用户名: 密码: 验证码:
微细粒钛铁矿选矿技术研究进展
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Research on Mineral Processing Status of Fine Ilmenite
  • 作者:张松 ; 文书明 ; 刘建 ; 先永骏 ; 韩广 ; 王瑜
  • 英文作者:ZHANG Song;WEN Shuming;LIU Jian;XIAN Yongjun;HAN Guang;WANG Yu;Faculty of Land & Resources Engineering, Kunming University of Science and Technology;State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization;
  • 关键词:微细粒 ; 钛铁矿 ; 浮选药剂 ; 设备 ; 选别工艺 ; 作用机理
  • 英文关键词:fine;;ilmenite;;flotation reagent;;separation equipment;;separation process;;interaction mechanism
  • 中文刊名:KCBH
  • 英文刊名:Conservation and Utilization of Mineral Resources
  • 机构:昆明理工大学国土资源工程学院;复杂有色金属资源清洁利用国家重点实验室;
  • 出版日期:2019-03-12 16:03
  • 出版单位:矿产保护与利用
  • 年:2019
  • 期:v.39;No.219
  • 基金:国家自然科学基金项目(51764037、51704135、51464029)
  • 语种:中文;
  • 页:KCBH201901025
  • 页数:7
  • CN:01
  • ISSN:41-1122/TD
  • 分类号:137-143
摘要
综述了微细粒钛铁矿浮选药剂的种类和机理、选别设备的特点以及微细粒级钛铁矿的选别工艺。结合实际案例,分析了调整剂和捕收剂的作用机理、介绍了新设备的研制和工艺流程的创新与运用。微细粒钛铁矿选矿技术研究的现状是研制具有协同效应的组合药剂以及应用复合力场的新型设备。多数选钛厂采用磁选与浮选联合工艺选别微细粒钛铁矿。实际生产中微细粒钛铁矿的回收率低,-0.019 mm粒级钛铁矿缺乏有效的选别方法是研究过程中面临的难点。
        The varieties and mechanisms of ilmenite flotation agents, the characteristics of the separation equipment and the technological process of fine ilmenite recovery of fine ilmenite were reviewed. Based on practical cases of production, the mechanisms of the regulators and collectors, ideas and innovation of new equipment developments, as well as application of process flow were fully analyzed. In recent years, the use of the flotation regent synergies to develop combination reagents and the development of new separation equipment with compound force field have been a research hot point in recovery of fine ilmenite resources. Moreover, the magnetic separation and flotation combined technological process is the widely used method for such fine ilmenite resources in most concentration plants. In industry, there is still no effective processing method for the recovery of -0.019 mm fine ilmenite, which has been become a challenge needed to overcome.
引文
[1] 莫畏,邓雹珠,罗方承.铁冶金[M].北京:冶金工业出版社,1998:133.
    [2] United States Geological Survey. Mineral commodity summaries 2017[J]. USGS, 2017:178-179.
    [3] 国家统计局.中国统计年鉴—2017[M].北京:中国统计出版社,2017:228.
    [4] 杨晶.钛铁矿浮选捕收剂的研究及应用状况浅述[J].云南冶金,2010,39(1):26-29.
    [5] 范先锋,罗森.钛铁矿活化浮选[J].国外金属矿选矿,1999(4):2-6.
    [6] Chen P, Zhai J H, Sun W, et, al. The activation mechanism of lead ions in the flotation of ilmenite using sodium oleate as a collector[J].Minerals engineering, 2017, 111:100-107.
    [7] Xu LH, Tian J, Wu HQ, et, al. Effect of Pb2+ ions on ilmenite flotation and adsorption of benzohydroxamic acid as a collector[J]. Applied surface science, 2017, 425:796-802.
    [8] Meng QY, Yuan ZT, Yu L, et, al. Study on the activation mechanism of lead ions in the flotation of ilmenite using benzyl hydroxamic acid as collector[J]. Journal of industrial & engineering chemistry, 2018, 62:209-216.
    [9] 高永明,王怀法.微细粒钛铁矿浮选行为研究[J].矿业工程,2012,10(4):31-33.
    [10] 马军二.钛铁矿与钛辉石浮选分离中无机抑制剂的作用机理研究[D].长沙:中南大学,2010:56.
    [11] 张国范,马军二,朱阳戈,等.含硅抑制剂对钛辉石的抑制作用[J].中国有色金属学报,2010,20(12):2419-2424.
    [12] 周军,钱鑫.混合药剂浮选原生钛铁矿的研究[J].有色金属(选矿部分),1996(6):29-32.
    [13] Yang YH, Xu LH, Tian J, et al. Selective flotation of ilmenite from olivine using the acidified water glass as depressant[J]. International journal of mineral processing, 2016, 157:73-79.
    [14] 徐翔,章晓林,许炳梁,等.钛铁矿浮选中的抑制剂研究[J].矿冶,2010,19(4):21-23.
    [15] 徐翔.用全浮选法从攀枝花钒钛磁铁矿中回收钛的工艺及理论研究[D].昆明:昆明理工大学,2011:101.
