量污染物[J].膜科学与技术,2010,30(5):103-106.
[23]Lu X U,Jiang W,Wang J,et al.Basic studies on the performance of domestic nanofiltration membranes for desalting brackish water with high fluoride[J].Membrane Science&Technology,2015,12(3):50-58.
[24]吕建国,王文正.纳滤淡化高氟苦咸水示范工程[J].给水排水,2009,35(7):25-27.
[25]马伟芳,刘文君.共存氯离子对饮用水纳滤除氟的影响研究[J].环境科学,2009,30(3):787-791.
[26]张阳,潘晶,孔健健,等.纳滤去除地表水中微污染物生产饮用水[J].辽宁工程技术大学学报,2009,28(3):482-484.
[27]杨庆娟,魏宏斌,王志海,等.纳滤膜去除饮用水中无机离子的中试研究[J].中国给水排水,2009,25(5):52-55.
[28]Zhao C,Wang T,Zhang J,et al.Arsenic removal from drinking water by self-made PMIA nanofiltration membrane[J].Advances in Chemical Engineering&Science,2012,37(2):20-71.
[29]Li X,Cai T,Chen C,et al.Negatively charged hyperbranched polyglycerol grafted membranes for osmotic power generation from municipal wastewater[J].Water Research,2016,89(12):50-58.
[30]陈丽珠,盛德洋,申露威,等.纳滤膜去除饮用水中多种重金属的研究[J].给水排水,2016,42(11):103-159.
[31]T U M,I MM,A I M,et al.Nanofiltration membrane process for the removal of arsenic from drinking water[J].Chemical Engineering&Technology,2007,30(9):1248-1254.
[32]Yaser A Z,Hilal N.Treatment of dye solution via low pressure nanofiltration system[M]//Membrane Technology for Water and Wastewater Treatment,Energy and Environment,2016,13(3):37-61.
[33]朱娜姗,陈诗弢,王莹,等.农村饮用水膜法处理应用工程[J].水处理技术,2009,35(3):110-112.
[34]Park M,Anumol T,Simon J,et al.Pre-ozonation for high recovery of nanofiltration(NF)membrane system:Membrane fouling reduction and trace organic compound attenuation[J].Journal of Membrane Science,2017,523(1):255-263.
[35]黄裕,张晗,董秉直.纳滤膜去除卡马西平的影响因素研究[C]//中国土木工程学会水工业分会全国给水深度处理研究会.上海:2010年年会,2010.
[36]吴芳,封莉,张立秋.纳滤去除水中中性药物的预测模型[J].膜科学与技术,2016,36(4):97-102.
[37]葛四杰,吴芳,张立秋,等.纳滤膜去除水中微量药物萘普生效能的影响因素研究[J].膜科学与技术,2013,33(6):92-96.
[38]丰桂珍,董秉直.藻类对纳滤膜去除萘普生的影响[J].环境科学与技术,2013,11(8):97-102.
[39]金叶,章宏梓,吴礼光,等.纳滤膜对邻苯二甲酸酯的动态吸附行为及截留特性[J].水处理技术,2011,37(12):59-63.
[40]Bots J,De B L,Snijkers T,et al.Exposure to perfluorooctane sulfonic acid(PFOS)adversely affects the lifecycle of the damselfly Enallagma cyathigerum[J].Environmental Pollution,2010,158(3):901-995.
[41]Dauwe T,Van d V K,De C W,et al.PFOS levels in the blood and liver of a small insectivorous songbird near a fluorochemical plant[J].Environment International,2007,33(3):357-361.
[42]Van G H,Bots J,Snijkers T,et al.Behaviour of damselfly larvae(Enallagma cyathigerum)(Insecta,Odonata)after long-term exposure to PFOS[J].Environmental Pollution,2009,157(4):1332-1336.
[43]张健,赵长伟,宋娜,等.纳滤去除饮用水中的PFOS[J].环境工程学报,2013,11(11):4236-4240.
[2]王晓琳,涂丛慧,方彦彦,等.纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J].膜科学与技术,2011,31(3):127-134.
[3]高麟.新型多孔膜及膜分离技术工业前沿应用[C]//第四届全国膜分离技术在冶金工业中应用研讨会论文集.成都:中国工业协会,2014.
[4]李祥,张忠国,任晓晶,等.纳滤膜材料研究进展[J].化工进展,2014,5(12):1210-1218.
[5]韩永萍,林强,李亚秋.纳滤膜传质过程的研究[J].化学世界,2011,52(30):760-764.
[6]尚洪涛.纳滤过程原理综述[J].科技信息,2013,20(1):67-70.
[7]Agboola O,Maree J,Kolesnikov A,et al.Theoretical performance of nanofiltration membranes for wastewater treatment[J].Environmental Chemistry Letters,2015,13(1):37-47.
[8]王晓琳,涂丛慧,方彦彦,等.纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J].膜科学与技术,2011,31(8):127-134.
[9]Rahimpour A.Preparation and modification of nano-porous polyimide(PI)membranes by UV photo-grafting process:Ultrafiltration and nanofiltration performance[J].Korean Journal of Chemical Engineering,2011,28(1):261-266.
[10]Mohammad A W,Teow Y H,Ang W L,et al.Nanofiltration membranes review:Recent advances and future prospects[J].Desalination,2015,3(56):226-254.
[11]Ladewig B,Al-Shaeli M N Z.Introduction to Membrane Bioreactors[M]//Fundamentals of Membrane Bioreactors.Singapore:Springer,2017,12(1):1-12.
[12]郑甜甜,黄丹,班允赫,等.膜法生产饮用水过程中纳滤膜生物污染的研究[J].水处理技术,2013,39(10):50-52.
