用户名: 密码: 验证码:
马来酸酐化液体聚丁二烯对天然橡胶/芳纶短纤维复合材料性能的影响
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Influence of Maleic Anhydride Modified Liquid Polybutadiene on Properties of Natural Rubber/Short Aramid Fiber Composite
  • 作者:周宗淘 ; 罗筑 ; 洪波 ; 陈维龙 ; 刘春利
  • 英文作者:ZHOU Zongtao;LUO Zhu;HONG Bo;CHEN Weilong;LIU Chunli;Guizhou University;
  • 关键词:芳纶短纤维 ; 天然橡胶 ; 马来酸酐化液体聚丁二烯 ; 复合材料 ; 相容剂 ; 力学性能
  • 英文关键词:short aramid fiber;;natural rubber;;maleic anhydride modified liquid polybutadiene;;composite;;compatibilizer;;mechanical property
  • 中文刊名:XJGY
  • 英文刊名:China Rubber Industry
  • 机构:贵州大学材料与冶金学院;
  • 出版日期:2018-03-25
  • 出版单位:橡胶工业
  • 年:2018
  • 期:v.65
  • 基金:贵州省橡胶科技重大专项[黔科合重大专项字(2013—2016)]
  • 语种:中文;
  • 页:XJGY201803030
  • 页数:5
  • CN:03
  • ISSN:11-1812/TQ
  • 分类号:66-70
摘要
研究马来酸酐化液体聚丁二烯(MLPB)对芳纶短纤维(SAF)补强天然橡胶(NR)复合材料性能的影响。结果表明:SAF和炭黑对NR的补强有协同作用,加入相容剂MLPB提高了橡胶基体与纤维的界面粘合性能,复合材料静态和动态力学性能明显提高;随着MLPB用量的增大,复合材料100%定伸应力增大,拉伸强度、拉断伸长率和撕裂强度在MLPB用量为4.5份时达到最大值。
        The influence of maleic anhydride modified liquid polybutadiene(MLPB)on the properties of short aramid fiber(SAF)reinforced natural rubber(NR)composite was investigated. The results showed that SAF and carbon black had a synergistic effect in the reinforcement of NR compound,and with MLPB the interface bonding between rubber matrix and fiber was improved and the static and dynamic mechanical properties of the vulcanized NR compound were significantly improved. When the addition level of MLPB increased,the modulus at 100% elongation of the vulcanized rubber increased,and the tensile strength,elongation at break and tear strength reached their respective best values when the addition level of MLPB was 4. 5 phr.
引文
[1]厉世能,顾嫒娟,梁国正.芳纶纤维表面改性的研究进展[J].化工新型材料,2012,40(4):1-3.
    [2]李源,萨日娜,严岩,等.对位芳纶纤维的多巴胺仿生修饰及硅烷偶联剂二次功能化[J].橡胶工业,2016,63(1):5-12.
    [3]周雪松,王习文,胡健,等.芳纶纤维分散性能的研究[J].造纸科学与技术,2004,23(6):46-49.
    [4]Lin T K,Wu S J,Lai J G,et al.The Effect of Chemical Treatment on Reinforcement/Matrix Interaction in Kevlar-Fiber/Bismaleimide Composites[J].Composites Science&Technology,2000,60(9):1873-1878.
    [5]严志云,刘安华,贾德民.芳纶纤维的表面处理及其在橡胶工业中的应用[J].橡胶工业,2004,51(1):56-60.
    [6]Lee-Sullivan P,Chian K S,Yue C Y,et al.Effects of Bromination and Hydrolysis Treatments on the Morphology and Tensile Properties of Kevlar-29 Fibres[J].Journal of Materials Science Letters,1993,13(5):305-309.
    [7]Downing J W,Newell J A.Characterization of Structural Changes in Thermally Enhanced Kevlar-29 Fiber[J].Journal of Applied Polymer Science,2004,91(1):417–424.
    [8]Jiang T,Rigney J,Jones M C G,et al.Processing and Characterization of Thermally Cross-Linkable Poly[p-phenyleneterephthalamide-co-p-1,2-dihydrocyclobutaphenyleneterephthalamide(PPTA-co-XTA)]Copolymer Fibers[J].Macromolecules,1995,28(9):3301-3312.
    [9]朱闰平,李燕敏,杨军.马来酸酐化聚丁二烯对NR硫化胶抗撕裂性能的影响[J].特种橡胶制品,2008,29(4):22-23.
    [10]Payne A R.The Dynamic Properties of Carbon Black-loaded Natural Rubber Vulcanizates.Part I[J].Journal of Applied Polymer Science,1962,6(19):57-63.
    [11]龙军,张志谦,魏月贞,等.接枝偶联剂对F-12纤维/环氧复合材料界面改性的研究[J].复合材料学报,2000,17(3):15-19.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700