    [16] 魏志聪,徐翔,方建军,等.钛铁矿和钛辉石对羧甲基纤维素的吸附机理研究[J].矿冶,2011,20(1):8-10.
    [17] 范桂侠.钛铁矿絮团浮选的界面调控研究[D].徐州:中国矿业大学,2015:115.
    [18] 罗溪梅.云南玉溪钒钛磁铁矿的选矿试验研究[D].昆明:昆明理工大学,2010:1.
    [19] Meng QY, Yuan ZT, Yu L, et, al. Selective depression of titanaugite in the ilmenite flotation with carboxymethyl starch [J]. Applied surface science, 2018, 440:955-962.
    [20] Liu X, Huang GY, Li CX, et al. Depressive effect of oxalic acid on titanaugite during ilmenite flotation[J]. Minerals engineering, 2015, 79:62-67.
    [21] 阙煊兰.苯乙烯膦酸的合成及应用[J].有色金属(选矿部分),1980(4):17-21.
    [22] 崔林,郑瞳彬,钟康年.用苯乙烯膦酸浮选钛铁矿时活化作用的机理[J].金属矿山,1983(2):25,52-55.
    [23] Li FX, Zhong H, Zhao G, et al. Adsorption of α-hydroxyoctyl phosphonic acid to ilmenite/water interface and its application in flotation[J]. Colloids & surfaces a physicochemical & engineering aspects, 2016, 490:67-73.
    [24] 任志民.苯乙烯膦酸作捕收剂浮选细泥钛铁矿初步研究[J].稀有金属,1980(5):24-30.
    [25] 张国范,鄢代翠,朱阳戈,等.pH对油酸钠在钛铁矿与钛辉石表面吸附的影响[J].中南大学学报(自然科学版),2011,42(10):2898-2904.
    [26] 张国范,朱阳戈,冯其明,等.油酸钠对微细粒钛铁矿的捕收机理[J].中国有色金属学报,2009,19(2):372-377.
    [27] Liu W, Zhang J, Wang W, et al. Flotation behaviors of ilmenite, titanaugite, and forsterite using sodium oleate as the collector[J]. Minerals engineering, 2015, 72:1-9.
    [28] 朱阳戈.微细粒钛铁矿浮选理论与技术研究[D].长沙:中南大学,2012:126.
    [29] 朱阳戈,张国范,冯其明,等.微细粒钛铁矿的自载体浮选[J].中国有色金属学报,2009,19(3):554-560.
    [30] 朱建光,朱玉霜,王升鹤,等.利用协同效应最佳点配制钛铁矿捕收剂[J].有色金属(选矿部分),2002(4):39-41.
    [31] 谢泽君.MOS捕收剂浮选微细粒级钛铁矿的研究[J].矿冶工程,1998,18:78-81.
    [32] 陈朝春.攀钢选钛厂工艺现状分析及对策[J].金属矿山,1998(10):24-28.
    [33] 朱建光,陈树民,姚晓海,等.用新型捕收剂MOH浮选微细粒钛铁矿[J].有色金属(选矿部分),2007(6):42-45.
    [34] 陈让怀,谢建国,张泾生.新型高效钛铁矿捕收剂ROB的制备及选矿效果研究[C]//全国选矿专业学术年会.成都:矿冶工程,2002:131-133.
    [35] 许向阳,张泾生,王安五,等.微细粒级钛铁矿浮选捕收剂ROB的作用机理[J].矿冶工程,2003,23(6):23-26.
    [36] 谢建国,张泾生,陈让怀,等.新型捕收剂ROB浮选微细粒级钛铁矿的试验研究[J].矿冶工程,2002,22(2):47-50.
    [37] 王洪彬,张红先.MOH捕收剂浮选攀枝花微细粒级钛铁矿试验研究[J].矿冶工程,2007,27(5):27-30.
    [38] 蒋昊,朱树生,孙忠诚,等.云南某低品位钛铁矿选矿试验研究[J].矿冶工程,2015,35(4):40-43.
    [39] 邓陈雄,姚金,印万忠,等.钛铁矿海滨砂矿尾矿的浮选试验研究[J].东北大学学报(自然科学版),2016,37(3):416-420.
    [40] 周军,钱鑫.攀枝花细粒钛铁矿混合药剂浮选研究[J].矿冶工程,1996,16(3):35-38.
    [41] 董宏军,陈正学.水杨羟肟酸浮选细粒钛铁矿的研究[J].矿冶工程,1991,11(1):19-22.
    [42] 傅文章,张渊,洪秉信,等.浮选攀枝花选铁尾矿中钛铁矿的试验研究[J].金属矿山,1999(6):29-32.
    [43] 袁国红,余德文.R-2捕收剂选别攀枝花微细粒级钛铁矿试验研究[J].金属矿山,2001(9):37-39.
    [44] 舒超,罗惠华,王昌良,等.新型捕收剂ZF-02高效环保浮选微细粒级钛铁矿[J].中国矿业,2017,26(10):131-135.
    [45] 孙欢,杨波,肖日鹏,等.悬振锥面选矿机的结构和分选机理[J].矿山机械,2017(6):51-54.