[13]陶润先,陈立,朱开东,等.生物活性炭作为纳滤预处理工艺的试验研究[C]//中国土木工程学会水工业分会全国给水深度处理研究会.上海:2010年年会,2010.
[14]杨忠盛,芦敏,袁东星,等.活性炭结合超滤及纳滤工艺深度处理饮用水的中试研究[J].给水排水,2011,37(5):29-34.
[15]何忠,王志良,杨绍贵,等.纳滤、反渗透工艺深度处理饮用水研究[J].长江科学院院报,2016,33(4):11-15.
[16]徐兵,杨程.纳滤膜处理微污染原水的中试研究[J].给水排水,2016,42(11):11-15.
[17]陈欢林,吴礼光,陈小洁,等.钱塘江潮汐水源的饮用水膜法集成系统示范运行经验[C]//2013给水深度处理及饮用水安全保障技术交流会.武汉:中国膜法协会,2013.
[18]王磊,李靖平,张岩,等.臭氧-生物活性炭-纳滤膜深度处理饮用水试验研究[J].给水排水,2009,35(8):17-20.
[19]侯立安,左莉.纳滤去除饮用水中有机物及类炭疽杆菌的研究[J].中国给水排水,2006,22(7):62-64.
[20]孔繁鑫,王小,杨宏伟,等.纳滤控制饮用水中消毒副产物的研究进展[J].中国给水排水,2013,29(18):28-32.
[21]吴礼光,项雯.纳滤膜去除饮用水中微量三唑磷的研究[J].环境科学与技术,2011,34(6):53-58.
[22]李清雪,肖伟,吴伟,等.纳滤组合工艺深度处理微量污染物[J].膜科学与技术,2010,30(5):103-106.
[23]Lu X U,Jiang W,Wang J,et al.Basic studies on the performance of domestic nanofiltration membranes for desalting brackish water with high fluoride[J].Membrane Science&Technology,2015,12(3):50-58.
[24]吕建国,王文正.纳滤淡化高氟苦咸水示范工程[J].给水排水,2009,35(7):25-27.
[25]马伟芳,刘文君.共存氯离子对饮用水纳滤除氟的影响研究[J].环境科学,2009,30(3):787-791.
[26]张阳,潘晶,孔健健,等.纳滤去除地表水中微污染物生产饮用水[J].辽宁工程技术大学学报,2009,28(3):482-484.
[27]杨庆娟,魏宏斌,王志海,等.纳滤膜去除饮用水中无机离子的中试研究[J].中国给水排水,2009,25(5):52-55.
[28]Zhao C,Wang T,Zhang J,et al.Arsenic removal from drinking water by self-made PMIA nanofiltration membrane[J].Advances in Chemical Engineering&Science,2012,37(2):20-71.
[29]Li X,Cai T,Chen C,et al.Negatively charged hyperbranched polyglycerol grafted membranes for osmotic power generation from municipal wastewater[J].Water Research,2016,89(12):50-58.
[30]陈丽珠,盛德洋,申露威,等.纳滤膜去除饮用水中多种重金属的研究[J].给水排水,2016,42(11):103-159.
[31]T U M,I MM,A I M,et al.Nanofiltration membrane process for the removal of arsenic from drinking water[J].Chemical Engineering&Technology,2007,30(9):1248-1254.
[32]Yaser A Z,Hilal N.Treatment of dye solution via low pressure nanofiltration system[M]//Membrane Technology for Water and Wastewater Treatment,Energy and Environment,2016,13(3):37-61.
[33]朱娜姗,陈诗弢,王莹,等.农村饮用水膜法处理应用工程[J].水处理技术,2009,35(3):110-112.
[34]Park M,Anumol T,Simon J,et al.Pre-ozonation for high recovery of nanofiltration(NF)membrane system:Membrane fouling reduction and trace organic compound attenuation[J].Journal of Membrane Science,2017,523(1):255-263.
[35]黄裕,张晗,董秉直.纳滤膜去除卡马西平的影响因素研究[C]//中国土木工程学会水工业分会全国给水深度处理研究会.上海:2010年年会,2010.
[36]吴芳,封莉,张立秋.纳滤去除水中中性药物的预测模型[J].膜科学与技术,2016,36(4):97-102.
[37]葛四杰,吴芳,张立秋,等.纳滤膜去除水中微量药物萘普生效能的影响因素研究[J].膜科学与技术,2013,33(6):92-96.
[38]丰桂珍,董秉直.藻类对纳滤膜去除萘普生的影响[J].环境科学与技术,2013,11(8):97-102.
[39]金叶,章宏梓,吴礼光,等.纳滤膜对邻苯二甲酸酯的动态吸附行为及截留特性[J].水处理技术,2011,37(12):59-63.
[40]Bots J,De B L,Snijkers T,et al.Exposure to perfluorooctane sulfonic acid(PFOS)adversely affects the lifecycle of the damselfly Enallagma cyathigerum[J].Environmental Pollution,2010,158(3):901-995.
[41]Dauwe T,Van d V K,De C W,et al.PFOS levels in the blood and liver of a small insectivorous songbird near a fluorochemical plant[J].Environment International,2007,33(3):357-361.
[42]Van G H,Bots J,Snijkers T,et al.Behaviour of damselfly larvae(Enallagma cyathigerum)(Insecta,Odonata)after long-term exposure to PFOS[J].Environmental Pollution,2009,157(4):1332-1336.
[43]张健,赵长伟,宋娜,等.纳滤去除饮用水中的PFOS[J].环境工程学报,2013,11(11):4236-4240.