    [46] 高建安,张雨田,纪翠翠.攀钢选钛厂微细粒级钛铁矿回收新工艺研究[J].矿山机械,2016(11):58-62.
    [47] 姚栋,杨波,肖日鹏,等.悬振锥面选矿机在微细粒矿物分选中的应用[J].矿山机械,2017(3):51-55.
    [48] 赵明,王丰雨.SSS-I新型高梯度磁选机选别微细粒级钛铁矿的应用[C]//金属矿产资源高效选冶加工利用和节能减排技术及设备学术研讨会.桂林:《金属矿山》编辑部,2009:397-381,397.
    [49] 张军.SSS-II高梯度磁选机回收微细粒钛铁矿的研究[J].材料研究与应用,2012,6(3):195-197.
    [50] Chen LZ, Zeng JW, Guan C P, et al. High gradient magnetic separation in centrifugal field[J]. Minerals engineering, 2015, 78:122-127.
    [51] 陈禄政,徐国栋,黄健雄.周期式离心高梯度磁选的原理及分选细粒钛铁矿的试验[J].昆明理工大学学报(自然科学版),2013,33(1):28-31.
    [52] Chen LZ, Xu GD, Huang JX, et al. Centrifugal high gradient magnetic separation of fine ilmenite[J]. Advanced materials research, 2013, 634-638(1):3304-3307.
    [53] 郑永明,陈禄政,官长平,等.离心高梯度磁选钛铁矿的试验研究[J].昆明理工大学学报(自然科学版),2017(4):32-37.
    [54] Fan G, Liu J, Cao Y, et al. Optimization of fine ilmenite flotation performed in a cyclonic-static micro-bubble flotation column[J]. Physicochemical problems of mineral processing, 2014, 50(2):823-834.
    [55] 伍喜庆,黄志华.磁力螺旋溜槽及其对细粒磁性物料的回收[J].中南大学学报(自然科学版),2007,38(6):1083-1087.
    [56] 陈力行,张昱.磁性矿物溜槽分选机:CN203663985U[P].2014-1-5.
    [57] 陈晓鸣,严鹏,陈力行.磁性螺旋溜槽回收细粒钛铁矿试验[J].金属矿山,2014,43(3):132-135.
    [58] 陈晓鸣,严鹏,陈力行.磁性摇床在回收细粒钛铁矿中的应用[J].矿冶,2015,24(1):71-73.
    [59] Gerardo, Alvarez.维修在设备全寿命周期中的作用(一)[J].中国设备工程,2006(1):60-62.
    [60] Zhai J, Chen P, Wang H, et al. Flotability improvement of ilmenite using attrition-scrubbing as a pretreatment method[J]. Minerals, 2017, 7(1):13.
    [61] Fan X, Kelly R M, Rowson N A. Effect of microwave radiation on ilmenite flotation[J]. Canadian metallurgical quarterly, 2013, 39(3):247-254.
    [62]范先锋,N.A.罗森.微波能在钛铁矿选矿中的应用[J].国外金属矿选矿,1999(2):2-7.
    [63] Nuri O S, Mehdilo A, Irannajad M. Influence of microwave irradiation on ilmenite surface properties[J]. Applied surface science, 2014, 311(9):27-32.
    [64] Nuri O S, Irannajad M, Mehdilo A. Microwave irradiation consequences on chemical reagent consumption in ilmenite flotation[J]. Journal of microwave power & electromagnetic energy a publication of the international microwave power institute, 2017, 51(2):93-105.
    [65] Irannajad M, Mehdilo A, Nuri O S. Influence of microwave irradiation on ilmenite flotation behavior in the presence of different gangue minerals[J]. Separation & purification technology, 2014, 132(6):401-412.
    [66] Fan G, Cao Y. The shear flocculation flotation behaviors of micro fine ilmenite and titanaugite[J]. Journal of China university of mining & technology, 2015, 44(3):532-539,572.
    [67] 董宏军,陈正学.微细粒钛铁矿载体浮选的研究[J].矿冶工程,1992,12(2):35-37.
    [68] 许新邦.磁-浮选流程回收攀钢微细粒钛铁矿的试验研究[J].矿冶工程,2001,21(2):37-40.
    [69] 王洪彬.攀西细粒级钛铁矿高效回收工艺研究[J].钢铁钒钛,2017,38(1):27-30.
    [70] 孟聪,李丽匣,申帅平,等.某钛铁矿分级磁选分级浮选试验研究[J].矿产保护与利用,2017(1):59-63.
    [71] 曹玉川,黄光耀,刘星.-38 μm粒级钛铁矿高效回收试验研究[J].矿冶工程,2012,32(4):48-50.
    [72] 陈树民.攀枝花微细粒级(-19 μm)钛铁矿回收探索试验[J].矿产综合利用,2004(5):7-11.
    [73] 王洪彬,李丽匣,申帅平,等.微细粒级钛铁矿预富集工艺研究[J].矿冶工程,2016,36(5):37-40.
    [74] 王建平.攀枝花某选铁尾矿窄粒级选钛试验[J].现代矿业,2017,33(10):92-98.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700